Modeling of Phase Transformation in Induction Hardening
Modeling of Phase Transformation in Induction Hardening
Open Access
Modeling of Phase Transformation in Induction Hardening
K. Palaniradja*, N. Alagumurthi and V. Soundararajan
Department of Mechanical Engineering, Pondicherry Engineering College, Pondicherry – 605 014, India
Abstract: Mechanical properties of machined components are controlled by inducing phase transformations in the outer layer
of the materials. Induction hardening is one such manufacturing process where the surface hardness is enhanced while the
core is retained with the original structure and characteristics. In this study, a mathematical model had been developed to
predict the hardness and the volume fraction of martensite present in the hardened surface. Experiments applying induction
hardening were conducted on the following specimen materials AISI 1040, AISI 4140, AISI 4340, AISI 1055, AISI 6150 and
AISI 9255. The microstructures obtained from the experiment showed a moderate phase transformation of austenite to
martensite. The hardness and the volume fraction of martensite estimated from the experiments were found to match the
results of mathematical modeling as well as the theoretical model using regression analysis.
Keywords: Modeling, phase transformation, induction hardening, volume fraction, validation
continuous cooling curve with Temperature –Time – 3.1. Model Regression Analysis
Transformation diagram. It must be remembered that cooling
AISI 1040
curves are difficult to obtain in Induction hardening
applications. This is because the exact conditions are Coeff =
difficult to duplicate in the laboratory (Scott Mackenzie.,
2002). 1.0000 5.5000 1.3400 15.0000 80
This paper deals with the model, which may be 1.0000 5.5000 1.3400 17.5000 78
considered as an extension of Yuan model, developed to 1.0000 5.5000 1.3400 20.0000 79
predict the volume fraction of martensite theoretically. A
1.0000 5.5000 1.7200 15.0000 80
Regression model has also been developed to estimate the
Hardness in HRA for steel materials, AISI 1040, AISI 4140, 1.0000 5.5000 1.7200 17.5000 78
AISI 4340, AISI 1055, AISI 6150 and AISI 9255. These
1.0000 5.5000 1.7200 20.0000 82
models overcome the drawbacks in the modeling system
explained above. Experimental validation of the developed 1.0000 5.5000 2.1400 15.0000 83
model has also been presented here. 1.0000 5.5000 2.1400 17.5000 74
3. MATHEMATICAL MODEL TO PREDICT THE 1.0000 5.5000 2.1400 20.0000 81
HARDNESS
1.0000 7.0500 1.3400 15.0000 74
In order to develop the mathematical model to predict the
hardness and volume fraction of martensite for Induction 1.0000 7.0500 1.3400 17.5000 78
hardening of steel materials (G1 – Material and G2 – 1.0000 7.0500 1.3400 20.0000 77
Material), Induction hardening experiments have been
1.0000 7.0500 1.7200 15.0000 78
conducted.
1.0000 7.0500 1.7200 17.5000 74
Table 1 shows the details about the operating conditions
and the materials. 1.0000 7.0500 1.7200 20.0000 76
3
Table 2 shows the experimental results in the 3 Design 1.0000 7.0500 2.1400 15.0000 78
Matrix for the G1 and G2 Induction hardening rack materials 1.0000 7.0500 2.1400 17.5000 74
respectively.
1.0000 7.0500 2.1400 20.0000 78
Regression analysis has been carried out using MATLAB
and the Regression equations (Equation to predict the 1.0000 8.5000 1.3400 15.0000 69
hardness of the materials) have been found and the same are 1.0000 8.5000 1.3400 17.5000 65
given below:
Group 2 AISI 1055 C-0.45%, Si-0.10%, Mn-0.50%, S&P each 0.06% (max)
AISI 6150 C-0.50%, Si–0.50%, Mn-0.50%, Cr-0.80%, V-0.15% S&P each -0.05 (each)
AISI 9255 C-0.55%, Si–1.50%, Mn-0.70%, S&P each -0.05 (max)
66 The Open Materials Science Journal, 2010, Volume 4 Palaniradja et al.
1 5.5 1.34 15 80 83 82 84 83 84
2 5.5 1.34 17.5 78 81 83 83 82 80
3 5.5 1.34 20 79 80 78 84 80 84
4 5.5 1.72 15 80 78 80 80 80 83
5 5.5 1.72 17.5 78 76 78 80 84 82
6 5.5 1.72 20 82 78 79 84 79 81
7 5.5 2.14 15 83 82 80 81 80 83
8 5.5 2.14 17.5 74 80 77 83 84 82
9 5.5 2.14 20 81 82 80 82 84 84
10 7.05 1.34 15 74 74 74 78 78 78
11 7.05 1.34 17.5 78 72 72 80 70 75
12 7.05 1.34 20 77 76 73 78 73 71
13 7.05 1.72 15 78 78 70 70 70 70
14 7.05 1.72 17.5 74 75 75 77 76 77
15 7.05 1.72 20 76 78 75 80 77 80
16 7.05 2.14 15 78 75 74 75 73 80
17 7.05 2.14 17.5 74 75 72 73 75 78
18 7.05 2.14 20 78 74 75 73 74 75
19 8.5 1.34 15 69 69 75 78 78 73
20 8.5 1.34 17.5 65 67 69 70 70 73
21 8.5 1.34 20 67 65 67 68 67 70
22 8.5 1.72 15 64 68 68 70 68 68
23 8.5 1.72 17.5 62 68 63 74 64 69
24 8.5 1.72 20 63 70 65 70 67 70
25 8.5 2.14 15 68 66 68 67 70 67
26 8.5 2.14 17.5 67 68 66 69 69 69
27 8.5 2.14 20 65 68 64 72 70 74
The coefficients for the formation of hardness equation For AISI 6150,
are, YH = 108.2939-4.1947P-0.2082S-0.2000Q (5)
4. MATHEMATICAL MODEL TO PREDICT THE variables P, Q and S (P = 5.5 kW/inch2, S = 1.72 m/minutes
VOLUME FRACTION OF MARTENSITE and Q = 15 litres/minutes) obtained in the optimization study
and it is found that,
To predict the volume fraction of marteniste for
Induction hardening of materials (G1 and G2 materials) Constant c = 75.28 = 13.68P
mathematical model has been developed as a part of the b = 90.85 = 6.05Q
current research work. For this modeling work, a computer
model given by Yuan et al., (2003), has been taken into a = 77.85 = 45.26S
account and extended to make it suitable for the present Therefore, the mathematical model to find the volume
research work. Yuan et al., (2003), developed the following fraction of martensite with the process variables P, Q and S
mathematical model (equation 7) to predict HRC and is derived as,
Volume fraction of martensite using FEM for the Induction
hardened components. fm = [(HRC) max – 13.68P +6.05Q] / 45.26S (14)
2
HRC = afm + bfm +c (7) (or)
where a, b and c are constants and dependent only on carbon fm = {[(HRC) max – 13.68P + 6.05Q] 0.02206S-1} (15)
content in the materials. Further, it is given that for the For the Group 1 materials (carbon content 0.35 – 0.45%)
materials, the hardness lies in the range 56 – 60 HRC (Thelning, K.E.,
AISI 1070 (0.65% Carbon) a = 80.91 b = -97 c = 81.61 1984) [7]. By extrapolation and interpolation it is found that
the constants a, b and c for the Group 1 materials as a =
AISI 1053 (0.55% Carbon) a =77.84 b = -90.85 c = 75.28 74.77, b = -83 and c = 68.95.
Equation 7 can be rewritten in the form of In order to verify the obtained constants the following
afm2 + bfm = HRC – c (8) calculation is carried out using the equation 11, by assuming
HRC as 60 when fm = 1.
fm (afm + b) = HRC – c (9)
fm = (HRC – c – b) / a
In general for the Induction hardened medium carbon
alloy steels the hardness value lies in the range 56 – 65 HRC fm = (60 – 68.95 +83) / 74.77
and volume fraction of martensite between 0.9 and 1.0 fm = 0.9903
(Thelning, K.E., 1984). Hence it is assumed that fm = 1,
therefore from the equation 9, it is obtained that, It shows that the obtained values of a, b and c are
absolutely correct. By following the same procedure as that
afm +b = HRC- c (10) adopted in the development of volume fraction of martensite
The equation 10 is used in the model development. of Group 2 materials, the mathematical model to predict the
Equation 10 becomes, ‘fm’ for the Group 1 materials has been obtained and
presented below.
fm = (HRC – c – b) / a (11)
fm = {[(HRC) max – 11.96P+5.27Q] / 43.5S} (16)
On substituting a, b, and c values of 0.55% carbon steel
material (AISI 1053) in the equation 11, we get (or)
fm = [(HRC) - 75.28 + 90.25] / 77.85 (12) fm = {[(HRC) max – 11.96P + 5.27Q] 0.0230S-1} (17)
For a maximum hardness of 65 HRC the volume fraction Thus the mathematical models( equations 1,2,3,4,5, and
of martensite should be equal to one. The following 6- pertaining to HRA; 14(or) 15 and 16 (or) 17 – pertaining
calculations will justify the above said statement. to fm) developed are used to predict the volume fraction of
martensite and hardness respectively without conducting the
fm = [65 – 75.28 + 90.25] / 77.85 = 1.027 (approximately = 1) trials on Induction hardening furnace [8,9].
Therefore, the equation 12 can be rewritten as
5. VALIDATION OF THE MODEL
fm = [(HRC) max - 75.28 + 90.25] / 77.85 (HRC) max = 65
In this study Induction hardening is carried out on AISI
(13)
1040, AISI 4140, AISI 4340, AISI 1050, AISI 6150 and
In the present analysis the process variables Power AISI 9255. These types of steel materials chosen for the
potential (P), Scan speed (S) and Quench flow rate (Q) of studies because such steels are typical candidate materials
Induction hardening process are taken for the study of phase for a variety of automobile components especially Rack that
transformation, model development, simulation and require local hardening [10]. The theoretical simulations
validation. Further, it is construed that there is a definite (results obtained from the model developed) are compared
relation between the above said process variables with the with results produced experimentally. Koistinen equation 18
hardness and volume fraction of martensite of the Induction is used to find the volume fraction of marteniste
hardened materials. theoretically,
In order to develop a mathematical model to predict the fm = 1- exp {-0.011 [Ms – Tq]} (18)
volume fraction of marteniste for the materials (Group 2 –
where, Ms – starting temperature of marteniste formation
carbon content 0.5 – 0.6%) using the above mentioned
(Rajan, T.V., et al., 1998) [11]
process variables an analysis has been carried out by
replacing the constants a, b and c with the optimal process
68 The Open Materials Science Journal, 2010, Volume 4 Palaniradja et al.
Ms (°C) = 561 -474(%C) – 33(%Mn) -17(%Ni) -17(%Cr)-21 The volume fraction of martensite (theoretical) is found
(%Mo) (19) as per the details given below using the model developed for
AISI 1040 steel material with the values of process variables
Tq – Quenchant temperature at which fraction of martensite
used in the trials.
is formed
fm = {[(HRC) max – 11.96P+5.27Q] / 42.2S}
For the material AISI 1040, the Ms temperature is found
as per the following procedure fm={[60-12*5.5+5.3*15]/42.2*1.72}
AISI 1040 - Carbon = 0.35%, Si = 0.1% and Mn = 0.6%, fm={[60-66+79.05]/72.6}
Ms (°C) = 561 -474(%C) – 33(%Mn) -17(%Ni) -17(%Cr)- fm=1.006
21(%Mo)
The hardness value (theoretical) is found by using the
= 561 – 474 (0.35) – 33 (0.6) Regression model equation.
= 375.3°C Regression equation for the AISI 1040
Similarly, for the other materials also the Ms YH = 107.2820-4.5995P+0.1873S-0.0889Q
Temperature is calculated and given in Table 3.
where, P=5.5, S=1.72 and Q=15
Table 3. Ms Temperature for G1 and G2 Materials
On substitution theoretical, YH =107.2820 -
4.5995*5.5+0.1873*1.72-0.0889*15
AISI Grade Ms (°C)
= 107.2820-25.3+0.322-1.3
1040 375.3 = 81 HRA
4140 359.1 For different conditions, theoretical “HRA” and “fm”
4340 338.65 values are predicted using the mathematical models and
results are compared with the experimental values in the
1055 331.2
following Tables 4-9 for the G1 and G2 materials.
6150 293.9
6. RESULTS AND DISCUSSION
9255 277.2
Micro structural analysis [12] of Induction hardened
Rack components can provide important information
Random trials are carried out by varying the process regarding material properties, reliability and intensity of
variables P, Q and S by subjecting the G1 and G2 materials surface hardening process. The photo micrographs [13] of
in the Induction hardening furnace and the temperature Tq the Induction hardened specimens are studied. The surface
(Quenchant temperature at which fraction of martensite is hardness for the different heat treatment conditions for the
formed) is measured using thermocouple. Hardness of the materials AISI 1040 AISI 4140, AISI 4340, AISI 1055, AISI
each specimen is measured using Rockwell hardness tester in 6150 and AISI 9255 are measured and reported in the Table
HRA. 2.
The volume fraction of marteniste (experimental) is From the microstructures of medium carbon steels (Figs.
found as per the calculation given below for the material 1-6) it is evident that there is a considerable conversion of
AISI 1040, (Ms = 375.3 from Table 3 and Tq = 65°C austenite to martensite at the outer surface which improves
through measurement when P = 5.5kW/inch2,, Q = 15 litres the hardness in Induction hardened components. It is seen
/min and S = 1.72 m /minutes) from the Tables 4-9 under optimal conditions that the
volume fraction of martensite is almost 95% for both the G1
fm = 1- exp {-0.011 [Ms – Tq] and G2 materials and also the required hardness (79 – 82
fm = 1 – exp {-0.011 [375.3 – 65]} HRA) is obtained.
fm = 0.9670 Because of the temperature dependent non-linear
properties in Induction hardening process, analytical solution
Table 4. Validation of Simulated Results for the AISI 1040 Steel Material
Table 5. Validation of Simulated Results for the AISI 4140 Steel Material
Table 6. Validation of Simulated Results for the AISI 4340 Steel Material
Table 7. Validation of Simulated Results for the AISI 1055 Steel Material
Table 8. Validation of Simulated Results for the AISI 6150 Steel Material
Table 9. Validation of Simulated Results for the AISI 9255 Steel Material
100X
100X
100X
Fig. (3). Microstructure of Induction hardened AISI 4340.
Modeling of Phase Transformation in Induction Hardening The Open Materials Science Journal, 2010, Volume 4 71
100X
Case to Core
Transition zone
100X
Case to Core
Transition zone
100X
Hardness Equations
S. No. Materials Volume Fraction of Martensite (fm)
(Hardness in HRA)
S. No. Materials Hardness Equations (Hardness in HRA) Volume Fraction of Martensite (fm)
is very difficult to obtain [14]. When surfaces with complex 7. CONCLUDING REMARKS
geometric shape are heat treated the problems become more
cumbersome. It must also be remembered that cooling • Microstructural analysis indicates that there is a
curves are difficult to obtain in Induction hardening moderate conversion of austenite to martensite (Phase
applications [15]. Hence, mathematical models will allow Transformations) at the outer surface which improves
engineers/metallurgists to experiment with the critical the Hardness in Induction hardened components.
process variables such as Power potential, Scan speed • A Mathematical Model (details are given in the Table
Quench flow rate and Frequency before expensive 11) to predict volume fraction of martensite and
investment or unforeseen failures in mass produced items. hardness in the induction hardening process has been
A Mathematical Model (details are given in the Table 10) developed. It is shown that the numerical predictions
to predict volume fraction of martensite and hardness in the of the hardened layer are in good agreement with the
Induction hardening process has been developed for the experimental results.
Group 1 and Group 2 materials. ACKNOWLEDGEMENTS
Comparisons between the theoretically simulated and The authors are thankful to Rane (Madras) Pvt. Ltd.,
experimental results are shown in the Tables 4-9. It can be Thirubhuvanai, Pondicherry and IGCAR Kalpakkam for
observed that there is a good agreement between the two providing the experimental, testing and measurement
results. The difference between the results (error) may be facilities.
attributed to the lack of precision in measurement of Tq. It
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Received: October 6, 2009 Revised: October 8, 2009 Accepted: October 27, 2009