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Haloalkanes and Haloarenes Q 4

The document is a chemistry practice paper for Class XII focusing on haloalkanes and haloarenes. It includes multiple-choice questions covering various reactions, mechanisms, and properties related to these compounds. The questions test knowledge on topics such as hydrolysis, iodoform tests, and Grignard reagents.

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Sujata Chandra
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15 views3 pages

Haloalkanes and Haloarenes Q 4

The document is a chemistry practice paper for Class XII focusing on haloalkanes and haloarenes. It includes multiple-choice questions covering various reactions, mechanisms, and properties related to these compounds. The questions test knowledge on topics such as hydrolysis, iodoform tests, and Grignard reagents.

Uploaded by

Sujata Chandra
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CLASS : XIIth SUBJECT : CHEMISTRY

DATE : DPP NO. : 4

Topic :-HALOALKANES AND HALOARENES


1. t-butyl chloride preferably undergo hydrolysis by
a) SN1 mechanism
b) SN2 mechanism
c) Any of (a) and (b)
d)None of the above

2. Which statement is wrong about chloroform?


a) Chloroform is used as anaesthetic
b) Chloroform has distorted tetrahedral shape
c) Chloroform is used as a solvent
d)Chloroform has 𝑠𝑝2-hybridised carbon atom

3. When CCl4 is boiled with KOH, the product formed is:


a) Formic acid b) Methyl alcohol c) Formaldehyde d)Carbon dioxide

4. Which set of reagents will produce freon(CCl2F2) ?


SbCl5
a) C + F2 + Cl2 ⟶ b) CH3Cl + F2 ⟶ c) CCl4 +HF d)CCl4 + F2 ⟶

5. Which of the following will not give positive iodoform test?


a) CH3CH2CHOHCH3b) CH3CH2CH2COCH3c) CH3CH2COCH2CH3d) CH3COC6H5

6. Which of the following does not react with benzene in presence of anhydrous AlCl3?
a) C6H5Cl b) C6H5CH2Cl c) CH3Cl d)C6H5CH2CH2CH2Cl

7. Iodoform is obtained when ethanol is heatd with


a) KI and aq. KOH b) I2 and aq. KOH c) I2/aq. KI d)HI and HIO3

8. 𝑛-propyl bromide reacts with ethanolic KOH to form:


a) Propane b) Propene c) Propyne d)Propyl alcohol

9. Which of the following statements regarding the SN1 reaction shown by alkyl halide is not
correct?
a) The added nucleophile plays no kinetic role in SN1 reaction.
b) The SN1 reaction involves the inversion of configuration of the optically active substrate.
c) The SN1 reaction on the chiral starting material ends up with racemization of the product.

PRERNA EDUCATION https://prernaeducation.co.in 011-41659551 | 9312712114


d)The more stable the carbocation intermediate the faster the SN1 reaction.

10. Pick up the correct statement about alkyl halides:


a) They show H-bonding.
b) They are soluble in water.
c) They are soluble in organic solvents.
d)They do not contain any polar bond.

11. The product of reaction between alcoholic silver nitrite with ethyl bromide is
a) Ethene b) Ethane c) Ethyl nitrile d)Nitro ethane

12. 1-phenyl, 2-chloropropane on treating with alc. KOH gives mainly:


a) 1-phenylpropene
b) 2-phenylpropene
c) 1-phenylpropan-2-ol
d)1-phenylpropan-1-ol

13. In the reaction,


OCH3
NaNH2/
liq.ammonia A

Cl
The major product A is
OCH3
OCH3 OCH3 H3CO

NH2

Cl
a) H2N b) NH2 c) d)

14. (CH3)3CMgCl on reaction with D2O gives:


a) (CH3)3CD b) (CH3)3OD c) (CD3)3CD d) (CD3)3OD

15. Grignard reagent shows addition on:


C O C S
a) b) —C≡N c) d)All of these

16. When tetrahydrafuran is treated with excess HI, the product formed is
a) 1, 4-diiodobutane b) 1, 4-butanediol
c) 2-iodotetrahydrofuran d)4-iodo-1-butanol

17. Lodoform can be used in medicine as:


a) Anaesthetic b) Antiseptic c) Analgesic d)Antifebrin

PRERNA EDUCATION https://prernaeducation.co.in 011-41659551 | 9312712114


18. A mixture of two organic compounds was treated with sodium metal in ether solution.
Isobutane was obtained as a product. The two chlorine compounds are:
a) Methyl chloride and propyl chloride
b) Methyl chloride and ethyl chloride
c) Isopropyl chloride and methyl chloride
d)Isopropyl chloride and ethyl chloride

19. Wurtz’s reaction involves the reduction of alkyl halide with


a) Zn/HCl b) HI c) Zn/Cu couple d)Na in ether

20. In the following sequences of reactions;


KOH(alc.) HBr
CH3CH2CH2Br (𝐴)
KOH(𝑎𝑞.)
(𝐵) (𝐶) the end product (𝐶) is :
a) Propene
b) Propyne
c) Propan-l-ol
d)Propan-2-ol

PRERNA EDUCATION https://prernaeducation.co.in 011-41659551 | 9312712114

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