Sample Paper-2 QP Xi Se
Sample Paper-2 QP Xi Se
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4. When two or more atoms of different elements combine with each other in a fixed 1
ratio, the molecule of a ____ is obtained.
(a) Compound (b) Element
(c) Atom (d) Ion
5. Which of the following has the largest size 1
(a) N–3 (b) O–2 (c) K+1 (d) Ca+2
6. The correct order of electronegativity is 1
(a) Cl > F > O > Br (b) F > O > Cl > Br
(c) F > Cl > Br > O (d) O > F > Cl > Br
7. MX 6 is a molecule with octahedral geometry. How many X – M – X bonds are at 1
180°?
(a) four (b) two (c) three (d) six
8. Which one of the following thermodynamic quantities is not a state function? 1
(a) Gibbs free energy (b) Enthalpy
(c) Entropy (d) Work
9. Enthalpy of sublimation of a substance is equal to 1
(a) enthalpy of fusion + enthalpy of vapourisation
(b) enthalpy of fusion
(c) enthalpy of vapourisation
(d) twice the enthalpy of vapourisation
10 What is the oxidation state of Br in BrO3 – ? 1
(a) +1 (b) +3 (c) +4 (d) +5
11. An olefin on reductive ozonolysis gives only ethanal as the major product. Name 1
the olefin.
(a) But-1-ene (b) Propene (c) Ethene (d) But-2-ene
12 The position of double bond in alkenes can be located by: 1
(a) Hydrogenation of oil (b) Ozonolysis
(c) Photolysis (d) Hydration
The questions given below consist of assertion (A)and reason (R).Use the following
key to select thecorrect answer.
(a) Both A and R are true and R is the correct explanation of A
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
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(d) A is false but R is true.
13. Assertion(A) : The 19th electron in potassium atom enters 4s-orbital and not 3d 1
orbital’
Reason(R): The energies of the orbitals can be compared with the help of(n+l)
rules
14. Assertion (A): The lesser the lattice enthalpy more stable is the ionic compound. 1
Reason (R): The lattice enthalpy is greater, for ions of highest charge and smaller
radii.
15. Assertion(A): The decomposition of hydrogen peroxide to form water and oxygen 1
is an example of a disproportionation reactions.
Reason(R): The oxygen of peroxide is in -1 oxidation state and it converted to zero
oxidation state in O2 and -2 oxidation in water
16. Assertion (A): IUPAC name of compound CH3CH = CH – CHO is But–2– enal. 1
Reason(R): Multiple bond gets preference over Functional group in IUPAC name
of a compound.
SECTION B
This section contains 5 questions with internal choice in one question. The
following questions are very short answer type and carry 2 marks each.
17 Out of peroxide ion (O22-) and superoxide ion (O2- ) which has larger bond length 2
and why?
18. (a) Identify the state functions and path functions out of the following : 1+1
enthalpy, heat, temperature, work
(b) For the reaction, 2 Cl(g) → Cl2(g), what are the signs of ΔH and ΔS ?
19. Calculate the enthalpy change for the reaction: H2(g) + Br2(g) → 2 HBr(g). 2
Given the bond enthalpies H2, Br2 and HBr are 435 kJ mol–1, 192 kJ mol–1 and 368
kJ mol–1 respectively
20. Balance the equation 2
MnO4– + I-→ Mn2+ + I2 + H2O
by ion electron method in acidic medium.
21. (a) Draw the structure of the following compound 1+1 = 2
2-Chloro-2-methylbutan-1-ol
(b) Explain.Why (CH3)3 –C+ is more stable than CH3-CH2 +and CH3+ is the least
stable cation.
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OR
(a)Explain the reason for the fusion of an organic compound with metallic sodium
for testing nitrogen, sulphur and halogens.
(b) Under what condition can the process of steam distillation is used.
SECTION C
This section contains 7 questions with internal choice in one question. The
following questions are short answer type and carry 3 marks each.
22. How many moles of Lead (II) chloride will be formed from a reaction between 6.5 3
g of PbO and 3.2 g of HCl ? [ Atomic mass of Pb = 207 u, Cl = 35.5u]
23. Calculate the wave number for the longest wavelength transition in the Balmer 3
series of atomic hydrogen.
24. Explain the structure of PCl5 according to hybridization. Why all P –Cl bonds 2+1=3
lengths are not equivalent in PCl5?
25. Do any two 1.5x2=
(a) The enthalpy of atomisation for the reaction CH4(g) → C(g) + 4H (g) is 1665 kJ 3
mol–1. What is the bond energy of C–H bond?
(b) For the reaction at 298 K, 2A + B → C
ΔH = 400 kJ mol–1 and ΔS = 0.2 kJ K–1 mol–1
At what temperature will the reaction become spontaneous considering ΔH and ΔS
to be constant over the temperature range.
(c) The equilibrium constant for a reaction is 10. What will be the value of ∆Gθ?
R = 8.314J K–1 mol–1, T = 300K.
26. (a) What is Le Chatelier’s principle? 1+2=3
(b) What is the effect of increasing pressure in the given reactions? Give reasons.
(i)PCl5(g) ⇌ PCl3(g)+Cl2(g)
(ii)N2(g)+O2(g) ⇌2NO(g)
27. (a) Name the type of isomerism exhibited by acetone and propanal. 1+2=3
(b). Distinguish between position and functional isomerism with example.
28. (a) The boiling point of hydrocarbons decreases with an increase in branching. Give 1+2=3
reason.
(b)Write structures of different chain isomers of alkanes corresponding to the
molecular formula C4H10. Also, write their IUPAC names.
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SECTION D
The following questions are case -based questions. Each question has an internal
choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer
the questions that follow.
29. According to Arrhenius theory, acids are substances that dissociate in water to give
hydrogen ions H +(aq) and bases are substances that produce hydroxyl ions OH-(aq).
The ionization of an acid HX (aq) canbe represented by the following equations:
HX (aq) → H+ (aq) + X – (aq) or HX(aq) + H2O(l) → H3O + (aq) + X – (aq)
Similarly, a base molecule like MOH ionizes in aqueous solution according to the
equation: MOH(aq) → M+ (aq) + OH– (aq)
Bronsted acids are proton donors where as Bronsted bases are proton acceptors.
Acids on donating proton form conjugate bases whereas bases form conjugate acids
after accepting proton. Buffer solution is asolution whose pH does not change.
By adding small amount of H+ or OH-.The decrease in concentration of the ion by
adding other ion as common ion is called common ion effect. Ksp (solubility
product) is product of molar concentrations of ions raised to power no. of ions per 1+1+2=
formula of ions per formula of the compound in sparingly soluble salt. 4
Precipitation occurs only if ionic product exceeds solubility product. Solubility of
salt decreases in presence of common ion. Kw the ionic product of water is 1x10-14
at 298 k. Kw increases with increase in temperature. pH is –log[H3O+]where
[H3O+]=cα in monoprotic acid , is molar conc., α is degree of ionisation.
Now answer the following
(a) What will be the conjugate base of (i)H2SO4 (ii) HCO3-?
(b) What will be the conjugate acid of (i)NH2- (ii)NH3?
(c) The conc. of H3O+ is 4x 10-4 find its pH [log 4 = 0.602]
OR
(c) Kb forNH3 is1.80 x 10-5, what will be Ka? [Kw is 1 x10-14]
30. In 1913, the English physicist, Henry Moseley observed regularities in the
characteristic X-ray spectra of the elements. A plot of ν (whereν is frequency of X-
rays emitted) against atomic number (Z ) gave a straight line and not the plot of ν vs
atomic mass. He thereby showed that the atomic number is a more fundamental
property of an element than its atomic mass.. This is known as the Modern Periodic
Law and can be stated as : The physical and chemical properties of the elements are
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periodic functions of their atomic numbers.. A modern version, the so-called “long
form” of the Periodic Table of the elements , is the most convenient and widely
used. The horizontal rows (which Mendeleev called series) are called periods and
the vertical columns, groups. Elements having similar outer electronic
configurations in their atoms are arranged in vertical columns, referred to as groups
or families. According to the recommendation of International Union of Pure and
Applied Chemistry (IUPAC), the groups are numbered from 1 to 18. There are
altogether seven periods. The period number corresponds to the highest principal
quantum number (n) of the elements in the period. The first period contains 2
elements. The subsequent periods consists of 8, 8, 18, 18,32 and 32 elements,
respectively. In this form of the Periodic Table, 14 elements of both sixth and
seventh periods (lanthanoids and actinoids, respectively) are placed in separate
panels at the bottom. the IUPAC has made recommendation that until a new
element’s discovery is proved, and its name is officially recognised, a systematic
nomenclature be derived directly from the atomic number of the element using the
numerical roots for 0 and numbers 1-9. The roots are put together in order of digits
which make up the atomic number and “ium” is added at the end.Groupwise
Electronic Configurations Elements in the same vertical column or group have
similar valence shell electronic configurations, the same number of electrons in the
outer orbitals, and similar properties. theoretical foundation for the periodic
classification. The elements in a vertical column of the Periodic Table constitute a
group or family and exhibit similar chemical behaviour. We can classify the
elements into four blocks viz., s-block, p-block, d-block and f-block depending on
the type of atomic orbitals that are being filled with electrons.
(a) What is IUPAC name of element having atomic number 107. 1
OR
(a)What is Modern periodic law?
(b) Why do the elements in a group show similar properties? 1
(c)Write general electronic configuration of s,p,d and f block elements 2
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SECTION E
The following questions are long answer type and carry 5 marks each. All questions
have an internal choice.
31 Do any five 1x5=5
(a) How many electrons can be filled in all the orbitals with n+l=5?
(b) Which series of lines of the hydrogen spectrum lie in the visible region’?
(c) Write the electronic configuration of Ni3+. (At. No. of Ni = 28)
(d) How many radial and angular nodes are present in 2p orbital.
(e) What are the maximum number of emission lines when the excited electron
of a H atom in n = 4 drops to the ground state ?
(f) The three electrons present in 2p subshell of nitrogen remain unpaired
(g) Cr has configuration 3d5 4s1 and not 3d4 4s2.
32 (a) How will you separate an organic compound dissolved in aqueous solution? 1+1+1+
(b) An organic liquid decomposes below its boiling point. How will you purify 2=5
it
(c) What is the hybridisation of each carbon in H2C = C = CH2?
(d) Give chemistry of detection test for the presence of Nitrogen in organic
compound.
OR
(a) Give three points of differences between inductive effect and resonance
effect. 3+1+1=
(b) What are electrophiles? Give an example 5
(c) Will CCl4 give white ppt of AgCl on heating with silver Nitrate. Give
reason for your answer.
33 (a) In the presence of peroxide, addition of HBr to propene takes place 2+2+1=
according to Anti-Markovnikov's rule but peroxide effect is not seen in the 5
case of HCl and HI. Explain.
(b) Draw the cis- and trans-structures for hex-2-ene. Which isomer will have
higher b.p and why?
(c) What happens when But-2-ene reacts with Bayers reagent?
OR
(a) Explain Wurtz reaction with an example.
(b) What happens when?
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(i) The vapours of Phenol are passed over heated zinc dust. 2+3=5
(ii) Ethyne (acetylene) on passing through red hot iron tube at 873K.
(iii) Benzene on treatment with excess of chlorine in the presence of anhydrous
AlCl3 in dark
End of Paper