SAFETY DATA SHEET

Printing Date:16.06.2021 Date:16.06.2021

SECTION I. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name ARALDITE® KLEAR 4 PLUS HARDENER IN

Product description Hardener

Product use Hardener for epoxy resins

Manufacturer/supplier PIDILITE ADHESIVES PRIVATE LIMITED

(Formerly known as Huntsman Advanced Materials Solutions Private Limited),
Ramkrishna Mandir Road,
Kondivita, Off: M. Vasanji Road, P.O. Box 17411,
Andheri (East), Mumbai 400059
Email: [email protected]

Telephone: +91-22-2835 7000 Fax: +91-22-2821 6007

SECTION II- IDENTIFICATION OF HAZARDS

Classification according to GHS

Acute toxicity (Oral) Category 4; Acute toxicity (Dermal) Category 5; Skin corrosion/irritation Category 1A;
Serious eye damage/eye irritation Category 1; Skin sensitization Category 1; Acute aquatic toxicity Category 2
Chronic aquatic toxicity Category 2

Hazard Labeling:

Signal word Danger

Hazard statements:
H302 Harmful if swallowed.
H313 May be harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention:
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

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Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately
call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P312 Call a POISON CENTER/doctor if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards which do not result in classification

SECTION III COMPOSITION/ INFORMATION ON INGREDIENTS

Chemical characterization: Mixture

Hazardous Substances:
Chemical name CAS-No. Concentration (% w/w)
Benzyl alcohol 100-51-6 30-60
Bisphenol A epoxy resin 25068-38-6 13-30
Isophorone diamine 2855-13-2 13-30
N'-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine 10563-29-8 13-30

SECTION IV- FIRST AID MEASURES

General advice: Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.
Treat symptomatically.
Get medical attention if symptoms occur.
If inhaled: If inhaled, remove to fresh air.
Get medical attention if symptoms occur.
In case of skin contact:Immediate medical treatment is necessary as untreated wounds from corrosion of the
skin heal slowly and with difficulty.
If on skin, rinse well with water.
If on clothes, remove clothes.

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In case of eye contact:Small amounts splashed into eyes can cause irreversible tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed: Keep respiratory tract clear.
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Notes to physician: There is no specific antidote. Treatment should be given symptomatically on the clinical
conditions.

SECTION V - FIRE-FIGHTING MEASURES

Suitable extinguishing media: Use extinguishing measures that are appropriate to

local circumstances and the surrounding environment.
Unsuitable extinguishing media: High volume water jet
Specific hazards during firefighting: Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion products: No data available
Specific extinguishing methods: Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.Fire residues and
contaminated fire extinguishing water must be disposed of in
accordance with local regulations.
Special protective equipment for firefighters: Wear self-contained breathing apparatus for firefighting if
necessary.

SECTION VI - ACCIDENTAL RELEASE MEASURES

Personal precautions: Avoid contact with the skin and the eyes. See sections VII & VIII for personal
protective equipment & handling.

Environmental precautions: Prevent product from entering drains.Prevent further leakage or spillage if safe
to do so.If the product contaminates rivers and lakes or drains inform respective
authorities.
Methods and materials for containment and cleaning up: Soak up with inert absorbent material (e.g.
sand, silica gel, acid binder, universal binder,
sawdust).Keep in suitable, closed containers for
disposal.

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SECTION VII- HANDLING AND STORAGE

Advice on protection against fire and explosion: Normal measures for preventive fire protection.
Advice on safe handling: Do not breathe vapours/dust. Avoid exposure - obtain special
instructions before use.Avoid contact with skin and eyes.For
personal protection see section 8.Smoking, eating and drinking
should be prohibited in the application area.To avoid spills
during handling keep bottle on a metal tray.Dispose of rinse
water in accordance with local and national regulations.Persons
susceptible to skin sensitisation problems or asthma, allergies,
chronic or recurrent respiratory disease should not be employed
in any process in which this mixture is being used.
Conditions for safe storage: Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.Observe label precautions.Keep
in properly labelled containers.
Further information on storage stability: Stable under normal conditions.

SECTION VIII- EXPOSURE CONTROL/ PERSONAL PROTECTIVE EQUIPMENT

Ventilation: Local exhaust ventilation and/or mechanical (general) exhaust are recommended.
General protective and hygienic measures:
Respiration protection: Maintain good ventilation in the area. Suggested MSHA/NIOSH approved respirator
where vapors concentrations is more
Personal protective equipment:
Skin and body protection :
Impervious clothing
Choose body protection according to the amount and concentration of the dangerous substance at the work
place.
Protection of hands:

Protective gloves

Remarks: The suitability for a specific workplace should be discussed with the producers of the protective gloves.

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Eye protection:

Tightly sealed goggles

Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing problems.
Hygiene measures :
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: liquid Colour: NA

Odour: NA Boiling point: NA
Flash point:NA Vapour pressure: NA
Relative density: 0.95g/cc (25°C)
Decomposition temperature: > 200 °C,estimated Water solubility: practically insoluble (20°C)

SECTION X - STABILITY AND REACTIVITY DATA

Reactivity: No dangerous reaction known under conditions of normal use.

Chemical stability: No decomposition if stored and applied as directed.
Possibility of hazardous reactions: No hazards to be specially mentioned.
Conditions to avoid : None known.
Incompatible materials : None known.
Hazardous decomposition products: No dangerous decomposition products known.

SECTION XI - TOXICOLOGICAL INFORMATION

Acute toxicity
Acute oral toxicity - Product : LD50(Rat): 1859 mg/kg
Acute dermal toxicity Product: LD50: 3180 mg/kg
Acute inhalation toxicity : No data available
Potential health effects
On the skin: Extremely corrosive and destructive to tissue.
On the eye: May cause irreversible eye irritation
Sensitization: Causes sensitization

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CMR Effects: The product has not been tested for CMR effects
STOT - single exposure: No data available
STOT - repeated exposure: No data available
Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects.

SECTION XII - ECOLOGICAL INFORMATION

Aquatic toxicity: Quantitative data on the ecological effect of this product are not available.

Persistence and degradability: Quantitative data on the product are not available

Behaviour in environmental systems:

Bioaccumulative potential: No further relevant information available.

Mobility in soil: No further relevant information available.

Results of PBT and vPvB assessment: No information is available

Other adverse effects: No further relevant information available.

Suggested not to allow to enter soil, waterways and open bodies of water. Resin used is toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic environment.

SECTION XIII - DISPOSAL INFORMATION

Waste from Residues / Unused Products:

The product should not be allowed to enter drainages or water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and national regulations.
Dispose of contents/ container to an approved waste disposal plant.
Contaminated Packaging:
Empty containers should be taken to local recyclers for disposal

SECTION XIV - TRANSPORTATION INFORMATION

IATA
UN/ID No.: UN 1760
Proper shipping name : Corrosive liquid, n.o.s. (DIMETHYL DIPROPYL TRIAMINE, ISOPHORONE DIAMINE)
Class: 8
Packing group: I
Labels: Corrosive
Packing instruction (cargo aircraft) : 854
Packing instruction (passenger aircraft): 850

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IMDG
UN number : UN 1760
Proper shipping name: Corrosive liquid, n.o.s. (DIMETHYL DIPROPYL TRIAMINE, ISOPHORONE DIAMINE)
Class: 8
Packing group: I
Labels: 8
EmS Code: F-A, S-B
Marine pollutant: No
Transport in bulk according to IMO instruments: Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based upon the
properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation
classifications may vary by mode of transportation, package sizes, and variations in regional or country
regulations.

SECTION XV - REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
The components of this product are reported in the following inventories: AICS (Australia), Canada (DSL),
New Zealand (NZIoC), Japan (ENCS), Korea (KECI), PICCS (Philippines), TSCA (US), Switzerland (CH Inv),
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION XVI - MISCELLANEOUS INFORMATION

DISCLAIMER:
The data presented here is based on information we believe to be reliable but unknown risks may be present.We
disclaim liability for damage or injury which results from the use of the above data and nothing contained therein
shall constitute a guarantee or a warranty (including warranty of Merchantability or fitness for a particular
purpose) or representation (including freedom from Patentability) by us with respect to the accuracy or
completeness of the data, the product described or their use for any specific purpose as known to us. The final
determination of the suitability of information, the manner of use of information or product and potential
infringement of patents is the sole responsibility of the user.
Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be
determined by the user and made known to handlers, processors and end users.
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED PIDILITE EMPLOYEE IS AUTHORIZED
TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR PIDILITE PRODUCTS. DATA SHEETS FROM
UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR
ACCURATE.

ABBREVIATIONS USED: NA - NOT APPLICABLE, NH - NON HAZARDOUS,

CI - CONTENT INSIGNIFICANT.

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