DPP: 02

Triumph
Solutions
Q1 A solution in which no more solute can be Q6 According to Henry’s law ‘the partial pressure
dissolved at the same temperature and of the gas in vapour phase (p) is proportional
pressure is called a to the mole fraction of the gas (x) in the
1. unsaturated solution solution’. For different gases the correct
2. saturated solution statement about Henry’s constant is
3. dissolution 1. higher the value of KH at a given pressure,
4. crystallization higher is the solubility of the gas
2. higher the value of KH at a given pressure,
Q2 Solubility of gases in liquids is affected by lower is the solubility of the gas
1. temperature
3. KH is not a function of nature of gas
2. pressure 4. KH value for all gases is same at a given
3. temperature and pressure pressure.
4. None of the above
Q7 The milli moles of N2 gas that will dissolve in
Q3 The energy that is responsible for the
1L of water at 298 K. when it is bubbled
dissolution of a solute is
through water and has a partial pressure of
1. Hydration energy
0.96 bar will be (Given that at 298 K KH = 76.8
2. Lattice energy
3. Internal energy k bar)
4. Bond energy 1. 0.59
2. 0.69
Q4 Which is the first law to give the quantitative 3. 0.79
relation between pressure and solubility of a 4. 0.89
gas in a solvent?
1. Raoult’s law Q8 KH value for Ar(g), CO2(g), HCHO (g) CH4(g)are
2. Dalton’s law 40.39, 1.67, 1.83 × 10–5 and 0.413 respectively.
3. Henry’s law Arrange these gases in the order of their
4. All of these increasing solubility.
1. HCHO < CH4< CO2< Ar
Q5 To increase the solubility of CO2 in soft drinks
2. HCHO < CO2< CH4< Ar
and soda water
3. Ar < CO2< CH4< HCHO
1. the bottle is sealed under high pressure
4. Ar < CH4< CO2< HCHO
2. the bottle is sealed under low pressure
3. the bottle is remained opened Q9 At high altitude the partial pressure of oxygen
4. the bottle is sealed under high is less than that at the ground level. This leads
temperature to
1. low concentration of oxygen in the blood
and tissues
 2. high concentration of oxygen in the blood 2. The entropy of mixing is zero
and tissues 3. The free energy of mixing is zero
3. release of dissolved gases and formation of 4. The free energy as well as entropy of
bubbles of nitrogen in the blood mixing are each zero
4. thickening of blood and tissues.
Q15 Vapour pressure of a solution of non-volatile
Q10 Low concentration of oxygen in the blood and solute is
tissues of people living at high altitude is due 1. directly proportional to the mole fraction of
to ............. the solvent
1. low temperature 2. Independent of mole fraction of the solute
2. low atmospheric pressure 3. inversely proportional to the mole fraction
3. high atmospheric pressure of the solvent
4. both low temperature and high 4. directly proportional to the mole fraction of
atmospheric pressure the solute

Q11 Henry’s law constant of oxygen is 1.4 × 10–3 Q16 The vapour pressure of benzene at a certain
mol temperature is 640 mm of Hg. A non-volatile
electrolyte solute weighing 2.175 g is added to
L–1. atm–1 at 298 K. How much of oxygen is
30.08 g of benzene. If the vapour pressure of
dissolved in 100 mL at 298 K when the partial
the solution is 600 mm of Hg, what is the
pressure of oxygen is 0.5 atm?
molecular weight of the solid substance?
1. 1.4 g
2. 3.2 g
1. 79.82
3. 22.4 mg
2. 90.23
4. 2.24 mg
3. 59.60
Q12 A solution containing components A and B 4. 49.50
follows Raoult’s law
1. A – B attraction force is greater than A–A Q17 Vapour pressure of pure ‘A’ is 70 mm of Hg at
and B– B. 25ºC. It forms and ideal solution with ‘B’ in
2. A – B attraction force is less than A – A and which mole fraction of A is 0.8. If the vapour
B – B. pressure of the solution is 84 mm of Hg at
3. A – B attraction force remains same as A –A 25ºC, the vapour pressure of pure ‘B’ at 25ºC is
and B – B. 1. 56 mm
4. volume of solution is different from sum of 2. 70 mm
volumes of solute and solvent. 3. 140 mm
4. 28 mm
Q13 If liquid A and B from ideal solutions
Q18 The vapour pressures of two liquids A and B in
1. The enthalpy of mixing is zero
their pure states are in the ratio of 1 : 2. A
2. The entropy of mixing is zero
binary solution of A and B contains A and B in
3. The free energy of mixing is zero
4. The free energy as well as entropy of the mole proportion of 1 : 2. The mole fraction
mixing are each zero of A in the vapour phase of the solution will
be:
Q14 If liquid A and B from ideal solutions 1. 0.33
1. The enthalpy of mixing is zero 2. 0.25
3. 0.52 4. 0.2
 Answer Key
Q1 2 Q10 2
Q2 3 Q11 4
Q3 1 Q12 3
Q4 3 Q13 1
Q5 1 Q14 3
Q6 2 Q15 1
Q7 2 Q16 2
Q8 3 Q17 3
Q9 1 Q18 4
 Hints & Solutions
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Q1 Text Solution: Total moles =

A solution in which no more solute can be
dissolved at the same temperature and
pressure is called saturated solution.

Q2 Text Solution:
Solubility of gases in liquids is greatly affected
by pressure and temperature.
Q8 Text Solution:
Q3 Text Solution: According to Henry’s law, the solubility of the
As hydration energy is the energy released gas in a given volume of liquid at a constant
during the attachment of water molecules to temperature is directly proportional to the
ions, hence it is responsible for dissolution pressure of gas exerted on the liquid. The
Q4 Text Solution: relation is stated as follows,
Henry was the first to give a quantitative
relation between pressure and solubility of a At constant pressure, the henry’s law constant
gas in a solvent which is called henry’s law. kH value is inversely proportional to the mole

Q5 Text Solution: fraction ‘x’.

The bottle is sealed under high pressure.

Q6 Text Solution: Therefore, the higher the value of kH lower is

According to Henry’s law, the solubility of the the solubility of a gas in the liquid, or the lower
gas in a given volume of liquid at a constant the value of kH higher is the solubility of the
temperature is directly proportional to the gas in the liquid.
pressure of gas exerted on the liquid. The Here, HCHO has the lower kH value followed
relation is stated as follows,
by CH4, CO2 and Ar. The correct order is
p = kH × x
written as, Ar < CO2 < CH4 < HCHO.
Where, kH is Henry’s law constant, p is the
partial pressure of the liquid and ‘x’ is the mole
fraction. Q9 Text Solution:

At constant pressure, the Henry’s law constant The atmospheric pressure around us is related

kH value is inversely proportional to the mole to the partial pressure of oxygen. The
atmospheric pressure exerted by the oxygen is
fraction ‘x’.
less at high altitudes.
Low concentration of oxygen in the blood and
Therefore, the higher the value of kH the lower tissues of people living at high altitudes is due
is the solubility of the gas. to low atmospheric pressure. As at high
altitude the partial pressure of oxygen is less
Q7 Text Solution:
than at ground level, causing the low
According to Henry law,
concentration of oxygen in the blood.

Moles of water in 1 L =
Q10 Text Solution: Q12 Text Solution:
The atmospheric pressure is the pressure Let's consider a binary solution of components
exerted by the air on us. The force exerted by A and B. The ideal solution obeys Raoult's law
the air is related to the density of air. The .an ideal solution have an identical force of
atmospheric pressure of a gas decreases with attraction between the A and A or B or B
an increase in altitude. At higher altitudes, the component. In other words, the force of
less dense air has a low concentration of attraction in AA and BB remains constant.
oxygen. Thus at heights, the living bodies have Q13 Text Solution:
a low concentration of oxygen in blood and When 2 liquids upon mixing form an ideal
tissue.
solution; then:
At high altitude, the partial pressure of the Enthalpy of mixing is 0.
oxygen is less than the ground level.
Entropy of mixing is greater than 0.
Therefore, the low concentration of oxygen in
The free energy of mixing is less than 0.
the blood and tissue of people living at high
Q14 Text Solution:
altitudes is due to low atmospheric pressure.
\
Q11 Text Solution:
Given: Henry law constant KH = 1.4 × 10–3 mol

L-1
Partial vapour pressure of oxygen p = 0.5 atm
= 23.8 × 0.9
We are interested in determining the solubility
= 21.42 mm of Hg
of oxygen gas in water. The solubility of
oxygen gas in the water is determined through Q15 Text Solution:
Henry’s law. It is given as follows, When the non-volatile solute is added to the
S = KH × p solvent the vapour pressure of the solution

Where S is the solubility of the gas, decreases. Now according to Raoult’s law, the

S = KH × p pressure of the solvent (let P1) in the solution

is given by,
⟹ S = (1.4 × 10–3) × (0.5)
\ S = 0.7 × 10–3 mol L–1
The solubility of a gas in the given volume is, Where, p10 is the vapour pressure of pure
solvent, x1 is the mole fraction of a solute, and
P1 is the pressure of the solution.

Now, the number of moles of oxygen gas in We can say that the vapour pressure of a non-
solution is calculated as follows, volatile solute is directly proportional to the
1 mole of O2 = 32 gm mole fraction of the solvent. It is,

then, Pµx

7 × 10–5 mol of O2 contain, Q16 Text Solution:

= 32 × 7 × 10–5 gm
= 2.24 × 10–3 gm P0 = vapour pressure of pure solvent
= 2.24 mg (640mmHg) P = vapour pressure of solution
(600 mm Hg)
 w = weight of solute (2.175gm) ⟹ 0.2 PB0 = 84 – 56
W = weight of benzene (30.08gm)
⟹
M = molecular weight of benzene (78gm)
On substituting the values
Q18 Text Solution:

Molecular weight = 90.23 g/mol

Q17 Text Solution: Let

Given: Vapour pressure of a pure component As per Raoult’s law
A and B are as follows,
PA0 = 70 mm of Hg
XA = 0.8
XB = 1 – 0.8 = 0.2
The total vapour pressure of the solution is
written as,

Substitute values in above equation. We have,

84 = 70 × 0.8 + (1 – 0.8)

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