Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_Elite, Target & LIIT-BTs JEE-MAIN Date: 26-03-2025
Time: 09.00Am to 12.00Pm GTM-31/26 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.@
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown belo w
 SRI CHAITANYA IIT ACADEMY, INDIA 26-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-31/26_Q.P

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
26-03-2025_Sr.S60_Elite, Target & LIIT-BTs_Jee-Main-GTM-31/26_Test Syllabus
MATHEMATICS : TOTAL SYLLABUS
PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-03-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-31/26_Q.P
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Let I be the set of positive integers. R is a relation on the set I given by
 a 
R  (a, b)  I  I : log 2   is a non  negative integer  ,then R is
 b 
1) neither symmetric nor transitive but reflexive
2) reflexive, transitive but not symmetric
3) neither reflexive nor transitive but symmetric
4) equivalence relation
2. Let P be the point of intersection of line
x  2 y  2 z 1
 
1 2 3
and plane x  y  z 11, then the image of P in the plane 2x  y  2z  6,is
1)  152 ,  50 , 11  2)  148 ,  40 , 113 
 9 9 9   3 3 3 

3)  60 ,  35 , 117  4)  76 ,  110 , 113 

 9 9 9   9 9 9 
3. C1 and C2 are two circles whose equations are given as x 2  y 2  25 and
x 2  y 2  10 x  6 y  1  0 respectively. Now C3 is a variable circle which cuts C1 and C2
orthogonally. Tangents are drawn from the center of C3 to C1, if the locus of the
13 2
midpoint of the chord of contact of tangents is ax  3 y  ( x  y 2 )  0 , (where a , b  Z  ,
b
b
and a and b are relative prime), then is
a
1) 1 2) 2 3) 4 4) 5

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4. A line is drawn from a point P( x, y ) on curve y  f ( x) , making an angle in anti-clockwise
with the +ve x-axis which is supplementary to the one made by the tangent to the curve at
P( x, y ) . The line meets the x-axis at A. Another line perpendicular to the first, is drawn
from P( x, y ) meeting the y-axis at B. If OA  OB , where O is the origin, then the curve
which passes through (1,1).
1) x 2  y 2  4 xy  4 2) x 2  y 2  2 xy  2  0
3) x 2  y 2  2 xy  2 4) x 2  y 2  4 xy  4  0
5. Let the area enclosed by the curve y  1  x 2 and the line y  a , where 0  a  1 ,be
A(0)
represented by A(a) . If  k , then
1
A 
2
3 3 5 5
1) 1  k  2)  k  2 3) 2  k  4) k 3
2 2 2 2
6.  
Let g ( x)  lim 22n 1  f n ( x) .
n 

For f : [0,1]  R , f ( x )  1  x , where f n ( x)  fofof .........of .
2   
n times
Then which of the following is correct?
2 2 2 2
1   1    1  2  1  4
1) g    2) g    3) g     4) g    
 2  18  2  18  2 9  2 9
7. If a1x1  a2 x2  a3 x3  a4 x4  1432 ,
a7 x1  a6 x2  a5 x3  a8 x4  2341 ,
a11x1  a12 x2  a13 x3  a10 x4  3412 ,
a17 x1  a16 x2  a15 x3  a14 x4  4321 ,
where a1, a2 , a3........, a17 are in A.P. with a1  a2  a3.........  a17  4369 .
Then the value of [ x1  x2  x3  x4 ] is
([.] denotes G.I.F)
1) 11 2) 10 3) 13 4) 9
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8. x
Consider the function f ( x )  xe  ( xe ) x 1 ,

Where x  R  {0} , then which of the following statement(s) is CORRECT?

1) f (x) attains its local maxima at x  x0 , where x0  (0,1) .

2) f (x) attains its local minima at x  1

3) f (x) attains its local maxima at x  x0

4) f (x) attains its local minima at x  x0 , where x0 (0,1)
2
9. General solution of the equation cos 3 x.sin x  sin 3 x.cos x  , is (where n  I )
8
n  n 
1) x   (1)n 2)  (1)n
4 16 4 9
n n 
3) 4) x  
9 9 2
10. A function f is defined on the complex number by f(z) = (a+ib)z, where a, b    . This
function has the property that the f-image of any point in the complex plane is equidistant
p
from that point and origin. If a  bi  10 and b 2  ; p , q   ,
q
gcd(p, q) = 1, then p + q is
1) 503 2) 403 3) 405 4) 410
11. Two coins A & B are kept in an urn. When coin A is flipped, the probability of getting head
is 1/4 while for B is 3/4. One coin is randomly chosen from this bag, tossed twice and it falls
head on both occasions. The probability that is coin A is:
9 1 3 1
1) 2) 3) 4)
10 4 4 10

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12. Let  and  are roots of 5t 2  3t  1  0 , then

  2   2  2 3  3  3    1 1  
 (   ) x   x   x  .... is ____  0  x  min  ,  
   
  2   3        

 x 2  3x  5   x 2  3x  5 
1) ln   2) ln  
 5   5 
   
  x 2  3x  5   x 2  3x  5 
3) ln   4) ln  
 5   5 
   
1 y 1
13. If (x, y) satisfy tan 1  sin 1 x  1  cos1 xy 2  cos 1 x(1  x) , then
1 y 2

1) x  2 y  3  1 2) 2 x  y  3  1 3) x  3 y  4 4) 3x  y  4

14. Let P be the 7th term from the beginning and Q be the 7th term from the end in the expansion
n
3 1 
of  3  3  where n  N .If 12P  Q then the value of n is
 4
1) 15 2) 10 3) 6 4) 9
n
 1 3  1 2 1 3  1 
15. If M is the matrix   then M  M  M .....    M n 1  ...
 1 1  3 9  3 

3 1  
   ,where is equal to
13   1  
1) 0 2) 4 3) 5 4) 3

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3 7 5 19 7 37
16. Sum of 20 terms of the series       ..... is
2 2 3 3 2 2 3 3 2 2 3 3
1 2 1 2 2 3 2 3 3 4 3 4
2684 2674 2640
2650
1) 2) 3) 4)
1331 1331 1331
1331
17. If shortest distance between the skew lines r  (4iˆ  ˆj )   (iˆ  2 ˆj  3kˆ) and
r  (iˆ  ˆj  2kˆ)   (2iˆ  4 ˆj  5kˆ) is , then value of [  ] is: (where [ ] is greatest integer
function)
1) 1 2) 2 3) 3 4) 4
2 n dy ( n ) 1
18. If y(n)  e xe x ....e x ,0  x  1 Then lim at x  is
n  dx 2
1) e 2) 4e 3) 2e 4) 3e
19. If the tangents drawn at the points P and Q on the parabola y 2  2 x  3 intersect at the point

R  0,1 , then the orthocenter of the triangle PQR is:

1)  3,1 2)  2,  1 3)  6,3 4)  2,1

x2 y2
20. Let the hyperbola H :
a 2

b 2 
 1 pass through the point 2 2, 2 2 .A parabola is drawn 
whose focus is same as the focus of H with positive abscissa and the directrix of the parabola
is the latus rectum through the other focus of H. If the length of the latus rectum of the
parabola is e times the length of the latus rectum of H, where e is the eccentricity of H, then
which of the following points lies on the parabola?


1) 2 3,3 2  
2) 3 3, 6 2  3)  3,  6  
4) 3 6,6 2 
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

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21. A jar contains 7 white marbles and 3 blue marbles. Given that the 4-marbles are chosen
from the jar at the same time, then the standard deviation of the number of blue marbles
a
choosen is where a and b are co-prime numbers and a is square free where a  b is
b
22. Given the system of equation
x  y  z  2,
2x  y  4z 1 and
x  y  z   , where  ,  0,1,2,3,4
Let A, B, C denotes the number of ordered pairs (, ) such that the system has unique
solution, no solution, infinitely many solutions respectively, then the value of (A 4B C)is
equal to
23. Let f ( x)  ( x  1) sgn( x) and g ( x)  max.( f (t )) ,   t  x ,   x   , then the number of
points where g(x) is non-differentiable is (sgn(x) represents signum function of x)

24.
  1 a 
Let S  
  0 b 




; a , b  1, 2,3,.....100 and let Tn  A  S : A
n n1

 I . Then the number

100
of elements in  Tn is ___.
n1
25. The number of 7-digit number which are multiples of 11 and are formed using all the digits
1,2,3,4,5,7 and 9 is_.

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PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

26. A proton enters into a region having a uniform magnetic field B  (0.3T )kˆ . The proton enters
the field region at the origin of the co-ordinate system with a velocity

 
v  2iˆ  2 ˆj  2kˆ  104 m / s .Find the time after which, the proton will touch the z-axis


for the first time, after entering into the field region q p  1.6  1019 C ; m p  1.6  1027 kg . 
6 7 7
1) 2.1  10 s 2) 3.1 10 s 3) 4.1  10 s 4) 2.1  10 7 s
27. A bulb is placed at a depth of 2 7 m in water and a floating opaque disc is placed over the
surface of water, so that the bulb is not visible from the surface. What is the minimum
 4
diameter of the disc   w   .
 3
1) 12 m 2) 6 m 3) 2 m 4) 4 m
28. Determine the change in entropy S of 100 gm of water when it is heated to the boiling
point from room temperature of T = 300 K, and it is transformed into vapour at the boiling
temperature and atmospheric pressure . It is given that for water: the molar heat capacity
C  75.4 J / (mol  k ); latent heat of vapourization L  2.26 MJ / kg . (Take
ln(1.24)  0.217 )
1) 697 J/K 2) 600 J/K 3) 500 J/K 4) 650 J/K
29. An oscillator is moving according to the law, x  x0 sin t because of a driving force
F  F0 cos t acting on it. What is the damping co-efficient  of the oscillator? Mass of the
oscillator is m. The resistive force is dependent on velocity v as F   mv .
F0 F0 F0 F0
1) 2) 3) 4)
x0 2 x0 mx0 2mx0
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30. A small particle of mass m is at rest on a horizontal circular platform that is free to rotate
about a vertical axis through its centre. The particle is located at a distance r form the axis, as
shown in figure. The platform begins to rotate with constant angular acceleration  .Because
of the friction between the particle and the platform, the particle remain at rest with respect
to the platform. When the particle has reached angular speed  , the angle  between the
static frictional force f s and the inward radial direction is


fs
θ

r

 2r  1
 2  1   
1)   2)   3)   tan   4)   tan  2 
g 2     
 
31. Isosceles glass prism    1.57  with small refracting angles ( ) is placed in front of parallel

beam of rays incident normally on it’s base (see figure). The size of the base 2a  5 cm .
Light falls on a screen at a distance of 100 cm from the prism with a dark patch of width of 1
cm near centre of screen. Find the value of refracting angle  .


2a


1) 30 2) 40 3) 3.430 4) 2.40
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32. Consider fraunhofer diffraction pattern obtained with a single slit illuminated at a normal
incidence. At the angular position of first diffraction minimum, the phase difference (in
radians) between the wavelets from the opposite edges of the slit is
 
1)  2) 2 3) 4)
4 2

33. Consider a system of n concentric conducting shells of radii r , 2r , 4r ,8r.......2n 1 r

respectively. If innermost shell is earthed and Q charge is given on outermost shell, then
charge appears on innermost shell is
Q Q
1) Q 2)  3)  4) Q
2n 2n 1
34. A piston fitted in cylindrical pipe is pulled as shown in the adjoining figure. A tuning fork is
sounded at open end, and the loudest sound is heard at open lengths 13 cm, 41 cm and 69cm.
The frequency of tuning fork, if velocity of sound is 350 m/s is

1) 1250 Hz 2) 625 Hz 3) 417 Hz 4) 715 Hz

35. Two blocks A and B of masses m and 2m respectively are connected by a spring of force
constant K. The masses are moving to the right with uniform velocity 10 m/sec each, the
heavier mass leading the lighter one. The spring in between them is of natural length during
the motion. Block B collides with a third block C of mass m, at rest. The collision being
completely inelastic. Find the minimum speed of block A in subsequent motion.
1) 5 m / s 2) 6 m / s 3) 8 m / s 4) 10 m / s
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36. A long solenoid of cross sectional radius R has a thin insulated copper wire ring tightly put
on its winding. One half of the ring has resistance 10 times that of the other half. The
magnetic induction produced by the solenoid varies with time as B = bt, where b is a
constant. Find the magnitude of the electrostatic field strength in the ring.
9 9
1) Rb 2) Rb 3) 9 Rb 4) Rb
11 22
37. A airplane is in supersonic flight at an altitude h. At what smallest distance a (along the
horizontal )from the observer ‘O’ on the ground, is there a point from which the sound
emitted by the airplane motors reaches to the observer earlier than sound emitted by plane,
when it is at a point A that is directly above the observer. ( v p  velocity of airplane, vs 
velocity of sound)
Airplane
A

h
a
O
 vp   vp 
2   
v v
1) a   2s  h 2) a   s2  h
 vp   vp 
  1   1
 vs   vs 
 vp 
2 
v
3) Not possible for any value of a 4) a   2s  h
 vp 
  1
 vs 
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38. Water is filled in a fixed container upto a height of 13m from ground. A sniper fires and
makes a small hole in the side at a height of 9m from the ground. The water jet strikes the
ground at X meter from the container. Find the value of X.

X
1) 6m 2) 9m 3) 12m 4)13m
39. A disc of mass m and radius R is hinged at periphery and suspended in vertical plane. A
particle of same mass m strikes the disc with an initial velocity ‘u’ in the horizontal
direction. It is given that particle rebounds in vertical direction. Co-efficient of restitution is
e. the angular velocity of disc just after the collision is

300

m u

u 2u 2u u
1)   2)   3)   4)  
3R 3R R 2R
40. A uniform dense rod with non-uniform young’s modulus is hanging from ceiling under
gravity. If elastic energy density at every point is same, then young’s modulus (Y) with x
will change as which of the shown graph?

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m,  g
x increases
x0
Y Y

1) x 2) x

Y Y

3) x 4) x

41. Statement-I: The equivalent emf of two non-ideal batteries connected in parallel is smaller
than either of the two emfs.
Statement-II: The equivalent internal resistance of two non-ideal batteries connected in
parallel is larger than the internal resistance of either of the two batteries.
In the light of the above statements, choose the correct answer from the options below.
1) Both Statement-I and Statement-II are false.
2) Both Statement-I and Statement-II are true.
3) Statement-I is false but Statement-II is true
4) Statement-I is true but Statement-II is false.
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42. Assertion (A): A simple pendulum is taken to a planet of mass and radius, 4 times and 2
times, respectively, than the earth. The time period of the pendulum remains same on earth
and the planet.

Reason (R): Time period of simple pendulum is T  2 . Where  = length of simple
g

pendulum and g = acceleration due to gravity.

In the light of the above statements choose the correct answer from the options below.
1) Both A and R are true and R is not correct explanation of A.
2) A is false but R is true.
3) Both A and R are true and R is the correct explanation of A.
4) A is true but R is false.
43. Given below are two Statement
Statement-I: The hot water flows faster than cold water.
Statement-II: Fresh water has higher surface tension as compared to soap water.
In the light of above Statement chose the correct answer from options given below.
1) Statement I is false but Statement II is true.
2) Both Statement I and Statement II are false.
3) Both Statement I and Statement II are true.
4) Statement I is true but Statement II is false.
44. Assertion (A): The binding energy per nucleon is found to practically independent of atomic
number A, for nuclei with mass numbers between 30 and 170
Reason (R): Nuclear force is a short range force.
In the light of above statements , choose the correct answer from the option given below:
1) (A) is false but (R) is true
2) Both (A) and (R) are true and (R) in the correct explanation of (A)
3) Both (A) and (R) are true and (R) is not the correct explanation of (A)
4) (A) is true but R is false

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45. Match List-I with List-II
List-I List-II
A) Permeability of free space I)  ML2T 2 
 
B) Magnetic field II)  MT 2 A1 
 
C) Magnetic moment III)  MLT 2 A2 
 
D) Torsional constant IV)  L2 A
 
Choose the correct answer from the options given below
1) A  ( IV ), B  ( III ), C  ( I ), D  ( II ) 2) A  ( III ), B  ( II ), C  ( IV ), D  ( I )
3) A  ( II ), B  ( I ), C  ( III ), D  ( IV ) 4) A  ( I ), B  ( IV ), C  ( II ), D  ( III )
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
r
46. A hemispherical bowl of inner radii R and outer radii 2R is charged with density    0 (
R
b0 R
where r is the distance from the center O).The electric field at point ‘O’ is . The
4 0
value of b is_____________

R O
2R

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47. A ball is thrown vertically downwards with velocity 2gh from a height h. After colliding
with the ground it just reaches the starting point. Co-efficient of restitution for collision is e .

The value of 2e2 is______

48. A uniform triangular plate of triangular area 1m2 , base length 60cm and thickness 10mm
(prism like shape) is lying vertically on a smooth ground as shown in the figure .Find the
maximum value of 100cot  for which it does not topple.

60cm
49. A rod of ferromagnetic material with dimensions 10cm  0.5cm  0.2 cm is placed in a

magnetic field of strength 0.5  10 4 amp / m as a result of which a magnetic moment of

5amp  m 2 is produced in the rod. Find the value of net magnetic induction in SI unit
(Give your answer to nearest integer)
50. A potassium surface is placed 75 cm away from a 100 W bulb.It is found that the energy
radiated by the bulb is 5% of the input power. Consider each potassium atoms as a circular
0
disc of diameter 1 A . The time (in sec) required for each atom to absorb an amount of energy
equal to its work function of 2.0 eV considering wave nature of light is t0 . Find the value of
5t0

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CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which
ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Arrange the following carbocations in the increasing order of their stability.

(I) (II) (III)

1) I > II> III 2) II > III > I 3) I > III > II 4) III > I > II
H  / H 2O
52. The major product of reaction is CH 2  C  CH 2 

1) CH 2  CH  CH 2 2) CH  CH 2  CH 3
| ||
OH O

3) CH 3  C  CH 3 4) OH
||
O
53. The major product obtained in the following reaction is
Cl

Alc.KOH


1) 2) 3) 4) Both (1) and (2)

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54. The product ‘R’ in the following reaction is
O

S Cl

O CH 3  COONa H  / H 2O, 
P Q R

OH
Cl
OH OH Cl

1) 2) 3) 4)
55. Compound X having molecular formula C6 H10O gives positive test with DNP and
hydroxylamine. It gives negative test with Tollen’s reagent and Fehling’s solution. Yellow
precipitate is obtained when it is treated with I 2 / NaOH .
The structure of compound X is
O
CH3
C CH3

CHO
O
1) 2) 3) O 4)
56. For the following reactions sequence, the product R is
O

( pH  4 to 6) CH  I H O
+ HN  P 
3  Q 
3 R

CH3 OH O
N
CH3 H3C CH3

1) 2) 3) 4)
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57. Which of the following compounds will be suitable for Kjeldahl’s method for nitrogen
estimation?

NH2 NO2 N 2Cl 

1) N 2) 3) 4)
58. In an acid-base titration, 0.1 M NaOH solution was added to the HCl solution of unknown
strength. Which of the following correctly shows the change of pH of the titration mixture in
this experiment?

pH pH pH pH

(i) V(mL) (ii) V(mL) (iii) V(mL) (iv) V(mL)

1) (i) is correct 2) (ii) is correct 3) (iii) is correct 4) (iv) is correct

59. Which among the following statements is not correct?
1) For p and d orbitals, the radial wave function ( ) approaches to zero as r approaches to
zero.

2) The radial probability density ( 2 ) for ‘1s’ orbital is maximum at r = 0.

3) The radial distribution function (4 r 2 2 ) for ‘1s’ is maximum at r = 0.

4) In plot of radial wave function ( ) changes its sign at nodes.
60. A current of 3.7 amp is passed for 6 hours between Ni-electrodes in 0.5L of 2M solution of
Ni ( NO3 ) 2 . What will be the molarity of solution at the end of electrolysis?
1) 2M 2) 1M 3) 0.5M 4) 0.25M

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61. The freezing point (in C ) of solution containing 0.1 g K3  Fe(CN )6  (mol. wt. 329) in 100
0


g of water K f  1.86 K kgmol 1 is 
1) 2.3  102 2) 5.7  102 3) 1.2  103 4) 1.2  102
62. In a system, a piston caused an expansion against an external pressure of 1.2 atm, given a
change in volume of 32 litre, in this process heat released by the system is 47.16 kJ. The
change in internal energy U (in kJ) is
1) -51 kJ 2) 51 kJ 3) -54.84 kJ 4) 54.84 Kj
63. Determine the concentration of [ S 2 ] ion in a 0.1 M H 2 S solution to which enough HCl has
been added to produce [ H  ] equal to 2  10 4 M .
Given- for H 2 S .
k1  10 7
k 2  10 14
1) 2.5  10 15 M 2) 2.5  10 18 M 3) 4  10 15 M 4) 4  10 18 M
64. The half life of the unimolecular elementary reaction

A( g ) 
 B ( g )  C ( g ) is 6.93 min. How long will it take for the concentration of A to be

reduced 10% of the initial value?

1) 10.053 min 2) 4.6 min 3) 46 min 4) 23.03 min
65. Which of the following overlaps is incorrect? (Z – axis is internuclear axis)
(i) 2 p y  2 p y -  bond formation

(ii) 2 p z  2 p z -  bond formation

(iii) 2 px  2 px -  bond formation
(iv) 3d xy  3d xy -  bond formation

1) Only iii 2) Only ii and iv 3) Only iii and iv 4) Only i and ii

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66. In each of the following species presence of lone pair(s) does not affect idealized bond
angle?

1) PF3 2) ClF3 3) IF4 4) NF3

67. Which of the following complex will be paramagnetic? (Assume all central atoms have
6 0
t2g eg )
5 3
1)  Fe  CN 5  O2   2) Co  C2O4 3 

4
3)  Fe  CN 5  O2   4) K 4  Fe  CN 6 

68. A pink coloured salt turns blue on heating. The presence of which cation is most likely?

1) Cu 2 2) Co 2  3) Zn 2  4) Fe 2 
69. When the following five anions are arranged in order of decreasing ionic radius, the correct
sequence is:

1) Se2 , I  , Br  , O 2 , F  2) I  , Se2 , O 2 , Br  , F 
3) Se2 , I  , Br  , F  , O 2 4) I  , Se2 , Br  , O 2 , F 
70. Which of the following is incorrect?

1) Ionization energy of Fg  is less than that of Clg 

2) Tl   In  Ga  : Order of stability

3) Both O2  PtF6  and Xe  PtF6  have same colour

4) NH 3  HF  H 2O : dipole moment
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases

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71. Number of moles of HIO4 consumed per mole of Methyl   D  glucopyranoside is
72. Total possible R – X involved in following reaction:

i ) Mg , dry ether
R  X 
 C C D
ii ) D2O

73. The following sequence of reaction occurs in commercial production of aqueous nitric acid.

4 NH 3 ( g )  5O2 ( g ) 
 4 NO ( g )  6 H 2O (l ) H  904 kJ ...(1)

2 NO( g )  O2 ( g ) 
 2 NO2 ( g ) H  112 kJ ...(2)

3 NO2 ( g )  H 2O (l ) 
 2 HNO3 (aq )  NO ( g ) H  140 kJ ...(3)

Determine the magnitude of total heat liberated (in kJ) at constant pressure for the
production of exactly 1 mole of aqueous nitric acid from NH 3 by this process.
74. A bottle of H 2O2 is labelled as 10 vol H 2O2 . 112 mL of this solution of H 2O2 is titrated
against 0.04 M acidified solution of KMnO4 . The volume of KMnO4 in litre is

75. If X g   X 2   3e , H1  900 kJ and X  X 2   2e  , H 2  650 kJ ; then the

 
g  
g g

value of  eg H of X is:

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