VELAMMAL BODHI CAMPUS - LADANENDAL

JEE/NEET - WORKSHEET

––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
SUB : CHEMISTRY TOPIC : EQUILIBRIUM
––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––––
CHARACTERISTICS OF EQUILIBRIUM INVOLVING PHYSICAL PROCESS :
1. Which of the following is a characteristic of a reversible reaction?
1) It never proceeds to completion
2) It proceeds only in the forward direction
3) The rate of only forward reaction is increased when cata
catalyst
lyst is added
4) Number of moles of reactants and products is the same
2. A chemical change A  B is said to be in equilibrium when:
1) Complete conversion of A to B has taken place
2) Only 10% conversion of A to B is just completed
complete
3) Conversion of A to B is only 50% completed
4) The rate of transformation of A to B is equal to the rate of transformation
trans of B
to A in the system.
EQUILIBRIUM CONSTANT :
1
3. For the reaction C O  g   O 2  g  CO2( g ) , K P / KC is
2
1) RT 2) (RT)-11 3) (RT)-1/2 4) (RT)1/2
4. The equilibrium constants for the reactions Zn( s )  Cu aq   Zn 2 ( aq )  Cu s  and
2

Cu( s )  2 Agaq   Cu2aq   2 Ag s  are K1 and K2 respectively then the equilibrium
constant for the reaction Zn s   2 Ag aq  Znaq2   2 Ag s  will be

1) K1  K 2 2) K1 . K 2 3) K1 / K 2 4) K1  K 2
5. 2 mole each of CH3OH & CH3COOH are taken and heated in the presence of
conc. H2SO4 so that equilibrium is established. If KC for esterfication process is
4, mass of ester present at equilibrium (in gm) is
1) 98.6 2) 56.3 3) 224.0 4) 37.2
6. For the reaction C  s   CO2  g   2CO  g  , the partiall pressures of CO2 and CO
are 2.0 and 4.0 atm respectively at equilibrium. What is the value of KP for this
reaction?
1) 0.5 2) 4.0 3) 8.0 4) 32
7. For the hypothetical reactions, the equilibrium constant(K) values are given

A B ; K1 = 2.0 B C ; K2 = 4.0 C D ; K3 = 3.0

The equilibrium constant for the reaction A D is
1) 48 2) 6 3) 24 4) 12
8. 2 mole of PCl5 is heated in a one litre vessel. If PCl
PC 5 dissociates to the extent of
80%, the equilibrium constant for the dissociation of PCPCl5 is
2
1) 2 10 2) 6.4 3) 0.67 4) 0.32
9. ion of A and B are same for A  B
The initial concentration 3C and when
equilibrium concentrations of B and C are same then KC is
1) 0.25 2) 0.75 3) 0.5 4) 1
1
10. Kp value for 2 SO2 g   O2 g   2 SO3 g  is 5.0 atm-1. What is the equilibrium partial
pressure of O2 if the equilibrium pressures of SO2 and SO3 are equal?
1) 0.2 2) 0.3 3) 0.4 4) 0.1 atm
11.  CaO s   CO2 g  , attainment of equilibrium state is
In the case of CaCO3 s  
noticed with the help of constancy in
1) CaCO3  2) CaO  3) Pressure 4) Colour
12. The equilibrium constants for the stepwise formation of MCl, MCl 2 and MCl3 are
a, b and c respectively. If the equilibrium constant of formation of MCl 3 is K,
which of the following is correct?
1 1 1 1 1 1 1
1) K = a + b + c 2)    3) logk=loga+logb+logc 4) K   
K a b c a b c
13. Initially 0.8mole of PCl5 and 0.2 mole of PCl3 are mixed in one litre vessel. At
equilibrium 0.4mole of PCl3 is present. Then the value of KC for the reaction
 PCl3 g   Cl2 g  , is
PCl5 g  
1) 0.13 mol.lit-1 2) 0.05 mol.lit-1 3) 0.065 mol.lit-1 4) 0.1mol lit-1
14. A mixture of 0.3 mole of H2 and 0.3 mole of I2 is allowed to react in a 10 lit
 2 HI is 64, the amount of unreacted I 2 at
vessel at 5000C. If KC of H 2  I 2 
equilibrium is
1) 0.15 mole 2) 0.24 mole 3) 0.03 mole 4) 0.06 mole
15.  NH 3 g   H 2 S g  , the total pressure at
For the following reaction, NH 4 HS s  
equilibrium is 30 atm. The value of KP is
1) 15 atm2 2) 225atm2 3) 30 atm2 4) 15 atm
16.  2 NO g  at certain temperature is 1.6  10 3 then KP for
KC for N 2 g   O2 g  
1 1
 N 2 g   O2 g  at same temperature will be
NO g  
2 2
1) 25 2) 5 atm 3) 625 4) 1.6  10 3 atm 1

K f 5
17. For A g   B g  
Kb 15
 2 AB g  , KC for
 A g   B g  is
2 AB g  
1
1) 3 2) 3) 3 4) 75
3
18.  CaO s   CO2 g  , reaction in a lime kiln goes to completion because
CaCO3 s  
1) It is a heterogeneous reaction 2) Backward reaction is very slow
3) Kc (or) KP has no units 4) CO2 formed escapes out
19.  PCl3 g   Cl2 g  . If
PCl5 dissociates as follows in a closed reaction vessel PCl5 g  
total pressure at equilibrium of the reaction mixture is ‘P’ and degree of
dissociation of PCl5 is x, the partial pressure of PCl3 will be
 x   2x   x   2x 
1)   P 2)   P 3)   P 4)  P
 x 1 1  x   x  1 1  2 x 
20. For an equilibrium reaction involving gases, the forward reaction is 1 st order
while the reverse reaction is 2nd order. The units of Kp for the forward
equilibrium is:
1) atm 2) atm2 3) atm-1 4) atm-2

2
21. For the reaction,
CuSO4 .5H 2O s  CuSO4 .3H 2O s   2 H 2O g 
Which one is correct representation?
1) K p  p2H 2O  2) Kc = [H2O]2 3) Kp = Kc(RT)2 4) All of these
22. Equilibrium constants K1 and K2 for the following equilibrium are related as:
1
NO g   O2 g  NO2 g  ; K1
2
2 NO2 g  2 NO g   O2 g  ; K 2
1 1 1
1) K 2  2
2) K 2  3) K2  K12 4) K1  2
K1 K1 K2
23. The equilibrium constant of a reaction is 20.0. At equilibrium, the rate constant
of forward reaction is 10.0. The rate constant for backward reaction is
1) 0.5 2) 2.0 3) 10.0 4) 200.0
24. In which of the following reactions K P  K C ?
1) N 2  g   3H 2  g  
 2 NH 3  g  2) H 2  g   I 2  g  
 2 HI  g 
3) PCl3  g   Cl2  g  
 PCl5  g  4) 2 SO3  g  
 2 SO2  g   O2  g 
25. 4 mole of A are mixed with 4 mole of B , when 2 mole of C are formed at
equilibrium according to the reaction, A  B  
 C  D . The equilibrium constant is
1) 4 2) 1 3) 2 4) 4
26. XY2 dissociates as XY2  g   XY  g   Y  g  . When the initial pressure is 600mm

of Hg, the total pressure at equilibrium developed is 800mm of Hg. Therefore
pressure of Y at equilibrium is
1) 200 2) 50 3) 100 4) 150
27. A reversible chemical reaction having two reactants in equilibrium. If the
concentration of the reactants are doubled, then the equilibrium constant will
1) also be doubled 2) be halved
3) become one-fourth 4) remain the same
28. At a given temperature, the equilibrium constant for the reactions
1
NO  g   O2  g  
 NO2  g  and 2 NO2  g  
 2 NO  g   O2  g  are K1 and K2
2
respectively. If K1 is 4 × 10 3 , then K2 will be
1) 8  10 3 2) 16  10 3 3) 6.25  10 4 4) 6.25  106
29. Active mass of 96g of O2 contained in 2 L vessel is
1) 16 mol L1 2) 1.5 mol L1 3) 4 mol L1 4) 24 mol L1
30. One mole of ethyl alcohol was treated with one mole of acetic acid at 25o C . 2/3
of the acid changes into ester at equilibrium. The equilibrium constant of this
reaction is
1) 1 2) 2 3) 3 4) 4
o
31. At 250 C the vapour density of PCl5 is 100, calculate the degree of dissociation
at this temperature (M.W of PCl5 = 208.5)
1) 0.4 2) 0.04 3) 0.02 4) 0.2

3
32. Equilibrium constant, K C for the reaction N 2  g   3H 2  g  
 2 NH 3  g  at 500K is
0.061. At a particular time, the analysis shows that composition of the reaction
mixture is 3.0 mol L1 N 2 . 2.0 mol L1 H 2` and 0.5 mol L1 NH 3 . In which direction
does the reaction tend to proceed?
1) At equilibrium 2) forward shift
3) backward shift 4) Cannot be predicted
33. For the equilibrium AB  g  
 A  g   B  g  at a given temperature, the pressure
at which one-third of AB is dissociated is numerically equal to
1) 8 times K p 2) 16 times K p 3) 4 times K p 4) 9 times K p
34. 100g of CaCO3 is taken in a ten lit vessel at 270C. 20% of CaCO3 is found to be
decomposed
CaCO3(s) CaO(s) +CO2(g)
then the value of Kp is ……….
1) 4.926 atm 2) 0.4926 atm 3) 49.26 atm 4) 0.448 atm
35. For a reaction, 2A  g   B  g  3C  g   2 D  g 
initially equal moles of A and B are taken in a 1 lit. vessel. At equilibrium the
concentration of B and D are found to be equal. Then KC is ………….
1) 6 2) 2/3 3) 4/3 4) 3
36. 10 mole of N2 and 8 mole of H2 are taken in a 10 lit vessel. At equilibrium 4 mole
of NH3 is found to be formed. The KC is ………..
1) 1/4 2) 5 3) 1/400 4) 25
37. The values of Kp1 and Kp2 for
1) M P+Q 2) A 2B
ratio of 1 : 8. If the degree of dissociation of M and A are found to be same, then
the ratio of their total pressures P1 and P2 at equilibrium is
1) 32 : 1 2) 1 : 32 3) 1 : 2 4) 2 : 1
38.  C g   D g  is 2.85 at room
The equilibrium constant for the reaction, A g   B g  
temperature and 1.4 102 at 698 K. This shows that forward reaction is
1) Exothermic 2) Endotherimic 3) Unpredictable
4) There is no relationship between H and K
39. 8 mole of a gas AB3, are introduced into a 1.0 dm3 vessel. It dissociates as:
2AB3(g) A2(g)+3B2(g)
At equilibrium, 2 mole of A2 are found to be present. The equilibrium constant of
the reaction is:
1) 2 mol2L-2 2) 3 mol2L-2 3) 27mol2L-2 4) 36 mol2L-2
40. The dissociation equilibrium of a gas AB2 can be represented as,
2AB2(g) 2AB(g)+B2(g)
The degree of dissociation is x and is small as compared to I. The expression
relating the degree of dissociation (x) with equilibrium constant Kp and total
pressure P is:
1)  2 K p / P  4)  2 K p / P 
1/ 2 1/ 3
2) K p / P 3) 2 K p / P
41. A vessel at 1000K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is
converted to CO on addition of graphite. If the total pressure at equilibrium is
0.8atm, the value of K is:
1) 1.8 atm 2) 0.36 atm 3) 0.6 atm 4) 1.4 atm

4
42. A mixture of 2 moles of N2 and 8 moles of H2 are heated in a 2 lit vessel to form
ammonia at equilibrium. At this stage 0.4 moles of N 2 was observed, the
equilibrium concentration of H2 is
1) 3.2M 2) 4M 3) 1.6M 4) 1M
43. CaCO3  s  
 CaO  s   CO2  g 
6400
For this equilibrium it is found that log K p  8  . At T  527 o C .
T K 
1) K p  7.2 105 2) K p  1 3) K p  13.94 103 4) K p  10
1
44.  AB2 g   B2 g  . When the initial pressure of AB3
AB3 g  is dissociates as AB3 g  
2
is 800 torr and the total pressure developed at equilibrium is 900 torr. What
percentage of AB3 g  is dissociated?
1) 10% 2) 20% 3) 25% 4) 30%
45. Match the chemical reactions in Column I with relation between KP and KC in
Column II.
Column – I Column – II
A)  2 NH 3 g 
N 2 g   3H 2 g   1) K p  KC
B) 2 SO2  g   O2  g  
 2 SO3  g  2) K p  KC /  RT 
2

C) PCl5  g  
 PCl3  g   Cl2  g  3) K p  K C /  RT 
D) H 2  g   I 2  g  
 2 HI  g  4) K p  K C  RT 
Codes :
A B C D A B C D
1) 1 4 2 3 2) 4 1 3 2
3) 2 3 4 1 4) 3 4 1 2
46. o
 2 SO2 g   O2 g  is 0.65. Then its
At 27 C , the Kp value for the reaction, 2 SO3 g  
Kc is_________ [R = 0.082 L.atm/mol.K]
1) 1 2) 0.65 3) 0.2 4) 0.026
47. For the reaction, A  B  3C . At 25 C a 3L vessel contains 1, 2 & 4 mole of A,
o

B and C respectively. Predict the direction of reaction if K c for the reactin is 10.
1) Backward 2) Forward 3) Equilibrium 4) Any direction
48. Inversion of cane sugar is based on hydrolysis
 C6 H12O6  C6 H12O6
C12 H 22O11  H 2O 
sugar Glucose Fructose
If at 400K, equilibrium constant is found to be 2  1014 then, the value of  G o will
be  R  8.314  10 3 kJmol 1 , log 2  0.301
1) 109.53 kJ mol 1 2) 109.53 kJ mol 1 3) 180.56 kJ mol 1 4) 180.56 kJ mol1
49. For the reaction N 2  3H 2   2 NH 3 in vessel, after the addition of equal number
of moles of N2 and H2 equilibrium state is formed. Which of the following is
correct at equilibrium.
1) [H2] = [N2] 2) [H2] < [N2] 3) [H2] > [N2] 4) [N2] =[H2] =[NH3]
50. A vessel of one litre capacity containing 1 mole of SO3 is heated till an
equilibrium state is attained. 2 SO3  g  
 2 SO2  g   O2  g  . AT equilibrium 0.4
moles of SO2 has formed. The value of equilibrium constant is
1) 0.04 2) 0.06 3)0.09 4) 0.12

5
51.  2 NO2 ; K C  4 . This reversible reaction is studied graphically as shown
N 2O4 
in the given figure. Select the correct statements out of I, II and III.
I. Reaction quotient has maximum value at pointpoin A.
II. Reaction proceeds left to right at a point when  N 2O4    NO2   0.1M .
III. K C  Q when point D or F is reached.

1) Both I and II 2) Both II and III 3) Both I and III 4) I, II and III
52. 
For the reaction, H 2 S  g   I 2  s   2 HI  g   S  s  equilibrium concentrations
concentration of
H2S is 0.25M and HI is 0.5M, then value of KC is
1
1) 1 2) 0.25 3)0 4)
2
is K P  K C  RT  . What is the
n
53. We know that the relationship between KC and KP
value of n for the reaction. CaCO3  s  
 CaO  s   CO2  g  ?
1) 1 2) 0.5 3) 1.5 4) 2
54. Consider the given reaction,
 2 NH 3  g 
N 2  g   3 H 2  g  
Whichich of the following is correct correct,, if the total pressure at which the equilibrium is
established is decreased without changing the temperature?
1) K will decrease 2) K will increase
3) K will increase initially and decrease when pressure is very high
4) K will remain the same
 NH 3  . The
2

55.  2 NH 3 g  is given by Q 

The reaction quotient Q for N 2 g   3H 2 g  
 N 2  H 2 
3

reaction will proceed in backward direction, when

1) Q  K C 2) Q  K C 3) Q  K C 4) Q  0
56. In which case does the reaction go farthest to completion :
1) K  1 2) K  1010 3) K  10 10 4) K  10 4
57. According to van’t Hoff equation, K varies with temperature as
K H  1 1 K H  1 1
1) log 2      2) log 1     
K1 2.303 R  T1 T2  K2 2.303 R  T2 T1 
K1 H  1 1 K2 H  1 1
3) log     4) log    
K2 2.303 R  T2 T1  K1` 2.303 R  T1 T2 

LECHATELIER’S PRINCIPLE :
 2SO3 , H  QKJ as per Lechatelier’s principle which of the
58. For 2SO2  O2 
following changes favours forward reaction yielding more SO3
A) Adding more O2 B) Removing SO3
C) Applying high P D) Usage of catalyst
1) A, B, C & D 2) A, B & D 3) A & D 4) A, B & C
6
59. Exothermic formation represented by equation
Cl2  g   3 F2  g  2ClF3  g  , H  339 KJ . Which of the following will
increase the quantity of ClF3 in equilibrium mixture?
1) Increasing temperature 2) Removing Cl2
3) Increasing volume of Vessel 4) Adding F2
60. Assertion (A): Introduction of catalyst does not affect position of equilibrium.
Reason (R) : For a reversible reaction, presence of a catalyst influences both
forward & backward reaction to same extent.
1) Both A & R are correct and R is correct explanation of A.
2) Both A & R are correct but R is not correct explanation of A.
3) A is correct and R is incorrect 4) Both A and R are incorrect
61. Inert gas has been added to the following equilibrium system at constant
volume.
1
 SO3 g  . Then to which direction will the equilibrium shift?
SO2  g   O2 g  
2
1) Forward 2) Backward 3) No effect 4) Unpredictable
62. The yield of product in the reaction 2 A g   B g    2C g   QKJ would be higher at
1) Low temperature and low pressure
2) High temperature and high pressure
3) Low temperature and high pressure
4) High temperature and low pressure
63. What would be the effect on addition of CaCO3 on the equilibrium of
CaCO3 CaO s   CO2 g  In a closed container.
1) conc. of CO2 increases 2) conc. of CO2 decreases
3) remains unaffected 4) cannot be predicted
64. In the system, CaF2 s  Ca2 aq  2F  aq
Increasing the concentration of Ca2+ ions 4 times will cause the equilibrium
concentration of F  ions to change to:
1) 1/4 of the initial value 2) 1/2 of the initial value
3) 2 times of the initial value 4) None of the above
65. C  s   H 2O  g  
 H 2  g   CO  g 
What will be the effect of increase in pressure on the above equilibrium process?
1) Remains unaffected 2) It will go in backward direction
3) It will go in forward direction 4) Unpredictable
66. For the reaction,
PCl5(g) PCl3(g)+Cl2(g)
The forward reaction at constant temperature is favoured by
1) Introducing inert gas at constant volume
2) Introducing chlorine gas at constant volume
3) Introducing an inert gas at constant pressure
4) None of the above
67. Given the following reaction at equilibrium
1
SO2  g   O2  g  
 SO3  g 
2
the addition of inert gas at constant pressure would cause.
1) The formation of more amount of SO3
2) The decomposition of SO3
3) No effect on the equilibrium concentration of SO3
4) The system moves to a new equilibrium position which cannot be theoretically
predicted
7
68. For a reversible reaction, at 250C the KC is 2 103 while at 400C the KC is 5 104
respectively. Then the correct statement is
1) Forward reaction is exothermic 2) H ( Heat of reaction )  0
3) Forward reaction is endothermic 4) In sufficient data.
69. Which of the following is correct regarding the gas solution equilibrium?
1) The solubility of the dissolved gas increases with the increase of pressure and
decrease with increase of temperature
2) The solubility of the dissolved gas increases with the increase of pressure as
well as temperature
3) The solubility of the dissolved gas decreases with the increase of pressure and
increases with the increase of temperature
4) The solubility of the dissolved gas decreases with increase of pressure as well
as temperature
70. The given reaction
H 2  g   I 2  g  
 2 HI  g 
can be made to move in forward direction by
1) Adding H2(g) 2) Adding I2(g) 3) Removing HI(g) 4) All of these
71. The equilibrium will be shifted in the backward direction if
PCl3  g   Cl2  g  
 PCl5  g 
1) PCl3 is added 2) PCl5 is removed
3) Catalyst is added 4) Pressure is reduced
72. Which of the following change will shift the given reaction in the forward
direction?
I 2  g  
 2 I  g  H r0  250 C   100kJ
1) Increase in concentration of I 2) Increase in temperature
3) Decrease in concentration of I 2 4) Increase in pressure
73. In which of the following reactions, the equilibrium will not get affected on
addition of small amount of inert gas at constant volume?
1 1
 HI  g 
1) H 2  g   I 2  g   2) NH 4Cl  s  
 NH 3  g   HCl  g 
2 2
3) N 2O4  g  
 2 NO2  g  4) All of these
74.  water, which of the
When pressure is applied to the equilibrium system, ice 
following phenomenon will happen?
1) More ice will be formed 2) More water will be formed
3) Equilibrium will not be disturbed 4) Water will evaporate

IONIC EQUILIBRIUM :
75. Identify Bronsted-Lowry acids in the reaction given
3 2
 Al  H 2O 6   HCO3 
  Al  H 2O 5  OH    H 2CO3


B   D
A C
The correct answers
1) A, C 2) B, D 3) A, D 4) B, C
76. HCl does not behave as acid in
1) Water 2) Ammonia 3) Benzene 4) Aq. NaOH
77. Which of the following is not a Lewis base
1) C6 H 5 NH 2 2) C2 H 5OH 3) NH 3 4) SnCl4

8
78.  2 NH 3 g   CO2 g  at certain
Equilibrium pressure for NH 4COONH 2 s  
temperature is 0.9 atm. Then, partial pressure of Ammonia at equilibrium (in
atm)
1) 0.9 2) 0.81 3) 0.03 4) 0.6
79. Which of the following failed to explain the relative strength of acids and bases?
1) Arrhenius theory 2) Bronsted theory
3) Lowry theory 4) Lewis theory
80. Strongest conjugate base among the following is
1) NH 2 2) F  3) OH  4) ClO4
81. In aqueous solution, HCl and HNO3 are equally strong. This is because
1) Their basicities are same
2) Both are oxy acids of non-metals
3) Both have lower molecular weights
4) Levelling effect of water
82. In the reaction AlCl3  Cl   AlCl4 , AlCl3 is
1) Lewis acid 2) Lewis base 3) Lewis salt 4) Arrhenius acid
83. The conjugate base of H 2 PO4 is :
1) H 3 PO4 2) H 2 PO4 3) HPO42 4) PO43
84. Which one of the following species acts only as a Bronsted base?
1) H 2 S 2) HS  3) S 2  4) H 2O
85. The Bronsted acid which gives the weakest conjugate base is
1) HF 2) H2S 3) HCl 4) H2O
86. Which of the following is not a base according to Arrhenius concept?
1) NaOH 2) Ca(OH)2 3) Al(OH)3 4) NH3
87. Which of the following cannot act both as Bronsted acid and as Bronsted base?
1) HSO4 2) HCO3 3) NH3 4) HCl
88. Conjugate acid and conjugate base of HSO4 are respectively.
1) H 2 SO4 , SO42  2) SO42 , H 2 SO4 3) HSO4 , SO42 4) SO42 , HSO4

89. The conjugate acid of  Al  H 2O  2  OH  4  is
2
1)  Al  H 2O 1  OH 3   2)  Al  H 2O 3  OH 3  

3)  Al  H 2O 3  OH 2  O   4)  Al  H 2O 3  OH 2  
90. Acidity of AlCl3 can be explained on the basis of which of the following concepts?
1) Arrhenius concept 2) Bronsted-Lowry concept
3) Lewis concept 4) Bronsted-Lowry as well as Lewis concept
91. Which of the following is not a Lewis acid?
1) AlCl3 2) SiF4 3)BF3 4) CCl4
92. Which of the following statements is correct?
(I) Bronsted acids are species which give H+ ions only in aqueous solution.
(II) HCl is an acid according to Arrhenius and Bronsted but not according to
Lewis
(III) NH3 can act as base according to both Bronsted and Lewis
1) I and II only 2) II and III only 3) III only 4) None of these
93. The strongest Bronsted base in the following anion is:
1) CN  2) Cl  3) I  4) Br 
94. Which of these does not act as a Lewis base?
1) F  2) BF3 3) H2O 4) NH3
9
95. The strongest conjugate base is :
1) NO3 2) Cl  3) SO42  4) CH 3COO 
96. Which of the following cannot act both as acid and base (Bronsted)
1) HCO3 2) HCrO4 3) H 2O 4) H 2 PO2
97. Which of the following is relatively stronger lewis acid?
1) BF3 2) BCl3 3) BBr3 4) BI3
98. Which of the following is not a conjugate acid – base pair?
1) H 2 PO4 , HPO42 2) HNO3 , NO3 3) H 3O  , OH  4) NH 4 , NH 3
99. Which of the following is relatively more strong acid in aqueous solution?
1) HClO4 2) H 2 SO4 3) HI 4) All are equally strong
100. Which of the following is relatively strong base?
1) ClO  2) ClO2 3) ClO3 4) ClO4
101. For a weak acid, HA; the dissociation constant is 10 -10. The pkb of its conjugate
base is …………
1) 10 2) 10-4 3) 4 4) 10-10
102. Which of the following fluoro-compounds is most likely to behave as a Lewis
base?
1) BF3 2) PF3 3) CF4 4) SiF4
103. Which of the following is neither bronsted acid nor Bronsted base?
1) HSO4 2) HNO3 3) Br  4) AlCl3
104. The correct order of Lewis acidic strength is
1) BF3  BCl3  BBr3  BI 3 2) BF3  BCl3  BBr3  BI 3
3) BCl3  BI 3  BBr3  BF3 4) BI 3  BBr3  BF3  BCl3
105. The conjugate base of Co( NH 3 )6 
3
is
2 2
1) Co  NH 3 6 OH  2) Co  NH 3 5 OH 
2
3) Co  NH 3 5 NH 2  4) Co  NH 3 6  OH
106. Which of the following is stronger base in aqueous solution?
1) CsOH 2) NaOH 3) RbOH 4) All are equally strong
107. The pH of a given HCl solution is 3.398. To a 10ml of this solution, 30ml of pure
water is added. Then the pH of resulting solution is ……..
1) 4 2) 3.8751 3) 6.98 4) 7.02
108. A 0.01M of weak acid, HX is 1% ionized, then the pH is
1) 4 2) 2 3) 6.96 4) 3
109. The pH of 0.0003M Ba(OH)2 is
1) 10.48 2) 3.523 3) 3.22 4) 9.78
110. The pH of a given solution is 12. Then the number of H+ ions present in 10ml of
that solution is
1) 6  1010 2) 6 1015 3) 6  109 4) 6 1012
111. 100ml of 0.02M H2SO4 and 200 ml of 0.04M NaOH are mixed. Then the pOH of
resulting solution is …….
1) 1.875 2) 2.875 3) 3.875 4) 1.625
112. The pH of a given HCl solution is 5. It is 100 times diluted. Then the pH of
resulting solution is
1) 7 2) 3 3) 3.3 4) 6.96
113. The pH of a 10 M of a strong acid is 2.7. Then the basicity of the acid is
-3

1) 3 2) 2 3) 4 4) 1

10
114. A solution with pH is equal to 8, is 1000 times more acidic than a solution with
pH
1) 5 2) 6 3) 11 4) 12
115. Equal volumes of two samples of HI solutions with pH= 3 and pH =4 are mixed.
Then the pH of resulting solution is
1) 3.5 2) 7 3) 9.5 4) 3.26
116. Which of the following is given in wrong order?
1) F   Cl   Br   I   Basic strength
2) NF3  NCl3  NBr3  NI 3  Lewis basic strength
3) Na   Mg 2   Al 3  Lewis acidic strength
4) H 2O  H 2 S  H 2 Se  H 2Te  Ka

pH SCALE :
117. For which of the following mixture pH is equal to 1:
M M M M
1) 60mL HCl  40mL NaOH 2) 55mL HCl  45mL NaOH
10 10 10 10
M M M M
3) 75mL HCl  25mL NaOH 4) 100mL HCl  100mL NaOH
5 5 10 10
118. For every diprotic acid of the type H2X, how would you relate ionization
constants K a1 and K a2 ?
1) K a1  K a2 2) K a1  K a2 3) K a2  K a1 4) Insufficient data
119. pKa values of four acids are given below at 250C.
The strongest acid is
1) 2.0 2) 2.5 3) 3.0 4) 4.0
120. The correct order of increasing  H 3O  in the following aqueous solution is


1) 0.01M H2S<0.01M H2SO4< 0.01M NaCl < 0.01M NaNO2

2) 0.01M NaCl < 0.01 M NaNO2< 0.01M H2S < 0.01M H2SO4
3) 0.01M NaNO2< 0.01 M NaCl < 0.01M H2S < 0.01M H2SO4
4) 0.01M H2S < 0.01 M NaCl< 0.01M NaNO2< 0.01M H2SO4
121. Among the following:
a) pH of water decreases with increase in temperature
b) pH of water decreases by the addition of base
c) pH or water increases by the addition of acid
d) At any temperature pH of water is equal to p Kw
1) All are correct 2) b, c, d are correct
3) a and d are correct 4) a, b and c are correct
122. The OH   of 0.005 M H2SO4 is
1) 2 1012 M 2) 5 103 M 3) 102 M 4) 1012 M
123. If the ionic product of water is 1.96  10 14 at 350C, its value at 100C is
1) 1.96  10 14 2) 3.92  10 14 3) 2.95  10 15 4) 1.96  10 13
124. Which of the following is relatively stronger base?
1) AOH(pkb=5.8) 2) BOH(pkb=6.8) 3) COH(pkb=2.4) 4) DOH(pkb=10.9)
125. The pH of a solution is 3.602. Its H + ion concentration is
1) 4  10 14 2) 2.5  10 11 3) 2.5  10 4 4) 5.0  10 4
126. Dissociation constant of water at 250C is
1) 1.0  10 14 2) 1.8  10 16 3) 1.0  10 16 4) 14
127. For which of the following pH of the solution is 3?
1) 10-3 M H2SO4 2) 10-3M NaCl 3) 10-3M HCl 4) 10-3M CH3COOH

11
128. The H+ ion concentration of a given solution is 10-10M. Then the pH of the
solution is ______
1) 10 2) 4 3) 6.96 4) 7.02
129. A 0.04 M of an acid, HX is 1% ionised then its pH is _____
1) 1.398 2) 3.398 3) 1.602 4) 3.602
130. The pH of a given HCl solution is 3.523. This solution is diluted by 3 times.
Then the pH of resulting dilute solution is _____
1) 4 2) 6.523 3) 3.823 4) 3.223
131. The dissociation constants of two acids HX and HY are 8  10 2 and 2  10 4
respectively. Then their relative strength respectively is_________
1) 400 : 1 2) 1 : 400 3) 20 : 1 4) 1 : 20
132. Assertion (A) : H3PO4 is stronger acid than HCl.
Reason (R) : H3PO4 is a tribasic acid while HCl is a monobasic acid.
1) Both A & R are correct and R is correct explanation of A.
2) Both A & R are correct but R is not correct explanation of A.
3) A is correct and R is incorrect. 4) A is incorrect and R is correct.
1) HClO4 2) H2SO4 3) HI 4) All are equally strong
133. The pH of 0.01M of a base MOH (Kb = 10 ) is _________ -6

1) 2 2) 12 3) 10 4) 8
134. A solution with pH = 10 is _____ times more acidic than a solution with pH=12.
1) 2 2)1/2 3) 1/100 4) 100
135. The PH of a solution is 10. Then the number of H+ ions present in one ml of that
solution is ______
1) 6.023  1010 2) 6.023  1013 3) 6.03  10 22 4) 6.203  1019
136. 100 mL of 0.2N NaOH is mixed with 100mL 0.1N HCl and the solution is made
1L. The pH of the solution is:
1) 4 2) 8 3) 10 4) 12
137. At certain temperature, the H ion concentration of water is 4  10 7 M then the
+

value of Kw at the same temperature is

1) 10-14M2 2) 2.5  10 13 M 2 3) 1.6  10 13 M 2 4) 4  10 7 M 2
138. What is the hydronium ion concentration of a 0.25M HA solution?  K a  4  108 
1) 10-4 2) 10-5 3) 10-7 4) 10-10
139. Given that KW for water is 10-13M2 at 620C, compute the sum of pOH and pH for
a neutral aqueous solution at 620C
1) 7.0 2) 13.30 3) 14.0 4) 13.0
140. 4.0g of NaOH and 4.9g of H 2SO4 are dissolved in water and volume is made upto
250mL . The pH of this solution is:
1) 7.0 2) 1.0 3) 2.0 4) 12.0
141. A weak base MOH of 0.1N concentration shows a pH value of 9. What is the
percentage degree of dissociation of the base?
1) 0.01% 2) 0.001% 3) 0.1% 4) 0.02%
142. Which of the following has lower pka value?
1) HCl 2) HI 3) HF 4) HBr
143. A 0.1M of weak acid (HX) is 0.1% ionized. Then H  ion concentration is …….M.
1) 101 2) 103 3) 104 4) 107
144. At 250C, the degree of dissociation of water is ………….
1) 107 2) 10 14 3) 1.8 109 4) 3.24 1018
145. The pH of a 0.1M weak acid (HA) is 3. Then the dissociation constant (Ka) of
weak acid (HA) is ……….
1) 105 2) 107 3) 106 4) 108
12
146. The pH of 0.001M of is strong acid is 2.523, then the basicity of the acid is …….
1) 1 2) 2 3) 3 4) 4
147. 20ml of a 0.04M a monobasic acid is completely neutralized by 40ml of given
NaOH solution. Then the pH of given NaOH solution is ……
1) 12.3 2) 12 3) 2 4) 11.7
148. The pH of 0.01M a weak base [MOH] with Kb = 10 is ……………
-6

1) 10 2) 4 3) 2 4) 12
149. 50ml of 0.01M H2SO4 and 50ml of 0.01M KOH are mixed. Then the pH of
resulting solution is
1) 7 2) 0 3) 2.3 4) 11.7
150. Assertion (A): As temperature increases, the pH of water increases.
Reason (R): As temperature increases the degree of dissociation of water
increases.
1) Both A and R are true and R is correct explanation of A
2) Both A and R are true, but R is not the correct explanation of A
3) A is true but, R is false 4) A is false but, R is true
151. The pH of 1.2% (W/V) aqueous solution of CH3COOH at 250C is (pka =4.7)
1) 5.0 2) 9.26 3) 2.7 4) 2.9

HYDROLYSIS OF SALTS :
152. Nature of 0.1M solution of sodium bisulphate is
1) Acidic 2) Alkaline 3) Neutral 4) Amphoteric
153. The hydrolysis constant Kh of a salt of NaOH and a weak acid (HX) if the Ka of
the acid is 2 106 is
1) 5 108 2) 5 10
6
3) 5 10
9
4) 2.5 10
7

154. pKa of a weak acid is 5.76 and pKb of a weak base is 5.25. What will be the pH of
salt formed by the two?
1) 7.255 2) 8.005 3)10.225 4) 4.225
155. the pH of 0.1M solution of the following compounds increases in the order.
1) NaCl < NH4Cl <NaCN< HCl 2) HCl < NH4Cl < NaCl <NaCN
3) NaCN< NH4Cl < NaCl < HCl 4) HCl < NaCl < NH4Cl <NaCN
156. Hydrolysis constant of salt derived from strong acid and weak base is 2  10 5 .
The dissociation constant of the weak base is
1) 5  10 10 2) 5  10 9 3) 5  10 8 4) 2  10 19
157. When a salt of weak acid and weak base is dissolved in water at 250C, the pH of
the resulting solution will always?
1) be 7 2) be greater than 7
3) be has less than 7 4) depend upon Ka and Kb values
158. Upon hydrolysis of sodium carbonate, the reaction takes place between:
1) Ni+ and water 2) Na+ and OH-
2
3) CO3 and water 4) CO32 and H 
159. A weak monobasic acid is half neutralized by strong base. If the pH of the
solution is 5.4, its pKa is:
a) 6.8 2) 2.7 3) 5.4 4) 10.8
160. The pKa value of weak acid HA is 4.80 and the pKb of a weak base BOH is 4.78.
The pH of an aqueous solution of the corresponding salt BA will be
1) 9.22 2) 9.58 3) 4.79 4) 7.01
161. How much sodium acetate should be added to 0.1M solution of CH 3COOH to
give a solution of pH 5.5(pKa of acetic acid is 4.5)?
1) 0.1M 2) 0.2M 3) 1.0M 4) 10.0M

13
  HA  OH  K a  1.0 105 . The degree of
162. In the hydrolytic equilibrium A  H 2O 
hydrolysis of 0.001 M solution of the salt is:
1) 10-3 2)10-4 3) 10-5 4) 10-6
163. Which of the following salts will give highest pH in water?
1) CuSO4 2) FeCl3 3) NaCl 4) Na2CO3
5
164. The ionization constant of ammonium hydroxide is 1.77 10 at 298K. Hydrolysis
constant of ammonium chloride is:
1) 5.65 1012 2) 5.65 1010 3) 6.50 1012 4) 5.65 1013
165. 0.05mole of NaOH is added to 5 litres of water. What will be the pH of the
solution?
1) 12 2) 7 3) 2 4) 10
166. The degree of ionization of an acid HA is 0.00001 at 0.1 M concentration. Its
dissociation constant will be
1)10-7 2) 10-11 3) 10-6 4) 10-7
167. For a polybasic acid, the dissociation constants have a different values for each
step, e.g.,

H3 A H   H 2 A ; K  K a1

H 2 A H   HA2 ; K  K a2

HA2  H   A3 ; K  K a3

What is the observed trend of dissociation constants in successive stages?

1) K a1  K a2  K a3 2) K a1  K a2  K a3
3) K a1  K a2  K a3 4) K a1  K a2  K a3
168. Which of the following does not undergo hydrolysis?
1) NaCN 2) (NH4)2SO4 3) KClO4 4) HCOOK
169. The hydrolysis constant of 0.01M of MX(salt of strong acid, HX and weak base,
MOH) is 10-8. Then the pH of the given solution is
1) 5 2) 6 3)6.96 4) 8
170. The pH values of equimolar solutions of CH3COONa is pH1, CH3COONH4 is pH2,
NH4Cl is pH3 and NaOH is pH4. Then the correct order is
1) pH4> pH1> pH2> pH3 2) pH1> pH4> pH2> pH3
3) pH1> pH2> pH4> pH3 4)pH4> pH2> pH1> pH3
171. For which of the following, pH of aqueous solution does not depend on its
concentration?
1) CuSO4 2) ZnCl2 3) CH3COOK 4) NH4CN
172. The pH of aqueous solution of ZnCl2 is
1) 7 2) < 7 3) > 7 4) 0
173. HA is a weak acid [Ka = 10-4] and BOH is a weak base [Kb =10-5]. BA is the salt
formed from them, in the aqueous solution of BA.
1)  H    107 2) pH  7 3) K h  10 5 4) All

BUFFER SOLUTIONS :
174. An aqueous solution at room temperature contains 0.1M NH4Cl and 0.01M
NH4OH(pKb = 5), the pH of the solution is:
1) 7.5 2) 6.8 3) 6.5 4) 8.0

14
175. Which of the following mixture acts as buffer solution?
1) 100ml 0.2M CH3COOH  100ml 0.1 M NaOH
2) 100ml 0.1M CH 3COOH  100ml 0.2 M NaOH
3) 100ml 0.2M CH3COOH  100ml 0.2 M NaOH
4) None of the above acts as buffer solution due to the presence of strong base,
176. When 0.1 mole of an acid is added to 2 lit of a buffer solution the pH of the
buffer decreases by 0.5. The buffer capacity of the solution is
1) 0.6 2) 0.4 3) 0.2 4) 0.1
177. 4 moles of NH4OH and 1 mole of H2SO4 are mixed and diluted to 1 lit solution.
The pKb of NH4OH is 4.8. the pH of solution is
1) 4.8 2) 8.4 3) 9.2 4) 9.5
178. 2g of NaOH per 250ml of solution is added to a buffer solution of buffer capacity
0.2. Then the change in pH is
1) 1 2) 1.5 3) 0.5 4) 2.0
179. A buffer solution contains 0.02M weak acid, HX and 0.04M X  . Ka of HX is 10-5.
Then the pH is ____
1) 5.3 2) 4.7 3) 2.8 4) 3.1
180. A buffer solution contains 100 ml of 0.06M NH 4Cl and 50ml of 0.02M
NH 4OH  Kb  2 105  . Then the pH of the buffer solution is _____
1) 5.478 2) 8.522 3) 5.177 4) 8.823
181. Buffer capacity of acid buffer solution is more when.
A) pka = pH B) [Salt] = [Acid] C) pka =7 D) [H +]=pka
1) All are correct 2) B, C and D are correct
3) A and B are correct 4) C and B are correct
182. The pH of a solution obtained by mixing 100mL of 0.2M CH 3COOH with 100mL
of 0.2M NaOH would be: (Given :pKa for CH3COOH=4.74)
1) 4.74 2) 8.87 3) 9.10 4) 8.57
183. One litre of a buffer solution containing 0.01M NH 4Cl and 0.1M NH4OH having
pKb of 5 has pH of:
1) 10 2) 9 3) 4 4) 6
184. In a mixture of a weak acid and its salt, the ratio of concentration of acid to salt
is increased ten-fold. The pH of the solution _____.
1) Decreases by one 2) Decreases by one-tenth
3) Increases by one 4) Increases tenfold
185. The dissociation constant of a weak acid is 1104 . In order to prepare buffer
solution with pH=5, the [salt]/[acid] ratio should be
1) 1 : 10 2) 4 : 5 3) 10 : 1 4) 5 : 4
186. Which of the following pairs of solution is not an acidic buffer?
1) HClO4 and NaClO4 2) CH3COOH and CH3COONa
3) H2CO3 and Na2CO3 4) H3PO4 and Na3PO4
187. When a buffer solution of CH3COOH and CH3COONa is diluted with water:
1) CH 3COO  ion concentration increases
2) H  ion concentration increases
3) OH  ion concentration increases
4) H  ion concentration does not change
188. The buffer solution responsible in maintaining the pH of blood around 7.4 is
1) CH 3COO   CH 3COOH 2) H 2CO3  HCO3
3) NH 4OH  NH 4 4) H 3O  CO32

15
189. The buffer capacity of a buffer containing an acid (Ka=10-5) will be highest when
its pH is equal to
1) 4 2) 5 3) 9 4) 10
190. A solution of equimolar concentrations of NH4OH and NH4Cl has pH, 9.25. Then
the pKb of NH4OH is ……………
1) 4.75 2) 9.25 3) 3.75 4) 8.25
191. A buffer solution contains 1 litre of 0.6M NH 4Cl and 0.4M NH4OH [pKb=4.75]. If
0.2 mole of HCl is added to this solution, then the pH of resulting solution is …
1) 4.926 2) 9.074 3) 8.648 4) 5.352
192. When 0.2 mole of NaOH is added to given 100ml of buffer solution then pH
changes from 9.18 to 9.20. Then the buffer capacity is
1) 10 2) 100 3) 1 4) 1000
193. Which of the following does not act as buffer?
1) 0.01M CH3COOH + 0.01M CH3COONa 2) 0.02M NH4Cl + 0.01M NH4OH
3) 0.04M CH3COOH + 0.01M NaOH 4) 0.02M NH4OH + 0.03M HCl
194. The pKa of HCN is 9.3. The pH of a solution prepared by mixing 2.5 moles of
HCN and 0.25 moles of KCN in water and making of the total volume to 500ml
is
1) 9.3 2) 7.3 3) 10.3 4) 8.3
195. A solution contains 400ml of 0.02M weak acid (HX) and 500ml of its salt, NaX
with 0.08M. Ka of HX is 10-5. Then the pH of resulting solution is ………
1) 5.7 2) 5.3 3) 3.3 4) 7.7

SOLUBILITY OF SPARINGLY SOLUBLE SALTS AND K SP :

196. Pure NaCl is prepared by saturating a cold saturated solution of common salt in
water with HCl gas. The principle used is
1)Law of mass action 2) Displacement law
3) Common ion effect 4) Fractional distillation
197. The solubility of calcium phosphate in water is x mol L -1 at 250C. Its solubility
product is equal to
1) 108 x2 2)36x3 3)36 x5 4) 108 x5
198. In which of the following, the solubility of AgCl will be maximum?
1) 0.1 M AgNO3 2) Water 3) 0.1M NaCl 4) 0.1M NaBr
199. The least soluble compound (Salt) of the following is
1) CsCl ( K sp  1012 ) 
2) HgS K sp  11052 

3) PbCl2 K sp  1.7 10 5
 4) ZnS  K sp  1.2 10 23

200. The solubility of CaF2 is 2 104 mole.litre. Its solubility product is
1) 2.0 104 2) 4.0 108 3) 4  8.0 1012 4) 3.2 104

201. The solubility product of BaSO4 of 180C is 1.6  10 . Its solubility (mole.lit-1) at
9

the same temperature is

1) 1.6  10 9 2) 4  10 5 3) 4  10 9 4) 1.6  10 5
202. pH of a saturated solution of Ba(OH) 2 is 12. The value of solubility product (ksp)
of Ba(OH )2 is
1) 3.3  10 7 2) 4.0  10 6 3) 5.0  10 6 4) 5.0  10 7
203. The molar solubility of PbI2 in 0.2M Pb(NO3)2 solution in terms of solubility
product (Ksp) is
1) (Ksp/0.2)1/2 2) (Ksp/0.4)1/2 3) (Ksp/0.8)1/2 4) (Ksp/0.8)1/3
204. Ksp of Zr3(PO4)4 in terms of solubility (S) is:
1) 108 S7 2) 4 S3 3) 6912 S7 4) None of these

16
205. Solubility of AgCl in 0.2M NaCl is x and that in 0.1M AgNO 3 is y, then which of
the following relation is correct?
1) x = y 2) x > y 3) x < y 4) Data insufficient
206. The solubility of a salt of weak acid (AB) at pH=3 is Y  10 3 mol L1 . The value of Y
is (given that the value of solubility product of AB(Ksp) = 2 1010 and the value of
ionization constant of HB  K a   1 108 )
1) 4.47 2) 5.02 3) 3.37 4) 5.47
9
207. The solubility product of BaSO4 is 1.5 10 . The precipitation in a 0.01M Ba2+
ions solution will start on adding H2SO4 of concentration:
1) 10-9M 2) 10-8 M 3) 10-7 M 4) 10-6M
208. The solubility product of a salt A2B is 4 109 . Its solubility would be:
1) 4 102 M 2) 2 104 M 3) 1104 M 4) 1103 M
2
209. If the concentration of CrO4 ions in a saturated solution of silver chromate is
2  104 , solubility product of silver chromate will be:
1) 4 108 2) 8 1012 3) 16 1012 4) 32 1012
210. The solubility product of AgCl is 4.0 1010 at 298. The solubility of AgCl in 0.04M
CaCl2 will be:
1) 2.0 105 M 2) 1.0 104 M 3) 2.2 104 M 4) 5.0 109 M
211. When equal volumes of the following solutions are mixed, precipitation of
AgCl  K sp  1.8 1010  will occur only with.
1) 10 4 M Ag   10 4 M Cl  2) 10 5 M Ag   10 5 M Cl 
3) 10 6 M Ag   10 10 M Cl  4) 10 10 M Ag   10 10 M Cl 
212. Which of the following metal sulphide will precipitate first by passing H 2S gas
through their salt solution?
1) PbS  K sp  8  1028  2) ZnS  K sp  1.6 1024 
3) CdS  K sp  8  1027  4) CuS  K sp  6.3  1036 
213. The solubility product of BaCl2 is 32  10 9 . What will be its solubility in mol L-1?
1) 4  10 3 2) 3.2  10 9 3) 2  10 3 4) 1 109
214. A solution containing Mn 2  , Fe 2  , Zn 2  and Hg 2 with a molar concentration of
10-3M each is treated with 10-16M sulphide ion solution. Which ions will
precipitate first if Ksp of MnS, FeS, ZnS and HgS are 10-15, 10-23, 10-20 and 10-54
respectively.
1) FeS 2) MnS 3) HgS 4) ZnS
215. The KSP values of two sparingly soluble salts AB and AB2 are respectively 10-10
and 4  10-12. Then which of the following is correct?
1) AB is more soluble than AB2
2) AB2 is more soluble than AB
3) Both AB and AB2 are equally soluble
4) Both AB and AB2 are insoluble in given solvent
216. The Ksp of a sparingly soluble salt, AB3 is 2.7  10-11. Then the weight of
AB3(MW = 200u) that can be dissolved in 1 lit of soluble is ……….. g.
1) 2 2) 20 3) 10 4) 0.2
10
217. If the solubility product of MOH is 110 M . Then the pH of its aqueous
2

solution will be
1) 11 2) 9 3) 13 4) 5

17
 218. The precipitate of CaF2(Ksp =1.7  10-10) is obtained when equal volumes of the
following are mixed?
1) 10 4 M Ca 2  10 4 M F  2) 10 2 M Ca 2  10 3 M F 
3) 10 5 M Ca 2   10 3 M F  4) 10 3 M Ca 2   10 5 M F 

********

ANSWER KEY
S.No. Ans S.No. Ans S.No. Ans S.No. Ans S.No. Ans S.No. Ans S.No. Ans S.No. Ans S.No. Ans
1 1 26 1 51 2 76 3 101 3 126 1 151 3 176 4 201 2
2 4 27 4 52 1 77 4 102 2 127 3 152 1 177 3 202 1
3 3 28 3 53 1 78 4 103 4 128 1 153 3 178 1 203 4
4 2 29 2 54 4 79 4 104 2 129 2 154 1 179 1 204 3
5 1 30 4 55 3 80 1 105 3 130 2 155 2 180 2 205 3
6 3 31 2 56 2 81 4 106 4 131 1 156 1 181 3 206 1
7 3 32 2 57 4 82 1 107 1 132 4 157 4 182 2 207 4
8 2 33 1 58 4 83 3 108 1 133 3 158 3 183 1 208 4
9 2 34 2 59 4 84 3 109 1 134 4 159 3 184 1 209 4
10 1 35 1 60 1 85 3 110 3 135 1 160 4 185 3 210 4
11 3 36 4 61 3 86 4 111 1 136 4 161 3 186 1 211 1
12 3 37 3 62 3 87 4 112 4 137 3 162 1 187 4 212 4
13 1 38 1 63 3 88 1 113 2 138 1 163 4 188 2 213 3
14 4 39 3 64 2 89 2 114 3 139 4 164 2 189 2 214 3
15 2 40 4 65 2 90 3 115 4 140 1 165 1 190 1 215 2
16 1 41 1 66 3 91 4 116 2 141 1 166 2 191 3 216 4
17 3 42 3 67 2 92 2 117 3 142 2 167 1 192 2 217 2
18 4 43 2 68 3 93 1 118 3 143 3 168 3 193 4 218 2
19 3 44 3 69 1 94 2 119 1 144 3 169 1 194 4
20 1 45 3 70 4 95 4 120 3 145 1 170 1 195 1
21 4 46 4 71 4 96 4 121 3 146 3 171 4 196 3
22 1 47 1 72 2 97 4 122 4 147 1 172 2 197 4
23 1 48 2 73 4 98 3 123 3 148 1 173 4 198 2
24 4 49 2 74 2 99 4 124 3 149 3 174 4 199 2
25 2 50 3 75 3 100 1 125 3 150 4 175 1 200 3

18