09-10-2024

6001WPE408574240002C PF

CHEMISTRY

SECTION-A

1) SbCl3 and BiCl3 on hydrolysis gives:

(1) Sb+3 and Bi+3

(2) Sb(OH)3 and Bi(OH)3
(3) SbOCl and BiOCl
(4) None of these

2) What is the difference between bond angles in cationic species of PCl5 and PBr5 in solid sate?

(1) 60°
(2) 109° 28'
(3) 0°
(4) 90°

3) Which of the following halides cannot be hydrolysed easily?

(P) TeF6 (Q) SF6
(R) NCl3 (S) NF3
Choose the correct code.

(1) R and S
(2) P, Q and R
(3) P, Q and S
(4) Q and S

4) Which metal will give nitrous oxide by cold and dil. HNO3?

(1) Zn
(2) Cu
(3) Pb
(4) Ag

5) The most stable compound is :

(1) PbF4
(2) PbCl4
(3) PbBr4
(4) BiCl5
6) First compound of inert gases was prepared by scientist Neil Bartlett in 1962. This compound is:

(1) XePtF6
(2) XeO3
(3) XeF6
(4) XeOF4

7)
When this equation is balanced correctly with the smallest integer coefficients, what is the
coefficient for H+?

(1) 1
(2) 6
(3) 8
(4) 16

8)
What is the coefficient for OH– when this equation is balanced with the smallest integer coefficients?

(1) 2
(2) 3
(3) 4
(4) 6

9) The reaction that does not produce nitrogen is :

(1) heating (NH4)2Cr2O7

(2) NH3 + excess of Cl2
(3) heating of NaN3
(4) heating of NH4NO3

10) Chlorine water on standing loses its colour and forms:

(1) HCl and HClO2

(2) HCl only
(3) HOCl and HOCl2
(4) HCl and HOCl

11) 20 mL of H2O2 after acidification with dilute H2SO4 required 30 mL of KMnO4 for complete
oxidation. The appproximate strength of H2O2 solution (in g/L) is : [Molar mass of H2O2 = 34]

(1) 2 g/L
(2) 4 g/L
(3) 8 g/L
(4) 6 g/L

12) Dichloroacetic acid (CHCl2COOH) is oxidised to CO2, H2O and Cl2 by 600 meq of an oxidising
agent. Same amount of acid can neutralize how many moles of ammonia to form ammonium
dichloroacetate:

(1) 0.0167
(2) 0.1
(3) 0.3
(4) 0.6

13)

What is the atomic mass of a metal whose specific heat capacity is cal/gm °C and whose
percentage by mass in its superoxide is 36%?

(1) 57.6
(2) 54
(3) 36
(4) 64

14) In the following converstion of sulphide of phosphorous Equivalent weight

of P4S3 (molecular weight = M) is:

(1)

(2)

(3)

(4)

15) A 25.00 mL sample of 0.1050 M H2SO4 is titrated with a NaOH solution of unknown
concentration. The phenolphthalein endpoint was reached when 17.23 mL of the NaOH solution had
been added. What is the concentration of the NaOH?

(1) 0.07617 M
(2) 0.1447 M
(3) 0.1524 M
(4) 0.3047 M

16) On mixing 15.0 ml of ethyl alcohol of density of 0.792 g ml–1 with 15 ml of pure water at 4°C, the
resulting solution is found to have a density of 0.924 g ml–1. The percentage contraction in volume is:

(1) 8%
(2) 2%
(3) 3%
(4) 4%

17) 100 ml of 0.2 M H2SO4 solution is mixed with 400 ml of 0.05 M Ba3(PO4)2. Calculate the
concentraction of [Ba+2] ion in resulting solution.

(1) 0.08 M
(2) 0.04 M
(3) 0.4 M
(4) 0.8 M

18) 1.4 g of an organic compound was digested according to Kjeldahl's method and the ammonia

evolved was absorbed in 60 mL of H2SO4 solution. The excess sulphuric acid required 20 mL of

NaOH solution for neutralization. The percentage of nitrogen in the compund is:

(1) 3
(2) 5
(3) 24
(4) 10

19) Bleaching powder and beach solution are produced on a large scale and used in several
household products. The effectiveness of bleach solution is often measured by iodometry.
25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4N acetic acid.
In the titration of the liberated iodine, 48 mL of 0.25 N Na2S2O3 was used to reach the end point. The
molarity of the household bleach solution is:

(1) 0.48 M
(2) 0.96 M
(3) 0.24 M
(4) 0.024 M

20) 56 V, 500 ml H2O2 solution is kept in an open container due to which some H2O2 is decomposed
and evolves 8 gm O2, simultaneously some H2O also vapourises. Due to all these changes, final
volume is reduced by 20%. Find final volume strengh of H2O2(aq):
(Assume 1 mole of an ideal gas occupies 22.4 L at STP)

(1) 56 V
(2) 44.8 V
(3) 11.2 V
(4) 33.6 V

21) 300 ml, 2 M H2SO4 solution is mixed with 200 ml, 2 M Ba(OH)2 solution then find final molarity of
sulphate ion in diluted solution, if resulting solution is diluted to 4 times. (BaSO4 formed is
precipitated)
(1) 0.2 M
(2) 0.8 M
(3) 0.3 M
(4) 0.1 M

22) 1.44 grams of Titanium (Ti) reacted with excess of O2 and produced x gram of non-stoichiometric
compound Ti1.44O. The value of x will be : [Ti = 48]

(1) 2.77 g
(2) 3.77 g
(3) 1.77 g
(4) 3.0 g

23) One mole mixture of FeO and Fe3O4 containing equal moles of each on reaction with exess O2
gives n moles of Fe2O3. What is the value of n ?

(1) 1
(2) 2

(3)

(4) None of these

24) A gaseous alkane is exploded with oxygen. The volume of O2 for complete combustion to CO2

formed is in the ratio . The molecular formula of alkane is:

(1) C2H4
(2) C2H6
(3) CH4
(4) C4H12

25) Equal volumes of 0.50 M of HCl, 0.25 M of NaOH and 0.75 M of NaCl are mixed. The molarity of
the NaCl solution is:

(1)

(2)

(3)

(4) 2.00 M

26) There is no hybridisation of the central atom in AsH3 because:

(1) As is of 3rd period element.

(2) The energy gap between 3s and 3p orbital is large enough.
(3) The energy gap between 3s and 3p orbital is sufficiently less.
(4) The energy gap between 4s and 4p orbial is large enough.

27) Which of the following pair of molecular orbital is the pair of degenerate orbital?

(1)
(2)
(3)
(4)

28) The value of which property decrease with an increase in the strength of intermolecular forces?

(1) Viscosity
(2) Boiling point
(3) Surface tension
(4) Vapour pressure

29) Symmetrical cleavage in diborance is given by:

(1) Me2O
(2) C5H5N
(3) MH
(4) All of these

30) Which of the following order is correct with respect to the given property?

(1) HClO < HClO2 < HClO3 < HClO4 (accidic strength)
(2) B2O3 < Al2O3 < Ga2O3 < In2O3 < Tl2O (acidic nature)
(3) F– < Cl– < Br– < I– (basic nature)
(4) H–F < HCl < HBr < HI (thermal stability)

31) For hydrazoic acid, which of the following resonating structure will be least stable? \(\eqalign{
& H - N = \mathop N\limits^ + = \mathop N\limits^ - \leftrightarrow \mathop N\limits^ + - \mathop
N\limits^ - = {N^{2 - }} \leftrightarrow H - \mathop N\limits^ - - \mathop N\limits^ + \equiv N \cr
&
\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(I)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(II)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\
,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,(III) \cr} \)

(1) I
(2) II
(3) III
(4) Both (I) and (III)

32) What is the order of the boiling points (from lowest to highest) for the hydrogen halides?

(1) HF < HCl < HBr < HI

(2) HI < HBr < HCl < HF
(3) HCl < HF < HBr < HI
(4) HCl < HBr < HI < HF

33) Which of the following order of radii is incorrect ?

(1) Sc < Y < La

(2) Ti < Zr Hf
(3) Al Zn
(4) He < Ne < Ar

34) CH3Cl has more dipole moment than CH3F because:

(1) electron affinity of chlorine is greater than that of fluorine.

(2) the charge separation is larger in CH3Cl compared to CH3F.
the repulsion between the bond pairs and non-bonded pairs of electrons is greater in CH3Cl than
(3)
CH3F.
(4) chlorine has higher electronegativity than fluorine.

35) Which has the highest ionization energy for the removal of the second electron?

(1) F
(2) Ne
(3) Na
(4) Mg

36) Which of the following carbide produces different gaseous product as compared to other, when
reacted with water?

(1) Al4C3
(2) CaC2
(3) SrC2
(4) BaC2

37) A silicate mineral having chemical formula Ca2MgxSi8O22(OH)2 and known as tremolite, predict
the value of x:

(1) 3
(2) 4
(3) 2
(4) 5

38) Which of the following metal does not produce NO2 gas as a side product when it reacts with
conc. HNO3?

(1) Sn
(2) Pb
(3) Zn
(4) None of these

39) Which group of atoms have nearly same atomic radius?

(1) Na, K, Rb, Cs

(2) Li, Be, B, C
(3) Fe, Co, Ni
(4) F, Cl, Br, I

40) O3 does not oxidise:

(1) KI
(2) FeSO4
(3) KMnO4
(4) K2MnO4

41) Identify the set of cyclic species, from the following:

I. H5P3O10 II. [B3O3(OH)5]2–
III. H5P5O15 IV. P3N3Cl6

(1) I, III
(2) I, III, IV
(3) II, III, IV
(4) I, II, III, IV

42) When PCl5 is fluorinated in polar solvent, the product formed is

(1)
(2)
(3) Both (A) and (B)
(4) PCl3F2

43) The reaction of sodium nitrate with sodamide result in the formation of

(1) N2O3
(2) N2O4
(3) NaN3
(4) N3H

44) Which of the following process is exothermic?

(1) F–→ F
(2) N → N2–
(3) O → O2–
(4) 2Cl → Cl2

45) The formation of is difficult compared to because:

(1) lone pair of phosphorus is optically inert.

(2) lone pair of phosphorus resides in almost pure p-orbital.
(3) lone pair of phosphorus resides at sp3 orbital.
(4) lone pair of phosphorus resides in almost pure s-orbital.

46) Which of the following parent oxy acid does not have its hypo acid?

(1) H2SO3
(2) HNO2
(3) H3PO3
(4) HClO3

47) The products formed by complete hydrolysis of PCl3 are:

(1) H3PO3 and HCl

(2) POCl3 and HCl
(3) H3PO4 and HCl
(4) H4P2O7 and HCl

48) XeF6 dissolves in anhydrous HF to give a good conducting solution which contains:

(1) H+ and ion

(2) and ions
(3) and F– ions
(4) None of these

SECTION-B

1) The desnity of 3 M sodium thisulphate is 1.25 g/ml. Identify the correct statements among the
following.

(1) % by weight of sodium thisulphate is 37.92.

(2) The mole fraction of sodium thiosulphate is 0.065.
(3) The molarity of Na+ is 2.53 and is 1.25.
(4) contains S–O–S linkage.

2) A 5 L vessel contains 2.8 g of N2 only, when heated to 1800 K, 30% molecules are dissociated into
atoms.

(1) Total no. of moles of N in the container will be 0.12.

(2) Total no. of molecules in the container will be close to 0.421 × 1023
(3) Total no. of moles in the container will be 0.098
(4) Pressure in the container decreased.

3) The density of air is 0.001293 g/cm3 at 1 atm and 273 K. Idenify which of the following satement
is correct ?

(1) Vapour density is 14.48.

(2) Molecular weight is 28.96.
(3) Vapour density is 0.001293 g/cm3.
(4) Vapour density and molecular weight cannot be determined.

4) x mol of oxalate FeC2O4. Fe2(C2O4)3 . 2H2O on reaction with Al2(Cr2O7)3 requires 500 mL 0.4 M of it.
Select the correct statement(s).

(1) n-factor of Al2(Cr2O7)3 is 6.

(2) n-factor of Al2(Cr2O7)3 is 18.
(3) Mole of oxalate which react with Al2(Cr2O7)3 is 0.4.
(4) Mole of oxalate which react with Al2(Cr2O7)3 is 0.65.

5) A sample containing 1 mol KHC2O4. H2C2O4 is titrated with different reagent. Select correct
statement.

(1) 1 mol of KOH are used.

(2)
moles of Ba(OH)2 are used.

(3)
mole of KMnO4 are used in alkaline medium.

(4)
mol of K2Cr2O7 are used in acidic medium.

6) Select the correct option(s)

(1) The reaction of P4O10 with PCl5 result in the formation of POCl3.
(2) H5P3O10 and diphosphonic acid both contains P–O–P linkage.
Pyrophosphoric acid is prepared by the controlled oxidation of red phosphorous with sodium
(3)
hypochlorite.
The reaction of potassium nitrite with potassium of ferrocyanide in the presence of acetic acid
(4)
result in the formation of a gas having paramagnetic nature.

7) Select the correct one

(1) SF4 act as a both electron donor as well as electron acceptor.

(2) SOCl2 act as a dehydrating agent when it react with FeCl3.6H2O
The reaction of BF3 with ClF result in the formation of compound of boron having tetrahedral
(3)
shape.
(4) Liquid BrF5 Snows appreciable conductivity due to self-ionisation.

8) Which of the following is /are obtained by the alkaline hydrolysis of XeF6 ?

(1) Xe
(2)
(3) O2
(4) XeO4

9) Select the correct one

(1) H3BO3 act as a strong acid in anhydrous H2SO4

(2) The thermal conductivity of diamond is more than graphite.
BaC2 reacts with water to produce ethyne gas where as it react with nitrogen (N2) to form
(3)
barium cyanide (Ba (CN)2)
(4) The C–C bond length in CaC2 is longer than LnC2.

10) Select the correct one

The reaction of Tin with hot aqueous alkali result in the formation of compound of tin having +4
(1)
oxidation state.
The reaction of nitrous acid with hydroxyl amine result in the formation of compound having
(2)
linear shape.
(3) The reaction of BF3 with N2O4 result in the formation of and .
(4) The reaction of N2O5 with I2 result in the formation of a gas with combines directly with lithium.

11) Sn + 2PCl5 → X + 2Y correct statement(s) is/are

(1) oxyacid obtained from the hydrolysis of Y can undergo tautomeric change.
(2) X is soluble in excess of NaOH.
(3) The reaction of Y with SOCl2 result in the formation of PCl5.
(4) Reaction of X with excess of HgCl2 result in first white precipitate and then grey precipitate.

12)

select the correct one

(1) P is a monobasic Lowry Bronsted acid

In the presence of ethylene glycol aqueous solution of P can be satisfactorily titrated with NaOH
(2)
solution
(3) Q Produce a green coloured flame
(4) Q is non volatile
 ANSWER KEYS

CHEMISTRY

SECTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 3 3 4 1 1 1 2 4 4 4 1 2 1 3 4 3 1 4 3 3
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. 4 3 1 2 2 4 3 4 4 1 2 4 3 2 3 1 4 4 3 3
Q. 41 42 43 44 45 46 47 48
A. 3 3 3 4 4 4 1 2

SECTION-B

Q. 49 50 51 52 53 54 55 56 57 58 59 60
A. 1,2 1,2 1,2 2,3 2,4 1,2,3,4 1,2,3,4 1,2,3 1,2,3 1,2,3,4 1,2,3,4 2,3
 SOLUTIONS

CHEMISTRY