Chemical Engineering Thermodynamics MCQ Questions & Answers Chemical Engineering Page-13 Section-2 3
Chemical Engineering Thermodynamics MCQ Questions & Answers Chemical Engineering Page-13 Section-2 3
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61. The amount of heat required to decompose a compound into its elements is
__________ the heat of formation of that compound from its elements.
A. Less than
B. More than
C. Same as
D. Not related to
Answer: Option C
Solution:
Lavoisier and laplace law : the law states that the quantity of heat which must be supplied to decompose a
compound in to its elemental form is equal to the amount of heat evolved during the formation compound from
its element assuming no losses involved during both process.
A. The same
B. Less than
C. Greater than
D. Different than
Answer: Option A
Solution:
Lavoisier and laplace law : the law states that the quantity of heat which must be supplied to decompose a
compound in to its elemental form is equal to the amount of heat evolved during the formation compound from
its element assuming no losses involved during both process.
D. None of these
Answer: Option C
Solution:
Lechalters principle: Actually for an equilibrium reaction on increasing the reactant concentration the
equilibrium shifts towards the right and therefore the reactants gets more dissociated and products
concentration increases but here we are increasing the product (H2 ) concentration so the equilibrium shifts
towards left and increases the formation of 2HI there by decreasing the dissociation of HI.
64. __________ does not change during phase transformation processes like
sublimation, melting & vaporisation.
A. Entropy
C. Internal energy
Answer: Option B
Solution:
Since during phase change the temperature and pressure remains constant we can say the gibbs free energy
remains constant and the relation is given by:
For single component and closed system : dG = V dP − SdT
A. Supersaturated
B. Superheated
C. Both A and B
D. Neither A nor B
Answer: Option B
Solution:
Adiabatic compression means no heat is allowed to transfer so δQ = 0 by first law we can say entire
compression work done is used to raise the fluid internal temperature and hence if enough work is done the
saturated water temperature raises and finally reaches the superheated state.
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