Transiton

elements Chemistry
Cant be oxidized but CO/CO
can be obtained by and H2
oxidation Fe2O3

230 to 300

REDUCTION
O2
OXIDATION

Fe3O4

400 to 700

FeO
O2 >700 Co

Cant be reduced but

can be obtained by

Fe reduction

Dr. Joseph Adel

 Transiton
elements Chemistry
+ O2 / ∆ (COO)2 Fe ∆
in prescence of air
(Steam)
+ H2O / 500oC
Fe3O4 ∆ "Roasting"
+ CO
Fe
FeCO3 in prescence of air >700oc
+ Cl2 / ∆ Or CO + H2
FeCl3 +O2 /∆
Fe3O4

Fe2O3
+CO S(s)
Fe2O3 Higher than 700Co FeS
+ (CO+H2) Fe +O2 /∆
+ CO
400oc -
FeO
+ dil . HCl FeO
FeCl2 700oc

dil . H2SO4 ∆
FeSO4
H2
Conc . H2SO4
FeSO4 +Fe2(SO4)3 +SO2 +H2O Fe(OH)3 >200 Co
230oc -
Fe3O4
∆ 300oc
«K2Cr2O7»
2Fe2O3.3H2O ∆
Roasting
Conc . HNO3
XX Passivity Conc .
H2SO4
Fe2(SO4)3
∆ + O2 / ∆ CO or H2
+O2 Fe2O3 Fe2O3 400o-700oC
+H2O
500oC
+ O2 / ∆
CO or H2
Fe3O4 400o-700oC

+ CO
400o-700oC FeCO3
Fe2O3 +CO
230 - 300oC
o Fe3O4 FeO FeO
+ H2SO4
dil FeSO4
+H2

FeCO ∆ + dil . HCl

Conc . H2SO4
FeSO4 + Fe2(SO4)3 + H2O
FeCO3
3
in absence of
air
FeCl2

∆
Conc . HCl (COO)2 Fe in absence of
FeCl2 + FeCl3 + H2O air

Dr. Joseph Adel