FIITJEE

ALL INDIA TEST SERIES

PART TEST – I

JEE (Main)-2025
TEST DATE: 16-11-2024

ANSWERS, HINTS & SOLUTIONS

Physics PART – A

SECTION – A

1. B
Sol. From conservation of momentum 102 sin 37
4v  3(10 2)cos37
Minimum length required is
 20 2 sin37 
  (10 2 cos37  v)   3 kg
 10 102 cos 37
 
 = 33.6 m
4kg
v
=0

2. A
 30m  60N 60N 20 kg
Sol. Initially spring force is (200 N / m)    60N 30 kg
 100 
Here only 20 kg block will move.
From work energy theorem, when spring attains its
natural length
W sp + W fr = k
1
 kx 2  mgx  k
2
Substituting value we get
k = 0

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 2

3. C
 2
 M    5M2
Sol. 
I   dy    y2   y
0
   12 
 12
dy

4. C
Sol. Speed of particle after 1st collision with wall is
v1  (4  3)  3  10 m/s towards left
nd
Speed of particle after 2 collision with wall is
v 2  (10  6)  22 m/s towards right

5. D
3v  v v 3v
Sol.  
2 
v m
vCM    3v

vCM  2v CM

1 2 1
K.E. mv CM  ICM2
2 2
1 1 (2 )2  v 2  v
 m(2v)2  m  
2 2 12  2 
mv 2 13
 2mv 2   mv 2
6 6

6. D
2
 R   3R 
    3 R3
 
Sol. x cm  4  4   64  3R
2
R 7R2 56
R2  2  
4 8
2
 R   3R 
    
ycm   4   4   3R
2 56
R
R2  2  
4
 3R ˆ ˆ
r  (i  j)
56

7. C
Sol. vbw sin   v w sin 45 vbw vb
5
15 sin  
2
1
 sin   
3 2 45
vw

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 3 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

5 km
Time T 
v w cos 45  v bw cos 
5 2
T 
5 15 7 1 7

2 3 2
 34  2 
T=   hr
 16
 

8. A
Sol. Since net applied force on the block is zero, so frictional force is zero.

9. B
Sol. For block T
T = 14g sin 30 T
T = 7g T
Taking wedge + block
T = kx 14 kg
 x = 7 cm
kx
14 g sin30
30

10. C
1
Sol. x a(n  1)2 …(i)
2
1
y  an2 …(ii)
2
1
x  y  at 2
2
a(n  1)2 an2 at 2
  
2 2 2
 t 2  (n  1)2  n2
 t 2  n2  1  2n  n2
 t 2  2n2  2n  1
 t  2n2  2n  1

11. B

Sol. u1  uiˆ  2ghˆj

v1  v ˆi  2ghˆj
   
u1  v1  u1  v1  0
 uv  2gh  0
uv
h
2g

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 4

12. C
Sol. F = 3T F
2T = mAg
T = 20 N

T T T
From (i) F = 60 N 2T
 20 t = 60
 t = 3 sec mA

mAg

13. A
Sol. mg sin   f N mg cos 
 mg sin   N
 mg sin   mg(1 cos )
sin  mg sin 
  m
1  cos 
f

 cot    
2 mg

14. D
 dv 
Sol. P = Fv = mav = m  v v
 dx 
x v
  Pdx  mv 2 dv

0 x
m 3
 Px 
3

v  u3 
3Px
 v 3  u3 
m
1/3
 3Px 
 v   u3  
 m 

15. C
Sol. Applying work energy theorem
w gr  wN  w fr  k f  ki
0mgcos x 2
 (mgsin )x  0  0
2
2 tan 
 x
0

16. A
mv 3 mu3
Sol. Area under power versus position graph is 
3 3
24 3
2  8  13  (v  1)
3
 v = 3 m/s

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 5 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

17. C
Sol. 0 = mv1 sin 30  mv2 sin 30 v1
 v 1 = v2 m

30
10 m/s m
m
30
Rest

v1

18. D
9.8 2 0.8
Sol. 0.4  t1  t1 
2 9.8
9.8 2 1.8
0.9  t 2  t2 
2 9.8
 required time
t = t2 t1 = 1/7 sec

19. D
g 11
Sol. geff  g   g
10 10
2(3)(1.5)  11g  11g
T 
(4.5)  10  5
 reading of spring balance is
2T
 4.4 kg
g

20. D
F  kx0 kx
Sol. aB  , aA  0
M M
aBA  aB  a A
F  2kx0
 aBA 
M

SECTION – B

21. 5
Sol. When the block breaks of the surface
2
cos  
3
  = MgR sin 
5
= MgR
3

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 6

22. 4
Sol. From COME
1 m 2 2 
  mg (1  cos  ) …(i)
2 3 2
From equation of motion
f 
m 2 
mgcos   N  …(ii)
2
From (i) and (ii)
mg mg
N (5 cos   3)
2
3
N becomes zero when cos   N
5
4
 sin  
5

23. 1
Sol. a A  g, aB  g
aB g
  1
aA g

24. 7
Sol. x = 3
U = 107 J
 5x2  20x + 2 = 107
 x2  4x 21 = 0
 x = 7m, 3m
 x = 7 m is maximum x-coordinate

25. 60
Sol. From conservation of momentum
(1 kg) (9 m/s) = (1 + 3)v
9
 v m/s
4
From conservation of energy
2
1 1 9
mg(1  cos max) = (1kg)(9)2  (4kg)  
2 2 4
 max = 60

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 7 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

Chemistry PART – B

SECTION – A

26. B
Sol.  egHo of Noble gases
He  48 kJ mol1
Ne  116 kJ mol1
Xe  77 kJ mol1
Rn  68 kJ mol1

27. C
Sol. (2p-3d) (3p-2p)

C C
Cl Cl Cl Cl
Cl

CCl 3 Electron rich, i.e. Nucleophile.

CCl 2 Electron deficient, i.e. Electrophile.

28. A
Sol. O O
O
H3Si H3C F 3Si SiF 3 ,
SiH3 , CH3 ,

Backbonding decreases basicity. Lone pair freely available Strong electron withdrawing
group so decreases basicity

29. C
Sol. CN and N2 are isoelectronic species and bond order = 3.
CN and N2 are isoelectronic species and bond order = 2.5.
 Stability of CN > CN and curve shows more decrease in PE.

30. C
Sol. Due to very small size and high inter electronic repulsions the formation of O  g from O  g 
becomes endothermic in nature.
Most of the compounds of oxygen are formed by O  g and it can be explained on the basis of
high lattice enthalpy.

31. B
COO
Sol. FeC2 O 4  Fe    aq   aq 
COO

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 8

Fe    aq   Fe    aq   e

COO
 aq   2CO2  g   2e 

COO

COO
Fe    aq    aq   Fe    aq  2CO2  g  3e

COO
In acidic medium
MnO4  aq  8H  aq   5e   Mn   aq   4H2 O   
5 3
 5FeC2O 4  3KMnO4  12H2SO 4  Fe2  SO4 3  3MnSO 4  K 2 SO4  12H2O  10CO2
2 2
OR
5FeC2 O4  s   3MnO4  aq  24H aq  5Fe   aq  3Mn   aq  10CO2  g  12H2O   
Since 5 mols of FeC2O4 requires 3 mols of KMnO4.
3
So, 3 mols of FeC2O4 requires 3  mols of KMnO4  1.8 mols .
5

32. A
Sol. 

nX  g 
 Xn  g 
Ini. 1 
1 x x 1
Equi. .
V n V

n
x  1 x 
KC  / 
n V  V 
xV n1
KC  n
1  x  .n
n
Since x << 1  1  x   1
xV n 1
KC  … (1)
n
x  1 n 
Total mols at equilibrium (neq) = 1  x   1  x
n  n 
 n  1
neq  1   x … (2)
 n 
Now, PV  neq.RT
PV
  neq
RT
Using (1) and (2)
PV  n  1   nK C 
 1    n1 
RT  n  V 
PV  n  1 K C
 1
RT V n 1

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 9 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

33. D
Sol. Since E    KEmax
h
4.25   x  Tx ,  x 
2me Tx
h
4.20   y  Ty ,  y 
2me Ty
Since, Tx  Ty  1.50
 y  2 x
 x  2.25 eV, Tx  2.00 eV
 y  3.70 eV, Ty  0.50 eV
h
y 
2me Ty
6.6  1034
y 
2  9  10 31  0.5  1.6  10 19
6.6
y   10 9
3  1.6
6.6
y   109
3  1.26
 y  1.746  109 m  1746 pm

34. B
Sol. Let order of the reactin is n.
1 d  X n
  K  X
3 dt
n
   X  d  X   3kdt
n 1
   X d  X  3k  dt  n1
 3kt  C
 n  1  X
1
At t  0,  X   Xo   C  n 1
n  1  Xo 
1 1
 n 1
 3kt  n 1
n  1  X  n  1  Xo 
1 n 1 n
  X   3k  n  1 t   Xo 
Comparing with graph
1  n  3  n  4
1
 3k  n  1  tan 45o  k 
9
1 d  X 4
Rate of the reaction    k  X
3 dt
1 4 16  104
Rate    0.2   Mmin1
9 9
16
Rate   10 4 M min1
9

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 10

35. C
Sol. CH3 COOH  NaOH 


 CH3 COONa  H2O
Ini. 600  2  1200 milim oles x milim oles  
Final 1200  x  milimoles  x milim oles x milim oles
For acidic buffer

pH  pK a  log
Salt 
 Acid
and for maximum buffer capacity [Salt] = [Acid]
 x  1200  x
 x  600milimoles
600
 WNaOH   40  24 g
1000
36. A
 2
Sol. OCO  1
 X  2
C N
 8
N C C C N   1
 8
C N
Y
H
H H
 12
  4
 3
H H
H
 Z
H H
H H
 9
C C C C    4.5
 2
H H
W 
  X   Y    Z   W 

37. C
2 2 2 2 2 2 2
Sol. N2   1s   1s    2s    2s    2px     2p y    2pz 
1
For N2  Bond order   9  4   2.5 and paramagnetic.
2
1
For N2  Bond order  10  5   2.5 and paramagnetic.
2
So, BO N2   BO N2 
But stability of N2 > Stability of N2
(Due to more number of electron(s) in ABMO in case of N2 )

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 11 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

38. C


 Y  Y  K X
Sol. X 
 Y  K1    1 
 X


 Z  Z  K X
X 
 Z  K2    2 
 X
 Xeq
Now, mole fraction of ‘X’ at equilibrium 
 Xeq   Y eq   Zeq
 Xeq 1
 
 Xeq  K1  Xeq  K 2  Xeq 1  K1  K 2

39. B
Sol. 

2XY  g 
 2X  g  Y2  g 
Ini. Po  
Equi. Po  2x 2x x
Po  2x  2x  x  P
P 8P P
Po   P  Po  as x 
9 9 9
2 1
 X  g   Y2  g
 KP   2
 XY  g 
2
 2P   P 

 2x   x  9   9 
2

KP  2
 2
Po  2x   8P  2P 
 9 9 

4P2  P 36P2 P
KP  / 2 
92  9 9 81
KP 1
 
P 81

40. C
n3
Sol. Tn 
Z2
33 23
 TLi  THe 
32 22
TLi 3 t 3
  
THe 2 THe 2
2
THe  t s  0.66t s
3

41. C
Sol. B  801 kJmol1
Al  577 kJmol1
In  558 kJmol1

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 12

Ga  579 kJmol1
T  589 kJmol1

42. A
Sol. x o  101o
y o  79o
zo  118o

43. D
Sol. NO3  aq  NO  g 
5 2
As2 S3  s   AsO34  aq   SO4   aq
 3  2   5   6 
Net increase in oxidation state = 2 × 2 + 3 × 8 = 28
Net decrease in oxidation state = 3
Net increase = Net decrease
28NO3  aq  3As2 S3  s   4H2 O     6AsO34  aq  28NO  g  9SO4  aq   8H  aq
 x  28, y  3, z  4
 x  y  z  28  3  4  35

44. A
Sol. 

4
Ag4 Fe CN 6   s  
 4Ag  aq  Fe  CN 6 

 aq
 4s s
4 1
K SP   4s   s 
K SP  256 s5
K SP 4
s 5 = Molarity of Fe  CN6  in saturated solution.
256

45. A
Sol. k  Ae Ea /RT
Ea
 nk  nA 
RT
d d d E 
 nk   n  A    a 
dT dT dT  RT 
d  nk  Ea
  … (1)
dT RT 2
z
Now, nk  x  ynT 
T
d  nk  y z
  
dT T T2
d  nk yT  z
  … (2)
dT T2
From (1) and (2)
Ea yT  z
2
  Ea  yRT  zR
RT T2

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 13 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

SECTION – B

46. 99
h h
Sol.     1 2 5
2 2
    1  2 5
    1  20
4
x = Number of orbitals = 2  1  9
 11x  11  9  99

47. 120
Sol. X  
 Y   Z g
t0 Ro   
t  Ro   Ro 
Ro   80 … (1)
X  
 Y   Z g
t0 Ro   
t  40 Ro  x  x x
x  40
 Ro  x   40 … (2)
X  
 Y   Z g
t0 Ro   
t  40 Ro  y  y y
y  70
 Ro  y   10 … (3)

Now, from Eq. (2) 

1
n
Ro 
40 Ro  x 
1 80 1
K n  n2
40 40 40

From, Eq. (3) 

1 1
n2  n
R o 
40 t Ro  y 
1 1 80 3
n2  n  n2
40 t 10 t
t = 120 min.
48. 4
Sol. Since G  Go  RT nQC
 G  RTnK eq  RTnQC
QC
 G  RTn
K eq

 G  RTn
 Z  K b
 X Y  K f

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 14

rb 1
 G  RTn  RTn 4  4RT
rf e
 x  G  4RT  4  2  300  2400 cal.
x 2400
  4
600 600

49. 8
Sol. H   H 
HX HY

 C  1.8  10 5  0.6  2.4  104

0.6  2.4  10 4
C  0.8  10  8
1.8  105
C=8M

50. 2
Sol.  MO4  Mx 
MO2  MO 2 
 4   4   7   x 
Net increase = 3, Net decrease = (4 – x)
Net increase = Net decrease
 4  x  MO2  3MO2    4  x  MO4  3x 
 
 Oxidation part  Re duction part 
4x 2
Now, 
3 3
x2

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 15 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

Mathematics PART – C

SECTION – A

51. B
Sol. Total function = 54 = 625
5
Total one-one function = C4  4!
= 5  24 = 120
Total many-one function = 625  120 = 505

52. A
Sol. From Venn diagram
n(C  B) = 34, n(C  A) = 35
n(A  B  C) = 1
 n(C  B) + n(C  A) + n(A  B  C) = 70

53. D
Sol. It is given that the subset must have exactly one element from A, B and C. Say {1, 4, 7} is one
such subset. If cannot include any number from {2, 3, 5, 6, 8, 9} only number left is 10.
So, there are two possible combinations {1, 4, 7} and {1, 4, 7, 10}.
Similarly we can have 3  3  3 = 27
Such combination from A, B and C. For each there are two possibilities.
Hence total number of subsets = 27  2 = 54

54. C
Sol. R is not reflexive as (2, 2)  R, (3, 3)  R. Also R is not transitive as (2, 1)  R and (1, 2)  R but
(2, 2)  R. However R is symmetric.

55. D
Sol. From analysis of the graph of f(x), we observe that f(x) = 6 has 2 real and distinct solutions.

56. D
lim  f  x  1g x 
Sol. Applying e x  a

57. D
Sol.
h(x)

x
4 2 O 2 4

From the graph of h(x) we can observe.

58. B
Sol. Here, g(x) is an odd function, so, g() + g() = 0
Also, g(x) is monotonically increasing function so, if  +  > 0
>
 g() > g()
 g() + g() > 0

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 16

59. C
Sol. The given differential can be written as
2y dy y2 1 1
2
 2
 3
1  y 2  dx 1  y x x
y2 2y dy dz
Put z = 2
 2

1 y 1  y  dx dx
2

dz z 1
   3 which is linear in z, after solving, we get
dx x x
2 2 2
x y = (cx  1) (1  y )

60. D
1 2 n
Sol. En  2
 2
 ..... 2
n n2 n n4 n  n  2n
1 2 n 1
Now, 2  2  .......  2 < En < 2 (1 + 2 + ….. + n)
n  3n n  3n n  3n n n2
1 1
  lim En 
2 n  2

61. B
Sol. Let (3, ) be the point on y = h(x)  (, 3) lies on y = f(x)   = 1
Also, x = f(h(x))
1 1 1
 h(3) =  
f   h  3   f  1 4
slope of normal at x = 3 is 4
Equation of normal
y  1 = 4(x  3)
 y  1 + 4x  12 = 0
4x + y  13 = 0

62. B
Sol. Assume
1 x
E  lim g  
x0 x  n 

g  x / n  g 0 
= lim
x 0 x0
x
Let  
n
g     g 0
E = lim
 0 n
g    g 0 1 1
E = lim  g  0  
 0 n n n
 
1 n x n 1
Hence, lim   1 g      1
x 0 x  n  n
n 1 n 1

n 1 1
=   1    ln 2
n 1 n

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 17 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

63. C
 1
 1  2  dx
Sol. I=   x 
 1  1
 x   2 x   1
 x  x
x2  x  1
= 2 tan1 c
x
 x2  x  1 
= 2   cot 1 c
2 x 
x2  x  1
= 2cot 1 c
x
 || = 2

64. B
1
1 x2
1
Sol. dx  dz   f  z   1 dz
   e 
0z  0
Integrating by parts, we get
1
 f  z  1dz   f   z  z dz  0
1 e 1

= zf  z    ze dz z2
 0

2

65. A

tan1 x  tan1 x
Sol. Assume F() =  dx
0
x
 
dF 1 x dx
  1   2 x 2  x dx   1  2 x 2
d 0 0

1 dx 1
 tan1  x 0  

=  
2 0
1
x2   2
2
2

Now dF = d
2
 d
 dF  2  

F() = ln   C
2
But F(1) = 0  C = 0

Hence F() = ln 
2

66. C
1/3
  r 2  
n    
 1    n  n3 
Sol. We can arrange this lim   
n 
r 1  n  r 
 
n

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AITS-PT-I-PCM(Sol.)-JEE(Main)/2025 18

1 1
x 2/3 1/3 3
=  x dx   x dx = 2
0 0

67. C
1 1

  2y  f  y   f  y  dy   y dy
3 6
Sol.
0 0
1
2
 f y  y 
3
 dy  0
0
 f(y) = y3  f(x) = x3
3 3
3 65
Hence area =  f  x  dx   x dx  4
sq. unit
2 2

68. B
6
Sol. Area =  g1  x  dx
2
6
=  t g(t) dt
2
6
6
= tg  t  2   g  t  dt
2
= 36  4  12 = 20
69. A
Sol. To fix up the focus of hyperbola we need two effective parameters. Thus order of corresponding
differential equation will be 2.
70. D
Sol. Consider a function h(x) = x g(x), here, h(x) is continuous in [0, 1] and differentiable in (0, 1) as
g(1) = 0  h(0) = 0 = h(1)
Hence, Rolle's theorem is applicable for h(x)
hence, for some   (0, 1)
h() = 0  g() + g() = 0
SECTION – B
71. 4
4
Sol. Assume I =  ln 13 sin y  3 3 cos y  dy
0
4
13
=  ln 14 sin  y    dy where cos =
14
0

 
= 4   ln sin  y    dy   ln14 
 
0 
Assume y +  = t

I= 4  lnsin tdt  4 ln14


  
= 4ln14 + 4  2    ln 2  = 4 ln7  = 4
 2 

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 19 AITS-PT-I-PCM(Sol.)-JEE(Main)/2025

72. 5
Sol. Since differentiable at x = 0, hence continuous at x = 0
 f(0+) = f(0)  a = 1
b 1
also f'(0) = f'(0+)  
c 2 8
2 1
4
 64b2 + c2 = 4  64b2 + c2 + a2 = 5

73. 20
Sol. From given information  +  + 1 = 0
dy y  
Also, 
dx x
dy  1   
Now,  2
dx 1,1 1   
  + 2 + 3 = 0
Solving for  and , get  = 2,  = 1
40      1
  40   20
 2

74. 9
Sol. Equation of tangent at P(2, 3) is x = 2y  4
3
2
Required area =   y  2  1   2y  4   dy  9 sq. unit.
0

75. 1000
sin2 x  x 2 1
Sol. Using the series expansion of "sinx" in lim  L
x 0 x 2 sin2 x 3
 |3000L| = 1000

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