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Test - 1 (Atomic Structure)

The document is an examination paper on Atomic Structure in Chemistry associated with DELTA, consisting of 30 objective-type questions worth a total of 120 marks. Each question carries 4 marks, with a penalty of 1 mark for incorrect answers. The questions cover various topics related to atomic structure, quantum numbers, and electron configurations.

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5 views5 pages

Test - 1 (Atomic Structure)

The document is an examination paper on Atomic Structure in Chemistry associated with DELTA, consisting of 30 objective-type questions worth a total of 120 marks. Each question carries 4 marks, with a penalty of 1 mark for incorrect answers. The questions cover various topics related to atomic structure, quantum numbers, and electron configurations.

Uploaded by

anal biswas
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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ENJOY CHEMISTRY (Associated with DELTA)

TOPIC : ATOMIC STRUCTURE


CHEMISTRY
Maximum Marks : 120 Time Duration : 1 hour : 15 mins

General Instructions :
Each questions carries 4 marks & for each wrong attempt 1 mark will be deducted

OBJECTIVE TYPE [ Marks:30X4 = 120]

Question No: 1
For emission line of atomic hydrogen from to , the plot of wave number against
will be (The Rydberg constant, is in wave number unit)
(a) Linear with intercept
(b) Non linear
(c) Linear with slope
(d) Linear with slope
Question No: 2
Match List I with List II

Choose the correct answer from the options given below:


(1) A-III, B-II, C-I, D-IV
(2) A-II, B-I, C-IV, D-III
(3) A-I, B-IV, C-III, D-II
(4) A-IV, B-III, C-II, D-I
Question No: 3
The size of the iso-electronic species and is affected by :
(a) azimuthal quantum number of valence shell
(b) electron-electron interaction in the outer orbitals
(c) principal quantum number of valence shell
(d) nuclear charge
Question No: 4
Ionization energy of gaseous atoms is . The lowest possible frequency of light
that ionizes a sodium atom is

(a)
(b)
(c)
(d)
Question No: 5
The number of radial nodes and total number of nodes in orbital respectively are :
A 2 and 3
B 2 and 2
C 3 and 4
D 4 and 4
Question No: 6
The ionization enthalpy of hydrogen atom is . The energy required to excite the
electron in the atom from to is
(a)
(b)
(c)
(d)
Question No: 7
Maximum number of electrons that can be accommodated in shell with are:
A 50
B 32
C 72
D 16
Question No: 8
Compare the energies of following sets of quantum numbers for multielectron system.
(A)
(B)
(C)
(D)
(E)
Choose the correct answer from the options given below :
(1)
(2) (E) ( C (D) (A) ( B
(3) (E) C A D B
(4) (C) (E) (D) (A) (B)
Question No: 9
The shortest wavelength of atom in the Lyman series is . The longest wavelength in the Balmer
series is is :
(a)
(b)
(c)
(d)
Question No: 10
The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to
stationary state 1 , would be (Rydberg constant )
(a)
(b)
(c)
(d)
Question No: 11
In which of the following pairs, the outer most electronic configuration will be the same?
A. and
B. and
C. and
D. and
Question No: 12
The correct set of four quantum numbers for the valence electrons of rubidium atom is:
(a)
(b)
(c)
(d)
Question No: 13
The orbital angular momentum for an electron revolving in an orbit is given by . This
momentum for an -electron will be given by
(a) zero
(b)
(c)
(d)
Question No: 14
The radius of the 2 nd orbit of is . The expected radius of the 3 rd orbit of is
A
B
C
D
Question No: 15
The region in the electromagnetic spectrum where the Balmer series lines appear is :
(a) Visible
(b) Microwave
(c) Infrared
(d) Ultraviolet
Question No: 16
The number of -electrons retained in (At. no. of ) ion is
(a) 4
(b) 5
(c) 6
(d) 3
Question No: 17
If the radius of first orbit of atom is , the de-Broglie wavelength of an electron in the third orbit
is
(a)
(b)
(c)
(d)
Question No: 18
Which of the following electronic configuration would be associated with the highest magnetic
moment?
(1)
(2)
(3)
(4)
Question No: 19
The pair, in which ions are isoelectronic with is :
A and
B and
C and
D and
Question No: 20
Which of the following sets of quantum numbers represents the highest energy of an atom?
(a)
(b)
(c)
(d) .
Question No: 21
Given
(A)
(B)
The maximum number of electron(s) in an atom that can have the quantum numbers as given in (A)
and (B) are respectively:
(a) 25 and 1
(b) 8 and 1
(c) 2 and 4
(d) 4 and 1
Question No: 22
Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason
Assertion A : Zero orbital overlap is an out of phase overlap.
Reason : It results due to different orientation / direction of approach of orbitals.
In the light of the above statements, choose the correct answer from the options given below
A Both and are true and is the correct explanation of
B Both and are true but is NOT the correct explanation of
C is true but is false
D is false but is true
Question No: 23
Consider the ground state of atom . The number of electrons with the azimuthal
quantum numbers, and 2 are, respectively
(a) 16 and 4
(b) 12 and 5
(c) 12 and 4
(d) 16 and 5
Question No: 24
Energy of an electron is given by .Wavelength of light required to
excite an electron in an hydrogen atom from level to will be :
and
(a)
(b)
(c)
(d)
Question No: 25
The ionic radius of ions is . The ionic radii (in oAAo) of and , respectively,
are
A. 1.05 and 0.99
B. 0.72 and 0.54
C. 0.85 and 0.99
D. 0.68 and 0.72
Question No: 26
The orbital having two radial as well as two angular nodes is:
A.
B.
C.
D.
Question No: 27
The magnetic moment of a transition metal compound has been calculated to be 3.87 B.M. The metal
ion is
A
B
C
D
Question No: 28
The electrons identified by quantum numbers and :
(A)
(B)
(C)
(D) can be placed in order of increasing energy as :
(a) (C) (D) (B) (A)
(b) (D) (B) (C) (A)
(c) (B) (D) (A) (C)
(d) (A) (C) (B) (D)
Question No: 29
The total number of orbitals associated with the principal quantum number 5 is :
(a) 20
(b) 25
(c) 10
(d) 5
Question No: 30
Which of the following sets of quantum numbers is not allowed?
A
B
C
D

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