BISE BWP (2025) Chemistry

Punjab Group of Colleges (Liaquatpur)

Time: 20 Min Objective Part Marks: 17
1. Formula of chloroform is:
a) CCl4 b) CHCl3 c) CH2Cl2 d) CH3Cl
2. The chemist who synthesized urea from ammonium cyanate was:
a) Berzelius b) Kolbe c) Wohler d) Lavoisier
3. Which of these polymers is a synthetic polymer?
a) animal fat b) starch c) cellulose d) polyester
4. Coordination number of Pt in [Pt(Cl)(NO2)(NH3)4] is:
a) 1 b) 2 c) 4 d) 6
5. All of following are included in calcareous materials except:
a) lime b) clay c) marble d) marine shell
6. The solution of which acid is used for seasoning of food?
a) formic acid b) acetic acid c) benzoic acid d) butanoic acid
7. Oxidation of NO in air produces
a) N2O b) N2O2 c) N2O4 d) N2O3
8. Rectified spirit contains about how many percent of alcohol?
a) 80% b) 85% c) 90% d) 95%
9. The reaction between fat and NaOH is called:
a) Esterification b) Hydrogenolysis c) Fermentation d) Saponification
10. Which of following element is not abundantly present in
a) silicon b) aluminium c) sodium d) oxygen
11. Alkali metals are present in which block of the periodic table.
a) s-block b) p-block c) d-block d) f-block
12. Which halogen occurs naturally in a positive oxidation state?
a) fluorine b) chlorine c) bromine d) iodine
13. For which mechanism, the first step involved is the same?
a) E1 and E2 b) E2 and SN2 c) SN1 and E2 d) E1 and SN1
14. Which of the following will have the highest boiling point?
a) methanal b) ethanal c) propanal d) 2-hexanone
15. Aromatic hydrocarbons are the derivatives of:
a) alkanes b) alkenes c) benzene d) cyclohexane
16. The pH range of the acid rain is:
a) 7 - 6.5 b) 5.5 - 6 c) 6 - 5.6 d) less than 5
17. Which hydride gets decomposed on heating?
a) LiOH b) NaOH c) KOH d) RbOH
 BISE BWP (2023) Chemistry
Pujnab Group of Colleges (Liaquatpur)
Time: 2:40 Hours Subjective Part Marks: 68
Section I
Q.2: Write answers of any eight parts from the following. (2 x 8 = 16)
i) Define saponification number with a suitable example.
ii) Write two points of difference between a fat and oil.
iii) Differentiate with at least two points between “Amylose” and “Amylopectin”.
iv) How boric acid is parepared on commercial scale from Colemanite?
v) Why Aluminium sheets are said to be corrosion free?
vi) Why CO2 is a gas at room temperature while SiO2 is a solid?
vii) Prepare benzene from acetylene and n-hexane.
viii) What is resonance energy?
ix) Explain X-Ray structure of benzene.
x) What are the conditions for the formation of smog?
xi) Discuss aeration of water for its purification.
xii) What is “Chemical Oxygen Demand (COD)”? How is it measured?
Q.3: Write answers of any eight parts from the following. (2 x 8 = 16)
i) What is “Catalytic Cracking”.
ii) Compounds containing double bonds are more reactive. Give reason.
iii) Write mechanism for the addition of halogen in alkene.
iv) What is tautomerism?
v) What is reforming?
vi) Starting from suitable Grignard’s reagent, prepare ethane and ethyl cyanide.
vii) Write reaction to prepare tetra ethyl lead and nitroethane.
viii) How an aqua regia dissolves gold?
ix) How orthophosphoric acid is converted into pyro and metaphosphoric acid?
x) Name four macronutrients and also mention per acre range of their requirement.
xi) Name argillaceous and calcareous raw materials of cement.
xii) What is Wolf – Kishner Reduction?
Q.4: Write answers of any six parts from the following. (2 x 6 = 12)
i) Prepare ethanol from starch.
ii) Convert ethanol to iodoform.
iii) Write Strecker synthesis to prepare amino acids.
iv) Name different forms of Iron and mention which is the purest form?
v) Describe Tollen’s test for the identification of aldehyde.
vi) Write any four uses of formaldehyde.
vii) What is chromyl chloride test?
viii) What is sacrificial corrosion?
ix) How bakelite is prepared?
Section II (3 x 8 = 24)
Q.5: (a) Explain “Electrical Conductance” as periodic property.
(b) Discuss peculiar behavior of Beryllium.
Q.6: (a) Explain the processes for manufacturing of “Bleaching Powder”.
(b) Discuss nomenclature of transition elements.
Q.7: (a) Explain homocyclic and heterocyclic compounds with examples.
(b) How benzene is converted into: a) Maleic acid b) Glyoxal c) m-Chloronitrobenzene
d) Acetone
Q.8: (a) How is ethyne converted into following compounds?
(i) Acetaldehyde (ii) Chlroprene (iii) Acetonitrile (iv) Divinyl acetylene
(b) Give oxidation of formaldehyde with mild oxidizing agents.
Q.9: (a) Give the order of reactivity of alocohls in case of electrophile and nucleophile attack respectively.
Give three reactions in case of C – O bond breakage.
(b) How does acetic reacts with PCl 5 and SOCl 2. Explain mechanism of reaction with SOCl 2.