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PCM Test Paper SET-A (With Answers) 17.04.25

The document is a JEE Simulation Test for Chemistry and Physics, containing multiple-choice questions across various topics. It includes sections for single correct choice, multiple correct choice, coding-based matrix, and integer-type questions. Each question has specific marking schemes and is designed to assess knowledge in physical chemistry and optics.

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0% found this document useful (0 votes)
17 views12 pages

PCM Test Paper SET-A (With Answers) 17.04.25

The document is a JEE Simulation Test for Chemistry and Physics, containing multiple-choice questions across various topics. It includes sections for single correct choice, multiple correct choice, coding-based matrix, and integer-type questions. Each question has specific marking schemes and is designed to assess knowledge in physical chemistry and optics.

Uploaded by

Avinesh agarwal
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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JEE Simulation Test NEON Set-A DATE : 17.04.

25
PART – I : CHEMISTRY

SECTION – I (Single Correct Choice Type) (3R-W)

This Section contains 9 Single Choice Questions. Each question has four choices A), B), C) and D) out of
which ONLY ONE is correct.

1. Which of the following binary mixture does not show the behavior of minimum boiling azeotropes?
(a) H2O  CH3COC2H5 (b*) C6H5OH  C6H5NH2
(c) CS2  CH3COCH3 (d) CH3OH  CHCl 3

2. Liquid A and B form an ideal solution. The vapour pressure of pure liquids A and B are 350 and 750 mm Hg
respectively at the same temperature. If x A and xB are the mole fraction of A and B in solution while y A and y B are
the mole fraction of A and B in vapor phase then
xA y A xA y A xA y A
(a)  (b)  (c*)  (d) ( xA  y A )  ( xB  y B )
xB y B xB y B xB y B

3. Given below are two statement


Statement I : When a system containing ice in equilibrium with water (liquid) is heated, heat is absorbed by the
system and there is no change in the temperature of the system until whole ice gets melted
Statement II : At melting point of ice, there is absorption of heat in order to overcome intermolecular forces of
attraction within the molecular of water in ice and kinetic energy of molecules is not increased at melting point.
In the light of the above statement, chose the correct answer from the options given below
(a) Statement I is true but Statement II is false (b) Both Statement I and Statement II are false
(c*) Both Statement I and Statement II are true (d) Statement I is false but Statement II is true

4. Match List-I with List-II


List-I List-II
(A) Solution of chloroform and acetone (I) Minimum boiling azeotrope
(B) Solution of ethanol and water (II) Dimerizes
(C) Solution of benzene and toluene (III) Maximum boiling azeotrope
(D) Solution of acetic acid in benzene (IV) Vmix  0
Choose the correct answer from the options given below
(a*) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) (b) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
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(c) (A)-(III), (B)-(IV), (C)-(I), (D)-(II) (d) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)

5. A solution is made by mixing one mole of volatile liquid A with 3 moles of volatile liquid B. The vapor pressure of
pure A is 200 mmHg and that of the solution is 500 mm Hg. The vapour pressure of pure B and the least volatile
component of the solution, respectively, are
(a) 1400 mm Hg, A (b) 1400 mm Hg, B (c) 600 mm Hg, B (d*) 600 mm Hg, A

6. Assume a living cell with 0.9% (w/w) of glucose solution (aqueous). This cell is immersed in another solution having
equal mole fraction of glucose and water. (Consider the data upto first decimal place only). The cell will
(a) Show no change in volume since solution is 0.9% (w/w)
(b) Shrink since solution is 0.5% (w/w)
(c) Swell up since solution is 1% (w/w)
(d) None of these

7. Consider the two figures given below :

Which of the following statements regarding the experiment is true?


(a) The solubility of a gas in liquid in beaker (i) is greater then that in beaker (ii)
(b) The solubility of a gas in beaker (i) is less then that in beaker (ii)
(c) The solubility of a gas in equal in both beakers
(d) The solubility of a gas remains unaffected by change in weights

8. In the given graph, pq, qr and st represent

(a) pq liquid state of solution, qr solid state of solution, st liquid state of solvent
(b) pq liquid state of solvent, qr solid state of solvent, st  liquid state of solution
(c) pq liquid state of solvent, qr solid state of solution, st liquid state of solution
(d) pq solid state of solvent, qr liquid state of solvent, st solid state of soluiton

9. Match the different solutions in List-I with their Tb in List-II and select the answer from the codes given below
List-I List-II
(I) 1 molal urea solution (P) Kb
(II) 1 molal KCl solution with 100% ionization (Q) 3.0 Kb
(III) 1 molal K2SO4 solution with 75% ionization (R) 2.0 Kb
(IV) 1 molal K4 [Fe(CN )6 ] solution with 50% ionisation (S) 2.5 Kb
(a) IP, IIR, IIIS, IVQ (b) IP, IIQ, IIIS, IVR
(c) IP, IIR, IIIQ, IVS (d) IR, IIS, IIIQ, IVP

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JEE Simulation Test NEON Set-A DATE : 17.04.25
SECTION – II (Multiple Correct Choice Type) (4R-2W)

This Section contains 5 Multiple Choice Questions. Each question has four choices A), B), C) and D) out of
which ONE or MORE is correct. WITH PARTIAL MARKING. Marking scheme: +4 if all correct options are
correct,+1 partial marks for each correct answer, 0 if not attempted and -2 any wrong option is marked

10. Select the correct statements


(a*) The melting of ice becomes fast if salt is separated on it
(b*) The boiling occurs late in pressure cooker
(c*) Osmosis is a bilateral (both direction) process
(d) 1N Na2SO4 solution is hypertonic with respect to 1N NaCl solution

11. Identify the correct statements


(a*) The solution formed by mixing equal volumes of 0.1 M urea and 0.1 M glucose will have the same osmotic
pressure
(b*) 0.1MK4 [Fe(CN )6 ] and 0.1M Al 2 (SO4 )3 are isotonic solutions
(c) For association of a solute in a solution, i > 1
(d) The ratio of van’t Hoff factors for 0.1 M glucose and 0.1 M sucrose is 2 : 1

12. If 1 m solution of benzoic acid in benzene has a freezing point depression of 2.4°C (Kf  5.12o C mol 1 kg ) and
boiling point elevation of 2.53o C(Kb  2.53o C mol 1kg ) then select the correct statements
(a*) Statement I : There is dimer formation when undergoing freezing
(b*) Statement II: There is no dimer formation when undergoing boiling
(c) Statement III : There is no dimer formation when undergoing freezing
(d) Statement IV : Dimer formation in freezing and boiling state

13. Consider 0.1 M solutions of two solutes X and Y. The solute x behaves as a univalent electrolyte while the solute Y
dimerises in solution. Which of the following statements are correct regarding these solution?
(a*) The boiling point of the solution of X will be higher than that of Y
(b*) The osmotic pressure of the solution of Y will be lower than that of X
(c*) The freezing point of the solution of X will be lower than that of Y
(d) The relative lowering of vapour pressure of both the solutions will be the same

14. Which of the following combinations are correct for a binary solution, in which the solute as well as the solvent are
liquids?
(a) C6 H6 and C6H5CH3 ; Hso ln  0 ; Vsol .  0 (b*) CH3COCH3 and CHCl3 ; Hso ln  0; Vsol  0
(c) H2O and HCl ; Hso ln  0; Vsol  0 (d*) H2O and C2H5OH ; Hso ln  0 ; Vsol  0

SECTION – III (Coding Based Matrix) (3R-W)

This Section contains 2 Coding Based Questions. Each question has four choices A), B), C) and D) out of
which ONLY ONE is correct.

15. Match the following


Column-I Column-II
(A) A nearly ideal solution (P) H2O  C2H5OH
(B) A solution showing positive deviation (Q) C6H6  C6H5CH3
(C) A solution showing negative deviation (R) C6H6  CHCl3
(D) An azeotropic mixture with high B.P. (S) Acetone + C2H5OH
(T) H & V are +ve
(U) H & V are –ve
(a*) A-Q, B-QST, C-QR, D-QS (b) A-PR, B-QST, C-PQS, D-QS
(c) A-QRT, B-QRP, C-PR, D-QS (d) A-PRT, B-QS, C-QR, D-QS

16. Matrix Match :


Mn = Normal molecular mass of solute
Mo = Observed molecular mass of solute from colligative property measurement
Column-I Column-II
(A) Mo  Mn (P) 0.1 M CH3COOH in benzene

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JEE Simulation Test NEON Set-A DATE : 17.04.25
(B) Mo  Mn / 3 (Q) 0.1 M urea in water
(C) Mo  Mn (R) 0.05 M barium chloride in water
(D) Mo  Mn (S) 0.1 MCH3COOH in water
(T) 0.1 M glucose in water
(a) A-PQ, B-PR, C-PT, D-S (b) A-PT, B-Q, C-PS D-PQ
(c) A-RS, B-T, C-PR, D-QS (d*) A-RS, B-R, C-P, D-QT

SECTION – IV (Single or Double Digit Integer Type) (3R)

This Section contains 4 Questions. The answer to each question is a Single or Double Digit Integer ranging
from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.
17. A mixture of one mole of H2O and 1 mole of CO is taken in a 10 litre container and heated to 725K. At equilibrium
40% of water by mass reacts with carbon monoxide according to the equation CO(g )  H2O(g ) CO2 (g )  H2 (g ).
The equilibrium constant KC  10 for the reaction is ………… (Nearest Integer)
2

18. If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality of the solution which shows
2.5K rise in the boiling point of the solution is ……..molal. (Rounded – off to the nearest integer)
Kb  0.52K kg mol 1 
Ans. 3

19. Consider the dissociation of the weak acid HX as given below HX (aq ) H  (aq )  X  (aq ), Ka  1.2  105 [Ka:
dissociation constant]. The osmotic pressure of 0.03M aqueous of solution of HX at 300K is …………. 102 bar
–1 –1
(Nearest Integer) [Given : R = 0.083 L bar mol K ]
Ans. 76

20. Depression in freezing point of 0.01 molal aqueous HCOOH solution is 0.02046. 1 molal aqueous urea solution
freezes at 1.86o C, assuming molality is equal to molarity, then the p H of HCOOH solution is
Ans. 3

PART – II : PHYSICS

SECTION – I (Single Correct Choice Type) (3R-W)

This Section contains 9 Single Choice Questions. Each question has four choices A), B), C) and D) out of
which ONLY ONE is correct.
0
21. Two plane mirrors are arranged as shown in figure. A ray has been incident on M 1 at an angle of 40 , find the
deviation produced in it after three reflections

0 0 0 0
(a) 40 clockwise (b) 40 anti-clockwise (*c) 140 clockwise (d) 140 anti-clockwise

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22. An object is present on the principal axis of a concave mirror of focal length 15 cm. Object is at a distance of 20 cm
–1
from mirror. If velocity of object is 5cms–1 towards mirror and velocity of mirror is 5 cms towards object then
velocity of image at the same instant is

–1 –1
(a) 35 cms towards left (b*) 95 cms towards left
–1 –1
(c) 30 cms towards right (d) 35 cms towards right

23. A convex mirror of focal length ‘f’ is placed at the origin with its reflecting surface towards the negative x-axis.
Choose the correct graphs between ‘v’ and ‘u’ for u < 0.
v v v
v
f0
f0/2 f0

f0/2 f0/2

u u u u
f0 O f0 O
(a) (b) f0 O *(c) f0 O (d)

24. A cube of side 2 m is placed in front of a concave mirror focal length 1m with its face P
at a distance of 3m and face Q at a distance of 5m from the mirror. The distance 2m
between the images of face P and Q and height of images of P and Q are P

(a) 1 m, 0.5 m, 0.25 m (b) 0.5 m, 1 m, 0.25 m 2m


3m
(c) 0.5 m, 0.25 m, 1 m (d*) 0.25 m, 1 m, 0.5 m Q

l
25. The period of oscillation of a simple pendulum is given by T  2 where l is about 100 cm and is known to have
g
1mm accuracy. The period is about 2s. The time of 100 oscillations is measured by a stop watch of least count 0.1 s.
The percentage error in g is
(a) 0.1% (b) 1% (c*) 0.2% (d) 0.8%

Paragraph for Questions 26 to 27


Plane mirror (M1) and a concave mirror (M2) of focal length 10cm are arranged as shown in figure. An object is kept at
origin. Answer the following questions. (Consider image formed by single reflection in all cases)

26. The co-ordinates of image formed by plane mirror. are

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(a) –20 cm, 0 cm (b) 10 cm, –60 cm (c*) 10 cm, –10 cm (d) 10 cm, 10 cm

27. The co-ordinates of image formed by concave mirror are


(a) 10 cm, –40 cm (b) 10 cm, –60 cm (c) 10 cm, 8 cm (d*) None of these

Paragraph for Questions 28 to 29


–1
The position of particle P at t = 0 s as shown in the figure. (Assume that, the point P is moving with velocity v = 3 cms
ˆi  4cms1ˆj )

28. The distance of second image of point object P formed by the plane mirror M 1 from the point object P is
(a) 20 cm (*b) 40 cm (c) 60 cm (d) 80 cm

29. The velocity of first image formed by mirror M2 is


(a) 3iˆ  4ˆj (b) 3iˆ  4ˆj (c*) 3iˆ  4ˆj (d) 3iˆ  4ˆj

SECTION – II (Multiple Correct Choice Type) (4R-2W)

This Section contains 5 Multiple Choice Questions. Each question has four choices A), B), C) and D) out of
which ONE or MORE is correct. WITH PARTIAL MARKING. Marking scheme: +4 if all correct options are
correct,+1 partial marks for each correct answer, 0 if not attempted and -2 any wrong option is marked

30. A convex and a concave mirror of radii 10 cm each are facing each other and 15 cm apart. A point object is placed
midway between them. The correct choice is (consider two reflection only)
(a) For first reflection at concave mirror, and then by convex mirror, image is formed at the position of object itself
(b*) For first reflection at concave mirror and then by convex mirror, final image is formed at a distance of 7.5 cm
from object
(c*) For first reflection at convex mirror and then by concave mirror, the final image is at a distance of 8.077 cm
from the convex mirror
(d*) For first reflection at convex mirror and then by concave mirror, the final image is at a distance 8.077 cm from
the convex mirror

31. For which of the pairs of u and f for a mirror image is smaller in size
(a*) u = – 10 cm, f = 20 cm (b) u = –20 cm, f = –30 cm
(c*) u = –45 cm, f = –10 cm (d*) u = –60 cm, f = 30 cm

32. Figure shows an object O kept at P. A plane mirror parallel to yz plane is moving with velocity 3i m / s . Select the
correct alternative

(a*) The velocity of image is 6iˆ m / s (b) The velocity of image is 6iˆ m / s
(c*) The velocity of image w.r.t. mirror is 3iˆ m / s (d) The velocity of image w.r.t. object is 6iˆ m / s

33. Check out the correct one(s).


(a) A concave mirror can give a diminished virtual image.
(b) A concave mirror can give a virtual image.
(c) A convex mirror can give a diminished virtual image.
(d) A convex mirror can give a real image.

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JEE Simulation Test NEON Set-A DATE : 17.04.25
9. (BCD) A concave mirror can give a virtual image which is always magnified. This virtual image is
obtained when object is placed between F and P. So (A) is the option giving wrong prediction.
34. A point object is placed on the principal axis of a concave mirror of focal length –20 cm. At this instant object is given
a velocity v towards the axis (event-1) or perpendicular to axis (event-2). Then speed of image

(a) In event -1 is 2v (b*) In event -1 is 4v (c*) In event -2 is 2v (d) In event -2 is 4v

SECTION – III (Coding Based Matrix) (3R-W)

This Section contains 2 Coding Based Questions. Each question has four choices A), B), C) and D) out of
which ONLY ONE is correct.

35. You are given different situation of incident ray in Column-I. Match them to the nature of images given in Column-II
Column-I Column-II
(A) (P) Real

(B) (Q) Erect

(C) (R) Magnified

(D) (S) Diminished

Which of following is/are correctly matched?


(a) APQS, BQR, CPQR, DPRS (b*) A PQ, B PQS, C QR, D PQR
(c) APSQ, BPR, CPS, DPQS (d) APS, BPQR, CPRS, DPQ

36. Match the following


Column-I Column-II
(A) (P) 3

Numbers of distinct images

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(B) (Q) 4

Numbers of distinct images


(C) (R) 6

Numbers of reflections
(D) (S) 7

Length in meters of wall (which is parallel to mirror) that can be seen by


observer(eye) in mirror
(a*) A S, BS, CP, DR (b) A R, BR, CP, DQ
(c) A S, BS, CQ, DR (d) A P, BS, CQ, DQ

SECTION – IV (Single or Double Digit Integer Type) (3R)

This Section contains 4 Questions. The answer to each question is a Single or Double Digit Integer ranging
from 0 to 99. The correct digit below the question number in the ORS is to be bubbled.

37. A concave mirror of radius of curvature 20 cm and a point source of light in front of it on its principle axis are at
separation 15 cm. If both start moving at speed 1 cm/s and 10 cm/s respectively away from each other as shown,
find the velocity with which the image start moving (in cm/s)

38. Find x such that rays retrace path after second reflection

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Ans. 20

39. A police car is chasing a thief jeep which is moving away with speed 54km/h. When the separation between jeep
and car is 30 m the thief observes in rear view mirror that car is approaching with speed 0.5m/s. Find actual speed of
police car in m/s. Given that the radius of curvature of mirror is 12m.
Ans. 33

40. A point source has been placed as shown in the figure. What is the length (in cm) on the screen that will receive
reflected light from the plane mirror?

Ans. 20

PART – III : MATHS

SECTION – I (Single Correct Choice Type) (3R-W)

This Section contains 9 Single Choice Questions. Each question has four choices A), B), C) and D) out of
which ONLY ONE is correct.

cos7 x  cos8 x
41. Evaluate :  1  2cos5 x
dx

1 1 1 1
(a*) sin2x  sin3 x  C (b) sin2x  sin3 x  C
2 3 2 3
1 1
(c) sin2x  sin3 x  C (d) None of these
2 3

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cos 2x
42. The value of 
cos x
dx is equal to

(a*) 2sin x  n | sec x  tan x | C (b) 2sin x  n | sec x  tan x | C


(c) 2sin x  n | sec x  tan x | C (d) sin x  n | sec x  tan x | C

cos 4 x  1
43. If  cot x  tan xdx  A cos 4x  B; where A & B are constants, then

(a) A  1/ 4 & B may have any value (b*) A  1/ 8 & B may have any value
(c) A  1/ 2 & B  1/ 4 (d) A  B  1/ 2

1
44. Value of  sin( x  a)cos( x  b)dx is equal to

1 sin( x  a) 1 cos( x  b)
(a*) n C (b) n C
cos(a  b) cos( x  b) cos(a  b) sin( x  a)
1 sin( x  a) 1 cos( x  a)
(c) n C (d) n C
sin(a  b) cos( x  b ) sin(a  b) sin( x  b )

1
45. The value of  [( x  1) ( x  2) ]
3 5 1/ 4
dx is equal to

1/ 4 1/ 4 1/ 4 1/ 4
4  x 1  4 x 2 1 x 1 1  x  1
(a*) C (b) C (c) C (d) C
3  x  2  3  x  2  3  x  2  3  x  1 

2x12  5 x 9
46. The integral 5  (x
 x 3  1)3
dx is equal to

Where C is an arbitrary constant


x10 x5
(a*) C (b) C
( x 5  x 3  1)2 2( x 5  x 3  1)2
 x10
(c) C (d) None of these
2( x  x 3  1)2
5

dx
47.  x  2x  2
2
is equal to

(a*) log | ( x  1)  x 2  2x  2 |  C (b) log | x  ( x 2  2x  2) |  C


(c) log | x  1  x 2  2x  2 |  C (d) None of the above

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dx
48.  2  sin x  cos x is equal to

 tan x / 2  1   tan x / 2  1 
(a*) 2 tan1   C (b) tan1   C
 2   2 
 tan x / 2 
(c) 2 tan1   C (d) None of these
 2 

49.  cos 4x cos7x dx is equal to


sin3 x sin11x
(a) sin3x  sin11x  C (b)  C
3 11
sin3 x sin11x
(c*)  C (d) None of these
6 22

SECTION – II (Multiple Correct Choice Type) (4R-2W)

This Section contains 5 Multiple Choice Questions. Each question has four choices A), B), C) and D) out of
which ONE or MORE is correct. WITH PARTIAL MARKING. Marking scheme: +4 if all correct options are
correct,+1 partial marks for each correct answer, 0 if not attempted and -2 any wrong option is marked

2 .3nx dx (when m, n N) is equal to


mx
50. The value of
2mx  3nx e( m n 2 n n 3) x
(a) C (b*) C
m n 2  n n3 m n 2  n n3
2mx.3nx (mn ).2x.3 x
(c*) C (d) C
n(2m.3n ) m n 2  n n3

 x  1

n 
 x  1  dx is equal to
51. The value of
x 1
2

1 2 x 1 1 2 x 1 1 2 x 1 1 2 x 1
(a) n C (b*) n C (c) n C (d*) n C
2 x 1 4 x 1 2 x 1 4 x 1

4e x  6e x
 9ex  4e x dx  Ax  B n | 9e  4 |  C, then
2x
52. If

(a*) A  18B  16 (b*) 18B  A  19 (c) A  18B  17 (d) A  18B  32

dx  x
 5  4cos x  P tan
1
53. If  m tan 2   C then
 
(a*) P  2/3 (b*) m  1/ 3 (c) P  1/ 3 (d) m  2/3

sec x dx
54.  (sec x  tan x ) 7/2
dx 

2 7
(a*) (sec x  tan x )7 / 2  C (b) (sec x  tan x )7 / 2  C
7 2
2 2
(c*) C (d) (sec x  tan x )7 / 2  C
7(sec x  tan x )7 / 2 7

SECTION – III (Coding Based Matrix) (3R-W)

This Section contains 2 Coding Based Questions. Each question has four choices A), B), C) and D) out of
which ONLY ONE is correct.

55. Match the following


SHIKHAR : Indra Complex, Vijaya Nagar, Chetakpuri, Gwalior (0751) 3551081 11
JEE Simulation Test NEON Set-A DATE : 17.04.25
Column-I Column-II
(A) 2x 1 (P) 5
If  sin1(2x )  C then k =
1  4x log k
(B) ( x )5 a nx k (Q) 2
If ( x )7  x 6
dx 
xk  1
 c, then 2k =

(C) sec xdx 1 (R) 4


If  (sec x  tan x ) 2

2(sec x  tan x )k
 C, then k =

(D) dx 1 1  (S) 3


If  (e x
 e  x )2
  bx
a  e  1 
 C then a + b =

(a*) AQ, BP, CQ, DR (b) AR, BP, CQ, DQ
(c) AP, BQ, CS, DR (d) AS, BR, CP, DQ

dx  qx  1
56.  9x 2
 6x  5
 p tan1 
 2 
 C

 sin x cos3 x dx  a cos2x  b cos6x  C where C is an arbitrary constant of integration


3

Column-I Column-II
(A) a= (P) 2
(B) b= (Q) 1/6
(C) p= (R) –3/64
(D) q= (S) 1
192
(a) AR, BP, CS, DQ (b*) AR, BS, CQ, DP
(c) AQ, BR, CS, DP (d) AP, BQ, CR, DS

SECTION – IV (Single Or Double Digit Integer Type) (3R)

This Section contains 4 Questions. The answer to each question is a Single or Double Digit Integer ranging
from 0 to 99. The correct digit below the question number in the ORS is to be bubbled.

4  x2 (a  x 2 )3 / 2 .( x 2  b)
57.  x6
If dx 
120 x 5
 C then a2  b2 equals to

Ans. 52.00

x 2 1  x 3 / 2 
58. If dx  sin  3 / 2   C, then k equals to
a3  x 3 k a 
Ans. 3


59. If f ( x )  cos x  cos2 x  cos3 x........... up to infinite term and g ( x )   f ( x )dx & g(0)  0. If g ( / 4)   b  1 then
a
value of a + b is
Ans. 6

dx
60. If  a cot x  b tan3 x  C, where C is an arbitrary constant of integration, then the values of
3 5
sin x cos x
a  10b equals to
2

Ans. 6

SHIKHAR : Indra Complex, Vijaya Nagar, Chetakpuri, Gwalior (0751) 3551081 12

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