PHYSICS
BOOKS - HC VERMA PHYSICS
(ENGLISH)
BOHR'S MODEL AND PHYSICS OF THE
ATOM
Example
1. Calculate the energy of a H e +
ion in its first
excited state solution
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2. Calculate the wavelength of radiation
emitted when He
+
makes a transtion from
the state n = 3 to the state n = 2
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3. The excitation energy of a hydrogen-like ion
in its first excited state is 40.8eV Find the
energy needed to remove the electron from
the ion
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Worked Out Example
1. Find the radius of Li
+ +
ions in its ground
state assuming Bohr 's model to be valid
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2. A particular hydrogen like radiation of
frequency 2.467 × 10
15
Hz when it makes
transition from n = 2 → n = 1 ,What will be
the frequency of the radiation emitted in a
transition from n = 3 → n = 1 ?
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3. Calculate the two highest wavelength of the
radiation emitted when hydrogen atoms make
transition from higher state to n = 2
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4. What is the wavelength of the radiation
emitted when the electron in a hydrogen atom
jumps from n = → n = 2 ?
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5. (a)Find the wavelength of the radiation
required to excited the electron is Li
+ +
from
the first to the third Bohr orbit (b) How many
spectral lines are obseved in the emission
spactrum of the above excited system?
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6. Find the wavelength present in the
radiation emitted when hydrogen atoms
emitted to n = 3 states return to their
ground state.
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7. How many different wavelengths may be
observed in the spectrum from a hydrogen
sample if the atoms excited to states with
principal quantum number n?
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8. Monnohramatic radition of wavelength λ is
incident on a hydrogen sample in ground
state hydrogen atoms obserb a frection of
light and subsequently and radition of six
different wavelength .Find the value of λ
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9. The energy needed to detach the electron of
a hydrogen like ion in ground state is a 4
Rydberg. (a) what is the wavelength of the
radiation emitted when the electron jumps
from the first excited state to the ground
state? (b) What is the radius of the orbit for
this atom?
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10. A hydrogen sample is prepared in a
particular state A photon of energy 2.55eV
get observed into the sample to take some of
the electron in a farther excited state B find
the quantum numbers of the state A and B
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11. (a) Find the maximum wavelength λ90 ) of
light which can ionize a hydrogen atom in its
ground (b) light of wavelength λ0 is inclined
on ahydrogen atom which is in its first excited
state find the kinrtic energy of the electron
coming out
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12. Derive an expression for the magnetic field
at the site of the necleas in a hydrogen atom
due to the circular motion of the electron
Assume that the atom is in its ground state
and the answer in lerms of fandmental
constants
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13. A lithium atom has electrons. Assume the
following simple picture of the atom Two
electron moves close to the nucleus making
up a spherical cloud it and the third moves
outside the cloud in a circular orbit . Bohr's
model can be used for the motion of this third
electron butn = 1 state are not available to it.
Calculate the ionization energy of lithium in
ground state using the above picture.
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14. A particle known as mu mean has a charge
equal to that of no electron and mass 208
times the mass of the electron B moves in a
circular orbit around a nucleus of charge + 3e
Take the mass of the nucles to be infinite
Assuming that the bohr's model is applicable
to this system (a)drive an eqression for the
radius of the nth Bohr orbit (b) find the value
of a for which the redius of the orbit it
approninately the same as that at the first
bohr for a hydrogen atom (c) find the
wavelength of the radiation emitted when the
u - mean jump from the orbit to the first orbit
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15. Find the wavelength in a hydrogen
spectrum between the range
500nm → 700nm
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16. A beem of ultraviolet radius hacking
wavelength between 100nm and 200nm is
inclined on a sample of atomic hydrogen gos
Assuming that the atoms are in ground state
which wavelength will have low intensity in the
transnilled been? If the energy of a photon is
equal to the ground state it haslarge
probobility of being observed by on atom in
the ground state
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17. A neutron moving with a speed v makes a
head-on collision with a hydrogen atom in
ground state kept at rest. Find the Minimum
Kinetic Energy of Neutron for which inelastic
collision will be take place is (assume that
mass of h-atom is nearly equal to the mass of
neutron)
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18. Light corresponding to the transition
n = 4 → n = 2 in hydrogen atom falls on
cesium metal (work function = 1.9eV ) Find
the maximum kinetic energy of the
photoelectrons emitted
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19. A small particle of mass m move in such a
1
way the potential energy U =
2
m ω r
2 2
when
2
a is a constant and r is the distance of the
particle from the origin Assuming Bohr's
model of quantization of angular momentum
and circular orbits , show that radius of the
nth allowed orbit is proportional to in
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Obejective I
1. The minimum orbital angular momentum of
the electron in a hydrogen atom is
A. h
B. h / 2
C. h / 2π
D. h / λ
Answer: C
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2. Three photons coming from excited atoms
hydrogen sample are pickedup .There energies
are 12.1eV , 10.2eV and 1.9eV these photons
must come from
A. a simple atom
B. two atoms
C. three atoms
D. either two atoms or three atoms
Answer: D
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3. Suppose the electron in a hydrogen atom
makes transition from
n = 3 → n = 2 ∈ 10
−8
s The order of the
torque acting on the electon in this period,
using the relation between torque and
angular momentum as discussed in the
chapter on rotational machanics is
A. 10 − 34
Nm
B. 10 − 24
Nm
C. 10 − 42
Nm
D. 10 −8
Nm
Answer: B
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4. In which of the following transition will the
wavelength be minimum ?
A. n = 5 → n = 4
B. n = 4 → n = 3
C. n = 3 → n = 2
D. n = 2 → n = 1
Answer: D
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5. In which of the following system will the
radius of the first orbit(n = 1) be minimum?
A. Hydrogen atom
B. Deuterium atom
C. single ionized helium
D. Doubly ionized lithium
Answer: D
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6. In which of the following system will the
wavelength corresponding to n = 2 → n = 1
be minimum ?
A. Hydrogen atom
B. Deuterium atom
C. single ionized helium
D. Doubly ionized lithium
Answer: D
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7. Which of the following cueve may
repressent the speed of the electron in a
hydrogen atom as afunction of the principal
quantum number n?
A.
B.
C.
D.
Answer: C
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8. As one considers orbits with higher value of
n in a hydrogen atom, the electron potential
energy of the atom
A. decreases
B. increases
C. remain the same
D. does not increases
Answer: B
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9. The energy of an atom (or ion) in the
ground state is − 54.4eV .It may be?
A. Hydrogen
B. deuterium
C. H e +
D. Li + +
Answer: C
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10. The radius of the shortest orbit in a one
electron system is 18pm it may be
A. Hydrogen
B. deuterium
C. H e +
D. Li + +
Answer: D
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11. A hydrogen atom in ground state absorbs
10.2eV of energy .The orbital angular
momentum of the electron is increases by
A. 1.05 × 10 − 34
Js
B. 2.11 × 10 − 34
Js
C. 3.16 × 10 − 34
Js
D. 4.22 × 10 − 34
Js
Answer: A
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12. Which of the following parameters are the
same for all hydrogen like atoms and ions in
their ground state?
A. Radius of the orbit
B. Speed of the electron
C. Energy of the atom
D. Orbital angular momentum of the
electron
Answer: D
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13. In a inser tube all the photons
A. have same wavelength
B. have same energy
C. move in same direction
D. move with same speed
Answer: D
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Obejective Ii
1. In a laboratory experiment on emission from
atomic hydrogen in a discharge tube only a
small number of lines are observed whereas a
large number of lines are pressent in the
hydrogen spectrum of a star .This is because
in a laboratory
A. the amount of hydrogen taken is smaller
than that pressent in the star
B. the temperature of hydrogen is much
smaller than that of the star
C. the pressure of hydrogen is much
smaller than that of the star
D. the gravitational pull is much smaller
than that of the star
Answer: B
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2. An electron with kinetic energy 5eV is
incident on a hydrogen atom in its ground
state.The collision
A. must be elastic
B. may be partially elastic
C. must be completely inelastic
D. may be completely inelastic
Answer: A
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3. Which of the following products in a
hydrogen atom are independent of the
principal quantum number n? The symbols
have theirusual meanings
A. un
B. Er
C. E pi
D. ur
Answer: A::B
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4. Let A_(0) be the area enclined by the orbit in
a hydrogen atom .The graph of in (A 0 / A 1 )
againest in(pi)
A. will pass through the origin
B. will be a straigth line with slope 4
C. will be a monotonically increasing
nonlinear curve
D. will be a circle
Answer: A::B
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5. Ionzation energy of a hydrogen like A is
greater than that of another hydrogen like ion
Let r, u, E and L repreasent the radius of the
orbit, speed of the electron energy of the
atom and orbital angular momentum of the
electron respectively, in ground state
A. r A
> rB
B. u A
> uB
C. E A
> EB
D. L A
> lB
Answer: B
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Exercises
2
ε0 h
1. The bohr radius is given by a0 =
2
πme
verify that the RHS has dimesions of length
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2. Find the wavelength of the radiation by
hydrogen in the transition (a)n = 3 to n = 2,
(b)n = 5 to n = 4 and(c) n = 10 to n = 9`
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3. Calculate the smaller wavelength of
radiation that may be emitted by (a) hydrogen
(b)H e and (c ) Li
+ + +
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4. Evalute Rydberg constant by putting the
value of the fundamental constants in its
expression
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5. Find the binding energy of a hydrogen atom
in the state n = 2
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6. Find the radius and energy of a H e + +
ion in
the states (a) n = 1, (b)n = 4 and (c)n = 10
is
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7. A hydrogen atom emits ultraviolet of
wavelength 102.5nm what are the quantum
number of the state involved in the transition?
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8. Find the first excitation potential of He
+
ion (a)Find the ionization potential of Li
+ +
ion
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9. A group of hydrogen atom are prepered in
n = 4 states list the wavelength that are
emitted as the atoms make transition and
return to n = 2 states
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10. A positive ion having just one electron
ejects it if a photon of wavelength Å or
228
less is absorbed by it. Identify the ion
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11. Find the maximum coulomb force can act
on the electron due to the nucleus in a
hydrogen atom.
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12. A hydrogen atom in a having a binding of
0.85eV makes transition to a state with
excited energy 10.2eV (a) identify the
quantum number n of theupper and the lower
energy state involved in the transition (b) Find
the wavelength of the emitted radiation
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13. Whenever a photon is emitted by hydrogen
in balmer series it is followed by another in
lyman series what wavelength does this latter
photon correspond to?
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14. A hydrogen atom in state n = 6 makes two
successive transition and reaches the ground
state in the first transition a photon of 1.13eV
is emitted (a) Find the energy of the photon
emitted in the second transition (b) what is
the value of n in the intermediate state?
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15. What is the energy of a hydrogen atom in
the first excited state if the potential energy is
taken to be zero in the ground state?
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16. A hot gas emites radition of wavelength
46.0nm, 82.8nm and 103.5nm only Assume
that the atoms have only two excited state
and the difference between consecutive
energy levels decrease as energy is increased
Taking the energy of the higest energy state
to be zero find the energies of the ground
state and the first excited state
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17. A gas of hydrogen like ions is prepared in a
particular excited state A. if emit photons
having wavelength equal to the wavelength of
the first line of the lyman series together with
photons of five other wavelength identify the
gas and find the principal quantum number of
the state A
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18. Find the maximum angular speed of the
electron of a hydrogen atoms in a statoonary
orbit
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19. A spectroscopic instrument can resolve two
nearly wavelength λ and λ + Δλ if λ / Δλ
is smaller than 8000 This is used to study the
spectral lines of the balmer series of hydrogen
Approximately how many lines will be resolved
by the instrument?
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20. Suppose in certine condition only those
transition are allowed to hydrogen atoms in
which the principal quantum number a
changes by2 (a) Find the smaller wavelength
emitted by hydrogen (b) list the wavelength
emitted by hydrogen in the visible range
(380nm → 780nm)
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21. According to maxwell's theiory of
electrodnamics, an electron going in a circle
should emit redastion of frequency equal to
the frequency of revolution what should be
the wavelength of the radiation emitted by a
hydrogen atom in ground state if this rule is
follewed?
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22. The avrage kinetic energy of molecules in a
gas at temperature T is 1.5KT find the
temperature at which the average kinetic
energy of the molecules of hydrogen equals
the binding energy of its atoms will hydrogen
remain in molecles form at this temperature ?
Take k = 8.62 × 10
−5
eV K
−1
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23. Find the temperature at which the everage
thermal kinetic energy is equal to the energy
needed to take a hydrogen atom from its
ground state n = 3 state hydrogen can now
emit rod light of wavelength 653.1nm because
of maxwellan distribution of speeds a
hydrogen sample emits red light at
temperature much lower than that obtained
from this problem Asuume that hydrogen that
hydrogen molecules dissociate into atoms
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24. Avarage lifetime of a hydrogen atom
excited to n = 2 state 10
−6
s find the number
of revolutions made by the electron on the
avarage before it jump to the ground state
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25. calculate the magnetic dipolemoment
corresponding to the motion of the electron
in the ground state of a hydrogen atom
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26. The ratio of magnetic dipole moment and
angular momentum of charged body of charge
q and mass m is
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27. A beam of light having wavelength
distributed uniformly between
450nm → 550nm passes through a sample of
hydrogen gas which wavelength will have the
least intensity in the transition beam?
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28. Radiation coming from transition
n = 2 → n = 1 of hydrogen atoms falls on
helium in n = 1 and n = 2 state what are
the possible transition of helium ions as they
absorb energy from the radiation?
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29. A hydrogen atom in ground state obsebe a
photon of ultraviolet radition of wavelength
50nm Assuming that the entire photon
energy is taken up by the electron with what
kinetic energy will the up by the electron with
what kinetic energy will the electron be
ejected?
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30. A parallel beam of light of wavelength
100nm passes through a sample of atomic
hydrogengas in ground state (a)Assume that
when a photon suppose some of its energy to
a hydrogen atom the rest of the energy
appears as another photon moving in the
same direction as the incident photon
Neglecting the light emitted by the excited
hydrogen ato in the direction of the incident
beam, ? (b) A radiation detector is placed near
the gas to detect radiation coming
perpenducular to the incident beam find the
wevelength of radiation that may be detected
by the detector
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31. A beam of momechromatic light of
wavelength λ ejectes photonelectrons from a
cesium (ϕ = 1.9eV ) these photonelectron
are mde to collide with h-atom in ground state
. find the maximum value of λ for which (a)
hydrogen atoms may be ionised (b) hydrogen
may get excited from the ground state to the
first excited state and (c ) the excited
hydrogen atoms may emit visible light
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32. Electron are emited from an electron gun
at almost zero velocity and are accelerated by
an electric field E through a distance of 1.0m
The electron are now scatteared by an atomic
hydrogen sample in ground state what should
be the minimum value of E so that red light of
wavelength 656.5nm may be emitted by the
hydrogen?
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33. A neutron having kinetic energy 12.5eV
collides with a hydrogen atom at rest negect
the difference in mass between the neutron
and the hydrogen atom and assume that the
neutron does not leave its of motion find the
posible kinetic energy of the neutron after the
event
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34. A hydrogen atom moving at speed υ
collides with another hydrogen atom kept at
rest .Find the minimum value of u for which
one of the atoms may get ionized the mass of
a hydrogen atom = 1.67 × 10
− 27
kg
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35. A neutron moving with a speed u strikes a
hydrogen atom in ground state in ground
toward it with the same speed Find the
minimum speed of the neutron for which
ineleastic (completely or perially) collision may
take place .The mass of neutron = mass of
hydrogen = 1.67 × 10
− 27
kg
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36. When a photon is emited by a hydrogen
atom , the photon carries a momentum with it
(a) calculate the momentum carreied by the
photon when a hydrogen atom emits light of
wavelength 656.3nm(b) with what speed does
the atoms recoil during this transition? Take
the mass of the hydrogen atom
= 1.67 × 10
− 27
kg (c ) Find the kinetic energy
of recoil of the atom
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37. When a photon is emitted from an atom ,
the atom recils The kinetic energy of recoils
and the energy of the photon come from the
difference in energy between the state
involved in the transition suppose a hydrogen
atom change its state from n = 3 → n = 2
calculate the fractional change in the
wavelength of light emitted , due to the recoil
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38. The light emitted in the transition
n = 3 → n = 2 in hydrogen is called H light
α
.Find the maximum work fonction a metel one
have so that H light can emit photoelectrons
α
from it
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39. Light from balmer series of hydrogen is
able to eject photoelectron from a metal what
can be the maximum work function of the
metal?
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40. Radiation from hydrogen discharge tube
falls on a cesium plate find the maximum
possible kinetic energy of the photeelectron
work function of cesium is 1.9ev
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41. A filter transition only the radiationof
wavelength greater than 440 nm. Radiation
from a hydrogen discharge tube goes through
such a filter and is incident on a metel of work
function 2.0eV . Find the stopping potential
which can stop the photoelectrons.
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42. The earth revolves round the sun due to
gravitatinal attraction. Suppose that the sun
and the earth are point particle with their
existing masses and that Bhor's quantization
rule for angular monentum is valid in the case
of gravitation (a) Calculate the minimum
radius the earth can have for its orbit. (b)
What is the value of the principle quantum
number n for the present radius ? Mass of the
earth = 24
6.0 × 10 kg, mass of the sun =
2.0 × 10
30
kg, earth-sun distance =
1.5 × 10
11
m .
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43. Consider a neutrom and an electron bound
to each other due to gravitational force.
Assuming Bohr's quantization rule angular
momentum to be valid in this case, derive an
expression for the energy of the neutron-
electron system.
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44. A uniform magnetic field B exists in a
region. An electrons projected perpendicular
to the field goes in a circle. Assuming Bohr's
quantization rule for angular momentum,
calculate (a) the smallest possible radius of
the electrons (b) the radius of the nth orbit
and (c) the minimum possible speed of the
electron.
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45. Suppose in an imginary world the angular
momentum is quantized to be even integral
multiples of h / 2π . What is the longest
possible wavelenght emitted by hydrogen
atoms in visible range in such a world
according to Bohr's model?
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46. Consider an excited hydrogen atom in
state n moving with a velocity υ(υ < < c) . It
emits a photon in the direction of its motion
and changes its state to a lower state m. Apply
momentum and energy conservation principle
to calculate the frequency v of the emitted
radiation, compare this with the frequency v0
emitted if the atom were at rest.
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Short Answer
1. How many wavelength are emitted by atomic
hydrogen in visible range (380nm − 780nm)
? In the range 50nm → 100nm ?
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2. The excited energy of a He
+
ion is the
same as the ground state energy of hydrogen
is it always true that one of the energies of
any hydrogen like ion will be the same as the
ground state energy of a hydrogen atom?
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3. Which wavelength will be emitting by a
sample of atomic hydrogen gas (in ground
state) if electron of energy 12.5eV collide with
the atoms of the gas?
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4. When white radiation is passed through a
sample of hydrogen gas at room temperature ,
absorption lines are observed in lyman series
only Explain
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5. Balmer series was observed and analysed
before the other series .Can you suggest a
reason for such an order?
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6. What will be the energy corresponding to
the first excited state of a hydrogen atom if
the potential energy of the atom is taken to
be 10eV when the electron is widely
separated from the proton ? Can be still write
2
En = E1 / n , or , r n = a0 n
2
?
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7. The differece is the frequency of series limit
of lyman series and balmar series is equal to
the frequency of the first line of the lyman
series Explain
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8. The ionization potential for the electron in
the ground state of the hydrogen atom is 13.6
eV atom
−1
. What would be the inization
potential for the electron in the first excited
state of Li +
?
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9. We have stimulated and spontaneous
emission .Do we also have stimulated
absorption and spontaneous obsorption?
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10. An atom is in its excited state ,Does the
probalility of its coming to ground state
depend on whether the radiation is alreasdy
pressent or not? If you does it also depends
on the wavelength of the radiation pressent?
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