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Chapter Name: Atomic Structure
Q.1 The nature of cathode rays depends upon:
A) Cathode C) Anode
B) Gas enclosed D) None of these
Q.2 The wave number of the light emitted is 2 x 106 m-1, its wavelength is
A) 500 nm C) 500 m
B) 400 nm D) 200nm
Q.3 The continuous spectrum is due to:
A) Individual atoms C) Bulk of atoms
B) Liquid atoms D) Solid atoms
Q.4 Which is correct for H-atom?
A) it possesses 2e C) it possesses 2s
B) it possesses 2p D) it has orbit
Q.5 The separation between two consecutive shells:
A) is constant C) is increasing
B) is decreasing D) increasing rapidly
Q.6 The unit of o is?
A) NmC-2 C) C2N-1m-2
2 1 -2
B) C N m D) C2N-1m2
Q.7 The mass of electron is?
A) 9.11 x 10-31 g C) 9.11 x 10-31 Kg
B) 9.10995 x 10-31 g D) 9.10995 x10-31 Kg
Q.8 Visible light originates from H-atom
A) Lymann series C) Pfund series
B) Balmer series D) Paschen series
Q.9 UV light originates from H-atom.
A) Balmer series C) Paschen series
B) Pfund series D) Lymann series
Q.10 Infra-red light originates from H-atom
A) Balmer series C) Paschen series
B) Pfund series D) Both b and c
Q.11 H and H lines belong to?
A) Pfund series C) Neo series
B) Balmer series D) Lymann series
Q.12 Limiting line of the Balmer series lies in the:
A) UV region C) IR region
B) X-ray region D) Visible region
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Q.13 When electron jumps from 2nd orbit to 3rd orbit it absorbs.
A) UV region C) IR region
B) X-ray region D) Visible region
Q.14 The limiting lines of the Paschen, Brackett and Pfund series lie in:
A) UV region C) IR region
B) X-ray region D) Visible region
Q.15 K of X-ray is associated with the transition from.
A) L → K C) M → K
B) N → K D) L → M
Q.16 Moseley law can be written as:
A) √𝑣 = 𝑎𝑧 C) √𝑣 = 𝑎𝑧 𝑏
B) √𝑣 = 𝑎(𝑧 − 𝑏) D) √𝑣 = 𝑎𝑍 − 𝑏
Q.17 Bohr’s Atomic model is suited to only:
A) Hydrogen atom C) Hydrogen like atoms
B) Helium atom D) He+2
Q.18 Which one of the following is not a property of neutrons?
A) They are highly penetrating particles C) They can be used as projectiles to
carry out some chemical reactions
B) They are also used to carry out fission process D) They are helpful in radiotherapy
of cancer
Q.19 Which of the following is incorrect?
A) Charge on Proton = +1.6022 x 10-19 C C) Mass of Electron = 9.1095 x 10-31 kg
B) Mass of Neutron = 1.6726 x 10-27 kg D) e/m of proton > e/m of electron
Q.20 The difference in energy of electron in 3rd and 2nd orbit of hydrogen atoms is?
A) 9.84.99 kJ mol-1 C) 182.49 kJ mol-1
-1
B) 63.84 kJ mol D) 0 kJ mol-1
Q.21 The wave number of the radiation emitted when an electron jumps from n = 5 to n =
4 orbit of hydrogen atom is
A) 82.20 x 105 m-1 C) 15.21 x 105 m-1
B) 5.30 x 105 m-1 D) 2.46 x 105 m-1
Q.22 Wave equation that helps to determine the probability of finding an electron in an
Hatom was developed by:
A) Heisenberg C) Schrodinger
B) Dirac D) Louis de-Broglie
Q.23 In Chadwick’s experiment for the discovery of neutron the stream of  -particles
have been produced from:
A) uranium C) Lead
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B) Polonium D) Radium
Q.24 Which of the following are is true about fast neutrons?
A) Having energy more than 1.2 eV C) Having energy in range of 1 eV to 1.2 eV
B) Having energy less than 1 eV D) Having energy more of 1.2 MeV
Q.25 The smallest charge on droplet as calculated by Millikan is:
A) 6.022 x 10-23 C) 1.59 x 10-19
B) 1.6022 x 10-19 D) 1.6726 x 10-27
Q.26 The value for vacuum permittivity constant o is:
A) 8.845 x 1012C2J -1m-2 C) 8.845 x 1012C2Jm-1
12 -1 -1
B) 8.845 x 10 CJ m D) 8.845 x 10-12CJ-1m-1
Q.27 Rutherford’s model of an atom failed because
A) The atom did not have a nucleus and electrons C) It did not account for the
attraction between protons and neutrons
B) It did not account for the stability of the atom D) There is actually no space
between nucleus and electonrs
Q.28 The line of Hydrogen spectrum having wave number 2.43 x 106 belongs to …….
A) Lyman Series C) Blamer Series
B) Paschen Series D) Pfund Series
Q.29 Which of the following is a correct relationship?
𝑧2ⅇ4𝑚 1 1 𝑧2ⅇ4𝑚 1 1
A) 𝛥𝐸 = [𝑛2 − 𝑛2 ] 𝐽𝑜𝑢𝑙𝑒𝑠 C) 𝑣 = [𝑛2 − 𝑛2 ] 𝐻𝑧
8𝜀02 𝑛2 1 2 8𝜀02 𝑛2 1 2
𝑧 ⅇ4𝑚 1
2 1 −1
B) 𝑣̅ = [ − 𝑛2 ] 𝑚 D) all of these are correct
8𝜀02 𝑛2 𝑛12 2
Q.30 Which of the following rays help in determination of size and movement of
electrons?
A) Radio waves C) Micro waves
B) X-rays D) UV Rays
Q.31 d-orbital has five different orientations, this information is revealed by:
A) Principal Quantum Number C) Magnetic Quantum Number
B) Azimuthal Quantum number D) Spin Quantum Number
Q.32 Which of the following is most appropriate for a proton and an electron moving
with same speed?
A) The wave number of proton is smaller than electron C) The wave number of
proton is 1836 times smaller than electron
B) The wave number of proton is greater than electron D) The wave number of
proton is 1836 times greater than electron
Q.33 Which of the following s most appropriate for a  - particle and an electron moving
with same speed?
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A) The wave number of  is smaller than electron C) The wave number of  is 7344
times smaller than electron
B) The wave number of  is greater than electron D) The wave number of  is 7344
times greater than electron
Q.34 Which of the following has same mass number?
A) He atom and H ion C) He atom and  particle
B) He atom and H2 molecule D) He atom and Li+ ion
Q.35 Which of the following is not valid for Heisenberg’s principle of Uncertainty?
A) It is valid for the Macroscopic bodies C) It is valid for those that are behaving like
waves
B) It is valid for microscopic bodies D) A measurement cannot be 100% certain
Q.36 How did the two American Scientists proved the wave nature of electrons?
(A) They observed the reflection of electron waves (C) They observed the reflection of
electron waves
(B) They observed the interference of Electron waves (D) They observed the
diffraction of Electron waves
Q.37 If there are two electrons in an Orbit, then what is most suitable for them?
(A) They should have opposite spin (C) They must have same spin in separate
orbitals
(B) They must obey Pauli’s Exclusion principle (D) They may or may not have same
spin
Q.38 What is the correct representation of the Quantum numbers for an electron in last S
subshell?
(A) 1,0,0, 1/2 (C) 7,0,0, ½
(B) 1,0,0-1/2 (D) 7,0,0-1/2
Q.39 What is the correct representation of the Quantum numbers for the last electron in
F atoms?
(A) 2,1,1, ½ (C) 2,0,0, -1/2
(B) 2,0,0, ½ (D) 2,1,1, -1/2
Q.40 What is the correct electronic configuration of Br35 is?

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(A) [Kr]5s-1 (C) [Ar]4s2 ,3d10,4p5
(B) [Kr]4s2 ,3d10, 4p5 (D) [Ar]4s2 ,3d09,4p5
Q.41 Which of the following pairs are isoelectronic?
(A) N-2,O-1 ,F-1 (C) N+2,O-1 ,F+1
(B) N-2 ,O- ,F (D) N-2 ,O-3 ,F-4
Q.42 What is the location of Fe26 if its electronic configuration is 1s2 , 2s2 , 2p6 , 3s2 , 3p6 ,
4s2 , 3d6?
(A) Group # VIIB, Period # 3, d-block (C) Group # VIIIB, Period # 3, d-block
(B) Group # VIIIB, Period # 4, d-block (D) Group # VIIIA, Period # 3, p-block
Q.43 What is the location of Kr36 if its electronic configuration is 1s2 , 2s2 , 2p6 , 3s2 , 3p6 ,
4s2 , 3d10, 4p6?
(A) Group # VIIB, Period # 3, d-block (C) Group # VIIIB, Period # 4, d-block
(B) Group # VIIIA, Period # 3, s-block (D) Group # VIIIA, Period # 4, P-block
Q.44 Spin quantum number was introduced to explain the
(A) Self rotation of electron (C) Pauli’s exclusion principle
(B) Doublet of each line in H-spectrum (D) All of these are explained from Spin
quantum number
Q.45 The probability of finding an electron b/w two orbital is
(A) 95% (C) 0%
(B) 100% (D) 90-95%
Q.46 The space b/w two orbital is termed as
(A) Nodal plane (C) Anti nodal plane
(B) sub shell plane (D) shell core
Q.47 What is correct order of probability of finding an electron?
(A) 1s>2p>2s>3d>3p>3s (C) 1s<2p<2s<3d<3p<3s
(B) 1s>2s>2p>3d>3p>3s (D) 1s>2s>2p>3s>3p>3d
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Q.48 The (n+l) value of 4f, 5d, 6p and 7s is 7, what is the correct order of Probability of
finding an e- .
(A) 4f>5d>6p>7s (C) 4f=5d=6p=7s
(B) 4f<5d<6p<7s (D) 4f=5d<6p=7s
Q.49 The correct probability of landing an electron is.
(A) s<p<d<f (C) s>p>d>f
(B) s>p>d=f (D) s≤p>d=f
Q.50 By obeying Hund’s rule what is the correct about electronic configuration for Mn-
25?
(A) Mn has +7 oxidation state (C) Mn has 5 paired electrons
(B) Mn has 5 unpaired electrons (D) Mn is d-block element
Q.51 A set of orbitals with same/value is called as?
(A) shell (C) Subshell
(B) degenerate (D) generate shells
Q.52 Each d-orbital consists of four lobes except
(A) dz2 (C) dz2+y2
(B) dx2+y2 (D) dxz-yz
Q.53 In Milikan method for determination of charge on electron the air in the chamber is
ionized by
(A) Protons (C) X-rays
(B) electric field (D)  particles
Q.54 M+3 ion containing 14 neurtrons & acquire configuration of Neon, its mass number
(A) 27 (C) 28
(B) 32 (D) 39
Q.55 Which of the following is incorrect for wavelength?

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(A) 105m-1 (C) 10-5m
(B) 10-11m (D) nm
Q.56  particles resembles
(A) He+2 (C) He+
(B) He Atom (D) He2 molecule
Q.57 The radius of first orbit of H-atoms is 0.529 A, that of 2nd orbit is 2.11 A, & of 3rd
orbit is
(A) 3.87 A (C) 8.4 A
(B) 4.76 A (D) zero
Q.58 Energy of electron in the in 1st orbit of one H-atom according the Bohr’s theory
(A) -2.178 x 10-18 J/atom (C) -2.178 x 10-18 KJ/atom
(B) -1313.32J/atom D) -1313.32 kJ/atom
Q.59 Energy of electron in the infinite Bohr orbit of 1 mole of H-atom is
(A) -1313.32kJ/mole (C) -1kJ/mole
(B) 0kJ/mole D) 1 kJ / mole
Q.60 In Bohr model of hydrogen atom the distance between adjacent orbits increases
away from the nucleus, the energy difference between the orbits
(A) increase (C) decrease
(B) remain same D) orbits coincide

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