Sec: OSR.

IIT_*COSC(MODEL-A) GTA-13 Date: 20-04-25

Time: 3 Hrs 2018_P2 Max. Marks: 180
KEY SHEET
MATHEMATICS

1 BD 2 AB 3 ABD 4 AB 5 BD

6 BCD 7 54 8 50 9 3.55 10 1.50

11 0 12 6.93 13 5.50 14 36 15 A

16 B 17 D 18 D

PHYSICS

19 ACD 20 CD 21 AC 22 ACD 23 AC
24 AC 25 48 26 25 27 5 28 2

0.88
29 2 30 To 31 6 32 11 33 B
0.89
34 B 35 C 36 D

CHEMISTRY

37 BCD 38 ABCD 39 ABC 40 ABCD 41 ABC

0.78
42 ABCD 43 6.00 44 TO 45 126.00 46 -121
0.80

47 02 48 4.00 49 7 50 7 51 B

52 A 53 A 54 B
Narayana IIT Academy 20-04-25_OSR.IIT_*CO SC(MODEL-A)_JEE-ADV_GTA-13(P2)_KEY&SOL
SOLUTIONS
MATHEMATICS
1. P(1) = 1, P(–1) = 3
P(x) = a (x – 1) (x + 1)
 x3 
P x  a   x   c
 3 
3  x3 
 P x    x 2
2 3 
 –4 and one more +ve value of 

1
2. ln   lim ln 1!2!3!.......n!    ln n 
n  n 2

ln 1!2!3!.....n!  n 2  ln n 
ln   lim
n  n2
n 1 n2 n 3
2 3 4  n  n  n  1
ln    ln    ln    ......  ln    ln n  n 2 ln n
ln   lim  n  n n n 2
n  n2
1
 
2
1 n  1 r r
ln   lim
n  n
  1    ln
r 2  n n n
1 3
3 
 ln   3 1  x  ln xdx   4     4


4

3. Z9  1   Z  1 Z  2   Z   2  .......  Z  8 
Z=2
8
 2     2
i 1
i 9
1

1     2  3   4  5   6   7  8  0
Z     2   3   4 and Z   5   6   7  8
1
 Re  Z   
2

4. Let centre of circle be  x1 , y1  and radius be ‘r’

x1  y1 x1  y1
r ;  r2  2
2 2
 x1  y1   x1  y1 
2 2

r 2
;  r2  2
2 2
 x1  y1   x1  y1 
2 2

  2
2 2
 xy = –1
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Narayana IIT Academy 20-04-25_OSR.IIT_*CO SC(MODEL-A)_JEE-ADV_GTA-13(P2)_KEY&SOL
Solving x + 2y = 1 and xy = –1
 1
P(–1, 1) and Q  2,  
 2
Equation of tangent at P  x – y + 2 = 0
Using family of circle  x  1   y  1    x  y  2  0
2 2

 1 5
Satisfying  2,      
 2 2
1 1
and equation of circle x 2  y 2  x  y  3  0
2 2

5. a  20  6 , b  10  30
a  b  4  10  c  10  3
 a+b+c=
1  1 
 sin 2x  cos x    sin 2x  cos 2x 
2

2  2 
1  1  5 1
    sin 2x  cos 2x   
2  2  max 2
 m = 5, n = 2 and p = 3

6. 10 + c = 11 + d = 8 + a + b = 13 + e + f
By observation k = 19
c = 9, d = 8, a, b = 5, 6; e, f = 2, 4

4r 64
7.  8 r  56 
3 3
 r  6 r  26  0
r  3  35  r  44  6 35
 m = 44, n = 6, k = 35
28 7
cos 2  
100 25
3
 tan  
4
4r 64
BD  ; EC 
3 3
PQ2  PF2  QF2

QF  16  r   16  r 
2 2

DE  QF  8 r
 c
8. Let hyperbola be xy  c2 ;  ct, 
 t
x 2  y2  2  4y  20  0

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2
c 4c
 ct   2ct   20  0
2 2
2
t t
 c t  2ct  20t  4ct  c 2  0
2 4 3 2

2c
  c t1  c  2
c2
  2 2 20 
m  c t  c
2 2
1
2
  t 
1
2
 2t1 t 2   c    2 2 
2

 c  c 
m = 44
1
n  c2 
t12
1 1 1 1
c2 x 4  4cx 3  20x 2  2cx  c2  0 ; , , ,
t1 t 2 t 3 t 4
  1 2 1  2   4c 
2
20 
n  c    2   2
2
  c   2   2  2 
  t1  t1 t 2   c  c 
n = 56

9. ax 4  bx 3   a  1 x 2  bx  1   x 2  1  ax 2  bx  1
 b2  4a
a = 1, b = 1 a = 4, b = 1 2, 3 a = 8, b = 1, 2, 3, 4, 5
a = 2, b = 1, 2 a = 5, b = 1, 2, 3, 4 a = 9, b = 1, 2, 3, 4, 5
a = 3, b = 1, 2, 3 a = 6, b = 1, 2, 3, 4 32
p
a = 7, b = 1, 2, 3, 4, 5 81

10. a 2  c 2  2kb 2
x  yz a …(1)
y  zx b …(2)
z  xy c …(3)
2 2 2
x  z  2k y
xy z xz
OG1  , BG 2  y
3 3
 xyz   xz y
  0
 3   3 
2 2 2
x  z  2x  z  2x  y  2y  z  3 y  0 …(4)
From equation (1), (2), (3) and (4)
2 2 2
x  z 3 y

11. Since f(x) is odd function, f   x  will also be odd funciton, hence answer is 0.

3 2 3 3 2
12. Area of pyramid is 6  y  y
4 2

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Narayana IIT Academy 20-04-25_OSR.IIT_*CO SC(MODEL-A)_JEE-ADV_GTA-13(P2)_KEY&SOL
1 3 3 2
Volume of pyramid is  y  x 2  y2
3 2
x = 20 – y
3 2
Maximum value of y 400  40y is 128 15
2

13.

1 1
x   22  x     20  x    a
2 2
 x = 21

14. x  4 , y  3 , 2 , 1 , 0
x  5 , y  5,  4,  3,  2,  1, 0

 1 1 1  1 1 
15. (P) 1   2  3  ........ 1   2  ........   3
 2 2 2  3 3 
(Q) b 2  c 2  a 2  54 , 2bc cos A  2a 2  b 2  c 2  81
(R) Circumcentre is (–1, 0)
Locus is  x  1  y 2  2 2
2


(S) Solving equation cos   sin   1    2n  ,    2n  1 
2

16. Conceptual

17. Conceptual

18. Conceptual

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PHYSICS
2
19. geff = gsin53° = 8 m/s and friction = fk = N = 0.5 mgcos
= 0.5  m  10  0.6 [ = 53°]
 Situation is

By work energy theorem:

1
mg eff  l sin   f k  l   mv 2
2
 16 sin   10  cos   16 sin   6
v is max when a11 = 0 mgeff cos  = fk
mgsincos = mgcos
 sincos = cos
3 3
 cos   0.5  
4 8
mv 2
Also, T  mg eff sin  
l
 T = 8sin + 16sin 6
= 6[4sin ]
1
= Tmax happens at cos  
4

1 1 1
20.  
t v u
fu
v
uf
2
 f 
dv     .du ….(1)
 u f 
From energy conservation
1
mg(h  x)  kx 2
2
1 5  1
10    x    800x 2
10  100  2
x = 1.25 cm = Amplitude of object
then dv = 0.837
so, length of path of image = 2 v
= 1.67 cm
k 
 T  2  second
m 20 5
 Speed of object v0  2gh  1 m / s 2
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1 1 1 40  9
   v cm
f v u 11
2
v
vl     v 0
a
vl  0.67 m / s

21. f1 = f2 5
f1 = f2 5
 340  10  350 35
f1  f 2   f2  f2
 340  10  330 33
35
f 2  f 2  10
33
f2 = 165 Hz
f1 = 160 Hz

22. Let r = side of square at any time t.


VBA is along the line joining A and B
 = 0
Also, let us calculate force on any one particle (let us say A)
GM 2 GM 2
FA   cos 45 2 
r2 ( 2r)2
2GM 2 GM 2
= 
r2 2r 2
GM 2
= (2 2  1)
2r 2
m (2 2  1)
= GM 
(r / 2) 2
4
 When we think of this situation as if a mass
2 2 1
M is kept at the centre, instead of B, C and D
4
Now, the situation is something like
2 2 1
M
4
This situation can be thought of that of an ellipse whose eccentricity e  1
r
 becomes the major axis and time would be half of the time period
2
Since time period is dependent only on the major axis  first we calculate time period (T) for a circular
r T
orbit of radius and our answer (t) would be
2 2 2

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3/ 2
2  r 
T   
2 2 1 2 2
G. .M
4
1 2 1
 t     L3/2
2 2 2 1 (16 2)1/2

GM
4
1/ 2
  L3 
  
2 4 2  2  GM 

23. MSD = 0.5 mm

LC = 0.05 mm
Zero error = 8 MSD  4VSD
1 9
 8  4  2.2 mm
2 20
1
Diameter = 30.5 mm + 5   (2.2) = 2.885 cm
2

24. X 2 
 X2  2x
N0 (1)N0 + 2 N0

Diatomic diatomic monoatomic
1 1 2

U f  U10  energy released

5 5 3
N 0 kT0   N 0  (1   0 kT  (2 N 0 )kT
2 2 2
5  5
T0   (1   )T  3T
2 k 2
1

4
5 1 5 3 1 
 T0    T  3 T   8
2 4k 2 4 4 
2
20T0   15T  6T
k
20 2 
T0  T
21 21 k
20 2 22
T0  T0  T0  T
21 21 21
RT0 RT

P1 P2
T0 5 T 4T0
 
P1 4 P2 5T

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25.

l1  LT
L
l 2  T
2
3L
l  T  x1  x 2  x 3
2
kx1 = 2kx2 = 3kx3
1 1 1
U  k1 x12  k 2 x 22  k 3 x 32
2 2 2
U  99  48 108 J

26. Let ball pass tangentially just passing the tower and boy B move distance dmin to catch the ball.
From similarity
d min 6
  d min  15 m
20 8
AC2 = (20)2 (15)2
AC  5 7 m
AC is the range of ball projection
u 2 sin 2
5 7
g
50 7
sin 2 
625
1  28 
  sin 1  
2  25 

27. Let liquid in vertical arm displaced by h1 downward

10h1 = 1  x
h2 = x sin 
= 10h1 sin
= 5h1
P = g (h1 + h2) = 6gh1

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3
P  gx
5
Here we need P = 0.18  103g and x = 0.6 mm
3
18  105 103 g = g  6  10 4
5
3
 = 500 kg/m

28. Required energy is the electrical energy present everywhere except the space occupied by conductors.
kq 2  1 1  kq 2  1 1  kq 2  1 1 
E           ....
2  a 2a  2  3a 4a  2  5a 6a 
kq 2
E ln 2
2a

29. x1x2 = (n + 1)

x3 x4 = n
x1 x2 x3 + x4 =  = (x1 x3 (x2 x4)
sin sin  = 


sin   sin 
For  =  and  = 
  5
  
sin   sin  3  4 7
5 5
3R R
30. C AB   = 2R
2 11
2R8T = QAB = 26RT
5 3
Q BCA  R(3T  9T)  R(T  3T)
2 2
 15RT  3RT  18RT
16 8
Ratio  
18 9
AB is polytropic process of order (1)
R R 3 R
C   R
 1  1 2 2
C = 2R

4 3
31. v  r
3
dv 3dr

v r
 dr 
9  3 %
 r 
dr
 3%
r

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C = 40r
dC dr
  3%
C r

32. At steady state potential across the capacitor is 1 V

 q = Cv0et/
 q(t ) = Cv0
= 11 C

mv 02
33. N  0  mg cos 37 
R
4
 v 0  Rg   0.8gR
5
 0.8gR  2gh
 h = 0.4R
 y0 = 0.2R and x0 = 0.6R
2 2
m h m h
Also, N1  mg   2g  and mg  N 2   2g 
R 2 R 2
 N1 N2 = 0.8 mg

34. A  B  C
N1 N2

dN 2
  1 N1   2 N 2
dt
dN 2
 1 N 0 e 1t   2 N 2
dt
1
N2  N 0 (e1t  e 2 t )
 2  1
 21
A2  2 N2  N 0 (e 1t  e 2 t )
 2  1
A1  N0 1e1t
If 1 = 82
 N 0  2  2 t
A2  (e  e 8 2 t )
7
A1  8N 0  2e 82 t
A 2 1  e 2 t  e 82 t  1 7  2 t
    (e  1)
A1 7  e 8  2 t  7
If 2 = 81

A 2  1 N 0 (e 1t  e 8 1t )
7
A1  N0 1e1t
If 1<<2
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A2 2
 (1  e ( 2 1 )t )
A1  2  1
A2
 (1  e2 t )
A1
A2
At t = , 1
A1

35. For (P) using ampere’s circuital law

B  2d = 0I
 I
B 0
2 d
For (Q)
r
Ir   2rdrJ
0

B  2r  0 Ir
0  I   r 
B    r 1  
2  d 2   d 
  I   d  1   I 1  I
 B   0 2   1    0   0
 2d   2  3  2d 3 6d
For (R)
 
sin  90  
 0 I dl  2
dB 
4 r 2


dI = dd, r  2d cos
2

 Idd cos
 dB  0 2
4  
2

 2d cos 
 2
I
B  0 ln ( 2  1)
4 d
For (S)
0 I
B  4  sin 45  sin 45 
d
4  
2

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2 20 I

d

36. When the sphere reaches bottom

 R r 
KE  mg  h   mg  
 2 
1 1 2 1
E not  I2   mr 2 2  mv 2
2 2 5 5
 R r 7
  mv
2
mg 
 2  10
10  R r
 mv 2  mg  
7  2 
2  R r 
E rot  mg  
7  2 
 0.8 
KE  10    4J
 2 
mg(h 2 )  KE  E rot  2.86
h 2  0.286
 h2 = h2 + r = 0.486
h1 = 0.2 + 0.4 = 0.6

CHEMISTRY

37.

Trans-optically inactive

Cis-optically – active
Pt(VI) 5d6
  t 62g , eg0 

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is low spin complex

41. At half life of overall reaction

Total pressure = PA + PB = PC
2 1 3 3 135
= 4.5   4.5   4.5 = 16.875 = atm
4 4 8
2 1
PB   9  4.5 atm
4
PC  20.25 atm
[B]t 2
 at any time
[C]t 9

42. In path A  B
Ratio of temperature> ratio of pressure
Only possible when volume is increasing, so work is done by system
In path B  C
Ratio of temp. = ratio of pressure
So, volume constant
So, P-V work involved is zero
At point A & C, P is constant
So, ratio of volume = ratio of temp.
VC TC 450 2  0.082  900
  and VB  = 36.9 L
VA TA 150 4

43. Blue solution / blue ppt / blue colour

Species are
Cu(NO3 ) 2 (aq.) [Cu(H 2 O) 4 ]2
[Cu(NH3 )4 ]2 , [Ni(NH3 )6 ]2
N 2 O3 (), liquid O3
While  Mn(H 2 O)6  and  Co(H 2 O) 6  are pink in aq. Solution
2 2

44. 3CuFeS2 + 5O2 2Cu + 2FeO + 6SO2

5 mole of O2 2mole of Cu
2  63.5
1 kg O 2  = 0.7937= 0.79 kg
6  32

45. MnCl 2  K 2S2 O8  H 2 O 

 KMnO 4  H 2SO 4  HCl
'a ' mole

C2 O 24  MnO4 
H
 CO 2  Mn 2
Meq of C2 O24  Meq of MnO24 = Meq of Mn O2
225
 2  a 5
90

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Wt. of MnO2 = 1  126 = 126 mg

46. C6 H10  H 2 
 C6 H12 H  ?
H   HC (Re ac tan ts)  HC (products)
 (3800  214)  (3920) = 121 KJ/mole

47. Let rate law for A  Product

r = K [A]n
at 5% and 10% decomposition
n
2.236  0.95 
 
2.000  0.90 
Solving by given log
n = 2.00 (Ans)

48.

51.

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SNAr
52. (P)   X  
SEAr
 Y
SEAr
(Q)    X  
radical
Y
SEAr
(R)    X  radical
Y
E* addition
(S)    X  SEAr
Y

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