T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 1/8
TAIACRYL BLUE GRF-T 200%
BB-18201
1. Identification of the substance/preparation and company
Taiacryl Blue GRF-T 200% BB-18201
Use pattern:
Textile dye
Company : T & T INDUSTRIES CORPORATION
Address : 6TH FLR.WAN-I-CHEN BLDG.
124 NANKING E.ROAD, SEC.2,
TAIPEI, TAIWAN, R. O. C.
Emergency phone : (02)2506-4107
(03) 483-1666 [AVAILABLE 24 Hours]
2. Hazards Identification:
Labelling in accordance with the GHS directives:
Acute toxicity: 4 (Oral)
Serious eye damage/eye irritation: 1
Hazardous to the aquatic environment,long-term (Chronic): Chronic 2
Danger
Hazard symbols:
Corrosion Exclamation Environment
Mark
Contains: C.I. Basic Blue 159
C.I. Basic Blue 3
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H411: Toxic to aquatic life with long lasting effects.
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 2/8
TAIACRYL BLUE GRF-T 200%
BB-18201
P280: Wear protective gloves/protective clothing/eye protection/face
protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you
feel unwell.
P330: Rinse mouth.
P305+P351P338: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses if present and easy to do. Continue
rinsing.
P310: Immediately call a POISON CENTER or a doctor/physician.
P273: Avoid release to the environment.
P501: Dispose of contents/container to waste treatment in accordance
with national regulations.
3. Composition/Information On Ingredients：
Preparation of oxazine/azacyanine dyestuffs
Components CAS Number Concentration %
Basic Blue 3 63589-47-9 4
Basic Blue 159 93783-70-1 35
Sodium Sulfate 7757-82-6 61
Hazardous ingredients:
C.I. Basic Blue 159
Content: 30-40% CAS-Number 93783-70-1 H phrases: H301-H318-H411
C.I. Basic Blue 3
Content: 1-5% CAS-Number 63589-47-9 H phrases: H301-H331-
H318-H410
4. First Aid Measures：
General information: Take off immediately all contaminated clothing.
After inhalation: Upon inhalation of aerosol/vapour/dust: Take the patient into
the fresh air; if there is difficulty in breathing, medical advice is required.
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 3/8
TAIACRYL BLUE GRF-T 200%
BB-18201
After contact with skin: Cleansing with plenty of water, soap or other non-
irritating cleansing agents.
After contact with eyes: Contamination of the eyes must be treated by thorough
irrigation with water, with the eyelids held open. Eventually a doctor (or eye
specialist) should be consulted.
After ingestion: Rinse mouth out immediately. In case of swallowing, drink
plenty of water. Do not induce vomiting. Consult a doctor.
5. Fire-Fighting Measures：
Suitable extinguishing media: water mist, foam, dry powder
Extinguishing media that must not be used for safety reasons: CO2
Special protective equipment for firefighting: Firemen have to wear self-
contained breathing apparatus.
Further information: Fire residues and contaminated firefighting water must be
disposed of in accordance with the local regulations.
6. Accidental Release Measures:
Personal precautions: Avoid formation and deposition of dust.
Environmental precautions: Do not empty into drains or waters.
Methods for cleaning up/taking up: Take up spilled product with dust-binding
material or suitable vacuum cleaner. Fill into labeled, sealable containers.
Additional information: For further disposal measures see chapter 13.
7. Handling and Storage:
Advice on safe handling: Avoid formation and deposition of dust.
Keep container tightly closed and dry.
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 4/8
TAIACRYL BLUE GRF-T 200%
BB-18201
Advice on protection against fire and explosion: Observe the usual
precautionary measures required for chemicals with dust-explosive properties.
Observe national regulations.
Requirements for storage rooms and vessels: Store in original container in a
cool, dry place.
In filling operations take precautionary measures against static discharges.
Do not allow product temperature to exceed 50℃
Storage class: 11 Combustible solids
Storage stability: Storage period: 2 Years
8. Exposure Controls/Personal Protection:
General protective measures: Do not breathe dust. Avoid contact with eyes and
skin. Take off immediately all contaminated clothing.
Hygiene measures: Keep away from food drink stuffs.
Do not eat, drink or smoke at work.
Wash hands before breaks and at end of work and use skin-protecting ointment.
Respiratory protection: Dust mask with particle filter.
Hand protection: Wear suitable gloves e.g. of PVC or nitrile rubber. In the
event of contamination, change protective gloves immediately.
Eye protection: Tightly fitting safety glasses.
Body protection: Wear protective clothing.
9. Physical And Chemical Properties：
Form: Powder
Colour: Blue
Odour: Odourless
Flash point: Not applicable
Bulk density: 450 – 600 kg/m3
Solubility in water: 60 g/l (25℃)
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 5/8
TAIACRYL BLUE GRF-T 200%
BB-18201
pH value: 2.0 – 3.0
Water
Impact sensitivity: Not impact-sensitive
10. Stability and Reactivity:
Thermal decomposition No thermal decomposition when stored and
handled correctly
Hazardous reactions: In the case of dusty organic products, the possibility of
a dust explosion should always be considered.
11. Toxicological Information:
Acute oral toxicity: LD50 657 mg/kg (rat)
Irritant effect on skin: non-irritant (rabbit)
Irritant effect on eyes: irritant – risk of serious damage to eyes
(rabbit eye)
Remarks: Test results of a similarly composed product
12. Ecological Information:
Biodegradability: < 10 %
Method: Evaluated from the components
Fish toxicity: LC50 10 – 100 mg/l (96h, Brachydanio rerio)
Bacteria toxicity: 1 – 10 mg/l
Method: 50% - inhibitory effects:
Test procedure: Respiratory inhibition of
activated sludge organisms according to D.
Brown et al. Chemosphere, 10(3), 245-261
(1981), and conforming to OECD Guideline
209.
Chemical oxygen demand (COD): approx. 1000 mg/g
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 6/8
TAIACRYL BLUE GRF-T 200%
BB-18201
Biochemical oxygen demand (BOD5): 46 mg/g
Remarks: Test results of a similarly composed product.
Product does not add to the AOX-value of the sewage. (DIN EN 1485)
This product contains approx. 4.72% ionic zinc.
The product does not release nitrogen which can contribute to eutrophication.
The product does not contain phosphates or organophosphorus compounds.
13. Disposal Considerations:
Product: if utilization or recycling of the product is not possible, it should
be disposed of according to the local regulations and laws, e.g. by
incineration in a suitable plant.
European Waste Catalogue (EWC) code: 040216 Dyestuffs and pigments containing
dangerous substances.
Unclean packaging: Soiled, empty containers are to be treated in the same way
as the contents
14. Transport Information：
UN number: UN 3077
UN proper shipping environmentally hazardous substance, solid,
name: n.o.s
Transport hazard 9
class(es):
Packing group: Ⅲ
Environmental hazards: yes
Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 7/8
TAIACRYL BLUE GRF-T 200%
BB-18201
DOT Classification
UN number: UN 3077
UN proper shipping name:environmentally hazardous substance, solid,n.o.s
Transport hazard class(es): 9
Packing group: Ⅲ
Environmental hazards: yes
ERG Code: 171
15. Regulatory Information：
Safety, health and environmental regulations/legislation specific for
the substance or mixture
Taiwan Regulation：
Toxic Chemical Substance Control Act(TCSCA)
Occupational Safety and Health Act(OSHA)
CNS 15030 Classification and Labelling of Chemicals
Regulation of Labelling and Hazard Communication of Hazardous Chemicals
by MoL
Labelling and Safety Data Sheets for Toxic Chemicals by EPA
European Regulation:
Registration REACH: All the substances in the product are listed.
Chemical safety assessment:
Chemical Safety Assessment has been carried out: No
16. Other Information：
Text of all H phrases referred to in sections 2 and 3:
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T&T INDUSTRIES CORPORATION
Safety Data Sheet in accordance with the GHS Directives
Revised Date: 2025/01/06 Page 8/8
TAIACRYL BLUE GRF-T 200%
BB-18201
H301: Toxic if swallowed.
H302: Harmful if swallowed.
H318: Causes serious eye damage.
H331: Toxic if inhaled.
H410: Very toxic to aquatic life with long lasting effects.
H411: Toxic to aquatic life with long lasting effects.
H412: Harmful to aquatic life with long lasting effects.
This information is based on our present state of knowledge. It should not
therefore be construed as guaranteeing specific properties of the products
described or their suitability for a particular application.
