Scribd
Upload
10 views2 pages

Org Ba - BSC 4th Sem 2021

Uploaded by

sarabjitsingh3090
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
10 views2 pages

Org Ba - BSC 4th Sem 2021

Uploaded by

sarabjitsingh3090
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 2

Exam.

Code : 103204
Subject Code : 1293

B.A./B.Sc. 4th Semester


CHEMISTRY
(Organic Chemistry–III)
Time Allowed—2 Hours] [Maximum Marks—35
Note :—There are EIGHT questions of equal marks.
Candidates are required to attempt any
FOUR questions.

1. (a) Identify the correct procedure for the conversion


of the following and specify the mechanism in
each case :

(i) Bromobenzene → benzoic acid

(ii) tert-Butyl chloride →2,2-dimethylpropanoic


acid

(b) Why CH3COCl is more reactive than CH3CONH2


towards nucleophilic acyl substitution ?

2. Write the mechanism for the following forward and


backward reaction. Also explain how do we control
the position of equilibrium.

RCOOR' + H2O RCOOH + R'OH

3165(2721)/II-6587 1 (Contd.)
3. (a) Write product(s) in the following reaction with 7. What product(s) would be formed when organolithium
mechanism and stereochemistry : reacts with acid chloride, epoxide, nitriles, CO2, alkynes
and carbonyl compounds ? Explain with mechanism in
each case.
Br2 OH–
? ? 8. What product(s) would be formed when
H2O
organomagnesium reacts with carbonyl compounds,
cyanogen chloride, halogenated compounds and alkyl
(b) What happened when tetrahydrofuran treated with
chloroformate ? Explain with mechanism in each case.
HI ? Explain with mechanism.
4. (a) Discuss one example in each case for electrophilic
and nucleophilic substitution reaction of heterocyclic
compound.
(b) Among the Pyrrole, Thiophene and Furan, which
is more aromatic and why ?
5. (a) Write mechanism for Hoffmann bromamide reaction
by taking suitable example.
(b) How 1º, 2º and 3º amines can be separated using
Hinsberg test ? Explain with suitable example.
6. Write short notes on :
(a) Basicity of amine
(b) Reductive amination.

3165(2721)/II-6587 2 (Contd.) 3165(2721)/II-6587 3

You might also like