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Assignment class 12

The document contains a series of multiple-choice questions related to coordination compounds for a Class 12 chemistry test. Topics covered include oxidation states, complex naming, coordination numbers, isomerism, and magnetic properties of various coordination complexes. Each question presents four answer options, requiring knowledge of coordination chemistry concepts.

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10 views5 pages

Assignment class 12

The document contains a series of multiple-choice questions related to coordination compounds for a Class 12 chemistry test. Topics covered include oxidation states, complex naming, coordination numbers, isomerism, and magnetic properties of various coordination complexes. Each question presents four answer options, requiring knowledge of coordination chemistry concepts.

Uploaded by

pavitpalsingh66
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Chemistry test

Class 12 ( coordination compounds)

1. The oxidation number of Cr in a [Cr(NH3)2F4]– complex is


(a) II
(b) III
(c) IV
(d) VI.
2. The formula of potassium dicyanodi (oxalato) nickelate (II) is
(a) K4[Ni(CN)(Ox)2]
(b) K3[Ni2 (CN)2 (Ox)2]
(c) K4[Ni(CN)2(Ox)2]
(d) K2[Ni(CN)2(Ox)2]
3.
The name of [Co(NH2)3 (NO2)3] is
(a) Trinitrotriamminecobalt(III)
(b) Trinitrotriamminecobalt(II)
(c) Trirtitrotriamjninecobalt (III) ion
(d) TrinitrotnamminecobaHate (III).
4.
The co-ordination number of cobalt in the complex [Co(en)2Br2]Cl2 is
(a) 4
(b) 6
(c) 5
(d) 2.

Question 5.
The number of halide ions in [Pt(NH3)3Cl3Br]Cl will be
(a) 4
(b) 3
(c) 2
(d) 1.
Question 6.
K3[Al(C2O4)3] is called
(a) Potassium alumino oxalate
(b) Potassium aluminium (III) trioxalate
(c) Potassium trioxalato aluminate (III)
(d) Potassium tris (oxalato) aluminium.
Question 7.
EDTA combines with cations to form
(a) chelates
(b) clathrates
(c) non-stoichiometric compounds
(d) polymers.

Question 8.
One among the following is an example of hexadentate ligands
(a) 2,2-bipyridyl
(b) ethylenediammine tetra acetate ion
(c) dimethyl glyoxime
(d) Tetracarbonyl nickel.

Question 9.
Amongst Ni (CO)4, [Ni(CN)4]2- and NiCl42-
(a) Ni(CO)4 and NiCl42- are diamagnetic and [Ni(CN)4]2- is paramagnetic
(b) NiCl42- arrd [Ni(CN)4]2- are diamagnetic and Ni(CO)4 is paramagnetic.
(c) Ni(CO)4 and [Ni(CN)4]2- are diamagnetic and [NiCl4]2- is paramagnetic.
(d) Ni(CO)4 is diamagnetic and [NiCl4]2- and [Ni(CN)4]2- are paramagnetic.

Question 10.
Which of the following coordination compounds can exhibit coordination somerism?
(a) [Co(en)2Cl2]Br
(b) [Co(NH3)6], [Cr(CN)6]
(c) [Co(en)3]Cl3
(d) [Co(NH3)5NO2]Cl2
Question 11.
Which of the following compounds can exhibit linkage isomerism?
(a) [Co(en)3]Cl3
(b) [Co(en)2Cl2]Cl
(c) [Co(en)2NO2Cl]Br
(d) [Co(NH3)5Cl]Br2.
Question 12.
In Ni (CO)4, the nickel atom is ……… hybridised
(a) sp²
(b) sp³
(c) dsp²
(d) sp³d.
Question 13.
Which of the following compounds can show optical isomerism?
(a) trans-[Co(en)2Cl2]Br
(b) [Co(en)3]Cl3
(c) trans-[Co(NH3)4Cl2]Cl
(d) [Co(NH3)5Cl]Cl2.Question 14.
How many ions are produced from [Co(NH3)5Cl]Cl2 in solution,
(a) 3
(b) 4
(c) 2
(d) 5
Question 15.
[Fe(NO2)3 Cl3) and [Fe (ONO)3 Cl3] show
(a) linkage isomerism
(b) geometrical isomerism
(c) optical isomerism
(d) none of these.
Question 16.
Which one of the following is expected to exihibit optical isomerism (en = ethylene
diammine).
(a) cis-[Pt (NH3)2Cl2)
(b) cis-[Co(en)2Cl2
(c) trans-[Co(en)2 Cl2]
(d) trans-[Pt (NH3)2Cl2]
Question 17.
Which one of the following is an inner orbital complex as well as diamagnetic in behaviour?
(a) [Zn(NH3)6]3+
(b) [Ni(NH3)2]2+
(c) [Cr(NH3)6]3+
(d) [Co(NH3)6]3+
Question 18.
Which of the following cyano complexes would exihibit the lowest value of paramagnetic
character?
(a) [Cr(CN)6]3-
(b) [Mn(CN)6]3-
(c) [Fe(CN)6]3-
(d) [Co(CN)6]3-
Question 19.
Which of the following compounds shows optical isomerism?
(a) [Cu(NH3)4]2+
(b) [ZnCl4]2-
(c) [Cr(C2O4)3]3-
(d) [Co(CN)6]3-
Question 20.
The spin magnetic moment of cobalt in the compound Hg [Co(SCN)4]
(a) √3
(b) √8
(c) √15
(d) √2
Question 21.
The diamagnetic species is
(a) [Ni(NH)4]2-
(b) [NICl4]2-
(c) [CoCl4]2-
(d) [CoF6]2-
Question 22 Considering H2O as a weak field ligand, the numbers of unpaired electrons in
[Mn(H2O)6]2+ will be [At. No. of Mn = 25]
(a) 3
(b) 5
(c) 2
(d) 4
Question 23.
How many isomers are possible in [Co(en)2 Cl2]?
(a) 2
(b) 4
(c) 6
(d) 1

Question 24.
The oxidation state of Cr in lCr(NH3)4Cl2]+ is
(a) + 3
(b) + 2
(c) + 1
(d) 0

Question 25.
Which type of isomerism is shown by, the octahedral complex [Co(NH3)4 Br2 ]Cl?
(a) Geometrical and ionisation
(b) Geometrical and optical
(c) Optical and ionisation
(d) Geometrical only
Question 26 .Which one of the following is an outer orbital complex?
(a) [Fe(CN)6]4-
(b) [Mn(CN)6]4-
(c) [Go (NH3)6]3+
(d) [Ni (NH3)6]4+
Question 27.In the spectrochemical series, the magnitude of the crystal field splitting is
maximum for which ion?
(a) Cl–
(b) F–
(c) NO2
(d) CN–
Question 28.
The complex used as an anticancer agent is
(a) mer-[Co(NH3)2 Cl3]
(b) cis-[PtCl2 (NH3)2]
(c) cis-K2[PtCl2Br2]
(d) Na2CoCl4
Question 29.
One mole of complex compound Co (NH3)5Cl3 gives 3 moles of ions on dissolution in water.
One mole of the same complex reacts with two moles of AgNO 3 solution to yield two moles
of AgCl (s). The structure of the complex is
(a) [Co(NH3)3Cl3] 2NH3
(b) [CO(NH3)4Cl2] Cl NH3
(c) [CO(NH3)4Cl]Cl2.NH3
(d) [CO(NH3)5Cl]Cl2
Question 30.
The correct order for the wavelength of absorption in the visible regionis
(a) [Ni(NO2)6]4- < [Ni (NH3)6]2+ < [Ni (H2O)6]2+
(b) [Ni(NO2)6]4- < [Ni (H2O)6]2+ < [Ni (H3)6]2+
(c) [Ni(H2O)6]2+ < [Ni (NH3)6]2+ < [Ni (NO2)6]4+
(d) [Ni(H3)6]2+ < [Ni (H2O)6]2+ < [Ni (NO2)6]4-

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