Lesson 2.
1
Development of the
Atomic Theory
Lecturer: Kevin Nick S. Bandibas
Democritus
• “Atomos” concept (5th century BC)
• “Matter is composed of tiny
indivisible objects”
• Not accepted by Aristotle and was
later ignored for centuries
John Dalton
• Atomic Theory (1803)
1. Each element is composed of extremely small
particles called atoms.
2. All atoms of a given element are identical, but
atoms of one element are different from the
atoms of all other elements.
3. Atoms of one element cannot be changed into
atoms of a different element, atoms are
neither created nor destroyed.
4. Compounds are formed when atoms of more
than element combine; a given compound
always has the same relative number and kind
of atoms.
Julius Plucker
• Pioneered investigations on
Cathode Rays
Joseph J. Thomson
• Discovered the Electron (1897)
• Plum-Pudding Model of the Atom
• Charge to mass ratio of electron =
1.758820 x 1011 C/kg
Thomson’s Cathode Ray Tube
Experiment
Robert Millikan
• Oil-drop Experiment
• Charge of Electron = 1.602 x 10-19 C
Millikan’s Oil-Drop Experiment
Ernest Rutherford
• α particle scattering experiment
• Discovered the Proton
• Nuclear Model of the Atom (1904)
Rutherford’s α Particle Experiment
Max Planck
• Originator of the quantum
theory (1900)
• Blackbody radiation
• “quanta”
• E = hv
Blackbody Radiation Plots
Albert Einstein
• Photoelectric Effect (1905)
• “photon”
Niels Bohr
• Planetary Model of the Atom (1913)
Emission Spectrum of Hydrogen
Louis de Broglie
• Wave-particle duality (1923)
physical entities possessing
both wave-like and particle-like
characteristics.
Erwin Schrödinger
• Quantum mechanical model (1926)
•Ĥψ=Eψ
Werner Heisenberg
• Uncertainty Principle (1927)
• Matrix Mechanics (1925)
James Chadwick
• Discovered the neutron (1932)
Chadwick’s Beryllium Experiment
Summary of the Subatomic Particles
Subatomic Particles, Ion, and Isotopes
• Atomic Numbers, Z - #p+ in the nucleus
• Mass Numbers, A - #p+ plus #n°
A = Z + #n°
• Ions – atoms that have a net positive (cation) or negative
(anion) charge due to e- gain or loss
– #p+ and #n° are constant
• Isotopes – atoms that have the same Z but different A due
to different #n°
Ex: 1H (hydrogen), 2H (deuterium), 3H (tritium)
Isotopes of Hydrogen atom
Atomic and Mass Numbers
Example
Element or #p+ #e- #n0
Ion
27 3+
13𝐴𝑙 13 10 14
16 8 8 8
8𝑂
80 - 35 36 45
35 𝐵𝑟
Assessment 2.1