HI-TEC INDUSTRIES

Date: October 29, 2014

SDS DATA SHEET
PROJECT 1 POLYURETHANE EXPANDING FOAM SEALANT

1. Identification
1.1 Product Identifier Project 1 Expanding/Insulating Foam Sealant Part No. 7000-12
1.2 Relevant Use One Component Polyurethane Foam Sealant HC
SDS Number P1F7000
1.3 Supplier/Manufacturer HI-TEC Industries
6100 S. Fairfax Road
Bloomington, IN 47401
Contact Telephone No. (800) 457-1313 (Monday-Friday 8:00am-5:00pm EST)

2. HAZARDS IDENTIFICATION
Emergency Overview:
2.1 Hazard Classification Flammable Aerosol- Category 1
Gases Under Pressure- Compressed Gas
Acute Toxicity Inhalation- Category 4
Skin Irritation- Category 2
Serious Eye Irritation Category 2A
Respiratory Sensitizing Category 1
Skin Sensitization 1
Specific Target Organ Toxicity SE 3
Specific Target Organ Toxicity RE 2
2.2 Label elements
Hazard Pictograms

Signal Word DANGER

Hazard Statements Extremely flammable aerosol
Contains gas under pressure; may explode if heated
Harmful if inhaled
Causes Skin Irritation
May cause an allergic skin reaction
May cause allergy or asthma symptoms or breathing difficulties if inhaled
Causes Serious Eye Irritation
May cause respiratory irritation
May cause damage to organs through prolonged or repeated exposure

Prevention Keep Out of Reach of Children

Keep away from heat/sparks/open flames/hot surfaces-No Smoking
Do not spray on an open flame or other ignition source
Pressurized Container: Do not pierce or burn, even after use
Do not breathe dust/fume/gas/mist/vapors/spray
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
In case of inadequate ventilation wear respiratory protection
Wear protective gloves/eye protection/face protection
Wash hands thoroughly after handling
Response: Get medical advice/attention if you feel unwell
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: get medical attention.
IF ON SKIN: Wash with plenty of water. If skin irritation or rash occurs: Get medical
advice/attention.
IF INHALED: Remove Person to fresh air and keep comfortable for breathing. Call a poison
center/physician.

Storage Do not expose to temperatures exceeding 50◦C/122◦F. Protect from sunlight. Store in a well-
ventilated place. Store locked up.

Disposal Dispose of contents/container in accordance with applicable

local/regional/national/international regulations.

2.3 Additional Information:

Hazards not otherwise
classified: Not applicable

WHMIS Classifications: Class A- Compressed Gas

Class B5- Flammable Aerosol
Class D2A- Respiratory Sensitizer
Class D2B- Skin Sensitization
Class D2B- Skin/Eye Irritant

WHMIS Signal Word: DANGER

WHMIS Hazard Symbols:

3. Composition/ Information on Ingredients

Ingredient CAS No. Wt. %

4,4’ Diphenylmethane diisocyanate 101-68-8 5-10

Polymethylene polyphenyl isocyanate 9016-87-9 5-10
Isobutane 75-28-5 3-7
Dimethyl ether 115-10-6 3-7
Propane 74-98-6 1-5

4. First Aid Measures

4.1 Description of first aid measures
Eye: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If
easy to do, remove contact lenses, if worn. If irritation persists, get medical attention.
Skin: In case of contact, immediately flush skin with plenty of soap and water. Remove
contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation
persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Obtain medical attention.
Ingestion: If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Get medical advice/attention.

4.2 Most important symptoms and effects, both acute and delayed:
Eye: May cause eye irritation.
Skin: May cause skin irritation. Symptoms may include redness, edema, drying, defatting and
 cracking of the skin. May cause an allergic reaction.
Inhalation May be harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma
symptoms or breathing difficulties if inhaled.
Ingestion: May be harmful if swallowed. May cause gastrointestinal irritation: stomach distress,
nausea, or vomiting.
4.3 Notes to the physician Symptoms may not appear immediately.
If case of an accident or if you feel unwell, seek medical advice immediately (show label or
SDS if possible).

5. Fire-fighting measures

5.1 Flammability Flammable by OSHA/WHMIS criteria

5.2 Extinguishing media

Suitable extinguishing media Dry chemical, carbon dioxide, Halon 1211, chemical foams
Unsuitable extinguishing media Water is not recommended unless used in large quantities and other extinguishing
agents are not available. Water may spread the fire.
5.3 Special hazards arising from the substance or mixture
Products of combustion: May include and are not limited to: oxides of carbon, oxides of nitrogen, hydrogen
fluoride, and traces of hydrogen cyanide.
5.4 Special protective equipment Keep upwind of fire. Wear full fire-fighting turn-out gear (full Bunker gear) and
and precautions for fire fighters respiratory protection (SCBA). Use water spray to keep fire-exposed containers cool.
Containers may explode if heated.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment recommended in Section 8. Isolate the hazard area and
deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition.
6.2 Methods and materials for containment and cleaning up:
Method for containment: Uncured product is very sticky; carefully remove the bulk of the foam by scraping it up and
then immediately remove the residue with a rag and solvent such as Handi-Cleaner, mineral
spirits, acetone (nail polish remover), paint thinner, etc. Once the product is cured it can only
be removed mechanically by scraping, buffing, etc. Do not flush to sewer or allow to enter
waterways. Use appropriate PPE.
Methods for cleaning up: Scoop up material and place in a disposal container. Dispose of as plastic waste in
accordance with all applicable guidelines and regulations. Vapors can accumulate in low
areas. Provide ventilation

7. Handling and storage

7.1 Precautions for safe handling

Handling: Keep away from sources of ignition- No smoking. Do not spray on an open flame or other
ignition source. Pressurized container: do not pierce or burn, even after use. Container may
explode if heated. Avoid contact with skin and eyes. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not swallow. Use only in a well-ventilated area or
outdoors. Avoid welding or other “hot work” in the vicinity of exposed cured foam. When
using do not eat, drink or smoke. (See section 8)
General hygiene advice: Launder contaminated clothing before reuse. Wash hands before eating, drinking or
smoking.
7.2 Conditions for safe storage including any incompatibilities
Storage: Store in a dry place. Ideal storage temperature is 60F to 80F (15.5C to 26.6C). Do not
expose aerosol cans to open flame or temperatures above 122F (50C). Excessive heat
can cause premature aging of components resulting in a shorter shelf life. Storage below
55F (12.7C) may affect foam quality if chemicals are not warmed to room temperature
 before using. Protect containers from physical abuse. Keep containers upright. Keep away
from children.

8. Exposure controls/personal protection

8.1 Control Parameters
Exposure Guidelines

Ingredient OSHA-PEL ACGIH-TLV Other

3
4,4’ Diphenylmethane diisocyanate .2 mg/m Ceiling 0.005 ppm Ceiling
Polymethylene polyphenyl
isocyanate
Isobutane 1000 ppm
Dimethyl ether WEEL- 1000 ppm TWA
Propane 1000 ppm 1000 ppm

8.2 Exposure Controls:

Engineering Controls: Use ventilation adequate to keep exposures below recommended exposure limits.
8.3 Individual Protective Measures
Personal Protective
Equipment:
Respiratory If atmospheric levels are expected to exceed the exposure levels, use a NIOSH approved air
Protection/Ventilation: purifying respirator equipped with an organic vapor cartridge and particulate filter. If
atmospheric levels exceed 10 times the TLV or PEL level for which an air-purifying respirator
is effective, use a powered air purifying respirator (PAPR). The type of respiratory protection
selected must comply with the requirements set forth in OSHA’s Respiratory Protection
Standard (29 CFR 1910.134).
Eye/Face Protection Wear safety glasses with side shields or goggles.
Skin Protection Wear chemical resistant gloves (nitrile). Wear suitable protective clothing.
General health & safety Do not smoke, drink, or eat while handling this product. Wash after handling. Ensure that
eyewash bottles or stations are in the area.

9. Physical and chemical properties

9.1 Information on basic physical and chemical

properties

General Physical Form Viscous liquid which forms off-white to yellowish foam upon
release.
Color Crème. Some products contain a dye or colorant i.e. Fireblock is
orange.
Odor Slight hydrocarbon odor during curing stage
Odor Threshold: Not available
Physical State: Gas/Pressurized Liquid/Semi-Solid
pH: Not available
Melting Point/Freezing Point Not available
Initial Boiling Point and Boiling Range Not available
◦
Flash Point: -156 F
Evaporation Rate: Not available
Flammability: Flammable
Lower Flammability/Explosive Limit: Not available
Upper Flammability/Explosive Limit: Not available
Vapor Pressure Aerosol product > 50 psig/ 345 kPa
Final product (sprayed): Very low (not determined)
Vapor Density: Not available
Relative Density/Specific Gravity: ~ 1.1 (Water = 1)
Solubility: Insoluble; reacts slowly with water during cure, liberating traces
of CO2
Partition coefficient: n-octanol/water: Not available
Auto-ignition Temperature: Not available
Decomposition Temperature; Not available
Viscosity: Not available
Explosive Properties: May be sensitive to mechanical impact or static discharge.
Vapor released during and immediately after dispensing may
accumulate and ignite explosively if proper ventilation is not
employed. Extinguish or remove all sources of ignition during
dispensing, until product becomes tack free or skins over.
Oxidizing Properties: Not available
VOC Content (calculated minus exempt compounds and 165 g/l
water)

10. STABILITY AND REACTIVITY

10.1 Reactivity:
No dangerous reaction known under conditions of normal use.
10.2 Chemical Stability:
Stable under normal storage conditions. Contents under pressure. Container may explode if heated. Do not pierce or burn,
even after use. Avoid temperatures below 40F (5C). For longest shelf life, avoid storage above 95F (35C).
10.3 Possibility of Hazardous Reactions:
No dangerous reaction known under conditions of normal use.
10.4 Conditions To Avoid:
Heat. Incompatible materials. Sources of ignition. Avoid temperatures below 40°F (5°C) or temperatures above 95°F
(35°C).
10.5 Incompatible Materials:
Alcohols, strong bases, amines, metal compounds, ammonia, and strong oxidizers.
10.6 Hazardous Decomposition Products:
May include, and are not limited to: oxides of carbon, oxides of nitrogen, hydrogen fluoride and traces of hydrogen cyanide.

11. TOXICOLOGICAL INFORMATION

11.1 Information on Toxicological effects:

Likely routes of exposure: Skin Contact, skin absorption, eye contact, inhalation and ingestion.

Symptoms related to physical/chemical/toxicological characteristics:

Eye: May cause serious eye irritation. Symptoms may include discomfort or pain, excessive
blinking and tear production, with possible redness and swelling.
Skin: May cause skin irritation. Symptoms may include redness, edema, drying, defatting, and
cracking of the skin. May cause an allergic skin reaction.
Ingestion: May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause
respiratory tract inhalation. Chronic overexposure to diisocyanates can cause permanent
lung damage.

Acute Toxicity:
Ingredient Inhalation LC 50 Oral LC 50 Dermal LC 50
3
4,4’ Diphenylmethane diisocyanate 490 mg/m , 4h rat >10,000 mg/kg, rat >9400 mg/kg, rabbit
Polymethylene polyphenyl isocyanate 310 mg/m3, 4h rat >10,000 mg/kg, rat >9400 mg/kg, rabbit
Isobutane 658 mg/l, 4h rat
Dimethyl ether 308.5 mg/l, 4h rat
Propane 658 mg/l 4h, rat

Ingredient Chemical Listed as Carcinogen or Potential Carcinogen

(NTP, IARC, OSHA, ACGIH, CP65)
4,4’ Diphenylmethane diisocyanate IARC-3
Polymethylene polyphenyl isocyanate IARC-3
Isobutane Not Listed
Dimethyl ether Not Listed
Propane Not Listed

11.2 Delayed, Immediate, and Chronic Effects of Short and Long Term Exposure
Skin Corrosion/Irritation Irritating to skin
Serious Eye Damage/Irritation Cause serious eye irritation
Respiratory Sensitization May cause sensitization by inhalation
Skin Sensitization May cause sensitization by skin contact
STOT-single exposure May cause respiratory irritation
Chronic Health Effects Carcinogenicity: Based on the available data, the classification criteria is not met
Germ Cell Mutagenicity: Based on the available data, the classification criteria is not met
Reproductive Toxicity Developmental: Based on the available data, the classification criteria is not met
Teratogenicity: Based on the available data, the classification criteria is not met
Embryo Toxicity: Based on the available data, the classification criteria is not met
Fertility: Based on the available data, the classification criteria is not met
STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure
Aspiration Hazard Based on available data, the classification criteria is not met
Toxicologically Synergistic: Not available
Other Information: Not available

SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:

CP65 California Proposition 65

OSHA (O) Occupational Safety and Health Administration.

ACGIH (G) American Conference of Governmental Industrial Hygienists.

A1 - Confirmed human carcinogen.
A2 - Suspected human carcinogen.
A3 - Animal carcinogen.
A4 - Not classifiable as a human carcinogen.
A5 - Not suspected as a human carcinogen.

IARC (I) International Agency for Research on Cancer.

1 - The agent (mixture) is carcinogenic to humans.
2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals.
2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in
humans in the absence of sufficient evidence of carcinogenicity in experimental animals.
3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans.

NTP (N) National Toxicology Program.

1 - Known to be carcinogens.
2 - Reasonably anticipated to be carcinogens.
12. Ecological Information

12.1 Ecotoxicity
Acute/Chronic Toxicity May cause long-term adverse effects in the aquatic environment.
12.2 Persistence and Degradability Not available
12.3 Bioaccumulative Potential Bioaccumulation: Not Available
12.4 Mobility in soil Not Available
12.5 Other Adverse Effects Not Available

13. Disposal considerations

13.1 Waste Treatment Methods

Disposal Method: Before disposing of containers, relieve container of any remaining foam and pressure.
Allow product to fully cure before disposing. Never discard in a liquid state. This
material must be disposed of in accordance with all local, regional, national,
international regulations.
Other disposal recommendations: Do not puncture or incinerate containers. Use appropriate Personal Protective
Equipment.

14. Transportation

Shipping Information

Containers 1000 cu. cm. (1 liter) or less:

Due to changes in December 2020: See
shipping papers for exact 49 CFR
descriptions.
Ground
Consumer Commodity ORM-D Limited Quantity

Air
UN1950 Aerosols, Flammable 2.1 UN1950 Aerosols, Flammable 2.1
(Flammable Gas Label) (Flammable Gas Label)
LIMITED QUANTITY LIMITED QUANTITY
Packing Instructions (Cargo & Passenger) 203 Packing Instructions (Cargo & Passenger) 203

Water
UN1950 Aerosols, Flammable 2.1 UN1950 Aerosols, Flammable 2.1
(Flammable Gas Label) (Flammable Gas Label)
LIMITED QUANTITY LIMITED QUANTITY

15. REGULATORY
15.1 Safety, Health, and Environmental Regulations/Legislations Specific for the Chemical
United States: SDS prepared pursuant to the Hazard Communication Standard (29 CFR 1910.1200)
Canada: This product has been classified in accordance with the hazard criteria of Controlled Products
Regulations.

Ingredient Section 302 (EHS) Section 301 EHS CERCLA RQ (lbs.) Section 313
TPQ (lbs.) RQ (lbs.)
4,4’ Diphenylmethane diisocyanate Not Listed Not Listed 5000 313
Polymethylene polyphenyl isocyanate Not Listed Not Listed Not Listed 313
Isobutane Not Listed Not Listed Not Listed Not Listed
Dimethyl ether Not Listed Not Listed Not Listed Not Listed
Propane Not Listed Not Listed Not Listed Not Listed

Ingredient US TSCA Canada DSL/NDSL

4,4’ Diphenylmethane diisocyanate Yes DSL
Polymethylene polyphenyl isocyanate Yes DSL
Isobutane Yes DSL
Dimethyl ether Yes DSL
Propane Yes DSL
California Proposition 65:
Based on information currently available, this product is not known to contain detectable amounts of any chemicals currently
listed under California Proposition 65.

16. OTHER
NFPA: Health Hazard 2; Flammability 3; Reactivity 1
HMIS: Health Hazard 2; Flammability 3; Physical Hazard 1
Hazard Rating: 0=minimal, 1= slight, 2=moderate, 3=severe, 4= extreme

The information and recommendations set forth herein are presented in good faith and believed to be correct as of the date
hereof. The manufacturer makes no representations as to the completeness or accuracy thereof. Information is supplied
upon the condition that the persons receiving it will make their own determination as to its suitability for their purposes prior
to use. In no event will the manufacturer be responsible for damages of any nature whatsoever resulting from the use of or
reliance upon information. No representations or warranties, either expressed or implied, of merchantability or fitness for a
particular use are made hereunder with respect to this information or the product to which information refers.

Information contained herein is deemed to be reliable, conservative and accurate.