Dropper JEE

MRJM/13 Milestone Test-01 Phase-1

DATE: 02/06/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (4) 31. (2) 61. (4)
2. (4) 32. (4) 62. (3)
3. (3) 33. (3) 63. (3)
4. (3) 34. (2) 64. (3)
5. (1) 35. (2) 65. (3)
6. (2) 36. (4) 66. (3)
7. (3) 37. (4) 67. (2)
8. (3) 38. (1) 68. (1)
9. (2) 39. (3) 69. (2)
10. (4) 40. (1) 70. (1)
11. (4) 41. (2) 71. (2)
12. (3) 42. (1) 72. (2)
13. (2) 43. (1) 73. (2)
14. (4) 44. (2) 74. (4)
15. (4) 45. (3) 75. (3)
16. (2) 46. (4) 76. (3)
17. (4) 47. (3) 77. (2)
18. (3) 48. (2) 78. (4)
19. (3) 49. (2) 79. (4)
20. (2) 50. (4) 80. (1)
21. (40) 51. (5) 81. (65)
22. (8) 52. (8) 82. (8)
23. (5) 53. (40) 83. (24)
24. (5) 54. (19) 84. (1)
25. (120) 55. (68) 85. (0)
26. (18) 56. (5) 86. (3)
27. (15) 57. (66) 87. (510)
28. (5) 58. (14) 88. (64)
29. (45) 59. (4) 89. (3)
30. (104) 60. (200) 90. (1)
 SECTION-I (PHYSICS)

1. (4) v= ( 3) + ( −10 ) = 9 + 100= 109= 10.44 ms −1
2 2

The straight dotted vertical line in the graph

represents change in the direction of velocity.
Initially velocity is positive then after collision 11. (4)
velocity becomes negative. Total distance travelled
Average speed =
Total time taken
2. (4)
x 5v1v2
1 = =
s = 0 × 1 + × 9.8 × 1 × 1 = 4.9 m 2 x / 5 3 x / 5 3v1 + 2v2
+
2 v1 v2
3. (3)
At maximum height, velocity is along horizontal. 12. (3)
dx
= 4t 3 − 2t
4. (3) dt
 
cosθ= A ⋅ B / AB or= dx 4t 3 dt − 2t dt
4t 4 2t 2 4 2
5. (1) Integrating, x = − =t − t
4 2
Acceleration of two bodies under gravity will have
When x= 2, t 4 − t 2 − 2= 0,
same acceleration g downwards, so they will have
zero relative acceleration between them − ( −1) ± 1 + 8
t2 =
2
6. (2) 1± 3
v = r ω = 0.5 × 70 = 35m / s or =
t2 = 2 (ignoring – ve sign)
2
2
d x
7. (3) Again, = 2
12t 2 − 2
Total distance to be covered for crossing the bridge dt
−2
= length of train + length of bridge When t 2 = 2, acceleration=12 ×2 − 2 =22ms
= 150m+850m=1000m
Distance 1000 13. (2)
=
Time = = 80 sec
Velocity 45 × 5 As,
18 u 2 sin 2 θ H1 sin 2 θ1 sin 2 30° 1 / 4 1
H= ,∴ = = = =
2g H 2 sin 2 θ2 sin 2 60 3 / 4 3
8. (3)
For same direction relative velocity= v1 − v2
14. (4)
( v1 − v2 )
2
s = (3t 3 + 7t 2 + 14t + 8) m
Distance covered, d =
2a d 2s
=
a = 18t + 14 at t= 1sec  
⇒ a= 32 m / s 2
(v − v )
2
dt 2
For no collision, d> 1 2
2a
15. (4)
9. (2) Let the car accelerate at rate 𝛼𝛼 for time 𝑡𝑡1 then
maximum velocity attained,
v = u + at   2
⇒ − = 10 + a × 4 ⇒ a = −3m / sec 2
v = 0 + αt1 = αt1
10. (4) Now, the car decelerates at a rate β for time ( t − t1 )

r = 3tˆi − t 2 ˆj + 4kˆ and finally comes to rest. Then,
 0 = v − β ( t − t1 ) ⇒ 0 = αt1 − βt + βt1
(
 dr d ˆ 2 ˆ
Velocity, v = = 3t i − t j + 4kˆ =3iˆ − 2tˆj
dt dt
) β αβ
 ˆ ⇒ t1 = t ∴v = t
At t = 5s ⇒ v = 3i − 10ˆj α+β α+β
16. (2) u 2 ( 2sin θ cos θ )
Note that the angle between two forces is 120 ° and ⇒ =
200 m ...(i)
g
not 60 ° .
R 2 = F 2 + F 2 + 2 F 2 cos120° 2u sin θ
Time of=
flight = 5s ...(ii)
g
or R 2 = 2 F 2 + 2 F 2  −  = F 2
1
 2 From equations (i) and (ii)
or R = F u cos θ =40 m / s

17. (4) 22. (8)

dx dy Second law of motion gives
v=
x = 2ct and v=
y = 2bt
dt dt 1
               h= ut + gT 2
∴=
v (
vx2 + v 2y= 2t c 2 + b )
2 1/2 2
1
0 + gT  2 ( u =
or             h = 0)
2
18. (3)
When two bullets are fired simultaneously,  2h 
∴           T =
 
horizontally with different speeds, then they cover  g 
different horizontal distance because there is no t=0
acceleration in this direction. u=0
s
Since, horizontal distance (R) = velocity × time.
But there is a vertical acceleration towards the earth t=T
|

|
(g), so the vertical distance covered by both bullet h 3

1
are given by y = gt 2 , which is independent of
2
initial velocity.
So, both the bullets will hit the ground Ot=T
simultaneously. Ground

T
19. (3) At                    t = s,
3
v =3t 2 − 75; a =6t 2
1 T 
=
F ma = 36t . = At t 4=
s, F 144 N                          s= 0 + g  
2 3
1 T2
20. (2) Or                    s = g.
2 9
10 6 g 2h  2h 
s= ×  T =
Or                                    
18 g  g 

C h
∴                     s = m
Using triangular inequality 9
C > 10 – 6 Hence, the position of ball from the ground
C < 10 + 6 h 8h
∴ 4 < C < 16                            = h − = m.
9 9

21. (40) 23. (5)

g
=
Range
u 2 sin 2θ
= 200 m Sn =
u+ ( 2n − 1) ;
g 2
=
when u 0,=
S1 : S 2 : S3 1: 3: 5
24. (5) 2u sin θ 2h  1 2
Velocity of Rain (vr) = 3 km/hr = = ∴ h
          gt B 
g g  2 
Velocity of man (vm) = 4 km/hr
2u 2 sin 2 θ
or h =
g
2
3 2
2 (10 )  
 2 
= = 15 m
Relative velocity of rain w.r.t. man: 10
  
vm= vr − vm
28. (5)
= −3 ˆj − 4iˆ  
= 2iˆ + 4 ˆj , B= 5iˆ + p ˆj
A
  
vm = (−3) 2 + (−4) 2 If A || B, then
= 9 + 16 = 25 2 4
= ⇒ p=
10
= 5km / h 5 p
Now
25. (120) B= 102 + 52= 125= 5 5
2 F sin θ
tan α = = ∞ (as α= 90°)
F + 2 F cos θ 29. (45)
Let height of minaret is H and body take time T
to fall from top to bottom

⇒ F + 2 F cos θ =
0
1
⇒ cos θ = −
2
θ 120°
= 1 2
H= gT …(i)
2
26. (18) In last 2 sec body travels distance of 40 m so in
=
5
y 10 x − x 2 = ( H − 40 ) m
(T – 2) sec distance travelled
9
1
( H − 40=) g (T − 2 )
2
 5x  …(ii)
= 10 x 1 −  2
 90  By solving (i) and (ii), T = 3 sec and H = 45m
Standard equation
 x
y= x tan θ 1 −  30. (104)
 R 
Since, acceleration is constant
On comparing, we get
  1
90 ∴s = ut + at 2
=
R = 18m 2
5
( ) 1
(
= 2iˆ − 4 ˆj t + 3iˆ + 5 ˆj t 2
2
)
27. (15)
Horizontal component of velocity of A is 10
( ) 1
(
=2iˆ − 4 ˆj 2 + 3iˆ + 5 ˆj 22 )
cos 60° or 5 ms −1 which is equal to the velocity of 2
B in horizontal direction. They will collide at C if = 10iˆ + 2 ˆj
time of flight of the particles are equal or t A = t B 
s= 102 + 22= 104
 SECTION-II (CHEMISTRY)
31. (2) 37. (4)
Required equation is given below, CHCl3 + C6H6 shows –ve deviation from Raoult′s
Zn + 2OH − → ZnO 22 − + 2H + + 2e − law.
NO3− + 8H + + 8e − → OH − + 2H 2 O + NH 3
38. (1)
From the above equation
Ratio of atoms
 8 moles of electron absorbed by 85 g of
20.0 6.66 47.33 26.01
NaNO3 C : H : N : O∷ : : :
12 1 14 16
85 = 1.67 : 6.66 : 3.38 :1.63
∴ 1 mole of electron absorbed by g of
8 = 1: 4 : 2 :1
NaNO3 = 10.625 g Empirical formula = CH 4 N 2 O
Empirical formula mass = 60 g
32. (4) Molecular formula = CH 4 N 2 O
Reductant reduces others and itself get oxidized.
39. (3)
33. (3) N in ( N 2 H 5 )2 SO 4 has −2 oxidation number
The balanced disproportionation reaction
involving white phosphorus with aq. NaOH is
40. (1)
Oxidation of P0 to P+1 state Meq. of conc. AgNO3 = Meq. of dil.  AgNO3
3 +1 40 ×10−3 16 ×10−3
P 0 + 3NaOH + 3H2O + a
PH3 3N H2PO2 i.e., = ×1 × V,
4 170 170
-
Reduction of P0 to P 3 state ∴ V = 2.5 mL

41. (2)
34. (2)
Average atomic weight
π1V1 + π2 V2 = πR ( V1 + V2 ) at.wt. × relative abundance + at.wt. × relative abundance
=
= 2.5 (1 + V )
100
1 × 1 + 3.5V
85 × 75 + 87 × 25
1 + 3.5V =2.5 + 2.5V = = 85.5
100
or V = 1.5 L
42. (1)
35. (2)
Ca + 2H 2 O → Ca ( OH )2 + H 2
∆Tb =
mK b
22400 × 8
∆Tf =
mK f 8 g of calcium will produce =
40
∆Tb K b 0.512 = 4480 cm H2
3
= =
∆Tf K f 1.86
0.512 43. (1)
∆T=
b × 0.186
1.86 Meq. of bleaching powder = Meq. of Cl2
= 0.0512 °C = Meq. of hypo
w 1
36. (4) ×1000 =50            
× ∴ w Cl2 =0.1775 g
35.5 10
Na 3 PO 4 will furnish more ions. More is vapour 0.1775
∴ percentage of Cl=
2 ×100= 3.55 %
pressure lowering, lesser is vapour pressure. 5
44. (2) wRT
M=
In first oxide, πV
Mass of arsenic = 65.2 g
π = × 10−3 atm, T = 300 K,
Here, w = 6 g ,    2
Mass of oxygen = 34.8 g
R = 0.080 L-atm mol–1 K–1,
65.2
∴ Eq. mass of arsenic= ×=
8 14.99 V = 200 mL = 0.2 L
34.8
6 ×0.080 × 300
In second oxide, =
M = 3.6 × 105    
Mass of arsenic = 75.7 g 2 × 10−3 × 0.2
Mass of oxygen = 24.3 g
75.7 50. (4)
∴ Eq. mass of arsenic = ×=
8 24.92
24.3 HX     H + + X −
Eq. mass of arsenic : Eq. mass of arsenic 1 mole 0 0 initial
(oxide I) (oxide II)
1–0.3 0.3 0.3 after dissociation
14.99 : 24.92 Or 3:5
Total moles = 0.7 + 0.3 + 0.3 = 1.3
1.3
45. (3) ∴  i= = 1.3
The reactions, in which the same element is 1
oxidised as well as reduced, are called ∆Tf =×
i k f × m =1.3 × 1.85 × 0.2 =0.481º C
disproportionation reactions. ∴ Tf = T − ∆Tf = 0 − 0.481°C = −0.481º C
Reduction - +1
0 1
2KOH + Cl2 K Cl + KOCl + H2O 51. (5)
Na2S4O6 is salt of H 2S4 O6 which has the
Oxidation
following structure
In this reaction, the same element, ie.,Cl2 is
oxidised as well as reduced, so it is an example of
disproportionation reaction.

46. (4) ⇒ Difference in oxidation number of two types of

Oxidation-reduction takes place simultaneously.
sulphur = 5

47. (3)
52. (8)
Oxidation number of N is changed according to
compounds According to Raoult’s law,
(–1 to +5) N has five types of oxides as NO2, NO, PA = PA X A
N2O3, N2O4 and N2O5. All have different oxidation PA 32mm Hg
states in different compounds or X A = 
= = 0.8
PA 40 mm Hg

48. (2)
53. (40)
Na 2SO 4 → 2Na + + SO 24−
Meq. of H 3 PO3 = Meq. of KOH
van’t Hoff factor for Na 2SO 4 = 3
20 × 0.1 × 2= 0.1 × 1 × V
∆Tf =×
i k f × m = 3 ×1.86 × 0.01
( H3 PO3 is dibasic, KOH is monobasic )
 0.01 
=
   m = 0.01 = 0.0558 K V = 40 mL
 1 

49. (2) 54. (19)

18 × 1000
πV =
w =m = 0.19 mol kg–1
  RT
M 60 × (1500 × 1.052 − 18 )
55. (68) Meq. of oxalate ion = Meq. of KMnO 4
Two solutions are isotonic if their osmotic w 1
pressure are equal. × 1000 =90 ×
88 / 2 20
π1 =π2
∴ weight oxalate ion = 0.198 g
M1RT = M 2 RT 0.198
∴ % of oxalate ion= ×100= 66%
( M1 and M 2 are molarities ) 0.3
M1 = M 2
1000w1 1000w 2 58. (14)
= =
       (V1 V=
2 100mL) 4CrO5 + 6H2SO4 → 2Cr2(SO4)3 + 6H2O + 7O2
m1V1 m 2 V2
(Cane sugar) (unknown)
59. (4)
w1 w 2
∴       = According to the equation,
m1 m 2
NaCl + AgNO3 → NaNO3 + AgCl
5 1
= 4.77
342 m 2 =
No. of moles of NaCl = 0.08154
58.5
342
m2 = =68.4 g mol−1    5.10
5 =
No. of moles of AgNO 3 = 0.03
170
56. (5) Thus, AgNO3 is the limiting reagent in the
∴ 4Zn + NO3− + 10H + → 4Zn 2 + + NH 4+ + 3H 2 O reaction.
Now, applying POAC for Ag (as Ag atoms are
(Net equation)
4Zn + NO3− + 10HCl → 4Zn 2 + + NH 4+ + 5Cl2 + 3H 2 O conserved in the reaction)
Moles of Ag in AgNO3 = moles of Ag in AgCl
1 mole of NO3− (or NaNO3 ) is reduced by
1 × moles of AgNO3 =
1 × moles of AgCl
=10 moles of HCl
1 0.03 × 143.5 ( for AgCl ) =
4.305g
∴ mole of NO3− will be reduced by
2
1 60. (200)
= 10 × moles of HCl Meq. of NaH 2 PO 4 = Meq. of NaOH;
2
= 5 moles of HCl 12
Thus, × 1000 =
1× V
120 / 2
57. (66) ∴ V = 200 mL

SECTION-III (MATHEMATICS)
61. (4)  75/2 × 55/2 
log  
(
⇒ log x 5 x + 4 x
2 3
)=
4
=
 25/2
 =  5=log17.5 5
log17.5 2 log17.5 2
⇒ 5 x 2 + 4 x3 =
x4

(
⇒ x2 x2 − 4 x − 5 =
0 ) 63. (3)
We have,
⇒ x 2 ( x − 5 )( x + 1) = 0 ⇒ x = 5
a 2 + 4b 2 =
12ab
[ x ≠ 0 and x > 0]
⇒ ( a + 2b ) =
2
16ab
⇒ 2log ( a + 2b ) =
62. (3) log16ab
We have,
⇒ 2log ( a + 2b ) = log a + log b + 4log 2
log 49 7 + log 25 5 − log 4 2
1
log17.5 ⇒ log ( a + 2=
b) ( log a + log b + 4log 2 )
2
64. (3) Y consists of all multiples of '9' from
3– x ≥0⇒ 3– x +7≥7 0, 9,....... while X consists of some multiples of 9.
Hence all values of X are subset of values of Y.
65. (3) Thus X ∩ Y = X

72. (2)
x2 – 2px + (8p – 15) = 0
f(1) < 0 and f(2) < 0
 2 
⇒ x ∈  − ,8  f(1) = 1 – 2p + 8p – 15 < 0
 3 
⇒ p < 7/3
66. (3)
1< x < 2
–2 < x < –1 or 1 < x < 2

67. (2)
f(2) = 4 – 4p + 8p – 15 < 0
A = [x : x ∈ R, – 1 < x < 1]
11
B = [x : x ∈ R : x ≤ 0 or x ≥ 2] 4p – 11 < 0 ⇒ p<
4
∴ A ∪ B = (−∞, 1) ∪[2, ∞) = R – {x : 1 ≤ x < 2}
p ∈ (−∞, 7 / 3) Ans.

68. (1)
73. (2)
Let f(x) = ax2 – bx + 1
Since, α2 = 5α – 3 ⇒ α2 – 5α + 3 = 0
and β2 = 5β – 3 ⇒ β2 – 5β + 3 = 0
These two equations shows that α and β are the
f(0) = 1
roots of the equation x2 – 5x + 3 = 0.
f(–1) = a + b + 1 > 0
∴ α + β = 5 and αβ = 3.
69. (2) α β α 2 + β2 (α + β) 2 − 2αβ
Now, + = =
(m – 2)x2 + 8x + m + 4 > 0 β α αβ αβ
(m – 2) > 0 ..... (i) 25 − 6 19 α β
= = and . =1
64 – 4(m + 4) (m – 2) < 0 3 3 β α
16 – [m2 + 2m – 8] < 0
∴ Required quadratic equation is
m2 + 2m – 24 > 0
19
(m + 6) (m – 4) > 0 .... (ii) ⇒ x2 – x + 1 = 0 ⇒ 3x2 – 19x + 3 = 0
3
from (i) & (ii)
m ∈ (4, ∞) 74. (4)
least integral value of m is 5 n(A ∪ B) = n(A) + n(B) – n (A ∩ B)
0 ≤ n (A ∩ B) ≤ 5
70. (1)
7 ≤ n (A ∪ B) ≤ 12
X ∩ (Y ∪ X)' = X ∩ (Y' ∩ X') = X ∩ X' ∩ Y' = φ
⇒ Statement-I true. 75. (3)
X ∆ Y = (X ~ Y) ∪ (Y ~ X) = (X ∪ Y) ~ (X ∩ Y) P(φ) = {φ} ⇒ n(P (φ)) = 1
⇒ number of element in X ∆ Y = m – n. n(P(P(φ))) = 21
⇒ Statement-II is true
76. (3)
71. (2) α+β=–6,αβ=λ
For n ∈ N 3α + 2β = – 20
X = {0, 9, 54....... (4n – 3n – 1)} so α = – 8 and β = 2
Y = {0, 9, 18....., 9(n – 1)} ∴ λ = – 16
77. (2) (D) α 2 – β2 =3
Σα = 5, Σαβ = 2
α 2 + β2 + γ 2 (α + β + γ ) 2 − 2(αβ + βγ + γα)
so = 81. (65)
α 2β 2 γ 2 α 2β 2 γ 2
N13 ∩ N5 = N65
25 − 4 21 3
= = = [ 13 and 5 are relatively prime numbers)
(−7) 2 49 7

78. (4) 82. (8)

–b
<0⇒b<0  x + 7,if x ≥ −7
(1) a < 0, 2x − 1 = x + 7 = 
− ( x + 7 ) ,if x < −7
2a
& f(0) < 0 ⇒ c < 0 ∴ If x ≥ −7, 2 x − 1= x + 7 ⇒ x = 8
If x < −7, 2 x − 1 = − ( x + 7 )
⇒ 3x =
−6
⇒x=−2, which is not possible

∴ abc < 0
(2) a < 0, 83. (24)

−b α2 – 11α + a = 0
>0⇒b>0
2a α2 – 14α + 2a = 0
α2 α 1
= =
–22a + 14a a – 2a –14 + 11
−a −8a −8a
α= ,α= , α2 =
f(0) > 0 ⇒ c > 0 −3 −a −3

⇒ abc < 0 8a a
=
(3) a > 0 3 3
8a a 2
=
3 9
⇒ a2 – 24a = 0
a = 0, a = 24
−b
>0 ⇒b<0
2a 84. (1)
f(0) > 0 ⇒ c > 0 We have,
⇒ abc < 0 4x + 9 =2
4x + 9 = 4
79. (4) –5
x=
4

x ∈ (– ∞,5) ∪ (9, ∞)
85. (0)
80. (1) n(M) = 23, n(P) = 24, n(C) = 19
(A) α2 + β2 = (α + β)2 – 2αβ = 5 n(M ∩ P) = 12, n(M ∩ C) = 9, n(P ∩ C) = 7
(B) (α – β)2 =1 n(M ∩ P ∩ C) = 4
(C) α3 + β3 = 9 n(M ∪ P ∪ C) = 42
86. (3)
Since x ≥ 27 ⇒ log3 x ≥ 3
⇒ y≥3
f(1) = 4 – 16 + λ > 0
87. (510) ⇒ λ > 12
Subsets = 29 – 1 – 1 f(2) = 16 – 32 + λ < 0
= 510 ⇒ λ < 16
f(3) = 36 – 48 + λ > 0
88. (64) ⇒ λ > 12
2
2x – 35x + 2 = 0 12 < λ < 16
So λ = 13,14,15 are 3 integral solutions.
[(2α – 35) (2β – 35)]3
= [4αβ – 70(α + β) + (35)2]3 90. (1)
= [4 – (35)2 + (35)2]3 = 64 e–x = 1 only at x = 0

89. (3)
4x2 –16x + λ = 0
f(1) > 0 and f(2) < 0 and f(3) > 0

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