Date : 27/04/2025 Laxmi Thakur Chapter : 1

Time : 1 hours Std 12 : Chemistry Total Marks : 38

Chemistry

Section A
Write the answer of the following questions : (Each carries 1 Mark) [38]

1. How does the solubility of gas change in a liquid, as described?

(A) Increases with decreasing pressure (B) Increases with increasing temperature
(C) Decreases with increasing temperature (D) Decreases with increasing pressure
2. Which of the following best describes the difficulty in breathing as one climbs to higher altitudes?
(A) Henry’s law (B) Raoult’s law
(C) Osmotic pressure (D) Relative lowering of atmospheric pressure
3. The law which indicates the relationship between solubility of a gas in liquid and pressure.
(A) Raoult’s law (B) Henry’s law
(C) Lowering of vapour pressure (D) Van’t Hoff law
4. The Solubility of gas in water depends on :
(A) Nature of the gas (B) Temperature (C) Pressure of the gas (D) All of these
5. Vapour pressure of pure A = 100 torr, moles = 2; vapour pressure of pure B=80 torr, moles = 3. Total vapour pressure of the mixture is
(A) 440 torr (B) 460 torr (C) 180 torr (D) 88 torr
um
6. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 300 K. the vapour pressure of propyl alcohol is 200 mm. If
the mole fraction of ethyl alcohol is 0.6, it’s vapour pressure (in mm) at the same temperature will be.
(A) 350 (B) 300 (C) 700 (D) 360
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7. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components (heptanes and octane) are
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105 kPa and 45kPa respectively. Vapour pressure of the solution obtained by mixing 25 g of heptane and 35 g of octane will be (molar mass of
heptane = 100 g mol-1 and of octane = 114 gmol-1)
(A) 72.0kPa (B) 36.1kPa (C) 96.2kPa (D) 144.kPa
8. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of pure hydrocarbons at 200C are 440 mm Hg for pentane and 120
mm Hg for hexane. The mole fraction of pentane in vapour phase would be :
(A) 0.786 (B) 0.549 (C) 0.478 (D) 0.200
9. Which of the following is true when components forming an ideal solution are mixed?
(A) ΔHm = ΔVm = 0 (B) ΔHm < ΔVm (C) ΔHm = ΔVm = 1 (D) ΔHm > ΔVm
10. Which of the following is not correct for ideal solution?
(A) ΔVmix = 0 (B) ΔHmix = 0
(C) ΔSmix = 0 (D) Obeys Raoult’s law
11. Azeotropic mixture are
(A) Constant temperature boiling mixture (B) Those which boils at different temperatures
(C) Mixture of two solids (D) None of the above
12. Which of the following liquid pair shows a positive deviation from Raoult’s law?
(A) Water-nitric acid (B) Acetone-Chloroform
(C) Water-hydrochloric acid (D) Benzene-methanol
13. In a mixture of A and B, components show negative deviation when
(A) A–B interaction is stronger than A-A and B–B interaction
(B) A–B interaction is weaker than A-A and B–B interaction

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 (C) Vmix > 0, Smix > 0
(D) Vmix = 0, Smix > 0
14. Which of the following mixture does not show positive deviation from the Raoult’s law?
(A) Benzene + acetone (B) Acetone + ethanol
(C) Acetone + chloroform (D) Water + ethanol
15. A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the
behaviour of the solution?
(A) The solution formed is an ideal solution
(B) The solution is non-ideal, showing positive deviation from Raoult’s law
(C) The solution is Non-ideal, showing negative deviation from Raoult’s law
(D) n-heptane shows positive deviation while ethanol show negative deviation from Raoult’s law
16. An ideal solution is that which
(A) Obey Raoult’s law (B) shows positive deviation from Raoult’s law
(C) shows negative deviation from Raoult’s law (D) has no connection with Raoult’s law
17. In a mixture A and B components show negative deviation as :
(A) ΔVmix = +ve
(B) ΔHmix = –ve
(C) A-B interaction is weaker than A–A and B–B interaction.
(D) None of the above reason in correct
18. Which of the following is an example of a non-ideal solution showing positive deviation?
(A) Acetone + Carbon disulphide (B) Chlorobenzene + Bromobenzene
(C) Chloroform + Benzene (D) Acetone + Aniline
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19. What deviation is shown by a mixture of equimolar phenol and aniline?
(A) Negative deviation (B) Positive deviation
(C) No deviation (D) Alternating positive and negative
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20. Colligative properties of a solution depends upon

(A) Nature of both solvent and solute (B) Nature of solute only
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(C) Number of solvent particles (D) The number of solute particles

21. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon ________.
(A) Temperature (B) Nature of solute (C) Pressure (D) Nature of solvent
22. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ________.
(A) Low temperature
(B) Low atmospheric pressure
(C) High atmospheric pressure
(D) Both low temperature and high atmospheric pressure
23. Colligative properties depend on ________.
(A) The nature of the solute particles dissolved in solution.
(B) The number of solute particles in solution.
(C) The physical properties of the solute particles dissolved in solution.
(D) The nature of solvent particles.
24. Which of the following are correct for an ideal solution?
(a) ∆Vmix = 0
(b) Vsolvent + Vsolute = Vsolution
(c) ∆Hmix = 0
(d) H2O + CO2 → H2CO3 is an example of ideal solution.
(A) a, b only (B) b, c only (C) a, b, c only (D) a, b, c, d
25. At 298 K, vapour pressure of two pure liquids A and B are 200 and 400 mm Hg respectively, If mole fractions of A and B in solution are 0.7
and 0.3 respectively. What is the mole fraction of B in vapour phase?
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 (A) 0.279 (B) 0.721 (C) 0.538 (D) 0.462
26. If 2 g of NaOH is dissolved to make 200 ml solution at 25 °C, the molarity (M) at 90 °C is
(A) M < 0.25 (B) 0.5 > M > 0.25 (C) M = 0.25 (D) 0.5 < M < 1.0
27. A sample of drinking water has 15 ppm (by mass) of a carcinogen (molar mass 120 g mol–1). The molality of carcinogen in water sample in
mol kg–1 is
(A) 2.50 × 10–4 (B) 2.50 × 10–3 (C) 1.25 × 10–4 (D) 1.25 × 10–3
28. Which mixture shows negative deviation from Raoult’s law ?
(A) ethanol and acetone (B) carbon disulphide and acetone
(C) hexane and heptane (D) phenol and aniline
29. 30mL, 0.5M NaOH diluted to 500mL by adding water. What will be molarity of that diluted solution ?
(A) 0.05 (B) 0.025 (C) 0.03 (D) 0.015
30. Which of the following is non-ideal solution ?
(A) Phenol + Aniline (B) Benzene + Touene
(C) n-hexane + n-heptane (D) Bromo ethane + chloro ethane
31. From following which is the example of solution in which solute is gas and solvent is solid ?
(A) Aqueous solution of oxygen (B) Chloroform mixed with nitrogen gas
(C) Camphor in nitrogen gas (D) Solution of hydrogen in palladium
32. What will be the molality of 10% w/w aqueous solution of NaOH ? (Molecular mass of NaOH = 40g mol–1)
(A) 2.5 m (B) 2.78 m (C) 2.87 m (D) 2.05 m
33. Which mixture shows positive deviation from Raoult’s law ?
(A) Phenol + Aniline (B) Ethanol + Acetone
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(C) Chloroform + Acetone (D) Nitric acid + Water
34. In which solution, solute is liquid and solvent is gas ?
(A) Chloroform mixed with nitrogen gas (B) Ethanol dissolved in water
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(C) Camphor in nitrogen gas (D) Solution of hydrogen in palladium

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35. If 5 gm NaOH is dissolved in 450 ml solution, molarity of solution is _______.

[Na = 23, O = 16, H = 1 g mol–1]
(A) 27.8 M (B) 0.278 M (C) 2.78 M (D) 278 M
36. Value of Henry’s constant KH _______.
(A) no effect by changing temperature
(B) decreases with increase in temperature
(C) increases with increase in temperature
(D) first decreases and then increases by increase in temperature
37. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon _______.
(i) Temperature
(ii) Nature of solute
(iii) Pressure
(iv) Nature of Solvent
(A) (ii) & (iv) (B) (ii) (C) (i) & (iii) (D) (iii)
38. Which of the following mixture is non-ideal solution ?
(A) Chlorobenzene and bromobenzene (B) Benzene and toluene
(C) Chloroform and acetone (D) Bromoethane and chloroethane

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 Date : 27/04/2025 Laxmi Thakur Chapter : 1
Time : 1 hours Std 12 : Chemistry Total Marks : 38

Answer Key

Section A
Write the answer of the following questions : (Each carries 1 Mark) [38]

1. How does the solubility of gas change in a liquid, as described?

 Ans. (C)
 Decreases with increasing temperature
2. Which of the following best describes the difficulty in breathing as one climbs to higher altitudes?
 Ans. (A)
 Henry’s law
3. The law which indicates the relationship between solubility of a gas in liquid and pressure.
 Ans. (B)
 Henry’s law
4. The Solubility of gas in water depends on :
 Ans. (D)
 All of these
5. Vapour pressure of pure A = 100 torr, moles = 2; vapour pressure of pure B=80 torr, moles = 3. Total vapour pressure of the mixture is
 Ans. (D)
 88 torr
 Ptotal = PoAXA + PoBXB
Where, P = vapour pressure
X = mole fraction
Total moles of A and B = 5
Mole fraction of compound A =
Mole fraction of compound B =
then, Ptotal = 100 × + 80 ×
= 88 torr
6. A mixture of ethyl alcohol and propyl alcohol has a vapour pressure of 290 mm at 300 K. the vapour pressure of propyl alcohol is 200 mm. If
the mole fraction of ethyl alcohol is 0.6, it’s vapour pressure (in mm) at the same temperature will be.
 Ans. (A)
 350
 According to Raoult’s law
p = PoAXA + PoBXB
∴ 290 = 200 × 0.4 + PoB × 0.6

PoB = 350
7. On mixing, heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components (heptanes and octane) are
105 kPa and 45kPa respectively. Vapour pressure of the solution obtained by mixing 25 g of heptane and 35 g of octane will be (molar mass of
heptane = 100 g mol-1 and of octane = 114 gmol-1)
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 Ans. (A)
 72.0kPa
8. A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of pure hydrocarbons at 200C are 440 mm Hg for pentane and 120
mm Hg for hexane. The mole fraction of pentane in vapour phase would be :
 Ans. (C)
 0.478
9. Which of the following is true when components forming an ideal solution are mixed?
 Ans. (A)
 ΔHm = ΔVm = 0
10. Which of the following is not correct for ideal solution?
 Ans. (C)
 ΔSmix = 0
11. Azeotropic mixture are
 Ans. (A)
 Constant temperature boiling mixture
12. Which of the following liquid pair shows a positive deviation from Raoult’s law?
 Ans. (D)
 Benzene-methanol
13. In a mixture of A and B, components show negative deviation when
 Ans. (A)
 A–B interaction is stronger than A-A and B–B interaction
14. Which of the following mixture does not show positive deviation from the Raoult’s law?
 Ans. (C)
 Acetone + chloroform
15. A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the
behaviour of the solution?
 Ans. (B)
 The solution is non-ideal, showing positive deviation from Raoult’s law
16. An ideal solution is that which
 Ans. (A)
 Obey Raoult’s law
17. In a mixture A and B components show negative deviation as :
 Ans. (B)
 ΔHmix = –ve
18. Which of the following is an example of a non-ideal solution showing positive deviation?
 Ans. (A)
 Acetone + Carbon disulphide
19. What deviation is shown by a mixture of equimolar phenol and aniline?
 Ans. (A)
 Negative deviation
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20. Colligative properties of a solution depends upon
 Ans. (D)
 The number of solute particles
21. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon ________.
 Ans. (C)
 Pressure
22. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ________.
 Ans. (B)
 Low atmospheric pressure
23. Colligative properties depend on ________.
 Ans. (B)
 The number of solute particles in solution.
24. Which of the following are correct for an ideal solution?
(a) ∆Vmix = 0
(b) Vsolvent + Vsolute = Vsolution
(c) ∆Hmix = 0
(d) H2O + CO2 → H2CO3 is an example of ideal solution.
 Ans. (C)
 a, b, c only
25. At 298 K, vapour pressure of two pure liquids A and B are 200 and 400 mm Hg respectively, If mole fractions of A and B in solution are 0.7
and 0.3 respectively. What is the mole fraction of B in vapour phase?
 Ans. (D)
 0.462
 Vapour pressure of liquids P0A = 200 mm Hg
Vapour pressure of liquids P0B = 400 mm Hg
Mole fractions of A (XA) = 0.7
Mole fractions of B (XB) = 0.3
We, know that,
P = P0A ⋅ XA + P0B ⋅ XB
P = 200 × 0.7 + 400 × 0.3
P = 260 mm Hg
So, mole fraction of B is-
XB = =
XB =
XB = 0.460
26. If 2 g of NaOH is dissolved to make 200 ml solution at 25 °C, the molarity (M) at 90 °C is
 Ans. (A)
 M < 0.25
 Mass = 2 g
Molecular mass of NaOH = 40
V = 200 ml
We know that
Molarity =

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 Mole of NaOH = =
Molarity = × = 0.25 M
Molarity is dependent on volume and volume rise as the temperature does, molarity is inversely proportional to temperature. So, if
temperature increases molarity decreases.
Thus at 90°C molarity is M < 0.25
27. A sample of drinking water has 15 ppm (by mass) of a carcinogen (molar mass 120 g mol–1). The molality of carcinogen in water sample in
mol kg–1 is
 Ans. (C)
 1.25 × 10–4
28. Which mixture shows negative deviation from Raoult’s law ?
 Ans. (D)
 phenol and aniline
29. 30mL, 0.5M NaOH diluted to 500mL by adding water. What will be molarity of that diluted solution ?
 Ans. (C)
 0.03
 M 1 ⋅ V 1 = M2 ⋅ V 2
(0.5)(30) = M2 ⋅ (500)
M2 = = 0.03
30. Which of the following is non-ideal solution ?
 Ans. (A)
 Phenol + Aniline
31. From following which is the example of solution in which solute is gas and solvent is solid ?
 Ans. (D)
 Solution of hydrogen in palladium
32. What will be the molality of 10% w/w aqueous solution of NaOH ? (Molecular mass of NaOH = 40g mol–1)
 Ans. (B)
 2.78 m
 m= = 2.78 M
33. Which mixture shows positive deviation from Raoult’s law ?
 Ans. (B)
 Ethanol + Acetone
34. In which solution, solute is liquid and solvent is gas ?
 Ans. (A)
 Chloroform mixed with nitrogen gas
35. If 5 gm NaOH is dissolved in 450 ml solution, molarity of solution is _______.
[Na = 23, O = 16, H = 1 g mol–1]
 Ans. (B)
 0.278 M
36. Value of Henry’s constant KH _______.
 Ans. (C)
 increases with increase in temperature
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37. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon _______.
(i) Temperature
(ii) Nature of solute
(iii) Pressure
(iv) Nature of Solvent
 Ans. (D)
 (iii)
38. Which of the following mixture is non-ideal solution ?
 Ans. (C)
 Chloroform and acetone

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