Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Date of issue: 30/08/2013 Revision date: : Version: 3.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : EC
Product name : Markate 50
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : insecticide
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Globachem NV
Brustem Industriepark - Lichtenberglaan 2019
B-3800 Sint-Truiden
T +32 11 78 57 17 - F +32 11 68 15 65
[email protected] - www.globachem.com
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 3 (Oral) H301
Acute Tox. 4 (Inhalation:dust,mist) H332
Skin Corr. 1A H314
STOT SE 3 H336
Asp. Tox. 1 H304
Aquatic Acute 1 H400
Aquatic Chronic 1 H410
Full text of H-phrases: see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20/22
Xn; R65
C; R34
N; R51/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
01/10/2013 EN (English) 1/7
Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :
GHS05 GHS06 GHS08 GHS09
Signal word (CLP) : Danger
Hazardous ingredients : lambda-cyhalothrin
Hazard statements (CLP) : H301 - Toxic if swallowed
H304 - May be fatal if swallowed and enters airways
H314 - Causes severe skin burns and eye damage
H332 - Harmful if inhaled
H336 - May cause drowsiness or dizziness
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing
P260 - Do not breathe spray
P280 - Wear face protection, protective gloves
P312 - Call a POISON CENTER/doctor/physician if you feel unwell
P391 - Collect spillage
EUH phrases : EUH401 - To avoid risks to human health and the environment, comply with the instructions for
use
2.3. Other hazards
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Composition
Trading I chemical name CAS No Function %w/w
LAMBDA CYHALOTHRIN content 91465-08-6 Active substance * 5.36
Tensiofix B7453 87917-07-5 Emulsifier 5.83
Tensiofix B7438 87917-07-5 Emulsifier 3.00
Solvesso 150ND Blended Solvent 85.81
product
Total 100
Full text of R-, H- and EUH-phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persist.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
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Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Avoid (reject) fire-fighting water to enter environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect
spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight.
Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
8.2. Exposure controls
Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : Wear protective gloves.
Eye protection : Chemical goggles or safety glasses.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
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Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Colour : Colourless.
Odour : aromatic.
Odour threshold : No data available
pH : 0-0%
pH solution : 6-8
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : 63 °C
Self ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Non flammable
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : 0,91 g/ml
Solubility : No data available
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : Not explosive.
Oxidising properties : Not oxidizing.
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No additional information available
10.2. Chemical stability
Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Toxic if swallowed. Harmful if inhaled.
Markate 50
LD50 oral rat 200 - 2000 mg/kg
LD50 dermal rat > 2000 mg/kg
ATE (oral) 200,000 mg/kg bodyweight
ATE (dust,mist) 1,500 mg/l/4h
lambda-cyhalothrin (91465-08-6)
ATE (oral) 100,000 mg/kg bodyweight
ATE (dermal) 1100,000 mg/kg bodyweight
ATE (dust,mist) 0,050 mg/l/4h
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 0 - 0 %
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Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Serious eye damage/irritation : Eye damage, category 1, implicit
pH: 0 - 0 %
Respiratory or skin sensitisation : Not classified
Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Based on available data, the classification criteria are not met
Reproductive toxicity : Not classified
Based on available data, the classification criteria are not met
Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness.
Specific target organ toxicity (repeated : Not classified
exposure) Based on available data, the classification criteria are not met
Aspiration hazard : May be fatal if swallowed and enters airways.
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
SECTION 12: Ecological information
12.1. Toxicity
Markate 50
LC50 fishes 1 < 1 mg/l (96 h) Oncorhynchus mykiss
EC50 Daphnia 1 < 1 mg/l (48 h) Daphnia magna
ErC50 (algae) 10 - 100 mg/l (72 h) Pseudokirchneriella subcapitata
12.2. Persistence and degradability
Markate 50
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Markate 50
Bioaccumulative potential Not established.
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
: Avoid release to the environment
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA
14.1. UN number
UN-No : 1760
UN-No.(IATA) : 1760
UN-No. (IMDG) : 1760
14.2. UN proper shipping name
Proper Shipping Name : CORROSIVE LIQUID, N.O.S.
Transport document description : UN 1760 CORROSIVE LIQUID, N.O.S. (lambda-cyhalothrin), 8, II, (E)
14.3. Transport hazard class(es)
Class (UN) : 8
Class (IATA)
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Markate
Class (IMDG)
50 : 8
Safety Data Sheet
according to Regulation (EC) No. 453/2010
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Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Hazard labels (UN) : 8
14.4. Packing group
Packing group (UN) : II
Packing group (IMDG) : II
14.5. Environmental hazards
Dangerous for the environment :
Other information : No supplementary information available.
14.6. Special precautions for user
14.6.1. Overland transport
Hazard identification number (Kemler No.) : 80
Classification code (UN) : C9
Orange plates :
Special provision (ADR) : 274
Transport category (ADR) : 2
Tunnel restriction code : E
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
EAC code : 2X
APP code : B
14.6.2. Transport by sea
No additional information available
14.6.3. Air transport
No additional information available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2. National regulations
No additional information available
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases::
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Markate 50
Safety Data Sheet
according to Regulation (EC) No. 453/2010
Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 2
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — AcuteHazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Asp. Tox. 1 Aspiration hazard, Category 1
Skin Corr. 1A Skin corrosion/irritation, Category 1A
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Narcosis
H301 Toxic if swallowed
H304 May be fatal if swallowed and enters airways
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H330 Fatal if inhaled
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
R20/22 Harmful by inhalation and if swallowed
R21 Harmful in contact with skin
R25 Toxic if swallowed
R26 Very toxic by inhalation
R34 Causes burns
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R65 Harmful: may cause lung damage if swallowed
C Corrosive
N Dangerous for the environment
T Toxic
T+ Very toxic
Xn Harmful
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product
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