DPP - Daily Practice Problems

Name : Date : ��------�

Start Time : End Time :

CHEMISTRYSYLLABUS :
Nitrogen Containing Compounds- I
[5 4]
Max. Marks : 120 Time : 60 min.
GENERAL INSTRUCTIONS
•
The Daily Practice Problem Sheet contains 30 MCQ's. For each question only one option is correct. Darken the correct drcle/
bubble in the Response Grid provided on each page.
•
You have to evaluate your Response Grids yourself with the help of solution booklet.
•
Each correct answer will get you 4 marks and 1 mark shall be deduced for each incorrect answer. No mark will be given/ deducted
if no bubble is filled. Keep a timer in front of you and stop immediately at the end of 60 min.
• The sheet follows a particular syllabus. Do not attempt the sheet before you have completed your preparation for that syllabus.
Refer syllabus sheet in the starting of the book for the syllabus of all the DPP sheets.
• After completing the sheet check your answers with the solution booklet and complete the Result Grid. Finally spend time to
analyse your performance and revise the areas which emerge out as weak in your evaluation.

DIRECTIONS (Q.l-Q.21) : There are 21 multiple choice Q.3 Triaminobenzene is a

questions. Each question has 4 choices (a), (b), (c) and (d), (a) 2° amine (b) 3° amine
out of which ONLY ONE choice is correct. (c) 1° amine (d) quarternarysalt
C3H9N represents
Q.4 Leakage ofwhich gas was responsible for the Bhopal
Q.l
tragedy in 1984
(a) Primary amine (b) Secondary amine
(c) Tertiary amine (d) All of these (a) CH3 - N = C = 0 (b) CH 3 - C - N = S
Q.2 Al l yl isocyanide has (c) CHCI3 (d) C6H5COCI
(a) 9 sigma bonds and 4 p i bonds Q.S Number of isomeric primary amines obtained from
(b) 8 sigma bonds an d 5 pi bonds C4H11 N are
(c) 8 sigma bonds, 3 pi bonds an d 4 non bon ding electrons (a) 3 (b) 4
(d) 9 sigma bonds, 3 pi bonds an d 2 non-bonding electrons
-

(c) 5 (d) 6

1. ®®@@ 2. ®®@@ 3. ®®@@ 4. ®®@@ 5. ®®@@

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214 t--- DPP/ C (54) w
Q.6 Amides may be converted into amines by reaction named Q.13 In the following reaction, X is
after Bromination y NaN02+HC I Boiling
X Z
C2H50H
(a) Perkin (b) Claisen
(c) Hofinann (d) Kolbe Tribromobenzene
Q.7 Ethylamine can be obtained by the (a) Benzoic acid (b) Salicylicacid
(a) Action ofNH3 on ethyl iodide (c) Phenol (d) Aniline
(b) Action ofNH3 on ethyl alcohol Q.14 Which ofthe following statements about primary amines is
(c) Both (a) and (b) 'False' ?
(d) None of the above (a) Alkyl amines are stronger bases than aryl amines
Q.8 When methyl iodide is heated with ammonia, the product (b) Alkyl amines react with nitrous acid to produce
obtained is alcohols
(a) Methylantine (c) Aryl amines react with nitrous acid to produce phenols
(d) Alkyl amines are stronger bases than ammonia
(b) Dimethylamine Q.15 Which ofthe following reacts with chloroform and a base to
(c) trimethylamine form pheoyl isocyanide ?
(d) A mixture of the above three amines (a) Aniline (b) Phenol
Q.9 ln the reaction (c) Benzene (d) Nitrobenzene
0 Q.16 Ethyl amine on heating with CS2 in presence ofHgC12 fonns
II
X ( H ) RCH2 NH2>·'X'is
(a) �f-IsNCS (b) (C2f-Is)2S
R - C-OH
(a) Isonitrile (b) Nitrile
(d) Oxime
Q.17 Which of the following reacts with NaN02 + HCl to give
(c) Nitrite phenol ?
QJO Which of the following compound is the strongest base? (b) (CH 3 )z NH
(a) C6H5CH2NHCH 3
(a) Ammonia (b) Aniline
(c) Methylamine (d) N-methylaniliue (d) C6H5NH2
Q.tt Following reaction is an example of Q.18 Starting from propanoic acid, the following reactions were
carried out
0
z
II
H 2S04 Propanoic acid SOCI2 X NH3 y Br2 +KOH
R - C-OH+HN3 ) R - NH2
What is the compound Z?
(a) Hofinann reaction (b) Curtius reaction
(a) CH3 - CH2 - Br (b) CH3 - CH1 - NH2
(c) Schmidt reaction (d) Lossen reaction
Q.12 When anilinereacts withNaN02 anddil. HCl at0°- 5°C, the
product formed is
(c) CH3 -CH2
- c<0Br (d) CK - CI-f - CH2 _ "''"2
� ''"2 1\ll.l
(a) Nitroaniline Q.19 Aromatic nitriles (ArCN) are not prepared by reaction
(b) Benzenediazonimn chloride (a) ArX + KCN (b) ArN ! + CuCN
(c) Benzene
(d) Trinitroaniline (c) ArCONH2 + P20 s (d) ArCONH2 + SOCl2

6. ®®00 7. ®®00 8. ®®00 9. ®®@0 10. ®®00

11.®®00 12. ®®00 13.®®00 14.®®@0 15. ®®00
16.®®00 17. ®®00 18.®®00 19.®®@0
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DPP/ C (54) ------------------..... 215
Q.20 Azo-dyes are prepared from : Q.23 Which ofthe following do not give primary amine on
(a) Aniline reduction?
(b) Salicylic acid
(c) Benzaldehyde (2) CH3C�N03
(d) Chlorobenzene (3) CH3CH2C�N03
Q.21 For the preparation of p-nitroiodobenzene from 0
p-nitroaniline, the best method is II
(4)
CH3 - CH 2 - N � O
(a) NaNO/HCI followed by KJ
(b) NaNO/HCI followed byCuCN
Q.24 Which of the following reduces C6H5N02 to aniline ?
(c) LiAIH4 followed by 12 (I) Sn!HCl (2) SnClz!HCl
(d) NaBH4 followed by I2 (3) Zn/HCI (4) LiAIH4

DIRECTIONS (Q.25-Q.27) : Read the passage given below

DIRECTIONS (Q.22-Q.24) : In the following questions, more and answer the questions that follows :
than one of the answers given are correct. Select the correct
answers and mark it according to the following codes: Observe the following reaction :
Codes : Mel (excess) (X) AgOH
RCHzCHzNHz
(a) l , 2 and 3 are correct (Y) heat
(Z)
(b) 1 an d 2 are correct
(c) 2 and 4 are correct
Q.25 The structure ofX is­
(a) RCHzCHzNMe3+ r­ (b) RCHzCHzNMet oH­
and 3 are correct
(c) RCH=CRz (d) None of these
(d) l
Q.22 Which of the following reactions yield an amine ?
Q.26 The structure ofY is­
(a) RCHzCHzNMe3+ r­ (b) RCHzCHzNMe3+ ow
(2)
(c) R.CH= CHz (d) None of these
RCH = N O H+[H] ----
c:-:
Na
::.,-:
-:2H.:., �
s OH Q.27 The structure of Z is-
(a) RCHzCHzNMe3+r­
RCONH2 + 4H LiAJ}{4
(3)
(b) RC�CRzNMe3+ oH­
(c) R.CH = CHz
(d) None of these

R�.SI'O:\SE 20.®®0@ 21.®®0@ 22. ®®0@ 23. ®®@@ 24. ®®0@

GRID 25.@@0@ 26.®®0@ 27.®®0@

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216 t--- DPP/ C (54) w
DIRECTIONS (Q. 28-Q.30) : Each ofthese questions contains Q.28 Statement-! : Methyl isocyanide reacts with ozone to form
two statements: Statement-! (Assertion) and Statement-2 methyl isocyanate.
Statement-2 : Methyl isocyanate was responsible for
Bhopal tragedy.
(Reason). Each of these questions has four alternative choices,
only one of which is the correct answer. You have to select the
correct choice. Q.29 Statement-! : Alkyl cyanide can be prepared bycarbylamine
reaction.
(a) Statement-! is True, Statement-2 is True; Statement-2 is a Statement-2 : Ethyl amine when heated with chloroform in
correct explanation for Statement- I . presence ofalcoholic KOH gives isocyanide.
(b) Statement-! is Tme, Statement-2 is Tme; Statement-2 is Q.30 Statement-! : In order to convertR-Cl to pureR-�, Gabriel
NOT a correct explanation for Statement-!. pthalimide synthesis can be used.
(c) Statement - 1 is False, Statement-2 is True. Statement-2 : With proper choice of alkyl halides,
(d) Statement - 1 is Tme, Statement-2 is False. phthalimide synthesis can be used to prepare I 0, 2° or 3°
amines.

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DAILY PRACTICE PROBLEM SHEET 54 - CHEMISTRY

Tota l Questions 30 Tota l Marks 120
Attempted Correct
Incorrect Net Score
Cut-off Score 36 Qual ifying Score 60
Success Gap = Net Score - Qual ifying Score
N et Score = (Correct x 4} - ( Incorrect x 1)

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104 �------
DAILY PRACTICE C H E M I STRY
PROBLEMS SOLUT IONS

1. (d) C3H9N can form all the three types ofamines. 0

II heat
CH3CH2CH2 -NH 2 , CH3 -CH2 -NH -CH3 (b) R - C - N3 R - NI-12
l0amine 2°amine
Azide

CH3 - N - CH3 (Curtius reaction)

I
CH3
0
3°amine II
(c) R - C - OH + Illi3 R - NH2
2. (d) Allyl isocyanide, CH2 • CH - CH2 - N ;> C (Schmidt reaction)

3. (c) H 2 �1NH 2
0
II OH "
R - NH 2

?°
(d) R- C - NHOH
(Lossen reaction)

1° NH2
amine
12.
Hydroxamic acid

4. (a)
5. (b) Four l 0 amines are possible

� �
CH3CH2CH2CH2NH2,(CH3hCHCH2NH2,

@
Aniline Benzenediazoium chloride

CH3CH(NH2 )CH2CH3, (CH3 h CNH 2

6. (c) Hofmann's bromamide reaction NH2 N H2 N2Cl

Br Br Br Br
H20
CH3 - CO - NH2 + Br2 + 4KOH 13. (d)
�
Br2
0 NaN02
0
Acetamide �

¥
CH3 NH2 + K2C03 + 2KBr + 2H20 r r
Methyl amine

C2H5I + NH3 -7 HI + C2H5 - NH2

Br Br
7. (c) Boiling
C2HpH 0
C2H50H+NH3 -7 H 2 0 + C2 H5 -NH2

(CH 3 )2 NH
NH3
r
A
8. CH3NH2
Methyl amine Dimethyl amine
14. (c) Aryl amines do not produce phenol on treatment with
nitrous acid.

@ __,@
(CH3 )J N NH2 N; C
Trimethyl amiue
15. (a) +CHC I3 + 3KOH +3KCI + 3H20.
Reduction
9.
[H]
(b) R - CH? - NH?
1° a i1i -
1 ne
C= N-
16. (a) C2H5 NH2 +CS2 + HgC12 � C2H5NCS+ 2HCI + HgS.
R-
d)
" -HCI --. C 61.1 5N 2Cl - -
Nitrile
I!
NaN02 H20
Hydrolysis 17. C 6H 5NH 2 - ,_
R - COOH +NH3 ___,

acid
C 6H5 0H + N2 + HCI
SOCI2
10. (c) Methylamine is the strongest base. 18. (b) CH3CH2COOH CH3CH2COCI + S02+HCI
X
0 CH3CH2COCI + NH 3 � CH3 CH2CONH2 + HCI
II 2 N y
11. (c) (a) R - C - NH2 _ �r � ��.... R - NH 2
CH3CH2CONH2 + Br2 /NaOH � CH3CH2NH2+ C02
(Hofmann reaction) Ethylamine, Z
DPP/ C (54) --------1 1os
19. (a) Due to +M effect of-Cl, C-X bond in ArX acquires
double bond character and hence becomes short and 22. (a) RCOOH + NH3
strong. Thus X can't be replaced easily. It yields amine when reduced as shown below.
ArN! + CuCN � ArCN + N 2 + Cu+ R -CN+H2 � R - CH2 -NH2
ArCONI-12 _-=-
P20 5
- �
H20
'----+ ArCN Thus option (d) is incorrect.
ArCONH 2 + SOCI2 � ArCN + S02 + 2HCI 0
20. (a) When aniline is treated with HN02 at 0-5°C then
II
23. (a) CH3 -CH2 -N --t 0 + 3H2 --t CH3CH2NH2 + 21-120
diazonium salt is formed and by the coupling of
diazonium salt and phenol , azo dyes are prepared. 24. (a) LiAlH4 does not reduce-N02 group.

6
+ Thus ( 1 ), (2), (3) are the correct choices.
N . Ncr
25. (a), 26. (b), 27. (c)
NaN02 + HCI
0-5°C �
The amine undergoes exhaustive when troated with
AgOH methylation forming RCHzC� NMe3+J-, (X)
Aniline Benzene which is converted to (Y), RCH2CHzNMe3+ow . (Y)
diazonium chloride when heated, Hofmann elimination occurs.
RC�C�NMt!:3+oR" - ... RCH = CH2 + Mt!:3N + HzO
(Y) (Z)
coupling 28. (b) The reason bein g that ti1e terminal carbon atom in
weakly alkaline, OH i socyanide has electron-deficient carbon having a
Aniline Phenol
sextet of electrons and hence undergoes addition

-<==>- -<==>
reactions with ozone.
29. (c) When primary amines are heated with chloroform in
HO N=N
the presence ofalcohoHc KOH, isocyaniides are formed.
Azo dye This reaction is known as carboylamine reaction, eg.
21. (a) p-Nitroiodobenzene from p-nitroaniline. ethyl amine gives ethyl isocyanide on treatment with
CHC13 and alcoholic KOH.
A
C2H 5 -NH 2+ CHCI3 +3KOH(alc) �
Ethylamine Chloroform

C2H5 -N = C + 3KCI+3H20
30. (d) Only primary aliphatic amines can be prepared by
p-nitroaniline p-nitroiodobenzene Gabriel phthalimide reaction.