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CLL111 Eb3

The document discusses the thermodynamic processes involved in the vaporization of phenol and the associated enthalpy changes. It includes various calculations related to specific enthalpies of gases and the heat transfer required for different chemical processes. Additionally, it references tables of enthalpy values for selected gases at various temperatures.

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0% found this document useful (0 votes)
4 views14 pages

CLL111 Eb3

The document discusses the thermodynamic processes involved in the vaporization of phenol and the associated enthalpy changes. It includes various calculations related to specific enthalpies of gases and the heat transfer required for different chemical processes. Additionally, it references tables of enthalpy values for selected gases at various temperatures.

Uploaded by

lavaniashivang
Copyright
© © All Rights Reserved
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__Hypethdiut Praca Pl - Q Construct a Rypolreliedd precers dpa ow Be indal Nl te fat pla coating of a foun oh Met ee ad comttandad far cantensenes— 15 Us fame as it fr Ihe po. wud by the prrcens Tepe plants ch UL fll atl AU for amy bracers. Fa example, we Wiel te cabeudile al fer a frets shee polish phened ak 25% aml [aw veittd do phenol vaper ak 300C and 3 ale. S, & Tabhe of, cathalpas for phenet wee could Unfund no Libalaid dale wo ovrhbl Ph.(b 25, late) p= = - 2-H Ve Paty », Plu. 200%, Sab.) An An h \ Alig Pl. (6, 428, Nakin) + x PRC, god, labu) . , B00c, Ply (L428 fale) + 4 AWS Yas, me (Uiarwe, fab) LE Pe Cv,181-4'¢, Lak.) ‘ x “ “ w a AW = 4H, + AH, + AH, + 4H, + AHe Emnth. change for ee malting of Phenol alt {alin dnd 2:59 — Nedmal Meng Pink of thenot change fr tne vaforuntion of Phowel ak [alm aud [914°C — Novant Prodan Pout of. thenel Firat, Ral Filth Slaps Cohange oT af conlint f) Serena, Foul Sheps (Change 1 phar at consent T ant? ) Sodle typ (Change ax P ak consti T) Phase CI wee made te ocan at be condition fo weit Labulated enthalpy changes Gre anailable. 4 Shp bt ad Toe Sk hao bee cnet excpertmredatly hot paternal enseyy unclebenslent of prusuns - ps fb ak a pred tenpewtot “Sheep al on Lagu 1 . = a p a eye Mh he Toe et may wr AU=0 at an gad + o(P%)\ = Var Bot U ad H ou siete Py rdek Comne nerdy, yer wed Ld ele alge ote eo Seti ons oh ore smvebved . ou aval bh fabubted a k(Tt ?) ay itll ab 200 Fr arouwaplury Sensible Heak > Heak tak vnuat be tranntened do rowae or Loner the tempers of o Pubs ok mutans of pale Fe quardaly of, heat reynat te produce 0 emf change as pin one be beret Lu fromm Bo apfrpriati form ofp ads frat w of theramodynanncs Qe AU Close Syste) G2 an (cfr Syatie) (KE, PE changes ond vorrk hae bee might) agG3) Ag AT 0 Ue asks AU /oT affmadea a sep Valuo (42 tas plfe of dee conve ak T))) wtih is by defmuliw de ent Cabsely a conatamt vetum eh Ake pabalenes denatid by Cy core I, Uns ao rt Naaight i itt Se te Av= { Cy(t)4T 1 Sf both Ha enfatan and valine of Sha Auboliner changer Break ta prrceas info tn slaps A Change V ak cooker T follaveed by oe coustant V . ACT, &) thes ace, Nj) Gh (aM, | J ia AG : x : Sime UW a dob f , aU = AU, +4U,. Buk for deal gare mn (15 got ffesmalod Ryu b> | PY apads oay/on 7 40 thal 7 Mw T 8 couslank a pub! | AU,/=0 for any 2 whalaner luk a mortdel poo Sree Mur peed Aap 1 a chong us ete a Av, com be estaba 4 f Berar: tT To Pavement - fo w Gencheakne change fore Tt 2 Tdeak Gao. Exact AU = Secon Selby ot Ligue: Gard te Now Ideal Gas > Valu only TEV ws cosat, / — Acetone (Ac) us adalf coudenred owt a . ar : cote oa Vopr and the balance mibogen recurs dead to Lhe [lerrchert Rawr below: Aa)s) 36-45 want/A 0-092 wat he(v) [mel 0-4 QS mC Nz | mol loo mets | ¢ doc , S alin. © 664 mmol hel) | 0-331 metN, J met ° 63-55 mol he(O/> 65°C, | alm. ai sak. of $s Re procs cherates at the Nandy plate. CoLlentate : L. Mabel Balawer Mot Required Q-We = AH + OE, tAEp Wez0 (No Mov" fouls an the pylons J mo eg ioe we os , eae vediel chabunes AE =0 (N lire a J odtet por) sage (ade [Pe Eaegey Belanee Redaro te ‘ : ‘ Azote Bonk — Zhahe 3 Choose Mfence plilde for acakmt anc. nator @ N34 (4, 28%, tabu) Convencend chore for wihogen ate labeled entvotpuss of Ni, rotate Ny (a, 25%, late) ox anwleble No tabubted cabtaty date owcaulele for Acclent Cnsese owe 2 flu jrrverne Abenma condones Re (4,20 Sal) a th ufeaewee abi. for Melons, WsBcdy vall eunble ua te pet dhe corresponding 4. Comabeck an salt -owll etratpy Table Feb wade dhe chase pajeuner Sales, Lem covlruck Ae Table Retainer Be (1,286 Sate), Na la,286, lab) Bin | Wowk out 5. Coletal oll unknouw Apeehe enUlbus G Ay: Speexye Ent Academe (% 68°C, latin Me alee Coakca an fa he (20, S abe) —> he-(v, 65, lake) Construct hybothelienl process pllhs from Une tapas po th the pb of Aba “| process ond evaluat BA for each pally at's vase fe er on presse (6) on Ligue pete with onal et td. 4 die value of V fos bipuad oretene may be dutirmusl ar 0-0734 Uwmel tree Us Abeerpe. geo o-T4l. Speefe granly =0-741 (Prvadble u& lerlbodte Be kao al ° = Breetone (C-5H:0) Motes Mara =36 +6416 258 3/mol Sp Nabawe = SP ghee 2 58 L.o-013hl +. TA Se Tq) mot mh An f Cat fx Pea ay ar, 1 te Tr ok couslent . 5 het): @ LAF) = o12en Be AID T | Ss hel): Co ( =O. OTIASETIONNIO T 10 3 oOo) eT BROT ESE TOOT eee ee eS Henk of Vaperiation AH (Ty) OH fr a © Ljuck to vapor at Lhe Typ) a0, tov Re clone sec ay (Top) 30-2 kT]mel Hupatheieat Pally from ae Refeuner Stabs [ Act 286, sas)| [eC 9&, la be (20%, 5 ab) in ne UL 25, Labs) he (SBE, lb) es alee he (vos lle) ket! ) 7 n | - 7 - i | Hy= AM + oo Sé ae =4 Chali - Saket f (Cp dt + lay) ptt) i ) rece ee Cc 2o at Cd rect set =(-0-0297 4468+ 302+ 0-158) Jone 235-11 ASfomet Referee Ac (4 09, Sab) Na(4, 2st, abe) @ Nin Ww ee ae 6. Cobentec a Ane SS nRe — 2 4,4, on re = (83S wutfa) (82 4 thet) + G2 S8)©) + (asco) NED _ (as. direy] 45 =-2320 &T/s 1 Q@z AW = -2520 45]s= -2520 kW Heak yuiat be trawsfemd frome iM cmd at a nah of 2520kW ls acluere he nope Ceokan J Coudintlion 66°49 mol he(w) Au 63°55 mot 33+) mot No ——— > °3.35 ae este , late Se lweeial 2c, Sab 66-4 mat be-(~) 63-55 wot he(Y) Sat mot Np 7 7 7 TT AF 9.35 wd hey) 6ST, latw Bal met Ny SA = 7 med ae) reo aie Satin Bol mel Ny (2ST) lala a tott eabhetty change for tha frst Alep, ae DW = AH + AW,= 2 He -Enhe CSmce erithathy si 7s Stila function ® Table B.8 Specific Enthalpies of Selected Gases: SI Units Ai(kS/mol) Reference state: Gas, Prep = 1 atm, Tyep = 25°C T Air O2 No, Hz co CO2 H,0 0 -072 -0.73 --0.73 -072 -073 -092 -0.84 25 +000 000 0.00 000 000 0.00 0.00 100 86219 2.24 249 216 2192.90 2.54 20000 «515531 5.13 5.06 5.16 7.08 =~ 6.01 300 «817 847-. 812 «7.96 = 88.17.1588 9.57 400 11.24 «1172 «1115 = 10891125 16351323 . 500. 1437 15.03 14.24 13.83 1438 21.34 17.01 ‘600 1755 1841 1739 1681 1757 2653. 2091 700 20.80 2186 «=. 2059 19.81 - 20.82. . 31.88 24.92 800 «24.10 925.35 23.86 ©=—22.85 24.13 «37.36 = 29.05 900 27.46 = 28.89 27.19 25.93 27.49 9 42.94 33.32 1000, 30.86 ©=3247 «30.56 © 29.04 30.91 48.60 37.69 100 3431 = 36.07 33.99 3219 9-34.37 5433 «42.18 1200. 3781 39.70 3746 «35.39 §= 3787. 60.14 46.78 1300 4134 «43.38. 40.97. 38.62 41.40 «65.98 51.47 1400-4489 47.07 44551 41.90 44.95 71.89 © 56.25 1500 4845 = 50.77 48.06 «45.22 48.51 (77.84 61.09 =

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