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The document discusses the thermodynamic processes involved in the vaporization of phenol and the associated enthalpy changes. It includes various calculations related to specific enthalpies of gases and the heat transfer required for different chemical processes. Additionally, it references tables of enthalpy values for selected gases at various temperatures.
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Construct a Rypolreliedd precers dpa ow Be indal
Nl te fat pla coating of a foun oh Met
ee ad
comttandad far cantensenes— 15 Us fame as it fr Ihe
po. wud by the prrcens
Tepe plants ch UL fll atl
AU for amy bracers.
Fa example, we Wiel te cabeudile al fer a frets
shee polish phened ak 25% aml [aw
veittd do phenol vaper ak 300C and 3 ale.
S, & Tabhe of, cathalpas for phenet wee could
Unfund no Libalaid dale wo ovrhblPh.(b 25, late) p= = - 2-H Ve Paty », Plu. 200%, Sab.)
An
An h
\ Alig
Pl. (6, 428, Nakin) +
x PRC, god, labu)
. , B00c,
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AWS
Yas,
me (Uiarwe, fab) LE Pe Cv,181-4'¢, Lak.)
‘ x “ “ w a
AW = 4H, + AH, + AH, + 4H, + AHeEmnth. change for ee malting of Phenol alt {alin
dnd 2:59 — Nedmal Meng Pink of thenot
change fr tne vaforuntion of Phowel ak [alm
aud [914°C — Novant Prodan Pout of. thenel
Firat, Ral Filth Slaps Cohange oT af conlint f)
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T ant? )
Sodle typ (Change ax P ak consti T)
Phase CI wee made te ocan at be
condition fo weit Labulated enthalpy changes
Gre anailable.4
Shp bt ad Toe
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paternal enseyy unclebenslent of prusuns
- ps fb ak a pred tenpewtot
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eye Mh he Toe et may wr
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ou aval bh
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ay itll ab 200 Fr
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theramodynanncs
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sep Valuo (42 tas plfe of dee conve ak T)))
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Av= { Cy(t)4T
1
Sf both Ha enfatan and valine of Sha
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A Change V ak cooker T follaveed by
oe coustant V .
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| J
ia AG : x :
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whalaner luk a mortdel poo Sree Mur peed
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tT
To Pavement - fo w Gencheakne change fore Tt 2
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AU = Secon Selby ot Ligue: Gard te
Now Ideal Gas > Valu only
TEV ws cosat,/
— Acetone (Ac) us adalf coudenred owt a .
ar : cote oa
Vopr and the balance mibogen recurs
dead to Lhe [lerrchert Rawr below:
Aa)s) 36-45 want/A
0-092 wat he(v) [mel
0-4 QS mC Nz | mol
loo mets | ¢ doc , S alin.
© 664 mmol hel) |
0-331 metN, J met
° 63-55 mol he(O/>
65°C, | alm. ai sak. of $s
Re procs cherates at the Nandy plate.
CoLlentate :
L. Mabel Balawer Mot Required
Q-We = AH + OE, tAEp
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eg ioe
we
os , eae vediel chabunes
AE =0 (N lire a J odtet por)
sage (ade [Pe
Eaegey Belanee Redaro te
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: ‘
Azote Bonk — Zhahe3 Choose Mfence plilde for acakmt anc. nator @
N34 (4, 28%, tabu) Convencend chore for wihogen
ate labeled entvotpuss of
Ni, rotate Ny (a, 25%, late)
ox anwleble
No tabubted cabtaty date owcaulele for Acclent
Cnsese owe 2 flu jrrverne Abenma condones
Re (4,20 Sal) a th ufeaewee abi. for Melons,
WsBcdy vall eunble ua te pet dhe corresponding
4. Comabeck an salt -owll etratpy Table
Feb wade dhe chase pajeuner Sales, Lem
covlruck Ae Table
Retainer Be (1,286 Sate), Na la,286, lab)
Bin | Wowk out5. Coletal oll unknouw Apeehe enUlbus G
Ay: Speexye Ent Academe (% 68°C, latin
Me alee Coakca
an fa he (20, S abe) —> he-(v, 65, lake)
Construct hybothelienl process pllhs from Une
tapas po th the pb of Aba “|
process ond evaluat BA for each pally
at's vase fe er on presse (6)
on Ligue pete with onal
et td. 4 die value of V fos bipuad
oretene may be dutirmusl ar 0-0734 Uwmel
tree Us Abeerpe. geo o-T4l.
Speefe granly =0-741 (Prvadble u& lerlbodte
Be kao al
° =
Breetone (C-5H:0) Motes Mara =36 +6416
258 3/mol
Sp Nabawe = SP ghee 2 58 L.o-013hl
+. TA Se Tq) mot mh
An f Cat fx Pea
ay ar,
1 te Tr ok couslent .
5
het): @ LAF) = o12en Be AID T |
Ss
hel): Co ( =O. OTIASETIONNIO T 10 3
oOo) eT BROT ESE TOOT
eee ee eSHenk of Vaperiation AH (Ty) OH fr a ©
Ljuck
to vapor at Lhe
Typ)
a0, tov Re clone sec
ay (Top) 30-2 kT]mel
Hupatheieat Pally from ae
Refeuner Stabs [ Act 286, sas)| [eC 9&, la
be (20%, 5 ab) in ne UL 25, Labs) he (SBE, lb)
es alee
he (vos lle) ket! ) 7
n
| - 7 - i
| Hy= AM + oo
Sé ae
=4 Chali - Saket f (Cp dt + lay)
ptt) i ) rece ee
Cc
2o at Cd rect
set
=(-0-0297 4468+ 302+ 0-158) Jone
235-11 ASfometReferee Ac (4 09, Sab) Na(4, 2st, abe) @
Nin Ww
ee ae
6. Cobentec a
Ane SS nRe — 2 4,4,
on re
= (83S wutfa) (82 4 thet) + G2 S8)©)
+ (asco) NED
_ (as. direy] 45
=-2320 &T/s
1 Q@z AW = -2520 45]s= -2520 kW
Heak yuiat be trawsfemd frome iM
cmd at a nah of 2520kW ls
acluere he nope Ceokan J Coudintlion66°49 mol he(w)
Au 63°55 mot
33+) mot No ——— > °3.35 ae
este , late Se lweeial
2c, Sab
66-4 mat be-(~) 63-55 wot he(Y)
Sat mot Np 7 7 7 TT AF 9.35 wd hey)
6ST, latw Bal met Ny
SA =
7 med ae) reo aie Satin
Bol mel Ny (2ST) lala
a tott eabhetty change for tha frst Alep, ae
DW = AH + AW,= 2 He -Enhe
CSmce erithathy si 7s Stila function
®Table B.8 Specific Enthalpies of Selected Gases: SI Units
Ai(kS/mol)
Reference state: Gas, Prep = 1 atm, Tyep = 25°C
T Air O2 No, Hz co CO2 H,0
0 -072 -0.73 --0.73 -072 -073 -092 -0.84
25 +000 000 0.00 000 000 0.00 0.00
100 86219 2.24 249 216 2192.90 2.54
20000 «515531 5.13 5.06 5.16 7.08 =~ 6.01
300 «817 847-. 812 «7.96 = 88.17.1588 9.57
400 11.24 «1172 «1115 = 10891125 16351323
. 500. 1437 15.03 14.24 13.83 1438 21.34 17.01
‘600 1755 1841 1739 1681 1757 2653. 2091
700 20.80 2186 «=. 2059 19.81 - 20.82. . 31.88 24.92
800 «24.10 925.35 23.86 ©=—22.85 24.13 «37.36 = 29.05
900 27.46 = 28.89 27.19 25.93 27.49 9 42.94 33.32
1000, 30.86 ©=3247 «30.56 © 29.04 30.91 48.60 37.69
100 3431 = 36.07 33.99 3219 9-34.37 5433 «42.18
1200. 3781 39.70 3746 «35.39 §= 3787. 60.14 46.78
1300 4134 «43.38. 40.97. 38.62 41.40 «65.98 51.47
1400-4489 47.07 44551 41.90 44.95 71.89 © 56.25
1500 4845 = 50.77 48.06 «45.22 48.51 (77.84 61.09
=