(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY

EXERCISE (O-I)
INTRODUCTION OF CONCENTRATION TERMS
1. 8 g NaOH is dissolved in one litre of solution, its molarity is :
(A) 0.8 M (B) 0.4 M (C) 0.2 M (D) 0.1 M

2. H2O2 solution used for hair bleaching is sold as a solution of approximately 5.0 g H 2O2 per
100 mL of the solution. The molecular mass of H2O2 is 34. The molarity of this solution is
approximately:-
(A) 0.15 M (B) 1.5 M (C) 3.0 M (D) 3.4 M

3. If 18 g of glucose is present in 1000 g of solvent, the solution is said to be :

(A) 1 molar (B) 0.1 molar (C) 0.5 molar (D) 0.1 molal

4. How much grams of CH3OH should be dissolved in water for preparing 150 ml. of
2.0 M CH3OH solution
(A) 9.6 (B) 2.4 (C) 9.6 × 103 (D) 4.3 × 102

5. Equal weight of NaCl and KCl are dissolved separately in equal volumes of solutions molarity of
the two solutions will be –
(A) Equal
(B) That of NaCl will be less than that of KCl
(C) That of NaCl will be more than that of KCl Solution
(D) That of NaCl will be half of that of KCl solution

6. Which one of the following modes of expressing concentration of solution is independent of

temperature–
(A) Molarity (B) Molality (C) % w/v (D) Grams per litre

7. A molal solution is one that contains one mole of a solute in

(A) 1000 g of the solvent (B) one litre of the solution
(C) one litre of the solvent (D) 22.4 litres of the solution

8. Which of the following solution has maximum mass of pure NaOH ?

(I) 50 g of 40% (W/W) NaOH

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY
(II) 50 mL of 40% (W/V) NaOH (dsol = 1.2 g/ml).
(III) 50 g of 12 M NaOH (dsol = 1 g/ml).
(A) I (B) II (C) III (D) III = II = I.

9. Mole fraction of C3H5(OH)3 (glycerin) in a solution of 36 g of water and 46 g of glycerin is :

(A) 0.46 (B) 0.36 (C) 0.20 (D) 0.40

10. The mole fraction of oxygen in a mixture of 7g of nitrogen and 8g of oxygen is :

8
(A) (B) 0.5 (C) 0.25 (D) 1.0
15

11. 1000 g aqueous solution of CaCO3 contains 10 g of calcium carbonate concentration of the
solution is :
(A) 10 ppm (B) 100 ppm (C) 1000 ppm (D) 10,000 ppm

12. The molarity of pure water is :

(A) 100 M (B) 55.5 M (C) 50 M (D) 18M

13. Molarity of liquid HCl if density of solution is1.17 g/cc. :

(A) 36.5 (B) 18.25 (C) 32.05 (D) 42.10

INTERCONVERSION OF CONCENTRATION TERMS

14. The molarity of 98% by wt. H2SO4 (d = 1.8 g/ml) is

(A) 6 M (B) 18 M (B) 10 M (D) 4 M

15. Mole fraction of A in H2O is 0.2. The molality of A in H2O is :

(A) 13.9 (B) 15.5 (C) 14.5 (D) 16.8

16. The molarity of the solution containing 2.8%w/v solution of KOH is :

(Given atomic mass of K = 39 ) is :
(A) 0.1 M (B) 0.5 M (C) 0.2 M (D) 1 M

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY
17. Calculate the molality of 40% weight by volume solution of MgO if the density of the solution is
2 g/mL:-
(A) 5 (B) 10 (C) 6.25 (D) 12.5

18. If the mole fraction of NaCl is same as that of water then molality of NaCl (aq.) solution is
(A) 5.55 (B) 55.55 (C) 0.18 (D) 58.5

PROBLEMS RELATED WITH MIXING & DILUTION

19. How much volume of 3.0 M H2SO4 is required for the preparation of 1.0 litre of 1.0 M solution?
(A) 300 ml (B) 320 ml (C) 333.3 ml (D) 350.0 ml

20. How much water should be added to 200 cc of semi molar solution of NaOH to make it exactly
Decimolar:
(A) 1000 cc (B) 400 cc (C) 800 cc (D) 600 cc

21. The molarity of a solution made by mixing 50 ml of conc. H2SO4 (18 M) with 50 ml. of water, is:
(A) 36 M (B) 18 M (C) 9 M (D) 6M

22. 100 ml of 0.3 M HCl solution is mixed with 200 ml of 0.3 M H2SO4 solution what is the molarity
of H+ in resultant solution.
(A) 0.9 (B) 0.6 (C) 0.4 (D) 0.5
23. 60 g of solution containing 40% by mass of NaCl are mixed with 100 g of a solution containing
15% by mass NaCl. Determine the mass percent of sodium chloride in the final solution.
(A) 24.4% (B) 78% (C) 48.8% (D) 19.68%

24. 125 ml of 8% w/w NaOH solution (sp. gravity 1) is added to 125 ml of 10% w/v HCl solution.
The nature of resultant solution would be ________.
(A) basic (B) neutral (C) acidic (D) can’t be predicted.

25. Equal volumes of 10% (v/v) of HCl is mixed with 10% (v/v) NaOH solution. If density of pure
NaOH is 1.5 times that of pure HCl then the resultant solution be.
(A) basic (B) neutral (C) acidic (D) can’t be predicted.

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY

SOME TYPICAL CONCENTRATION TERMS

26. A fresh H2O2 solution is labeled as 11.35 V. Calculate its concentration in %w/v ?
(A) 2.5% (B) 3.4% (C) 4.2% (D) 5.4%

27. 100 ml each of 2M H 2O 2 and 11.35 V H 2O 2 solution are mixed then find the strength
of final solution in g/L.
(A) 25 (B) 51 (C) 42 (D) 54

28. If 50 gm oleum sample rated as 118% is mixed with 18 gm water, then the correct option is
(A) The resulting solution contains 18 gm of water and 118 gm H2SO4
(B) The resulting solution contains 9 gm water and 59 gm H2SO4
(C) The resulting solution contains only 118 gm pure H2SO4
(D) The resulting solution contains 68 gm of pure H2SO4

EUDIOMETRY

29. For a chemical reaction occurring at constant pressure and temperature.

2A(g) + 5B(g) ⎯→ C(g) + 2D(g)
(A) Contraction in volume is double the volume of A taken if B is taken in excess.
(B) Contraction in volume is more than the volume of B taken if A is in excess.
(C) Volume contracts by 20 mL if 10 mL A is reacted with 20 mL B.
(D) No change in volume due to reaction

30. One litre of CO2 passed over hot coke the volume becomes 1.4 litres then the composition of
products will not be (At STP)
400
(A) VCO2 : VCO = 3 : 4 (B) VCO2 = 1.6 ltr. (C) n CO2 : nCO = 3 : 4 (D) % v/v of CO =
7

31. C6H5OH (g) + O2 (g) ⎯→ CO2 (g) + H2O (l)

Magnitude of volume change if 30 ml of C6H5OH (g) is burnt with excess amount of oxygen, is
(A) 30 ml (B) 60 ml (C) 20 ml (D) 10 ml

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY

32. A mixture of C2H2 and C3H8 occupied a certain volume at 80 mm Hg. The mixture was completely
burnt to CO2 and H2O(l). The pressure of CO2 was found to be 230 mm Hg at the same
temperature and volume. The fraction of C2H2 in mixture is
(A) 0.125 (B) 0.5 (C) 0.85 (D) 0.25

33. The % by volume of C4H10 in a gaseous mixture of C4H10, CH4 and CO is 40. When 200 ml of the
mixture is burnt in excess of O2. Find volume (in ml) of CO2 produced.
(A) 220 (B) 340 (C) 440 (D) 560

34. 20 mL of a gaseous hydrocarbon was exploded with 120 mL of oxygen. A contraction of 60 mL

was observed, and a further contraction of 60 mL took place when KOH was added. What is the
formula of the hydrocarbon :
(A) C3H6 (B) C3H8 (C) C2H6 (D) C4H10

35. A definite amount of gaseous hydrocarbon was burnt with just sufficient amount of O2.
The volume of all reactants was 600 ml, after the explosion the volume of the products
[CO2(g) and H2O(g)] was found to be 700 ml under the similar conditions. The molecular formula
of the compound is
(A) C3H8 (B) C3H6 (C) C3H4 (D) C4H10

36. 10 ml of a compound containing 'N' and 'O' is react completely with 30 ml of H 2 to produce H2O
(l) and 10 ml of N2 (g). Molecular formula of compound if both reactants react completely, is
(A) N2O (B) NO2 (C) N2O3 (D) N2O5

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY
EXERCISE (S-I)
INTRODUCTION OF CONCENTRATION TERMS
1. Calculate the molarity of the following solutions:
(a) 4g of caustic soda is dissolved in 200 mL of the solution.
(b) 5.3 g of anhydrous sodium carbonate is dissolved in 100 mL of solution.
(c) 0.365 g of pure HCl gas is dissolved in 50 mL of solution.

2. 0.115 gm of sodium metal was dissolved in 500 ml of the solution in distilled water.
Calculate the molarity of the solution?

3. The average concentration of Na+ ion in human body is 3 to 4 gm per litre. The molarity of
Na+ ion is about.

4. What is the concentration of chloride ion, in molarity, in a solution containing 10.56 gm

BaCl2.8H2O per litre of solution? (Ba = 137)

5. How much BaCl2 (in gm) would be needed to make 250 ml of a solution having the same
concentration of Cl– as one containing 1.825 gm HCl per 100 ml ? (Ba = 137)

6. Equal moles of H2O and NaCl are present in a solution. Find molality of solution?

7. What is the quantity of water (in g) that should be added to 16 gm methanol to make the mole
fraction of methanol as 0.25:

8. If 0.5 M methanol undergo self dissociation like CH3OH CH3O– + H+ & if concentration of H+ is
2.5 × 10–4 M then calculate % dissociation of methanol.

INTERCONVERSION OF CONCENTRATION TERMS

9. Density of a solution containing 13% by mass of sulphuric acid is 0.98 g/ml. Then molarity of
solution will be

10. 15 g of methyl alcohol is present in 100 mL of solution. If density of solution is 0.90 g mL –1.
Calculate the mass percentage of methyl alcohol in solution

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY

11. A 6.90 M solution of KOH in water contains 30% by mass of KOH. What is density of solution in
gm/ml.

12. The concentration of a solution of NaOH is 8% (w/w) and 10% (w/v). Calculate density
(in gm/m) of solution?

13. The mole fraction of solute in aqueous urea solution is 0.2. Calculate the mass percent of solute?

14. Calculate molality (m) of Cl– (aq) present in the aqueous solution of 2M NH4Cl assuming 100%
dissociation according to reaction.
NH4Cl (aq) ⎯→ NH4+ (aq) + Cl– (aq)
Given : Density of solution = 3.107 gm / ml.

15. The concentration of Ca(HCO3)2 in a sample of hard water is 405 ppm. The density of water
sample is 1.0 gm/ml. Calculate the molarity of solution ?

16. Units of parts per million (ppm) or per billion (ppb) are often used to describe the concentrations
of solutes in very dilute solutions. The units are defined as the number of grams of solute per
million or per billion grams of solvent. Bay of Bengal has 1.9 ppm of lithium ions. What is the
molality of Li+ in this water ?

PROBLEMS RELATED WITH MIXING & DILUTION

17. Find molarity of Na+ ions if 500 mL of 0.2 M NaCl(aq) solution is mixed with 500 mL 0.5 M Na2SO4
(aq) solution ?

18. Find out the volume of 98% w/w H2SO4 (density = 1.8 gm/ ml), must be diluted to prepare
12.5 litres of 2.5 M sulphuric acid solution

19. Determine the volume (in mL) of diluted nitric acid 20% w/v HNO3 that can be prepared by
diluting 50 mL of conc. HNO3 with water 69.8% w /v.

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY
20. When V ml of 2.2 M H2SO4 solution is mixed with 10 V ml of water, the volume contraction of 2%
take place. Calculate the molarity of diluted solution ?

21. 500 ml of 2 M NaCl solution was mixed with 200 ml of 2 M NaCl solution. Calculate the final
volume and molarity of NaCl in final solution if final solution has density 1.5 gm/ml.

22. Calculate the amount of the water "in ml" which must be added to a given solution of
concentration of 40 mg silver nitrate per ml, to yield a solution of concentration of 16 mg silver
nitrate per ml ?

23. What volume (in ml) of 0.8 M AlCl3 solution should be mixed with 50 ml of 0.2M CaCl2 solution
to get solution of chloride ion concentration equal to 0.6 M ?

24. A mixture containing equimolar amounts of Ca(OH)2 and Al(OH)3 requires 0.5 L of 4.0 M HCl to
react with it completely. Total moles of the mixture are :

25. How would you prepare exactly 3.0 litre of 1.0 M NaOH by mixing proportions of stock solution
of 2.50 M NaOH and 0.40 M NaOH. No water is to be used. Find the ratio of the volume (v1/v2).

26. 20 mL of 0.2M Al2(SO4)3 is mixed with 30 mL of 0.6 M BaCl2. Calculate the mass of BaSO4 formed
in solution.
BaCl2 + Al2(SO4)3 ⎯→ BaSO4 + AlCl3

SOME TYPICAL CONCENTRATION TERMS

27. 50 ml of '20V' H2O2 is mixed with 200 ml, '10V' H2O2. Find the volume strength of resulting
solution?

28. 500 ml of a H2O2 solution on complete decomposition produces 2 moles of H2O. Calculate the
volume strength of H2O2 solution? [Given: Volume of O2 is measured at 1atm and 273 K]

29. An oleum sample is labeled as 118 %, Calculate

(i) Mass of H2SO4 in 100 gm oleum sample.
(ii) Maximum mass of H2SO4 that can be obtained if 30 gm sample is taken.

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY
(iii) Composition of mixture (mass of components) if 40 gm water is added to 30 gm given
oleum sample.
30. A mixture is prepared by mixing 10 gm H2SO4 and 40 gm SO3 calculate,
(a) mole fraction of H2SO4 (b) % labeling of oleum

EUDIOMETRY

31. Calculate the volume of CO2 evolved by the combustion of 50 ml of a mixture containing
40% C2H4 and 60% CH4 (by volume)

32. A gaseous hydrocarbon (CxHy) requires volume of O2 for complete combustion which is 6 times
of its own volume & produces volume of CO2 which is 4 times of its own volume. Find X + Y.

33. When 20 ml of mixture of O2 and O3 is heated, the volume becomes 29 ml and disappears in
alkaline pyrogallol solution. What is the volume percent of O2 in the original mixture?
(A) 90% (B) 10% (C) 18% (D) 2%

34. 20 ml of a mixture of C2H2 and CO was exploded with 30 ml of oxygen. The gases after the
reaction had a volume of 34 ml. On treatment with KOH, 8 ml of oxygen remained. Calculate the
volume of C2H2 in the mixture.

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(Physical Chemistry) CONCENTRATION TERMS AND EUDIOMETRY
ANSWER KEY
EXERCISE (O-I)
1. (C) 2. (B) 3. (D) 4. (A) 5. (C) 6. (B) 7. (A)
8. (C) 9. (C) 10. (B) 11. (D) 12. (B) 13. (C) 14. (B)
15. (A) 16. (B) 17. (C) 18. (B) 19. (C) 20. (C) 21. (C)
22. (D) 23. (A) 24. (C) 25. (A) 26. (B) 27. (B) 28. (B)
29. (A) 30. (B) 31. (B) 32. (A) 33. (C) 34. (B) 35. (A)
36. (C)

EXERCISE (S-I)
1. (a) (0.5 M) (b) (0.5 M) (c) (0.2 M)
2. (0.01M) 3. (0.15 M) 4. (0.06 M) 5. (13gm)
6. (55.55m) 7. (27)
8. (0.05) 9. (1.3) 10. (16.66%) 11. (1.2888)
12. (1.25gm/ml) 13. (45.45%) 14. (0.67)
15. (𝟐. 𝟓 × 𝟏𝟎−𝟑 𝐌) 16. (𝟐. 𝟕 × 𝟏𝟎−𝟒) 17. (𝟎. 𝟔𝐌) 18. (1. 736litre)
19. (174.5ml) 20. (0.204M) 21. (2M) 22. (1.5ml)
23. (5.56ml) 24. (0.8) 25. (0.4) 26. (2.796)
27. (12) 28. (44.8)
29. ((i) 20gm 𝐇𝟐 𝐒𝐎𝟒 (ii) 35.4 gm 𝐇𝟐 𝐒𝐎𝟒 (iii) 𝐇𝟐 𝐒𝐎𝟒 = 𝟑𝟓. 𝟒 𝐠𝐦, 𝐇𝟐 𝐎 = 𝟑𝟒. 𝟔 𝐠𝐦,)
30. ((a) 0.169 (b) 118%) 31. (70 ml) 32. (012) 33. ((B) 10%)
34. (𝐂𝟐 𝐇𝟐 = 𝟔𝐦𝐥, 𝐂𝐎 = 𝟏𝟒𝐦𝐥)
EXERCISE (O-II)
1. (A) 2. (D) 3. (B) 4. (A) 5. (A) 6. (A)
7. (AC) 8. (A) 9. (BD) 10. (BD) 11. (AC) 12. (B)
13. (C) 3 14. (C) 3/5 15. (B) 0.45 16. (C) 109
17. (34%)18. (C) 18.52 19. (D) 20. (A) 21. (B)
22. (B) 23. (C) 24. (B) 25. (A→Q, B→P, C→S, D→R)
26. (A→Q, B→P, C→S, D→R) 27. (A→PQRS, B→QRT, C→QS, D→P)

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