CHEM (ATOMIC STRUCTURE)

1. The threshold frequency of a metal is 4 ×1014 s−1. The minimum energy of photon to cause photoelectric effect
is:
(h = 6.6×10–34 Js)
−12
(A) 3.06 ×10 J
−18
(B) 1.4 × 10 J
−19
(C) 3.4 × 10 J
−19
(D) 2.64 × 10 J
2. Which one of the following particle(s) is/are not present in the nucleus of an atom?
(A) proton
(B) electron
(C)
(D) both proton and neutron
3. According to Bohr's atomic theory, which of the following is correct?
2
Z
(A) Potential energy of electron ∝ 2
n
(B) velocity of electron ∝ Z 2 /n
2
Z
(C) Frequency of revolution of electron in an orbit ∝ 3
n
2
Z
(D) Coulombic force of attraction on the electron ∝ 2
n
4. In Bohr series of lines of hydrogen spectrum, third line from the red end corresponds to which one of the
following inner orbit jumps of electron for Bohr orbit in atom of hydrogen:
(A) 4 →1
(B) 3 →2
(C) 2 →5
(D) 5 →2
5. The orbital angular momentum of an electron in 2s orbital is:
+1 h
(A) ⋅
2 2π

(B) 0
h
(C)
2π
h
(D) √2
2π
6. Radius of first Bohr’s orbit of hydrogen atom is:
(A) 0.24 Å
(B) 0.48 Å
(C) 0.53 Å
(D) 1.06 Å
7. In order to increase the kinetic energy of ejected photoelectrons, there should be an increase in:
(A) Intensity of radiation.
(B) Wavelength of radiation.
(C) Frequency of radiation.
(D) Both wavelength and intensity of radiation.
8. If the Planck’s constant h=6.6 ×10−34 Js , the de Broglie wavelength of a particle having momentum of
−24 −1
3.3 ×10 kg m s will be:
(A) 0.002 Å
(B) 0.5 Å
 CHEM (ATOMIC STRUCTURE)
(C) 2Å
(D) 500 Å
9. The energies of the electron in a hydrogen like ion are given by:

En =−( 2.18 ×10

−18
(n )
) Z 2 12 , where n is principal quantum number and Z is the atomic number of the element.

The ionisation energy (in kJ mol−1 ) of the Li 2+¿¿ ion is:

3
(A) 1.18 ×10
3
(B) 118 × 10
3
(C) 0.118× 10
3
(D) 11.8× 10
10. The figure indicates the energy level diagram for the origin of six spectral lines in the emission spectrum (e.g.
line no. 5 arises from the transition from level B to X). Which of the following spectral lines will not occur in the
absorption spectrum?

(A) 1, 2, 3
(B) 3, 2
(C) 4, 5, 6
(D) 3, 2, 1
11. An electron revolves round Li 2+¿¿ nucleus at a distance of 1.587 Å . The speed of electron should be
6
(A) 2.188 ×10 m/ s
6
(B) 6.564 × 10 m/s
5
(C) 7.293 ×10 m/s
6
(D) 7.293 ×10 m/s
12. Given below are two statement: one is labelled as Assertion A and the other is labelled as Reason R:
Assertion A: In the photoelectric effect, the electrons are ejected from the metal surface as soon as the beam of
light of frequency greater than threshold frequency strikes the surface.
Reason R: When the photon of any energy strikes an electron in the atom, there is no transfer of energy from the
photon to the electron.
In the light of the above statements, choose the correct answer from the options given below:
(A) A is true but R is false.
(B) A is false but R is true.
(C) Both A and R are true and R is the correct explanation of A.
(D) Both A and R are true but R is NOT the correct explanation of A.
13. In a hydrogen atom, if energy of an electron in ground state is –13.6 eV , then the energy in the 2nd excited state
is:
(A) –1.51 eV
(B) –3.4 eV
(C) –6.04 eV
(D) –13.6 eV
14. A radio station is emitting the radiations of frequency 2 × 104 Hz. If its frequency is doubled,
(A) wavelength will be doubled
(B) energy per quanta will be doubled
(C) wave number will be halved
(D) all of these
 CHEM (ATOMIC STRUCTURE)
15. How many spectral lines are produced in the spectrum of Hydrogen atom from 5th energy level to ground level?
(A) 5
(B) 10
(C) 15
(D) 4
16. A ball of mass 200 g is moving with velocity of 10 m.s –1. If the error in measurement of velocity is 0.1%, the
uncertainity in its position is:
–34
(h = 6.6×10 J s)
(A) 3.3 × 10–37 m
(B) 3.3 × 10–27 m
(C) 5.3 × 10–25 m
(D) 2.63 × 10–32 m
17. The position of both, an electron and a helium atom is known within 1.0 nm. Further the momentum of the
electron is known within 5.0 ×10−26 kg ms−1. The minimum uncertainty in the measurement of the momentum of
the helium atom is
−26 −1
(A) 8.0 ×10 kg ms
−1
(B) 80 kg ms
−1
(C) 50 kg ms
−26 −1
(D) 5.0 ×10 kg ms
18. The velocity of particle A is 0.1 m/sec and that of particle B is 0.05 m/sec . If the mass of particle B is 5 times
that of particle A, then the ratio of de-Broglie wavelength associated with particle A and B :
(A) 2 :5 (C) 6 : 4
(B) 3 :4 (D) 5 :2
19. Cathode rays are made up of
(A) Positively charged particles
(B) Negatively charged particles
(C) Neutral particles
(D) None of these
20. The ionization energy of H atom is 13.6 eV. The ionization energy of Li2+ ion will be:
(A) 54.4 eV
(B) 40.8 eV
(C) 27.2 eV
(D) 122.4 eV
+¿¿
21. The ratio between radii of first orbit of both He ion and H atom is:
1
(A) 1 C)
2
3
(B) (D) 2
2
22. If the uncertainty in velocity and position are same, then the uncertainty in momentum would be:

(A)
√ hm
4π
(B) m
√h
4π
(C)
√ h
4 πm

23.
(D)
1 h
m 4π√
The ratio of ionization energy of H and Be+3 is
(A) 1 :1 (c) 1:9
 CHEM (ATOMIC STRUCTURE)
(B) 1 :3 (D) 1:16
24. Calculate the momentum of a particle having a de-Broglie wavelength of 10–20 where h = 6.625×10–35 Js.
(A) 6.625 × 10–14 kgms–1 (C) 1.509 × 1014 kgms–1
(B) 0.1509 × 1014 kgms–1 (D) 6.625 × 10–54 kgms–1

25. Which of the following sets of quantum numbers represent an impossible arrangement?
(A) n→3 ; l→2; m→ –2 ; ms→ ¿
(B) n→4 ; l→0; m→ 0 ; ms→ ¿
(C) n→3 ; l→2; m→ –3 ; ms→ ¿
(D) n→5 ; l→3; m→ 0 ; ms→ ¿
 CHEM (ATOMIC STRUCTURE)

1. (D)
2. (B)
3. (C)
4. (D)
5. (B)
6. (C)
7. (C)
8. (C)
9. (D)
10. (C)
11. (A)
12. (A)
13. (A)
14. (B)
15. (B)
16. (D)
17. (D)
18. (D)
19. (B)
20. (D)
21. (C)
22. (A)
23. (D)
24. (C)
25. (C)
 CHEM (ATOMIC STRUCTURE)

1. Text Solution:
(4)
Threshold energy required for emission
−34 14
¿ hυ 0=6.6 × 10 × 4 ×10
−19
¿2.64 ×10 J

Video Solution:

2. Text Solution:
Protons and neutrons are present in the nucleus of an atom and electrons revolve around the nucleus in the shell.
Video Solution:

3. Text Solution:
(3)
2 3
−z z z
P.E∝ 2 V ∝ F∝ 4
n n n
Video Solution:

4.
Video Solution:

5. Text Solution:
For the 2s orbital, the value of l is zero. Hence the value of the orbital angular momentum will be zero.
Video Solution:
 CHEM (ATOMIC STRUCTURE)

6. Text Solution:
2
n
Radius of nth orbit, r n =0.53 × Å
Z
n = number of orbit, Z = atomic number
For Bohr's orbit, n = 1, Z = 1 (H-atom)
2
1
r 1=0.53× =0.53 Å
1
Video Solution:

7. Text Solution:
Kinetic energy of ejected photoelectrons directly proportional to the frequency of radiation.
∘
K . E=hυ−hυ❑
Video Solution:

8. Text Solution:
According to the de Broglie wavelength we have; λ = ℎ/ 𝑝 where; h=Planck’s constant, p= momentum
Putting all the values;
−34
6.6 ×10 −10
Å λ= −24
=2 ×10 m=2 Å
3.3× 10
Video Solution:

9. Text Solution:
(4)
2
−18 Z
En =−2.18 ×10 × 2 for Li2+, n = 1, z = 3
n
 CHEM (ATOMIC STRUCTURE)
( 3 )2
ELi 2+
= 2.18 × 10 –18
× 2 I . E=−¿
( 1)
−18 –3
E=19.62× 10 × 10 = 19.62 × 10–21 × 6.022 × 1023
= 11.8 × 103 kJ/mol
Video Solution:

10. Text Solution:

(3)
Emission lines correspond to downward electronic transitions (higher to lower level). For an absorption spectrum,
the electron must move up from a populated level (normally the ground state). Transitions 4, 5, 6 all start from
excited levels (X or B), which have negligible population under normal conditions, so those three lines do not
show up in the absorption spectrum.
th
[New NCERT Class 11 Page No. 46]
Video Solution:

11. Text Solution:

(1)
We will use the Bohr model of the atom, which can estimate the speed of an electron revolving around a nucleus.
For a hydrogen-like atom, the speed of the electron in the 𝑛 n-th orbit is given by:
2
Ze 1
ν= ⋅
4 π ε0 ℏ n
Video Solution:

12. Text Solution:

There is a characteristic minimum frequency, or “threshold frequency,” for each metal below which the
photoelectric effect is not seen. The ejected electrons leave with a specific amount of kinetic energy at a
frequency v > v0 with an increase in light frequency of these electron kinetic energies also rise.
Video Solution:
 CHEM (ATOMIC STRUCTURE)

13. Text Solution:

In a hydrogen atom, the energy of an electron in a specific orbit (or energy level) is given by the formula:
−13.6
En = 2
eV where:
n

• En is the energy of the electron in the n-th energy level,

• n is the principal quantum number corresponding to the energy level.

Given:
• The energy of the electron in the ground state ( n=1) is 13.6 eV (negative because the electron is bound to the
nucleus).
• We are asked to find the energy in the 2nd excited state.
The 2nd excited state corresponds to n=3 (since the first excited state is n=2, and the ground state is n=1).

Energy in the 2nd excited state (for n=3):

Using the formula:
−13.6 −13.6
E3 = 2 = E3 =−1.51eV
3 9

Conclusion:
The energy of the electron in the 2nd excited state (with n=3) is −1.51 eV .
Video Solution:

14. Text Solution:

E = n.hv
15. Text Solution:
The number of spectral lines produced when an electron de-excites from a higher energy level ( ni ) to the ground
state is given by the formula:
n i ( n i−1 )
Number of spectral lines=
2
 CHEM (ATOMIC STRUCTURE)
Given:
Initial energy level, ni =5
Now, calculating the number of spectral lines:
5 (5−1 ) 5 × 4 20
= = =10
2 2 2
Video Solution:

16. Text Solution:

=2.63 × 10–32 m
Video Solution:

17.
Video Solution:

18. Text Solution:

h
de-Broglie wavelength, λ=
mv
λ A h/m A v A mB v B 5 mA × 0.05
∴ = = ¿ =5 ×0.5=2.5=5 /2∴ λ A : λB =5 :2
λ B h/mB v B mA v A mA × 0.1
Video Solution:
 CHEM (ATOMIC STRUCTURE)

19. Text Solution:

Cathode rays are made up of negatively charged particles.

Video Solution:

20. Text Solution:

The ionization energy for a hydrogen-like atom can be calculated using the formula:
2
z
E = 13.6eV × 2E = 13.6eV × n2Z2
n
where ZZ is the atomic number and nn is the principal quantum number.
For Li2+ 2+
Li , Z = 3Z = 3 and n = 1n = 1.
2
3
E = 13.6 × 2 = 13.6 × 9 = 122.4eVE = 13.6 × 1232 = 13.6 × 9 = 122.4 eV
1
Video Solution:

21. Text Solution:

(3)

2
n 0
• Radius of nth orbit = 0.53 × A Where n is the principal quantum number and Z is the atomic number.
Z
• Atomic Number of H(Hydrogen) is 1 and the atomic number of He(Helium) is 2.
• ¿
+¿¿
• So, electronic configuration of He is 1 s 1.
• Electronic configurtaion of the element H(Hydrogen) is 1 s 1.
+¿¿
• So, principal quantum number of He is 1 and also the prinicipal quantum number of Hydrogen atom is 1.
 CHEM (ATOMIC STRUCTURE)
2 2
n 0 1 0 0.53 0
Radius of He+¿¿ ¿ 0.53 × A =0.53 × A = A
Z 2 2
2 2
n 1
Radius of H = ¿ 0.53 × A 0=0.53 × A0 =0.53 A 0
Z 1
0
0.53 A
+¿¿
Ratio between radii of He and H = 2 1
¿ 0
=
0.53 A 2
22. Text Solution:
(1)
h
Δx . Δp=
4π Δ
x = Δv (given)
h
Δx . mΔυ=
4π
2 2 mh
or m . Δυ =
4π

23. Text Solution:

Δp =
2 mh
4π
Δp=
4π √
mh [New NCERT Class 11th Page No. 24]

(4)
1 :16
Video Solution:

24. Text Solution:

−34
h 6.625 ×10
Momentum ¿ = −20
v 10
−14 −1
¿ 6.625 ×10 kg ms
Video Solution:

25. Text Solution:

(c)
The value of m can never be higher than l.
Video Solution:
CHEM (ATOMIC STRUCTURE)