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Chem Notes

The document outlines the physical and chemical properties of metals, including characteristics like luster, high melting points, and reactivity with water and acids. It also presents the reactivity series, ranking metals from most to least reactive, and discusses the implications of this series for predicting reactions and extracting metals. Understanding these properties is essential for predicting the chemical behavior of metals in various contexts.

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0% found this document useful (0 votes)
5 views4 pages

Chem Notes

The document outlines the physical and chemical properties of metals, including characteristics like luster, high melting points, and reactivity with water and acids. It also presents the reactivity series, ranking metals from most to least reactive, and discusses the implications of this series for predicting reactions and extracting metals. Understanding these properties is essential for predicting the chemical behavior of metals in various contexts.

Uploaded by

ngarekuebridget
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Here's a breakdown of the *physical and chemical properties of metals*

and the *reactivity series*:

### I. Physical Properties of Metals


1. *Luster (Shininess):* Most metals have a characteristic shiny surface
when freshly cut or polished.
2. *High Melting and Boiling Points:* Generally high (exceptions: Mercury
(Hg), Gallium (Ga), Cesium (Cs)).
3. *High Density:* Usually heavy for their size (exceptions: Alkali metals
like Lithium (Li), Sodium (Na), Potassium (K)).
4. *Malleability:* Can be hammered or rolled into thin sheets without
breaking.
5. *Ductility:* Can be drawn into thin wires.
6. *Good Conductors of Heat:* Transfer heat efficiently.
7. *Good Conductors of Electricity:* Allow electric current to flow easily
(due to delocalized electrons).
8. *Solid State (at Room Temp):* Except Mercury (Hg), which is liquid.
9. *Sonorous:* Produce a ringing sound when struck.
10. *Hardness:* Generally hard (exceptions: Alkali metals are soft, can be
cut with a knife).

### II. Chemical Properties of Metals


1. *Electron Donors (Form Cations):* Lose electrons to form positive ions
(e.g., Na → Na⁺ + e⁻).
2. *Reaction with Oxygen:* Form metal oxides (basic or amphoteric).
* 4Na + O₂ → 2Na₂O (Sodium Oxide - Basic)
* 2Mg + O₂ → 2MgO (Magnesium Oxide - Basic)
* 4Al + 3O₂ → 2Al₂O₃ (Aluminium Oxide - Amphoteric)
* Note: Gold & Platinum don't react.
3. *Reaction with Water:*
* *Very Reactive (K, Na, Ca):* React violently with cold water,
displacing hydrogen gas and forming hydroxides.
2Na + 2H₂O → 2NaOH + H₂
* *Moderately Reactive (Mg, Al, Zn, Fe):* React with steam (hot water
vapor), forming oxides and hydrogen gas.
Mg + H₂O(g) → MgO + H₂ (or 3Fe + 4H₂O(g) → Fe₃O₄ + 4H₂)
* *Less Reactive (Pb, Cu, Ag, Au, Pt):* Do not react with water or
steam.
4. *Reaction with Dilute Acids:*
* *Reactive Metals (above H in series):* Displace hydrogen gas from
dilute acids (HCl, H₂SO₄).
Zn + 2HCl → ZnCl₂ + H₂; Mg + H₂SO₄ → MgSO₄ + H₂
* *Less Reactive Metals (below H in series):* Do not displace hydrogen
(e.g., Cu, Ag, Au, Pt).
5. *Reaction with Chlorine:* Form metal chlorides (ionic salts).
2Na + Cl₂ → 2NaCl; Mg + Cl₂ → MgCl₂; 2Al + 3Cl₂ → 2AlCl₃
6. *Displacement Reactions:* A more reactive metal displaces a less
reactive metal from its compound (solution or molten state).
Zn + CuSO₄ → ZnSO₄ + Cu (Zinc displaces Copper)
Mg + 2AgNO₃ → Mg(NO₃)₂ + 2Ag (Magnesium displaces Silver)

### III. The Reactivity Series


This lists metals in order of decreasing chemical reactivity (ease of losing
electrons). The most reactive metal is at the top.

| Metal | Symbol | Key


Reactions |
Notes |
| :-------- | :----- | :----------------------------------------------------------------------------
| :-------------------------------------------------------------------- |
| Potassium | K | *Violently* with cold water, acids. Bursts into flame in
air. | *M*ost Reactive. Stored under oil. |
| Sodium | Na | *Violently* with cold water, acids. Burns brightly in
air. | Very Reactive. Stored under oil. |
| Calcium | Ca | *Less violently* with cold water, acids. Burns in
air. | Forms slaked lime with water. |
| Magnesium | Mg | Slowly with cold water, *vigorously* with
steam/dilute acids. Burns brightly. | Forms protective oxide
layer. |
| Aluminium | Al | *Slowly* with steam/dilute acids. Burns if
powdered. | Forms *very protective* oxide layer (anodizing).
*A*mphoteric oxide. |
| Zinc | Zn | *Slowly* with steam/dilute acids. Burns
brightly. | Forms protective oxide layer. Used for
galvanizing. |
| Iron | Fe | *Slowly* with steam/dilute acids. Rusts (corrodes) in
moist air. | Requires oxygen and water for
rusting. |
| Lead | Pb | *Very slowly* with dilute acids. Forms protective oxide
layer. | Oxide layer makes it appear unreactive.
|
| Hydrogen | H | Non-metal reference
point | *H*ydrogen is placed here as
metals above displace it from acids. |
| Copper | Cu | No reaction with water/steam. *Slowly* with strong
oxidizing acids (HNO₃). | Develops green patina (basic copper
carbonate). |
| Silver | Ag | No reaction with water/steam/dilute acids. Tarnishes
(Ag₂S) with sulfur. | |
| Gold | Au | *No reaction* with water, steam, air, or any single acid
(except aqua regia). | *L*east Reactive. Noble
metal. |
| Platinum | Pt | *Extremely unreactive.* Resists most
acids. | Noble metal.
Catalyst. |

*Common Mnemonic (UK):* *Please **Send **Charley's **Monkeys **And


**Zebras **In **Large **Cages **Securely **Guarded **Platinum (G*old)
(Potassium, Sodium, Calcium, Magnesium, Aluminium, Zinc, Iron, Lead,
Copper, Silver, Gold, Platinum)

### IV. Importance & Uses of the Reactivity Series


1. *Predicting Displacement Reactions:* Determines if a metal will
displace another from a solution or molten compound.
2. *Predicting Reaction with Water/Steam/Acid:* Tells us which metals will
react and how vigorously.
3. *Extraction of Metals:* Metals below carbon (like Fe, Zn, Pb) can be
extracted by reduction of their oxides with carbon/carbon monoxide. Very
reactive metals (K, Na, Ca, Al, Mg) require electrolysis.
4. *Galvanizing:* Coating iron/steel with zinc (more reactive) protects it
sacrificially from rusting.
5. *Sacrificial Protection:* Attaching blocks of more reactive metals (like
Mg or Zn) to iron structures (e.g., ships, pipelines) protects them from
corrosion.
6. *Explaining Stability:* Why gold/silver/platinum are found native (as
elements) while reactive metals are always found as compounds (ores).
7. *Choosing Storage Methods:* Highly reactive metals (K, Na) are stored
under oil to prevent reaction with air/water.

Understanding both the fundamental properties and the reactivity series


order is crucial for explaining and predicting the chemical behavior of
metals.

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