Boards

Objective Test - 01

Q1 Given below are two statements: Amalgam of

Statement I: The solubility of any gas in any B. Solid in gas II. mercury with
liquid is an exothermic process. sodium
Statement II: All the gases are highly soluble Liquid in Camphor in
C. III.
solid nitrogen gas
in any liquid.
Solution of
In the light of the above statements, choose
D. Gas in liquid IV. hydrogen in
the most appropriate answer from the options
palladium
given below: Choose the correct answer from the options
(A) Statement I is correct but Statement II is given below;
incorrect. (A) A-IV, B-III, C-II, D-I
(B) Statement I is incorrect but Statement II is (B) A-IV, B-II, C-I, D-III
correct. (C) A-III, B-I, C-IV, D-II
(C) Both Statement I and Statement II are (D) A-I, B-IV, C-III, D-II
correct.
(D) Both Statement I and Statement II are Q5 The law which states that “the partial pressure
incorrect. of the gas in vapour phase (p) is proportional
to the mole fraction of the gas (χ) in the
Q2 If a solution is described as 10% glucose in solution” is:
water by mass, it means: (A) Raoult’s law
(A) 10 g of glucose is dissolved in 10 g of water. (B) Henry’s law
(B) 10 g of glucose is dissolved in 90 g of water, (C) Dalton’s law
making a 100 g solution. (D) Van’t Hoff’s law
(C) 10 g of glucose is dissolved in 100 g of
water. Q6 How does the solubility of gas change in a
(D) 10 g of glucose is dissolved in 1000 g of liquid, as described?
solution. (A) Increases with decreasing pressure.
(B) Increases with increasing temperature.
Q3 Out of following which one is not an example (C) Decreases with increasing temperature.
of solution? (D) Decreases with increasing pressure.
(A) Air
(B) Brass Q7 How does an increase in temperature affect
(C) Benzene in water the vapour pressure of a liquid?
(D) Sugar syrup (A) Vapour pressure increases.
(B) Vapour pressure decreases.
Q4 Match the List-I with List-II. (C) Vapour pressure remains the same.
List-I (D) Vapour pressure becomes zero.
List-II
(Type of
(Common examples)
solution) Q8 Colligative properties are observed when :
Oxygen dissolved (A) A non-volatile solid is dissolved in a volatile
A. Gas in solid I.
in water liquid

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(B) A non- volatile liquid is dissolved in another (A) 0.8 (B) 0.5
nonvolatile liquid (C) 0.3 (D) 0.2
(C) A gas is dissolved in non-volatile liquid
Q15 Given below are two statements. One is
(D) A volatile liquid is dissolved in another
labelled as Assertion A and other is labelled as
volatile liquid
Reason R.
Q9 Which of the following gases has highest Assertion A: Relative lowering of vapour
solubility in water at 298 K? pressure is equal to mole fraction of the
(A) A (KH= 40.3 k bar) solute.
(B) B (KH= 1.67 k bar) ReasonR: Relative lowering of vapour
(C) C (KH= 1.83×10–5k bar) pressure is a colligative property.
(D) D (KH= 145.2 k bar) In the light of the above statements, Choose
the most appropriate answer from the options
Q10 The vapour pressure of a liquid in a closed
given below:
container depends upon:
(A) A is true, but R is false.
(A) Amount of liquid.
(B) A is false, but R is true.
(B) Surface area of the container.
(C) Both A and R are true and R is the correct
(C) Temperature.
explanation of A.
(D) Volume of the container.
(D) Both A and R are true, but R is NOT the
Q11 In one molal solution that contains 0.5 mole of correct explanation of A.
a solute, there is:
Q16 Which of the following will show a positive
(A) 1000 g of solvent
deviation from Raoult’s law?
(B) 400 mL of solvent
(A) Acetone + Chloroform
(C) 500 g of solvent
(B) Benzene + Toluene
(D) 100 mL of solvent
(C) Ethanol + Water
Q12 If molecular interaction of two different liquid (D) Acetone + Carbon disulfide
molecules are stronger than the molecular
Q17 An ideal solution is that which:
interactions of the same liquid molecules the
(A) Obey Raoult's law
mixture is expected to show :
(B) Shows positive deviation from Raoult's law
(A) Positive deviations
(C) Shows negative deviation from Raoult's law
(B) Negative deviations
(D) Has no connection with Raoult's law
(C) No deviations
(D) Positive as well as negative deviations Q18 Given below are two statements:
Statement I: Molality is preferred over
Q13 If the concentration of glucose (C6H12O6) in
molarity for expressing concentration in
blood is 0.9 g L–1, what will be the molarity of temperature-dependent studies.
glucose in blood? Statement II: Molality changes with
(A) 5 M (B) 0.5 M temperature, while molarity remains constant.
(C) 0.005 M (D) 50 M In the light of the above statements, choose
the most appropriate answer from the options
Q14 Relative lowering of vapour pressure of a
given below:
dilute solution is 0.2. What is the mole fraction
(A) Statement I is correct but Statement II is
of non volatile solute?
incorrect.

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(B) Statement I is incorrect but Statement II is Q23 The boiling point of C6H6, CH3OH, C6H5NH2
correct. and C6H5NO2 are 80°C, 65°C, 184°C and 212°C
(C) Both Statement I and Statement II are
respectively. Which will show highest vapour
correct.
pressure at room temperature?
(D) Both Statement I and Statement II are
(A) C6H6 (B) CH3OH
incorrect.
(C) C6H5NH2 (D) C6H5NO2
Q19 Vapour pressure of chloroform and Q24 Given below are two statements : one is
dichloromethane at are labelled as Assertion A and the other is
and respectively. labelled as Reason R.
Vapour pressure of the solution obtained by Assertion A : Helium is used to dilute oxygen
mixing of and of in diving apparatus.
at the same temperature will be (Molecular Reasons R : Helium has high solubility in .
mass of and molecular In the light of the above statements, choose
mass of ) the correct answer from the options given
(A) below :
(B) (A) Both A and R are true but R is NOT the
(C) correct explanation of A.
(D) (B) A is true but R is false
(C) A is false but R is true
Q20 Vapour pressure of a liquid is defined as: (D) Both A and R are true and R is the correct
(A) The pressure exerted by the liquid explanation of A.
molecules at the bottom of the container.
(B) The pressure exerted by vapours of the Q25 Mole fraction of in molal aqueous
liquid when it is in equilibrium with its solution is:
liquid phase. (A) (B)
(C) The atmospheric pressure above the liquid. (C) (D)
(D) The boiling point of the liquid.

Q21 Among the following, that does not form an

ideal solution is;
(A) C6H6and C6H5CH3
(B) C2H5Cl and C6H5OH
(C) C6H5Cl and C6H5Br
(D) C2H5Br and C2H5I

Q22 The vapour pressure of a liquid in a closed

container depends on :
(1) temperature of liquid
(2) quantity of liquid
(3) surface area of the liquid
(A) 1 only (B) 2 only
(C) 1 and 3 only (D) 1, 2 and 3

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Answer Key
Q1 A Q14 D

Q2 B Q15 C

Q3 C Q16 D
Q4 A Q17 A

Q5 B Q18 A
Q6 C Q19 C

Q7 A Q20 B

Q8 A Q21 B
Q9 C Q22 A

Q10 C Q23 B

Q11 C Q24 B
Q12 B Q25 B

Q13 C

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Hints & Solutions

Note: scan the QR code to watch video solution

Q1 Text Solution: Q4 Text Solution:

The solubility of any gas in any liquid is an
Gas in solid: Solution of H2 in Pd
exothermic process.
Solid in gas: Camphor in N2
Video Solution:
Liquid in solid: Amalgam of Hg with Na
Gas in liquid: O2 dissolved in H2O

Video Solution:

Q2 Text Solution:
In a 10% (w/w) solution, 10 g of glucose is
present in a 100 g solution. Since the solvent is
water, this means 90 g of water is present.
Q5 Text Solution:
Video Solution:
Henry’s law states that “the partial pressure of
the gas in vapour phase (p) is proportional to
the mole fraction of the gas (χ) in the solution”.

Video Solution:

Q3 Text Solution:
Non-polar benzene is immiscible in water. Air
is a homogenous mixture of gases (mainly
nitrogen, oxygen, and smaller amounts of
other gases like carbon dioxide, argon, etc.).
Air is homogenous on a macroscopic level. A Q6 Text Solution:
solution typically involves a solvent and solute 1.Effect of Temperature on solubility:
where one component is dissolved in another.
As the temperature increases, the
Brass is a metal alloy in which zinc and copper
solubility of a gas in a liquid decreases
forms homogenous mixture, and it’s
because higher temperatures provide
considered a solid solution.
more energy to gas molecules, making it
Video Solution: easier for them to escape from the liquid
into the gaseous phase.

2. Effect of Pressure on solubility:

Higher pressure increases gas solubility,

and lower pressure decreases it.

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Video Solution:

Q10 Text Solution:

Q7 Text Solution: Vapour pressure of a liquid in a closed
An increase in temperature directly leads to an container increases with increase in
increase in the vapour pressure of a liquid. temperature.
This is because as the temperature rises, the
Video Solution:
kinetic energy of the liquid molecules
increases, making it easier for them to
overcome intermolecular forces and escape
into the gas phase, thus increasing the
pressure exerted by the vapour above the
liquid.

Video Solution: Q11 Text Solution:

Molality is defined as the number of moles of
solute per kg of the solvent.
∴ m = nB × 1000 / wA
1 = 0.5 × 1000 / wA
∴ wA = 500 g

Q8 Text Solution: Video Solution:

A non-volatile solid is dissolved in a volatile
liquid

Video Solution:

Q12 Text Solution:

The intermolecular attractive forces between
A−B are stronger than those between A−A and
B−B and this leads to a decrease in vapour
Q9 Text Solution:
pressure resulting in negative deviations.
According to Henry's law:
Solubility of a gas in water Video Solution:

Video Solution:

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Q13 Text Solution: ∆P = P° – P = P° – ( P°)

Molar mass of glucose C6H12O6 = 180 g/mol ∆P = (1 – ) P°
concentration of gluocose = 0.9 g/L ∆P = P°
mass of glucose in 1 L = 0.9 g So, we can infer that relative lowering of
vapour pressure is a colligative property.
Molarity,
Video Solution:
no. of moles,

Video Solution:

Q16 Text Solution:

Positive deviation occurs when intermolecular
forces between solute and solvent are weaker
than in pure components.

Q14 Text Solution: Video Solution:

According to Raoult’s law, the relative lowering

in vapour pressure of an ideal solution
containing the non-volatile solute is equal to
the mole fraction of the solute. Given– Relative
lowering of vapour pressure = 0.2. So, Mole
fraction will be also 0.2.
Q17 Text Solution:
Video Solution:
The solutions which obey Raoult's law over the
entire range of concentration are known as
ideal solutions.

Video Solution:

Q15 Text Solution:

We can define the vapour pressure of a liquid
as- The pressure of the vapour, which is in
equilibrium with the liquid. The vapour
pressure of a solvent is lowered when a non- Q18 Text Solution:

volatile solute is dissolved in it to form a Molality is temperature-independent, whereas

solution. molarity depends on volume, which changes
with temperature. Hence, Statement I is
correct, but Statement II is incorrect.
[Here, Pº is the vapour pressure of the pure
solvent] Video Solution:
This reduction of vapour pressure of solvent is
given as

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Q19 Text Solution: Q21 Text Solution:

Molar mass of C2H5Cl and C6H5OH do not form ideal solution
because of hydrogen bonding in C6H5OH.

Video Solution:
Moles of

Molar mass of

Moles of
Q22 Text Solution:
Total number of moles Vapour pressure of a liquid in a closed
container depends only on temperature —
Mole fraction of component 2 not on quantity or surface area.

✔ Temperature affects kinetic energy

Mole fraction of component 1
and evaporation rate.
✘ Quantity does not affect vapour
We know that:
pressure as long as some liquid is
present.
✘ Surface area affects rate of
evaporation, but not equilibrium vapour
pressure.

Video Solution:

Video Solution:

Q23 Text Solution:

Lower the boiling point, higher is the vapour
Q20 Text Solution:
pressure.
The pressure exerted by vapours of the liquid
when it is in equilibrium with its liquid phase. Video Solution:

Video Solution:

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Q24 Text Solution:

Correct Answer – B: A is true but R is false
Helium is used to dilute O₂ in diving apparatus
because it has low solubility in blood, not
high. Hence, assertion is true, but reason is
false.

Video Solution: Video Solution:

Q25 Text Solution:

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