BRC
Rate of diya. o| A= axt02 mole | ibe See] -
Coltulate © Rte} diss:o} B
0) Rate of fowmatin | C
Nye Arx"W
oP tg= BF
Ya = Prats mele ysecl =
“in 8 mele eel
Ne = uany
(y = up C
oF" my AEN, BNL
OReler of Reachom
4.
Moleceitarity
Rate af wen =k TA Cay &
Cleyy i x \
4. topal Nove} sbecter coly
veo _ &Sroulkaneouly Pa emer
Aum a} power of con-<| Reackuk Chemical Reachon :
M™ Rate ellam expressin7
q 8: not frachinal
Order of Ren = aN not Revo
2 okdes | Remy ~ moy be S- tnags motenarity =32
negabbe
frachona}
posiPve
Inax order of wEN =I Cop =5
bp nNA+.B
=
Rrew = x X Rog «
here > XHme Con: a} Rencanty chit
ia M = mder af rey
ey hog S04 BOR.
1, Reto) Neto ROR
nly)
x ® D=0 N=) Nea | N=3 n=4
§ [double) | Rvew= Bora | Rn=2Ro Pru= A By |Ru= aR, P= Be
- os = Ro
altri) | Rr = Roxy |Rw* Bho, |Ru=3 Re | Be Fee] Ra Be
(hol) Riye'Ro Ryz Ro Rus = Ro |
= | g | Gp=6 320 order of Reachory \ : g
A>8B
~dn- KALE K
x -Rulea} THY of Jew ard EY TH
Rates| Ren= K > hs Const ancl equal tok
¥ does Not depend Wbor ton:
o} Renctant
¥ tole} hyne fo Complete ger under wXAN [T) = axby,
& Unit | Ke (a) xsecl
sh
Pe \ Pale he
’ + : te by
pate
Be Gp=t 1 osder Reachon
a |
A— 5
~da. \
at =KTAQ
Rate a} Yar] = ~ ap = KT!
eke tobe Laue 9
+ Ar ara J ‘Be
Fags Roe KE
x Xs Ao (reo *t)
a) “je —-a Be
be 0 Be
Reo ,? Sie ke SBE
Lge
Ay= [An-%) \ hy “i 5 ke 2363 Is4 Ay
\ ou IN Bea,
toSec bgt)
Ay, > [Peep a
\ i
Yo
(b) by = 016932 _ 3-803ax1093
TAQ K te Rei
> by 4 Indenpend ton} Reackant-!
nth, hok depend por Core]
tA Co
% ¥%, o| yt order tA
Remttant
2 ‘ | 6
(¢) aA-'B \
tsec 4 ry Pen C
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Cp § 1” osder Ren Py term o| Pav sel prevure
yg
PRenRr
Pe (8) RT = cer \
[Pae), > Itimeny /gourse mole to dso
‘Cite ‘Kete ho Lose hi preyyre
Ko bhi Akh Zakte ho «
bo
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P= Po oO teo
PelPo-R: Bon) HOT Pakm, thee,
ks “9.3049 Jen Be = Q:3029 win bbe’
Sey eae egg?
loheve > P= Inthe! Premsure of Reactan-
Pee after Ebme pieshure of Reacta
Ve { y | | '
© scamnes Cod
nth oder o} Ren
NA —> B
ROR= KTAT
ie oe te
iol @y"t im]
),2 > appbeable
ke n=2 | 2d order o} xn)
ke LJL -t
ET vad
le = ol gtd 3
2 Oak ic ; ty, ot (m0)'™
neal ity, Gi a order rxn)
Japh [a™ord er af>rn)
u Stope=K
Ly ope
Ay 4
. i) \ ae
K
to
(d _ Te
So=10 Activahen Ene: w ety of Temperelure
@)X dime _ Fa 5 Vanth half Equahoy
ar Ry?
HY ke gen MRT A ontus Cqueahon
here> k= Rte Const
Eq> Ackvahn energy
T= temp:
R= Universe) bay Conthamk
= O86 Sy Soule KI mile!
4199-9 2 Glare KT mole?
2 0+08.2) obmaline KT mo] e7
a
A= Arrhenius factor of Aaehenius Const
Of pre exponential factor
1o* Adbvahon eneag => Minimura energy wequired ‘fo
Teach achvahon complex (Threshold
energy Barder )
Cxothermic.
Pave (a) Fa AA Hheretraly clepend “upon! femb. bub Very
high aarge of tie changes He value 2] AB ae
change VA not Atgnifican. $0 plpueshon Alove
Kste dime hum temp, s¢ Tndepend Aupbore keke
challe har’
le) T-k—>-&
Te BE
Tae la Sy Woyel
fst vvA
- . 0 dtftesentte
- els a oe - ")
=
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e=K rad” Rw
a= tgUAID”
:
19
Carep [ROR Py TK
ROR > R, ot Tak
salt i
% 2039 Cay F A=>8
f e-3 T. n Catal
os { prexence dy lys {
k, = Ae" a) RT .
— absente of catalyst
«Cp = 8 eo Miler |
: Be Peete Gt
ged he
Slopes aly
i Slope = $6 5-6
0 R932,
fy } " ] f
t ct 4 | Mi |
kK \ | |
T Cpzh temperature CeoWretenk)
Rate of Ran depend upon deiop » QacR P>4 eps
|
Jie Katie 2 Raho a} toe const ant ak 10
d Kr!
|
Jerap- ceofftcternt- i TK ere:
Ho bs 408) vider by
“TH Voambeadtacdh Mayeryy
goes each love rhye Py terp: , Rate 9 san ly
double ye Ie he a ) \ SDE 25 B 5 comper'er
(Mech vig, ARS K,- Ratelonst E) ||
Vf oe) AP BP ee ——é,
ny — a} oh ——&
‘ , |
Overall Rate Const o Ke KA hb KE ann
Aubpore an calecdate
© overall Adralon Enesgy (£)
© overall Raskentus Const ( Ar) ’
B= axe, +bKE $CKE EH
Py = GxApvhyb¥tyt
a
Ppa AP AC EAS -
exo A KG putt
Gay
B= 160 K5)nvle
Be G0 KS] mile
p= 50 KJ] ole
Ca} eutake Achiahern Ev af Over Rxn.
2 x
so)? fer kr ky ee
= 2x6 42
Be a*E) + axe,
PR= uo ks
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