NEET : CHAPTER WISE TEST-2
SUBJECT :- CHEMISTRY DATE.............................................................
th
CLASS :- 12 NAME.............................................................
CHAPTER :- ELECTROCHEMISTRY SECTION.......................................................
(SECTION-A)
1. In a galvanic cell 9. Find the emf of the Given, Eº Pb2+ / Pb = –
(A) chemical reaction produces electrical 2+
0.12 V ; Eº Zn / Zn = – 0.76V.
energy 2+ 2+
cell Zn/Zn (0.1 M) || Pb (1 M) | Pb.
(B) electrical energy produces chemical
(A) – 0.637 (B) + 0.637
reaction
(C) reduction occurs at anode (C) > 0.637 (D) + 0.889
(D) oxidation occurs at cathode
10. Which respresent a concertration cell ?
2. Which is not true for a standard hydrogen (A) Pt | H2 | HCl || HCl | PtH2
electrode ? (B) Pt | H2 | HCl || Cl2 | Pt
(A) The hydrogen ion concentration is 1 M (C) Zn | Zn2+ || Cu2+ | Cu
(B) Temperature must be 25°C
(D) Fe | Fe+2 || Cu2+ | Cu
(C) Pressure of hydrogen is 1 atmosphere
(D) All are correct 2+ 2+
11. Zn | Zn (C1)|| Zn (C2)|Zn. for this cell
3. KCl can be used in salt bridge as G is negative if -
electrolyte in which of the following cells? (A) C1 = C2 (B) C1 > C2
(A) Zn | ZnCl2 || AgNO3 | Ag (C) C2 > C1 (D) None
(B) Pb | Pb(NO3)2 || Cu(NO3)2 | Cu
(C) Cu | CuSO4 || AuCl3 | Au
(D) Fe | FeSO4 || Pb(NO3)2 | Pb 12. During the electrolysis of fused NaCl, the
reaction that occurs at the anode is :
4. The E M3 /M2 values for Cr, Mn, Fe and (A) Chloride ions are oxidized
(B) Chloride ions are reduced
Co are – 0.41, + 1.57, + 0.77 and +1.97 V
respectively. For which one of these (C) Sodium ions are oxidized
metals the change in oxidation state from (D) Sodium ions are reduced
+2 to +3 is easiest?
(A) Co (B) Mn (C) Fe (D) Cr 13. An acidic solution of copper () sulphate
containing some contaminations of zinc
5. Standard reduction electrode potentials of
three metals A, B and C are +0.5 V, – 3.0 and iron () ions was electrolysed till all
V and – 1.2 V respecitvely. The reducing the copper is deposited. If electrolysis is
power of these metals are : further continued for sometime, the
(A) B > C > A (B) A > B > C product liberated at cathode is
(C) C > B > A (D) A > C > B (A) Fe (B) Zn
(C) H2 (D) Alloy of Zn and Fe.
6. The metal that cannot be produced on
reduction of its oxide by aluminium is :
(A) K (B) Mn (C) Cr (D) Fe 14. The amount of an ion discharged during
electrolysis is not directly proportional to :
7. If EºFe2 / Fe = – 0.441 V and EºFe3 Fe2 = (A) resistance
0.771 V, the standard EMF of the reaction (B) time duration of electrolysis
Fe + 2Fe3+ 3Fe2+ will be: (C) charge
(A) 1.212 V (B) 0.111 V (D) electrochemical equivalent of the element
(C) 0.330 V (D) 1.653 V
15. Faraday's law of electrolysis fails when :
8. What is the electrode potential (in V) of the (A) Temperature is increased
following electrode at 25ºC ? (B) Inert electrodes are used
2+
Ni (0.1 M) | Ni(s) (C) A mixture of electrolytes is used
(Standard reaction potential of Ni2+ | Ni is – (D) In none of the above cases
2.303 RT
0.25 V, = 0.06)
F 16. How many faradays are required to reduce
(A) – 0.28 V (B) – 0.34 V one mol of MnO4¯ to Mn2+ -
(C) – 0.82 V (D) – 0.22 V (A) 1 (B) 2 (C) 3 (D) 5
PG #1
17. The amount of electricity that can deposit 26. The position of some metals in the
108 g. of silver from silver nitrate solution electrochemical series in decreasing
is : electeopositive character is given as Mg >
(A) 1 ampere (B) 1 coulomb Al > Zn > Cu > Ag . What will happen if a
(C) 1 Faraday (D) 2 ampere copper spoon is used to stir a solution of
aluminium nitrate?
18. An electrolysis of a oxytungsten complex (A) The spoon will get coated with
ion using 1.10 A for 40 min produces aluminium
0.838 g of tungsten. What is the charge of (B) An alloy of copper and aluminium is
tungsten in the material ? (Atomic weight :
formed
W = 184)
(A) 6 (B) 2 (C) 4 (D) 1 (C) The solution becomes blue
(D) There is no reaction
19. The weight ratio of AI and Ag deposited
2+ +
using the same quantity of current is: 27. For Zn / Zn, E° = –0.76 V, for Ag /Ag E°
(A) 9 : 108 (B) 2 : 12 = 0.799 V. The correct statement is -
(C) 108 : 9 (D) 3 : 8 (A) the reaction Zn getting reduced Ag
getting oxidized is spontaneous
20. When a lead storage battery is discharged
(B) Zn undergoes reduction and Ag is oxidized
(A) PbSO4 is formed (B) Pb is formed
(C) Zn undergoes oxidation Ag+ gets reduced
(C) SO2 is consumed (D) H2SO4 is formed
(D) No suitable answer
21. The units of conductivity are
28. Electrode potential data are given below.
(A) ohm–1 (B) ohm–1 cm–1
–2 2 –1 Fe3+ (aq) + e–
Fe2+ (aq);E0 = + 0.77
(C) ohm cm equiv (D) ohm–1 cm2
Al3+ (aq) + 3e–
Al (s); E0 = – 1.66 V
22. At 18ºC, the equivqlent conductivity of H+ Br2 (aq) + 2e– 2Br– (aq) ; E0 = +
and CH3COO– at infinite dilution are 315 1.08 V
and 35 mho cm2 eq–1 respectively. The Based one the data given above, reducing
equivalent conductivity of CH3COOH at power of Fe2+, Al and Br – will increase in
infinite dilutoin is ......mho cm2 eq–1 the order :
(A) 350 (B) 280 (A) Br – < Fe2+ < Al (B) Fe2+ < Al < Br –
(C) 30 (D) 315 (C) Al < Br – < Fe2+ (D) Al < Fe2+ < Br –
23. The ionization constant of a weak 29. Given standard electrode potentials :
electrolyte is 25 × 10–6 while the Fe3+ + 3e¯ Fe ; E° = –0.036 volt
equivalent conductivity of its 0.01 M
Fe2+ + 2e¯ Fe; E° = –0.440 volt
solution is 19.6 S cm2 eq–1. The equivalent
The standard electrode potential E° for
conductivity of the electrolyte at infinite
Fe3+ + e¯ Fe2+
dilution (in S cm2 eq–1 ) will be
(A) 250 (B) 196 (A) –0.476 volt (B) –0.404 volt
(C) 392 (D) 384 (C) 0.440 volt (D) 0.772 volt
24. Which of the following is/are function(s) of 30. Which of the following statements about
salt - bridge ? the spontaneous reaction occurring in a
(A) It completes the electrical circuit galvanic cell is always true ?
(B) It maintains electrical neutrality by flow (A) Eºcell > 0, Gº < 0, and Q < K
of ions between the two compartments (B) Eºcell > 0, Gº < 0, and Q > K
through salt - bridge (C) Eºcell > 0, Gº > 0, and Q > K
(C) It minimises the liquid - liquid junction (D) Ecell > 0, G < 0, and Q < K
potential
(D) All of these 31. In a galvanic cell the electrical work done
is equal to –
25. KCl can't be used in salt bridge if (A) Free energy change
electrolyte of a galvanic cell contains : (B) mechanical work done
(A) Ag+- ions (B) Pb2+- ions (C) Thermodynamic work done
2+
(C) Hg2 -ions (D) All (D) All of these
PG #2
H2 H H H2 39. Electrolysis can be used to determine
32. Pt Pt (where p1
(p1 ) (1M) (1M) (p 2 ) atomic masses. A current of 0.550 A
and p2 are pressures) cell reaction will be deposits 0.55 g of a certain metal in 100
spontaneous if :
(A) p1 = p2 (B) p1 > p2 minutes. If valency of metal is 3 then it's
(C) p2 > p1 (D) p1 = 1 atm atomic mass will be :
33. The EMF of a concentration cell consisting (A) 100 (B) 45.0
of two zinc electrodes, one dipping into (C) 48.25 (D) 144.75
M
sol. of zinc sulphate & the other into
4 40. When lead stroage battery is charged :
M (A) lead dioxide dissolves
sol. of the same salt at 25C is
16 (B) sulphuric acid is regenerated
(A) 0.0125 V (B) 0.0250 V (C) the lead electrode becomes coated
(C) 0.0178 V (D) 0.0356 V with lead sulphate
(D) the amount of sulphuric acid decrease
34. When current passed through electrolye
cation move towards cathode and anion 41. Which is not correct method for prevention
move towads anode. If the cathode is
pulled out of the solution of iron from Rusting -
(A) the positive and negative ions will (A) Galvanisation
move towards anode
(B) the positive ions will start moving (B) Connecting to sacrificial electrode of Mg
towards the anode while negative ions will (C) Making medium alkaline
stop moving (D) Making medium acidic
(C) the negative ions will continue to move
towards anode while positive ions will stop 42. Which of the following curve represents
moving the variation of M with C for AgNO3 ?
(D) the positive and negative ions will start
moving randomly
(A) (B)
35. In an electrolytic cell of Ag | AgNO3 | Ag,
when current is passed, the concentration C C
of AgNO3
(A) Increases (B) Decreases
(C) (D)
(C) Remains same (D) None of these
C C
(SECTION-B)
36. Three faradays of electricity was passed 43. Molar conductivitys of BaCl2, H2SO4 and
through an aqueous solution of iron (II) HCl at infinite dilutions are x1, x2 and x3,
bromide. The mass of iron metal (at. mass respectively. Equivalent conductivity of
56) deposited at the cathode is - BaSO4 at infinite dilution will be :
(A) 56 g (B) 84 g [x x 2 x 3 ] [x x 2 x 3 ]
(A) 1 (B) 1
(C) 112 g (D) 168 g 2 2
(C) 2 (x1 + x2 – 2x3) (D) [x1 x 2 2x 3 ]
37. A current of 9.65 ampere is passed 2
through the aqueous solution NaCl using
suitable electrodes for 1000 s. The amount
44. Molar conductivity of 0.1 M acetic acid is 7
of NaOH formed during electrolysis is
(A) 2.0 g (B) 4.0 g ohm 1 cm2 mol 1. If the molar cond. of
(C) 6.0 g (D) 8.0 g acetic acid at infinite dilution is 380.8 ohm 1
2 1
cm mol , the value of dissociation
38. If 0.224 L of H2 gas is formed at the constant will be :
5 3
cathode, the volume of O2 gas formed at (A) 226 10 mol dm
the anode under identical conditions, is (B) 1.66 10 3 mol dm 1
(A) 0.224 L (B) 0.448 L (C) 1.66 10 2 mol dm 3
(C) 0.112 L (D) 1.12 L (D) 3.442 10 5 mol dm 3
PG #3
45. Kohlrausch's law states that at : 48. Assertion : The resistivity for a substance is
(A) Finite dilution, each ion makes definite its resistance when its is one meter long and
contribution to equivalent conductivity of
its area of cross section is one square
an electrolyte, whatever be the nature of
the other ion of the electrolyte. meter.
(B) Infinite dilution, each ion makes definite Reason : The SI uints of resistivity are ohm
contribution to equivalent conductivity of an metre ( m) and ohm centimeter ( cm) .
electrolyte depending on the nature of the
(A) If both assertion and reason are true
other ion of the electrolyte.
and the reason is the correct explanation
(C) Infinite dilution, each ion makes
of the assertion.
definite contribution to conductance of an
(B) If both assertion and reason are true
electrolyte, wheatever be the nature of the
but reason is not the correct explanation of
other ion of the electrolyte.
the assertion.
(D) Infinite dilution, each ion makes definite
(C) If assertion is true but reason is false.
contribution to equivalent conductivity of an
(D) If the assertion and reason both are
electrolyte, whatever be the nature of the
false.
other ion of the electrolyte.
49. Assertion : Zn metal is formed when a Cu
46. Which of the following expressions
plate in dipped in ZnSO4 solution.
correctly represents the equivalent
conductivity at infinite dilution of Al2(SO4)3. Reason : Cu being placed above Zn in
Given that Al3+ and SO2 are the electrochemical series.
4
(A) If both assertion and reason are true
equivalent conductivitys at infinite dilution
and the reason is the correct explanation
of the respective ions?
of the assertion.
(A) 2 Al3+ 2 +3
SO4 (B) If both assertion and reason are true
but reason is not the correct explanation of
(B) Al3+ + SO2
4
the assertion.
(C) ( Al3+ + 3 SO2 ) × 6 (C) If assertion is true but reason is false.
4
(D) If the assertion and reason both are
1 1
(D) Al3+ + 2 false.
3 2 SO4
50. Assertion : Salts like KCl, KNO3 i.e., inert
47. Consider the following relations for emf of
an electrochemical cell : electrolytes are used in salt bridge.
(i) EMF of cell = (Oxidation potential of Reason : An inert electrolyte can easily be
anode) – (Reduction potential of cathode) filled in the U-tube.
(ii) EMF of cell = (Oxidation potential of
(A) If both assertion and reason are true
anode) + (Reduction potential of cathode)
and the reason is the correct explanation
(iii) EMF of cell = (Reduction potential of
of the assertion.
anode) + (Reduction potential of cathode)
(B) If both assertion and reason are true
(iv) EMF of cell = (Oxidation potential of
but reason is not the correct explanation of
anode) – (Oxidation potential of cathode)
the assertion.
Which of the above relations are correct
(C) If assertion is true but reason is false.
(A) (iii) and (i) (B) (i) and (ii)
(D) If the assertion and reason both are
(C) (iii) and (iv) (D) (ii) and (iv)
false.
PG #4
