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Assignment 1 Complete Unitary Solved

The document contains a series of chemistry assignment problems that utilize the unitary method to solve for various chemical quantities, including molar masses, limiting reagents, and concentrations. It covers calculations involving reactions, neutralization, and molarity, as well as the mole concept and significant figures. Each problem is presented with its respective calculations and results.

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Deepa Bhardwaj
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21 views3 pages

Assignment 1 Complete Unitary Solved

The document contains a series of chemistry assignment problems that utilize the unitary method to solve for various chemical quantities, including molar masses, limiting reagents, and concentrations. It covers calculations involving reactions, neutralization, and molarity, as well as the mole concept and significant figures. Each problem is presented with its respective calculations and results.

Uploaded by

Deepa Bhardwaj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Assignment ?

1 (Complete Answers using Unitary Method)

1. C2H4 + O2 ? CO2

Molar mass: C2H4 = 28, O2 = 32, CO2 = 44

C2H4 = 4.95g ? 4.95/28 mol = 0.1768 mol

O2 = 3.25g ? 3.25/32 mol = 0.1016 mol

From equation, 1 mol C2H4 needs 3 mol O2

? 0.1768 mol C2H4 needs 0.5304 mol O2

Only 0.1016 mol O2 available ? Limiting reagent = O2

3 mol O2 ? 2 mol CO2

? 0.1016 mol O2 ? (2/3)×0.1016 = 0.0677 mol CO2

? CO2 = 0.0677×44 = 2.98 g

2. 1 L juice = 3 g HCl ? 2.5 L = 3×2.5 = 7.5 g HCl

Moles HCl = 7.5 / 36.5 = 0.205 mol

1 mol Al(OH)3 neutralizes 3 mol HCl

? 0.205 mol HCl needs 0.0683 mol Al(OH)3

? mass = 0.0683×78 = 5.33 g

One tablet = 0.4 g ? tablets = 5.33 / 0.4 = 14

3. Mass of 1L acid = 1.83×1000 = 1830 g

91% acid ? 1830×0.91 = 1665.3 g

Moles = 1665.3 / 98 = 17 M

To make 3.5L of 0.5M ? M1V1 = M2V2

? V1 = (0.5×3.5)/17 = 0.103 L = 103 mL


4. ppm = (mass of solute / mass of solution) × 10^6

= (6×10?³ / 1050) × 10? = 5.71 ppm

5. MgSO4·7H2O = 246 g/mol ? moles = 132 / 246 = 0.537 mol

Na2CO3 = 106 g/mol ? 0.537 mol × 106 = 56.92 g

6. K4[Fe(CN)6] has 6 C atoms ? 0.5 mol × 6 = 3 mol C

? mass = 3×12 = 36 g

7. H2O = 14.4 g ? moles = 14.4 / 18 = 0.8 mol

From equation: 4 H2O ? 3 Fe ? 0.8 H2O ? (3/4)×0.8 = 0.6 mol Fe

? mass = 0.6×56 = 33.6 g

8. H2 = 0.4 g = 0.2 mol ? Cl2 needed = 0.2 mol

? mass = 0.2×71 = 14.2 g

? HCl formed = 0.4 mol ? 0.4×36.5 = 14.6 g

9. C = 4 g = 0.333 mol, S = 8 g = 0.25 mol

1 C + 2 S ? CS2, need 0.666 mol S, only 0.25 available ? S limiting

? 0.25 mol S = 0.125 mol CS2 ? mass = 0.125×76 = 9.5 g

10. Assertion & Reason Answers:

(i) (c) (ii) (a) (iii) (c) (iv) (a) (v) (e)

11. Mole Concept:

(a) 5.8×44 = 255.2 g

(b) 8/32 = 0.25 mol


(c) 8.5 ÷ (11.2 / 22.4) = 17 g/mol

(d) 1 mol P4 = 6.022×10^23 molecules ? 2.41×10^24 atoms

(e) 58.5 g × Rs. 0.01/g = Rs. 0.585 per mole

12. Significant Figures:

(i) 4, (ii) 4, (iii) 1, (iv) 2

13. CuSO4 = 160, Cu = 63.5 ? 110/160 × 63.5 = 43.7 g

14. Molality preferred as it doesn?t change with temperature.

15. AgNO3 = 8.45 g ? 0.0497 mol, NaCl = 2.9 g ? 0.0496 mol

? AgCl = 0.0496 mol × 143.5 = 7.11 g

16. Hydrated salt loses 51.2% = MgSO4·7H2O

17. CH3OH mole fraction = 0.02 ? molality ? 1.13 mol/kg

18. P4 = 0.0465 mol, O2 = 0.1803 mol ? limiting

? P4O10 = 0.036 mol ? 10.22 g, excess P4 = 1.31 g

19. CaCO3 used = 1.45 g ? 0.0145 mol

? HCl = 0.029 mol ? M = 0.58 M ? 21.17 g/L

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