rs Chemical kinetics (Notes jor date a Bloomasa) yQepine Rate of ax” Rate ofa xM tevdetned as tre cha ean core: o> He Species involved sper unit hme Wee wether. Xx” Rob ob ax. ~ sshange in cont: of swe time o “siete de Sn n time phase xn) a) Waite the Loli pan ential cob eyr je the 4oll A Unit = reoll Cis atm! (yor gas (ij) A 28 pate = —d[A] = +. 3Le arti‘ et‘ iy eA + y® —9 gor md Rate = —1i da] = alg =+L4Le] : x “dE GY de Lae = +d {fo vw “de 3) Deliina Gz4 at & ~pastionlan ingtant ake Nye called jnstantaneous Xn, qh avamape. mate TRe chang upd ei a iver te i 2 IM cone of suadanb on Wotenvol of Hme in a chum Avendze nab - 4) Bibb Rab + Rat const ( su}. boo 5) Dey Rab. law: Rate Sos ss an expredaron that solates the sah of the x” with tre wenc oO} swortan® TA + GB —> Po Acc. to ste Jaw , Rok = R [a] = Behe Whose ka > suk const the W wrt m as oxdan Of i n aw WoW ony n &B S Sverald ordenCEES Fae tose tne a aha HOEY ipududk Hue pt bela tro Ace do Rats Law, Rak of tHe Xr & ~Har Udredtly properKord do tre pdt 9h te Lone of He swasian® with @Gth Cenc: tesun siaiged to Some egucl oumm whith may oT roay nok be pre Btoi chlomeltic Codf. of Hu xn 6) Gepins siete congtabl Rate eorah is pa one fa oh tha xm whan crooctante U ening. the were of He 4) Oepine xr oc o F a Ble jeame Ob the sedan ~pownre oe ies expoudionof aA+ Le _» Pdt, Rak= p fa)™ Ca]? ordi = Mth. oxen can be Udletanrnined g Beh mobedanity, capiall. MoLrwbani is dap. a the total: no. oF suostants involved in an elementary Xh. Tt ts alsa GQ whole ho. £4 A+B —>Pd& Molecahosi by = 2.a¢ Limoleulan. q) el,- elementony kh An -2lere ntan XY dg va sing Btep Xx” in Uobith he steocdants cainectly ; irae Step, withow an we ~palts ree OG P tes : tT — 3 2Hr & zich + 7 Ho We ta intenmudiale | aher is 2lementony Step te axe l h Eau + every aingh Btep ina ¥ called stlementosy x0 Neth W H,0 + wt i ey eg: H,0, + = —» Ho ton Hoon + of 7. Md: 217 — 5 ae On Qh, Or ean ones * Thost. OSte 2 alomentosty Akepo-Fz. D) Dif bet olen d- prolecul amity CTR boty Rate iW) Benve an exp hee T eds KY. A —y Pdte CT etd KU Rok = — d [A] C lps ential sot eg) dt tee = ALA ( ow te sok 1a LHS osu agp Bo quel RHS SoA] — LA A —dca| = kt [al Stniagrats both gi oer Facal ra i 0A = Asde fa _ (Lp . ( a) = £2], | ae nfa] —Lnlad = & Le) | _ tnfa) + Lnfas] = #E | o kt = tn (as) —Lo[4] Rt = Qn [as] [a] ic - te [asl ma | canventing Ln +o fog: An 2585 tay LAS) cA Unit dime ——— aon decorepes Pen of Nas ie 1 thiowy PasO ois | chlosideC jobst & Rate LSetenrorning Akp. oa Most 0 Hie cham xine iag ocaun In mulfi- | gieps fe Beqpana of steps, one will Se i gloe- This £lowerk Akh ‘U~walled ala miniog Atep- on ee H2%2 + —» Ho + ote (Ablow) Hy 2 +9 —» H,o + o,+ A 2H,0, > 24,9 +02 Thess, Os 2 aleme ntosy Abeps- \At_2tep ‘@ Blow: +} u called RDS. ly sopical - og a T Stolen x” T eolen Rate eg = gel A= Wn LAs t cA Rt = Ln Las) cA Ae = Lo [acl-Ao[4) Anfa] = bn [A2) akt Tea | the Jone at SeerPlot & GFoPh of] 3] te fabs {iat Sas sunt A —— : - Sut = erken yn 38 a Suodlion tak ig . ob Aighan @olan, bur Oppeans to fellows pour euler Kinetica Leeowme thy enc of Hrs Suortank Ca spnuent in Longe excdhs. eg: ttyl neat 4+ Ho — > elie odds eMryl wobchel Rat = [ester] [us] Tous. Solan =2- TL cone of woatn ( taken in Horse exes, Han Ra = KR Leste ihe B= AES) Paewole erin = | QA ~ wok —s¢ (18) Oeyins 0 orobn xh wive 296 Th the owl of the Xr a Inde pendent Of the wene: oF ths swacenG , than it & calkho Zero Orden KP. > Mites oy ond Eg:=, Is 1 oanie the eqn Zero Ovdun x” A —> Padé. Ae do crab Jaw pot = ACAl® == 6 po = - ALA] A : zt ( difpnentiol sot eqn) 6 Lys ose. egal. go equate tse BS. pla” = - 4a] frre, dt k= ~ otal cs dt bat = —d[A] ATnteg2at bot ides. papbical Repprss enti Sst = sae A= Caf) a ke = “oe ee [a = [ad Rr at — ca LAI = pe =~ +0) foie bm Br et mX we = [ef - Peel dt19) E; Bir ieae Ee ome des; = jHat de To? ahd ay) chgcOCHs + peut cH BOC T 4 HT Nod —— 2 > = N+ Lo $02 q) ep! i ; 1q) dayne hal, Sipe ypeniad 4- dlenive expres TK | an On ag the hime. Fale of @ suachon 4g opined Se Jor th, wane of He seacank ne Half, of iB initial valor Hod DLipe peusd yr a iden Xx”! weet & = 2308 Seg [ad] t ‘Tal at tetp, I = [as] /2 A= 2303 log Las) ty2 ° CAal/? 2303 log LAS** tj [As] = 2303 Ang 2 R 3010 iy b> a} T orden xn Ww + oy initial cone [Ab 9 6982 | 40 b> independ?”| << H ; ee Zeno Orden x” Fov Zero ordi x", A = [Al -C4 t ac t= #2, [al = [Ado A = [Ac] - [43] bh = faa-(a] _ oeLAr]-[4] _ [As] 7 “ar eo 2k Ao ty 42 wos Hy We “er jae nih endun X= wore OO ha Ee nab, Lhe ob vi ees =f fi, = es |= Go REA pet 2 0 entional to the inital f pp Canc:| ee i ) Considen H 4 - aye re oxid of hittic Oalds to erm wo 2 go J2NO + 02 —> 2N02 | expruts the mok : a) Ob the XM in in the COHE OL NO, OF d'vo terme of chong’ 5 a Seeley instant, Jooren [oz] & Ving at o2 ma LES!) ab t : t whak sob “a ay that instant ? een a) Rete = Ld Le) — -dfog = «1 d[hoal dt “dE 2 “ap py —dLo2) = o-2 mole! dt +d([Noi] =? ot Bole: WekT Rab = dino] — d [oz] xp dled ae = ar Pdr aot Ca RE —dforl = +1 dLve) dr 2 ak o2 = 41 dino) 2 dt acl! AO dno) = 2022 OF yoo! Lit & ——— oe dt | Evaluate Yourselh? Pq 2It : ate exp bom te ENTARY ne fou x M4 assuming" )SAt+ 5B.—> Acd 3 por = READ [0.9% Xa Yo —> 2Xy W Tas pte = RIX.) "Ty] Eval: Yourselh 1 : Poa soe 9) Consthe decompetition Oh N205 to fem NO, + 03. i a ~posttioutan instant, [w,05 daappeau) at a WG oh 25 C1 rol/dm3/2. Ar what sgtes ara NO,+0, What & the mate of Hu yn? N.05 —_y NO, + Oy 2N205 —> 4N0, + 02 Balana : —> given? —d[N, 03] = 25 x15 Pool [de®/4 dt +d[no] =7 +dfox] = a nore Rok =? Acc: to Rate law, Rate = —LdLNaos] = +1dfvodl - afoi) 2 Ge 4 dt r Pde} VY WAH A ; given qpodnpling 0x), mate 7 by a. fachr o) 9. ae onginel Rab low expression ‘a Rak = RLXI™ LY)" ——. @ 70n qpradupling Dd, nab bewrmu g hime. 7B Rok =k [aa Ly)” ——. © Lon gpa. dousplin both pa¢Ly, wtats bewmer Ibhms Bo |b Rab = 2 Ca” fay” een) ; e dilcik Weel. Aon]: a Rob = kDO"D" @ 8 Rab = & [wa Ly" —— 6 iy Rate = Rk CH" Cad)” ® m =? n=? mth=? Qi> 8 = pu 8 geet ee as 2 3]x. 1. gpa 244 ‘ Pe? pra eb cay! ee ia Rak cay Rate (8) ari OW, inod Bo New pote = 87 eeTTT mere oe aEos A + B doubled. co =k cay [3] cy ?/> re! = # [24* (ae) [4 = Asfay*ope] (* = oR ay cepa” fear = a roy Gi) conc: 4 [A] & Aalved > pote = ALA CSL] por! = & [aps] Co] LI = & LAC Ra 3) 4+ fore, = ale a7. (iv) cone: 9} [al we suducet fo Is + conc of we wqpracdouspled- is Rate = ara Telly] ys = ALS] 2f, 8] ae Ica) as _ aca req Cd! c eh) 2? ey *reqcu (8) ES,= \ os wate © i bs oh Jovreation o} a dimen in @ Second ovdn X® WTS XICF mol TS ak 0-05 mold” yonomen COMC™ Cal: Hie nate constant. aa Gag) 22 monomsns comslhe togethsn 70 Jorm @ Be go =F SKID taolL S [reonormsa] = 0°05 wol prdasn = A a? | 2 | pce: to neh lew, Rak = & [monomer] | 3 or 45 115 = C005) | Beas 45x10" | oO SK 00D a 2 45 107 2 en — om Uy 25 x16 perk A = 3 sec! OE 12) For a x" xtyrg— > produds , ine sae Sous J& iven by nate =k EI Pry i= What & the overall orden oh the xB what & Orden Of tre work Z aon: ovdin writ Z = 6 ( bew, Z core & not tose in Hu en pressi on ),"5) dhe. . L: ele sompesisan of L297 at pin ak St ee ae 7 orden xh A ale ook, the cprust usu el er ee ~orn 070 tO F : OO atin. Gall: he Aah me contt in St. a T= 500K enn - in ovobs =! oes Initial pressum = 0708 aie press atten hs = £ = 0:04 atm. ~mate worst Aoln}: aR J aad dog Fo Pp = 2503 Jog 0-08 6d OOF = 2303 Jeg G7 = 303 %O5O!0 bo x Go * log 2303= 0.562" lop o-go1oe EAE 23) The sul cpprsk of 2 =.ghb9 ovdin x? & oa a0 BE cal] Jogeo 7192 its £ ge? Pe B06) fee obs? 5 oe pre SF 2 aS PS uKe J p15 5x10 5 3 = Ob432NIT = ong gases" rs 6h= ti 2 6952419 Jog 6932=35- 9408 Vo Dog 154 = 0° 1875 3 76555 = ASX x10" 3 $95" as x10” Ls 4-500 X10" = 45s —_———— 2) ghe ©']2 4 Aomogenous aaeous xP a S0,h,—> Se tde Whidh obeys — orosn Riruka Ww So mine How long coin iF take 1S the conc Of SO,d, io be suduud to Ii of He inihol volur E, = Bg mint b=? [Ae] =!0° [al =) k= 0693? = 06932 = 9-303 X O'Bo!° = 0673! 0618 oo See £4, 8 8 Rk = 2:.303 109 [acl pa 2-303 log LAs R rAd = 2363 * 8 Jog 100 = gx2a_ lb ae aon SS D30pk oslo 1 63010 o:3010= 1b ee = Ibx10% golontet Zold = 5-3ib x10! Sng ib = 204! = 58-16 reine ag 10° =e SS og 204! pox] lng ote Ag aeee 1-72-54 he 06-6952 AL= 3 53203, = 9-08 665 Pee B-ZIbXIO! b 2° 303 log [#3 z£ ped b= 1 50866 4g 81 “arse 1-123 8 = 21303 x2 D ebb AL 5294803 = 4 bob = 52% p08 6& 4 bo = abot ee a 6087 8re The Hi eco ee Aly change Fag wretten Of & ani tars a ovdsn sill be ee ein op aoe ji Life aj ten 18> 260 4A WY oa = ae is ieee eee < [Al=? fool: © w= obis> tye ! 1155-33 = 0 S — 5 oo = Sasa A = Ng 533 KIO te 10 Ast! ty R= 259% log [As a “cad 2303 Log Fico eae a 180 pal uge28 6a180 . leg 0° 1% (Al 21308 4028 X16 = gel A Sig A= 2-2 deat | eat eres = 3 0626 | pod tog 15° Bi000° = 2 553 1% iB aw (ove Jeg 2 elaet? Jog 230 0 3624AGO y Pee xn Le 207. corep lore jn ee nn at sa the Value of, the ch 6 natabk, Tn ushat time wll uy e@ 8or Complete 2 a) A= [acl- [Al 3° t = [po- 0 20 {oo7so = a ami a | Pt min Bom pmo! 2 in! i) A= [as -[A +t p= loo — 20 le go wins | t gw) AT orden x 407 complete th Bore ns Gal the value ob the state constant: Tr What Time ewoin He xe be go7- comple pa 2303 19 [Ae cal 23038 = 0-3623 = 2393 40g 108 1e9 pemsole TA eb 5o 6p pbk? 7 op 64 = 2305 Jog 157 ' 66 log 59 = tr 6990 5D BX Z005F be 2307 x 02201 ALS pole 50 ope -2 yin! pol 4 xe = job x10 ean- & = 21303 log [Ae] k Al og 9503.2 08623 sc 2303 5 Do, 2 2218009 — log 8 on Fol xe> d a Seg orbite =D 9445S . 2 22068 = ses x O6990 fag oi 3 0088 ' —_——— 2008 = SRK rO” ming Exp Collision The oy 159 xId Zapered by Marx Tmauts + Wiliam CLUS Painuple + Kinetic theowy of gore: d& cham KY Cue on os utt OF collision of He : wwocking moleuwtes- —- HEORY ? > consider th yOu Aa +B. > 298 Rocthon Rak «% collision state Callrston ROK &% [ar] [62] =a Z [Az] [e.] Hrs Z& O consk2 not all collisions ome e}peckve. ae jrement of ebfectve colistO’” collisions! Gj ne _collidin moleults must posses? oinimurs Shungy called ackyalion energy oS Eo) @ Faockon oh, effack ie a collision with oy yicent = + -e [Rt = Eo. 2 Props orientation of He saan F yoo ye les Frackhon 3} eyyedsve a) Comtentation collision uit pops youre ovientaKbon f x41 collision mate ee z [alles Beto mate te, Rae spe nes in Fate of te x? Go ropa ng a 4B fal pedepee pga ps ee (Kage ®-Q— 8 ee on = = ©8608 > ND ceBpihenius Eqn. ov Epject 5 7 oP ye sas yersrall cake of @ KX” vases wlth T, a do Axnhenius, Rak of a x? Wasure temp in Auch a way that Bo eT BART Bon wer ERT po 2 = mab const A= peyery jacten ( sutated fe He n ob coll’siong q¢ owe omienfabon ob suadank ) ackvakon erage C minimure Ea = evengy susgd hot ths x” be ocwsn) R= uni versed 94 consk + oF _adgolute trewp : 0 Ralvin Ag terP +e, Rave : jeg VERS Ty Ea UB nigh, mote & glow + VIS a. gaapnicol Rapsusent alfon’ = Ee —Ea/RT Wek T R= fe beet Din & = sna Min & = Jna -&o Ine RT Lnwk = Ann - Ga (vane =D RvFe > SN “Byt) R £)) y és Of Hee nw / > yy of @ Ate ly # jo Qa Ww sth ws Eafp _—_ yr Ponhenius Eqn [or hemp vaniations wet B = ae &4/Rr Bn R= Ina —Ee RT AT, 2 Dn, = InA- Ea © RTM Abts = inks = £o8- Ga —® RT @-© D> Dn Bs In, = —Ea —/-£a say RT Cs) ieee ane T. RT Ln Re = Ba(—b+a) Thi R 13: : E ee 2.303 Leg ae = Es( + 4) Log Rr 2 me (BD Y