Sri Chaitanya IIT Academy., India. 03-04-25_2025_Jee-Main_Shift-I_Q.

Paper, Key & Sol’s

Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
2025_Jee-Main_03-Apr-2025_Shift-1
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY
ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
sin x cos x sin x  cos x  1
d2y
01. If y  x   27 28 27 , x   , then  y is equal to
dx 2
1 1 1
1) -1 2) 27 3) 28 4) 1
Key: 1
Sol: Using C2  C2  C1, C3  C3  C1
sin x cos x  sin x cos x  1
y  x   27 1 0    cos x  1
1 0 0
dy d2y
 sin x,  cos x, Given expression  cos x  cos x  1  1
dx 2
dx
02. Let A be a matrix of order 3  3 and A  5 . If 2 adj  3 A adj  2 A   2 .3 .5 ,
 ,  ,   N ; then      is equal to
1) 28 2) 27 3) 26 4) 25
Key: 2
n 1
Sol: Use Adj B  B , and KA  K n A
2
Given question  23. 3 A.adj  2 A   23.36. A. Adj  2 A   23.36.52 2 A
2
  2 2

4 4
 23.36.52. 2 A  23.36.52.212. A  215.36.56        27
03. A line passes through the origin and makes equal angle with the positive coordinate axes.
It intersects the lines L1 : 2 x  y  6  0 and L2 : 4 x  2 y  p  0 , p  0 at the points A and
9
B respectively. If AB  and the foot of the perpendicular from the point A on the line
2
AM
L2 is M, then is equal to
BM
1) 5 2) 3 3) 2 4) 4
Key: 2
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 Sri Chaitanya IIT Academy., India. 03-04-25_2025_Jee-Main_Shift-I_Q.Paper, Key & Sol’s
2  1 AM
Sol: tan   3
1 2 BM

M B


z 2  3i
04. Let z  C be such that  2  3i . Then the sum of all possible values of
z 2i
z 2 is
1) 19  2i 2) 19  2i 3) 19  2i 4) 19  2i
Key: 2
Sol: z 2  3i  z  2  3i    2  3i  i  2   z  2  3i   7  4i
 z 2  z  2  3i   7  7i  0 has roots  , 
So     2  3i,     7 1  i 
2
So sum of all possible values of z 2   2   2       2
2
  2  3i   14 1  i 
  19  2i
x x
05. Let g be a differentiable function such that  g  t  dt x   t g  t  dt , x  0 , and let
0 0
dy  
y  y  x  satisfy the differential equation  y tan x  2  x  1 sec x g  x  , x   0,  . If
dx  2
 
y  0   0 , then y   is equal to
3
4 2 4 2
1) 2) 3) 4)
3 3 3 3 3 3
Key: 1
x x
1 dy
Sol:  g  t  dt  x  t.g  x  dt , differentiate both sides  g  x 
1  x dx
 y tan x  2sec x,
0 0
I.F  cos x , solutions is y cos x  2 x  c
   4
y  0   0  C  0  y  2 x sec x  y   
3 3
06. The radius of the smallest circle which touches the parabolas y  x 2  2 and
x  y 2  2 is

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7 2 7 2 7 2 7 2
1) 2) 3) 4)
2 16 8 4
Key: 3
Sol: x 2  y  2 & y 2  x  2 are Symmetrical and about the line y  x
 t2 t 
Let P  2  ,  be any point on y 2  x  2
 4 2 

So tangent at P, is parallel to the line y  x
1 9 1
  1  t  1, P  , 
t  4 2
9 1

So, r  perpendicular distance from P to the line x  y  0  4 2 7 2 7 2
  
12   1
2 4 2 2 8

x2 y 2
07. A line passing through the point P  
5, 5 intersects the ellipse 
36 25
 1 at A and

 
B such that  PA    PB  is maximum. Then 5 PA2  PB 2 is equal to
1)218 2) 377 3) 290 4) 338
Key: 4
x2 y 2
 
Sol: Let A, B  5  r cos , 5  r sin  lines on the ellipse 
36 25
1

 2
2 cos  sin 
2   2 5 cos 2 5 sin    5 5 
r     r      1  0 is a quadratic
 36 25  
 36 25   36 25 
equation in ' r ' . So ' r ' has two values , r1  PA, r2  PB
So that r1  r2 is maximum

 r1  r2 
 595  is maximum
25cos 2   36sin 2 
 25cos 2   36sin 2  is minimum
 25  11sin 2  is minimum for   00
2
Consider PA2  PB 2  r12  r22   r1  r2   2r1r2 for   0


So 5 PA2  PB 2  338 
08. Let a1, a2 , a3....... be a G.P. of increasing positive numbers. If a3a5  729 and
111
a2  a4  then 24  a1  a2  a3  is equal to
4
1) 128 2) 129 3) 130 4) 131
Key: 2
Sol: ar 2 .ar 4  729  a 2r 6  729  ar 3  27  a4  27

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111 3 1 43
a2   27   a  , r  6, a1  a2  a3   24  a1  a2  a3   129
4 4 8 8
09. Line L1 passes through the point 1, 2,3 and is parallel to z-axis. Line L2 passes through
the point   ,5,6  and is parallel to y-axis. Let for   1, 2 , 2  1 , the shortest
distance between the two lines be 3. Then the
square of the distance of the point  1, 2 , 7  from the line L1 is
1) 40 2) 37 3) 32 4) 25
Key: 4
x 1 y  2 z  3 x y 5 z 6
Sol: L1 :   , L2 :  
0 0 1 0 1 0
 1 3 3
0 0 1
a  c b d  0 1 0
Shortest distance    3
bd i j k
0 0 1
0 1 0
 1    3     2,4
 1  4, 2   2
P 4,2,7

Q1,2,t 3
1,2,3
 0,0,1
  3, 4, t  4   r  0,0,1
 t  4,  Q 1, 2,7 
 PQ 2  9  16  25
x 1 y  2 z  3
10. Let a line passing through the point  4,1,0  intersect the line L1 :   at
2 3 4
the point A  ,  ,   and the line L2 : x  6  y   z  4 at
1 0 1
the point B  a, b, c  . Then    is equal to
a b c
1) 6 2) 16 3) 12 4) 8
Key: 4
Sol:

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A12t,23,3
t 4t ,, 

R 4,1,0

B 6,,4  a,b,c

A, R, B are collinear  AR parallel BR

2t  3 1  3t 3  4t
  
2    1 4  
1
Solving we get    3t  t   1,   3  or  t  ,  1
3
Take   3, t   1
A  ,  ,     1, 1, 1 , B  a, b, c    9,3,1
1 0 1
So given determinant 1 1 1  1 2   1 6   8
9 3 1
11. Let A  3, 2, 1,0,1,2,3 . Let R be a relation on A defined by xRy if and only if
0  x 2  2 y  4 . Let l be the number of elements in R and m be the minimum
number of elements required to be added in R to make it a reflexive relation.
Then l  m is equal to
1) 20 2) 17 3) 18 4) 19
Key: 3
Sol: If x  0  y  0,1,2  3
x  1  y  0,1  4
x  2  y  2, 1,0  6
x  3  y  3,  2
15
So n  R   15  l
minimum number of elements added
to R so that R is reflexive is ‘3’
 1, 1 2,2,  3,3  m  3  l  m  18
  3 
12. The number of solution of the equation 2 x  3tan x   , x   2 ,2     ,   is:
 2 2 
1) 6 2) 3 3) 4 4) 5
Key: 4

  2x  x
Sol: tan x   
3 3  
3
2

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 Sri Chaitanya IIT Academy., India. 03-04-25_2025_Jee-Main_Shift-I_Q.Paper, Key & Sol’s
 x
Draw the graphs of y  tan x, and y   , (straight line) we get ‘5’ points of
3  
3
2
intersection.
9 9
 r 3 9 3 2
13. If     Cr       ,  ,    , then     is equal to
r 2
r 1 2 
1) 9 2) 27 3) 81 4) 18
Key: 3
9 9
1 1 1  9 1
Sol: Given expression   r. Cr . . 9
 3  9Cr .  diff 1  x  wrto ' x ' and put x  
2 2 r 1 r 2
r 1 r 1 2 
9  1    1   310 310
8 9 9
310 3
   1     3   1    1   3  3  6    3    6,   3
2  2    2   29 29 28 2
   

2
So      81


1  ax 1 x , x  0

14. Let f  x   1  b ,x  0 be continuous at x  0 . Then eabc is equal to:
 12
  x  4  2
 , x0
13
  x  c   2
1) 48 2) 64 3) 72 4) 36
Key: 1

1  1
f  0   b  1, R.H .L  Lt
 x  4 2  2
 0 
 3
Sol:
 1 1 c 20c 8
x 0  x  c  3  2  
 c3  2 
1
 x 2 1 1
1    1 
4
Lt   2 4  3  b 1  b  2
1 1 1
x 0  
 x 3
1    1 3 8
 8
 1 1 ax 1 
By LHL  Lt  e x   ea  b  1
x 0 
 
 
so e a .bc   b  1.b.c  3.2.8  48

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2
15. Let  and  be the roots of x  3 x  16  0 , and  and  be the roots of
P  3P24 Q25  Q23
x 2  3 x  1  0 . If Pn   n   n and Qn   n   n , then 25  is
2 P23 Q24
equal to
1) 3 2) 7 3) 5 4) 4
Key: 3
Sol: by Newton’s theorem Pn  2  3 P n1  16 Pn  0  put n  23  P25  3P24  16 P23
Qn  2  3Qn 1  1.Qn  0  Put n  23  Q25  3Q24  Q23

So given expression 
16 P23

 3 Q24   8  3  5
2 P23 Q24

 
8
16. The sum of all rational terms in the expansion of 2  3 is
1) 33845 2) 18817 3) 16923 4) 3763
Key: 2
r
8 8 r
Sol: Tr 1  Cr .2 .3 , for rational r  0,2,4,6,8
2

Sum 8C0 .28 8 C2 .26.3 8 C4 .2432 8 C6 .22.33 8 C8.20.34  16  1171  81  18817 .

 2x  3  1  4  3x 
17. If the domain of the function f  x   loge    sin   is  ,   , then
 5  4x   2x 
 2  4 is equal to
1) 3 2) 7 3) 4 4) 5
Key: 3
3  2 x  5   3  4  3x
Sol:  0  x   ,    ,   .................1 ,  1  1
5  4x  4  2  2 x
4  3x 4  3x
0 1 & 1  0
2 x 2x
6  2x 2  4x
0 & 0
2 x 2 x
x3 2x 1
0& 0
x2 x2
 1
x   3, 2  & x   ,     2,  
 2
 1
So x   3,           2  & x  2
 2
 5
From (1) & (2) x   3,  
 4
5
So    3,      2  4  9  5  4
4

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 Sri Chaitanya IIT Academy., India. 03-04-25_2025_Jee-Main_Shift-I_Q.Paper, Key & Sol’s
18. Let f  x    x3 3  x 2 dx . If 5 f  2    4 , then f 1 is equal to
8 2 4 2 6 2 2 2
1)  2)  3)  4) 
5 5 5 5
Key: 3
5 3
    2 C
5
3 t2 3  x2 2
3  x2
Sol: Let 3  x  t  f  x     3  t  t    dt   t 2  C 
2 1

 2 5 5 1
6 2
 
5 f 2  4  C  0, f 1 
4 2
5
2 2 
5
19. 
Let the domain of the function f  x   log 2 log 4 log 6 3  4 x  x 2 be  a, b  . If 
ba  2 
 x dx  p  q  r , p, q, r  , gcd  p, q, r   1 , where  is the greatest integer
0  
function, then p  q  r is equal to
1) 10 2) 9 3) 11 4) 8
Key: 1
Sol: 
3  4 x  x 2  0  x 2  4 x  3  0  x  2  7,2  7       1 
 
log 4 log 6 3  4 x  x 2   0  log4 1  log6 3  4 x  x2   1  log6 6
 3  4 x  x 2  6  x 2  4 x  3  0   x  1 x  3   0  x  1,3        2 
From (1) & (2) domain of f  x   1,3   a, b   b  a  2
2 2 1 2  2 3  2 2  2
So  x dx   x 2  dx 
 x dx    x dx   x dx
0  0  1   2  3 
 0 1   
2 1  2  
3  2 3 2 3 5 2  3 
p  q  r  10
20. The sum 1  3  11  25  45  71  ....... upto 20 terms, is equal to
1) 8124 2) 6982 3) 7130 4) 7240
Key: 4
Sol: Differences of consecutive terms are in AP
S  1  3  11  25  45  ....  Tn
Let S  1  3  11  25  ..............  Tn
on substrating we get 0  1   2  8  14  20  ......  Tn
 Tn  1  2 1  4  7  10  ... n  1 terms   AP 
 n 1
 1  2   2.1   n  2  3
 2 
 1   n  1 3n  4   3n 2  7 n  5
20 20 20
Sn   Tn  3 n  7 n  51  8610  1470  100  7240
2
1 1 1
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2
(or) let Tn  an  bn  C , use T1  1, T2  3, T3  11 solve we get a  3, b  7, c  5
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases..
    
21. Let a  i  j  k , b  3i  2 j  k , c   j   k and d be a unit vector such that a  d  b  d
   2
and c  d  1. If c is perpendicular to a , then 3 d   c is equal to _____
Key: 5
    
Sol:    
a  d  b  d  d   a  b   2i  j  2k is unit vector   
1
3


 d 

2i  j  2 k 
3
   2
 c  d  1   1    2  3
  3
c  a  0      0      solving   1,    1
2 2 2 
c  2 , so 3 d   c  9 2  d   2 c  6 d  c
2

9265
22. The area of the region bounded by the curve y  max  x , x x  2  , the x-axis and the
lines x   2 and x  4 is equal to ____
Key: 12
Sol: Draw the graph of y  max  x , x x  2  in  2, 4 

Required area
1 4
1
 1

 2.2   2 x  x 2 dx  .2.1  3   x 2  2 x dx
2 2
 
0 3
2 16
2  4   12
3 3
23. 
Let the product of the focal distance of the point P 4,2 3 on the hyperbola 
x2 y2
H:  1 be 32. Let the length of the conjugate axis of H be p and the length of
a 2 b2
its latus rectum be q . Then p 2  q 2 is equal to _____
Key: 120

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Sol: Product of focal distances   ex1  a  ex1  a   e2 x12  a 2  32
 b2  b2
 16e 2  a 2  32  16 1    a 2  32  16  a 2  16       1
 2
a  a 2


 
P 4,2 3 Lies on H 
16 12
a 2

b 2
 1        2

Solving (1) & (2) we get a  8, b 2  12

2

2b2 24
p  2b  2  12, q   6 2
a 2 2
p 2  q 2  48  72  120
24. All five letter words are made using all the letters A, B, C, D, E and arranged as in an
English dictionary with serial numbers. Let the word at serial number n be denoted by
Wn . Let the probability P Wn  of choosing the word Wn satisfy
2
P Wn   2 P Wn 1  , n  1 . If P  CDBEA   , ,    , then    is equal to: ____
2  1
Key: 183
Sol: Total words formed with letters A, B, C, D, E are 120
“CDBEA” occurs at 64th place.
Let P W1   k , P W2   2 k , P  w3   22 k ,.....

 
So P W1   P W2   ...  P W120   1  k 1  2  22  ...  2119  1  k 
1
2120  1
263
So P W64   263 K       63  120  183
2120  1
25. If the number of seven-digit numbers, such that the sum of their digits is even, is
m  n  10n ; m, n  1,2,3,......,9 , then m  n is equal to ____
Key: 14
Sol: Total 7 digit numbers  9 106
9  106
Sum of these 7 digit numbers is even   9  5  105  m  9, n  5
2
So m  n  14

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PHYSICS
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY
ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. A particle is released from height S above the surface of the earth. At certain height its
kinetic energy is three times its potential energy. The height from the surface of the earth
and the speed of the particle at that instant are respectively.
S 3 gS S 3gS S 3 gS S 3 gS
1) , 2) , 3) , 4) ,
2 2 4 2 4 2 2 2
Key: 3
Sol: KE  P.E  mgS
3P.E  P.E  mgS
4 mg S1  mg s
S
S1 
4
S
K .E  3mg
4
1 3
m v 2  m gs
2 4
3 gs
v
2
27. Match the List – I with List – II
LIST – I LIST - II
A) Gravitational constant I)  LT 2 
 
B) Gravitational potential energy II)  L2T 2 
 
C) Gravitational potential III)  ML2T 2 
 
D) Acceleration due to gravity IV)  M 1L3T 2 
 
Choose the correct answer from the options given below:
1) A  III , B  II , C  I , D  IV 2) A  I , B  III , C  IV , D  II
3) A  IV , B  III , C  II , D  I 4) A  II , B  IV , C  III , D  I
Key: 3
Sol: A) Gravitational contact
FR 2
G
M1M 2
 M 1L3T 2
B) Gravitational potential energy
GM1M 2
U
R

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1 2 2
M L T
C) Gravitational potential
GM
 M 0 L2T 2
R
D) Acceleration due to gravity
M 0 L1T 2
A  IV , B  III , C  II , D  I
28. The work function of a metal is 3eV . The color of the visible light that is required to cause
emission of photoelectrons is
1) Yellow 2) Blue 3) Green 4) Red
Key: 2
hc
Sol: E 

1240

  nm 
1240

E
 413nm
Among all colours blue colour has the above wavelength
29. During the melting of a slab of ice at 273 K at atmospheric pressure:
1) Positive work is done by the ice-water system on the atmosphere
2) Positive work is done on the ice-water system by the atmosphere
3) Internal energy of the ice-water system decreases.
4) Internal energy of ice-water system remains unchanged
Key: 2
Sol: When a slab of ice at 273K (i,e 00 C ) melts in to water, volume of water formed is less
compared to volume of ice , i.e volume decreases hence work done by ice water system is
negative. So work done on the ice-water system is positive by atmosphere
30.

A piston of mass M is hung from a massless spring whose restoring force law goes as
F   kx 3 , where k is the spring constant of appropriate dimension. The piston separates
the vertical chamber into two parts, where the bottom part is filled with ' n ' moles of an
ideal gas. An external work is done on the gas isothermally (at a constant temperature T)
with the help of a heating filament (with negligible volume) mounted in lower part of the
chamber, so that the piston goes up from a height L0 to L1 , the total energy delivered by
the filament is: (Assume spring to be in its natural length before heating)

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  MgL12
1) nRT ln   
  2
  L20
 L1  L0  
k
4
 L14  L40 
L 
2) nRT ln  1   Mg  L1  L0  
 L0 
k
4
 L14  L40 
L 
3) 3 nRT ln  1   2Mg  L1  L0  
 L0  3
 L1  L0 
k 3 3

L 
4) nRT ln  1   Mg  L1  L0  
 L0 
3k 4
4
L1  L40  
Key: 2
Sol: At any position of the piston, say at a distance x from the bottom, net force on it is zero

Fext kx3

PA mg
PA  Fext  mg  kx3
 P  Fext  mg  kx3
 External work done by the gas is

wgas   PdV  
 Fext  mg  kx3  Adx
A
L1 L1 L1
3
  Fext dx mg  dx  k  x dx
L0 L0 L0

 Wext  mg  L1  L0  
K 4 4
4
L1  L0  
L 
 nRT ln  1   mg  L1  L0  
 L0 
K 4
4
L1  L40  
According to I law of thermodynamics for the gas
Q  U  Wgas  0  Wgas  Q  Wgas
L 
Q  nRT ln  1   mg  L1  L0  
 L0 
K 4
4
L1  L40  
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31. The radii of curvature for a thin convex lens are 10cm and 15cm respectively. The focal
length of the lens is 12cm . The refractive index of the lens material is
1) 1.4 2) 1.5 3) 1.2 4) 1.8
Key: 2
1  1 1 
Sol:     1   
f  R1 R2 
Convex lens
R1  Ve, R2  Ve
1  1 1 
    1   
f  R1 R2 
1 1 1
    1   
12  10 15 
1  25 
    1  
12  150 
6  6 
1
 
2
1 3
 1 
2 2
  1.5
32. A gas is kept in a container having walls which are thermally non-conducting. Initially the
gas has a volume of 800 cm 3 and temperature 27 0 C . The change in temperature when the
gas is adiabatically compressed to 200 cm 3 is:
(Take   1.5;  is the ratio of specific heats at constant pressure and at constant volume)
1) 327 K 2) 300 K 3) 600 K 4) 522 K
Key: 2
Sol: TV  1  cont
T1V1 1  T2V2 1
 1
T2  V1 
 
T1  V2 
1.51
 800 
 
 200 
1
  4 2
T2
2
T1
T2  2T1
 2  300
 600K
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T  T2  T1
 600  300
 300K
33. A wire of length 25 m and cross-sectional area 5 mm 2 having resistivity of 2  10 6  m is
bent into a complete circle. The resistance between diametrically opposite points will be
1) 12.5  2) 50  3) 100  4) 25 
Key: No key (correct answer 2.5 )
Sol: Resistance
l
R
A
2  106  25

5  106
 10
Diametrically opposite points
5

5
55
R eff 
55
25

10
 2.5
34. Consider a completely full cylindrical water tank of height 1.6m and of cross-sectional
area 0.5m 2 . It has a small hole in its side at a height 90cm from the bottom. Assume the
cross-sectional area of the hole to be negligibly small as compared to that of the water
tank. If a load 50kg is applied at the top surface of the water in the tank then the velocity


of the water coming out at the instant when the hole is opened is: g  10 m s 2 
1) 5 m s 2) 4 m s 3) 3 m s 4) 2 m s
Key: 2
Sol:

Acc to Bernoulli’s principle

P  1  v 2   gh  const at points 1 and 2
2
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mg 1
P0   0   gH  P0  V 2   gh
A 2
mg 1
 V 2   g  H  h 
A 2
50  10 1
  103V 2  103  10 1.6  0.9 
0.5 2
Solving V  4m / s

35. The angle of projection of a particle is measured from the vertical axis as  and the
maximum height reached by the particle is hm . Here hm as function of  can be presented
as

1) 2) 3) 4)
Key: 2
Sol:
u 2 cos 2  u 2 1  cos 2 
hm  
2g 2 g  2 
hm

0 
900
36. The radiation pressure exerted by a 450 W light source on a perfectly reflecting surface
placed at 2m away from it, is
1) 1.5  108 pascal 2) 6  108 pascal
3) 0 4) 3  108 pascal
Key: 2
2I 2P 2  450
Sol: Radiation pressure   
C 4 r 2C 4  22  22  3  108
7
 6  108 pascal

37. A parallel plate capacitor is filled equally (half) with two dielectrics of dielectric constants
1 and  2 , as shown in figures. The distance between the plates is d and area of each
plate is A. If capacitance in first configuration and second configuration are C1and C2
C
respectively, then 1 is:
C2
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41 2  0  1   2  1  22 1 2
1) 2) 3) 4)
2 2 1  2
1   2  2  1   2 
Key: 1
Sol: In case I, two di-electric slabs are inserted such that plates separation is halved, hence
21 2
effective di-electric constant is
1   2
 2    A
 C1   1 2  0
 1   2  d
In case II, two di-electric slabs are inserted such that plates area is halved, hence effective
 
di-electric constant is 1 2
2
   A
 C2   1 2  0
 2  d
C 41 2
 1
C2     2
1 2

38. A person measure mass of 3 different particles as 435.42g, 226.3g and 0.125g.According
the rules for arithmetic operation with significant figures, the addition of the masses of 3
particles will be
1) 661.845 g 2) 661.84 g 3) 661.8 g 4) 662 g
Key: 3
Sol: 435.42  226.3  0.125
`  661.845
In addition and subtraction, the final result should have least number of decimal places as
they are in the given individual values
 661.8
39. Consider following statements for refraction of light through prism, when angle of
deviation is minimum.
A) The refracted ray inside prism becomes parallel to the base
B) Large angle prisms provide smaller angle of minimum deviation
C) Angle of incidence and angle of emergence becomes equal
D) There are always two sets of incidence for which deviation will be same except at
minimum deviation setting.
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E) Angle of refraction becomes double of prism angle.
Choose the correct answer from the options given below:
1) B,C and D only 2) A,B and E only 3) A,C and D only 4) B,D and E only
Key: 3
Sol: When the angle of prism (A) increases the minimum deviation may or may not decrease.
 A  dm 
sin  
And hence B is wrong. According to    2 
 A
sin  
2
40. The electrostatic potential on the surface of uniformly charged spherical shell of radius
R=10cm is 120V. The potential at the centre of shell, at a distance r=5 cm from, centre,
and at a distance r=15cm from the centre of the shell respectively, are
1) 0V ,0V ,80V 2) 120V ,120V ,80V 3) 0V ,120V , 40V 4) 40V , 40V ,80V
Key: 2
Sol: In case of uniformly charged spherical shell, potential at any point inside is constant and
equal to potential on the surface
KQ KQ
On the surface of shell  120 at outside ?
R r
KQ 120  10
  80
r 15
41. Choose the correct logic circuit for the given with table having inputs A and B.

Key: 4
Sol: On verifying the truth tables
42. Two blocks of masses m and M,(M>m), are placed on a friction less table as shown in
figure. A massless spring with spring constant k is attached with the lower block. If the
system is slightly displaced and released, then
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 Sri Chaitanya IIT Academy., India. 03-04-25_2025_Jee-Main_Shift-I_Q.Paper, Key & Sol’s
(   Coefficient of friction between the two blocks)

A. The time period of small oscillation of the two blocks is T  2

m  M 
K
kx
B. The acceleration of the blocks is a  
M m
(x-displacement of the blocks from the mean position)
m x
C. The magnitude of frictional force on the upper block is
M m
  M  m g
D. The maximum amplitude of the upper block, if it does not slip, is
k
E. Maximum frictional force can be   M  m  g
Choose the correct answer from the options given below:
1) C, D, E Only 2) A, B, C Only 3) A, B, D Only 4) B, C, D Only
Key: 3
Sol:
m

kx M

kx
a
M m
Force on upper block is F  ma
kxm

M m
Option C is wrong 
 Maximum frictional force is F   mg
So option E is wrong
43. A force of 49N acts tangentially at the highest point of a sphere (solid) of mass 20kg, kept
on a rough horizontal plane. If the sphere rolls without slipping then the acceleration of the
center of the sphere is

1) 0.25m / s 2 2) 2.5m / s 2 3) 0.35m / s 2 4) 3.5m / s 2

Key: 4
Sol:

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F  49 N

a
R 
f
 The net force acting on the sphere is the applied force F and the friction force
F  f  ma …….(1)
 The torque is due to the applied force and the frictional force.
  FR  fR   I 
FR  fR  I
2 a
FR  fR  mR 2  
5 R
2
F  f  ma......... 2 
5
from 1& 2 a  3.5m / s 2

44. Which of the following curves possibly represent one-dimensional motion of a particle?

1) 2)

3) 4)
Choose the correct answer from the option given below.
1) A,B and C only 2) A,B and D only 3) A and B only 4) A,C and D only
Key: 2
Sol: A, B belong to linear SHM, time is always positive and increases hence C is wrong
In case of body moving in a straight line in forward motion with non- uniform speed.
Distance increases with time, hence D is correct.
45. Match the List-I with List-II

LIST-I LIST-II
A. 1 235 140 94 1 I chemical reaction
0 n  92 U 54 Xe  38 Sr  2 0 n
B. 2 H 2  O2  2 H 2O II fusion with +ve Q value

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C. 2 2 3 1 III. fission
1 H 1 H  2 He  0 n
D. 1 3 2 2 IV fusion with –ve Q value
1 H 1 H 1 H 1 H
Choose the correct answer from the option given below.
1) A  II , B  I , C  III , D  IV 2) A  III , B  I , C  IV , D  II
3) A  III , B  I , C  II , D  IV 4) A  II , B  I , C  IV , D  III
Key: 3
Sol: A  III , B  I , C  II , D  IV

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If
answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
46. Three identical spheres of mass m, are placed at the vertices of an equilateral triangle of
length a, when released, they interact only through gravitational force and collide after a
time T=4 seconds. If the sides of the triangle are increased to length 2a also the masses of
the spheres are made 2m, then will collide after ____ seconds.
Key: 8sec
Sol:
2m
m

a a 2a 2a

a 2m
m m 2m 2a
According to the conservation of energy
Gm2 1 2 Gm2
3  0  3. mV  3 , (x= side length of triangle at any time t)
a 2 x
mV 2 1 1
 Gm 2   
2 x a
1 1
V  2Gm   
x a
dl 1 1
  2Gm   
dt x a

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x
x
l
3
1 dx 1 1 dx
  2Gm      dt
3 dt x a 1 1
6Gm   
 x a
t 0
dx
 dt    1 1
0 6Gm   
a
x a
On the calculation the above integration using method of substitution
Put x  a cos2  , we will get
a3
t
m
3
t2 a  m
  2  1
t1  a1  m2
3
t2  2a  m
   
4  a  2m
t2  8sec
47. A 4.0cm long straight wire carrying a current of 8A is placed perpendicular to a uniform
magnetic field of strength 0.15 T. The magnetic force on the wire is ______ mN.
Key: 48mN
Sol: Given l  4cm  l  4  102 m
i  8 A B  0.15T
Magnetic force on the wire is F  Bil sin 

  900 
F  0.15  8  4  102 sin 900
F  48mN
48. A loop ABCDA, carrying current I=12 A, is placed in a plane consists of two semi-
circular segments of radius R1  6 m and R2  4 m. The magnitude of the resultant
magnetic field at center O is k  107 T . The value of k is _______
(Given 0  4  107 TmA1 )
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Key: 1
Sol:

 i 12
B1  0    107  
4 r1 6
B1  2  107 T
 i 107  12
B2  0      3  107
4 r2 4
Bnet  B2  B1  3  2   107  1  107 T
49. In the figure shown below, a resistance of 150.4 is connected in series to an ammeter A
of resistance 240 . A shunt resistance of 10 is connected in parallel with the ammeter.
The reading of the ammeter is ______ mA.

Key: 5
Sol:

R1R2
R
R1  R2
240  10

250
 9.6
Rtot  9.6  150.4  160
V 20 1
I   A
R 160 8
V1  V2
I1R1  I 2 R2
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I1 10 1
 
I 2 240 24
I1  x
I 2  24 x
1
 25 x
8
1
x
200
I1  x
1 1000
 
200 1000
= 5mA
50. Two coherent monochromatic light beams of intensities 4I and 9I are superimposed. The
difference between the maximum and minimum intensities in the interference pattern is
xI. The value of x is ______
Key: 24

     25I
2 2
Sol: I max  I1  I 2 4I  9I

I min   I2    9 I   1I
2 2
I1  4I 
Difference between I max and I min  ?
I max  I min  25 I  1I  24 I

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CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY
ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Which of the following is the correct structure of L – Fructose?

1) 2)

3) 4)
Key: 3
Sol: The structure of L- fructose
CH 2OH OH

O
C O
H OH
OH
HO H (or) HO
HO H
HO
CH 2OH OH

The structure of D- fructose

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CH 2OH

C O
HO H
H OH
H OH

CH 2OH
3 3
52. The correct order of the complexes Co  NH 3 5  H 2O    A , Co  NH 3  
 6  B ,
3 2
Co  CN    C  and CoCl  NH 3    D  in terms of wavelength of light absorbed
 6  5
is
1) C  B  A  D 2) D  A  B  C 3) D  C  B  A 4) C  B  D  A
Key: 2
1
Sol: Crystal field splitting energy    
 abs 
  Strength of ligand.
If the strength of ligand is more, the wave length of light absorbed by the corresponding
complex is less.
2 3 3 3
 abs  : CoCl  NH 3 5   Co  NH 3 5  H 2O    Co  NH 3 6   Co  CN 6 

53. Number of molecules from below which cannot give iodoform reaction is:
Ethanol, Isopropyl alcohol, Bromoacetone, 2-Butanol, 2-Butanone, Butanal, 2-Pentanone,
3-Pentanone, Pentanal and 3-Pentanol.
1) 3 2) 5 3) 2 4) 4
Key: 4
Sol: Molecules which can give iodoform reaction are ethanol, isopropyl alcohol, 2-Butanol, 2-
Butanone, 2-Pentanone, Bromo acetone. Molecules which cannot give iodoform reaction
are butanal, 3-pentanone, pentanal and 3-ethanol. Molecules containing either a methyl
O
R  C  CH3
ketone ( ) (or) a secondary alcohol that can be positive for the test.

54. Which of the following properties will change when system containing solution 1 will
become solution 2?

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1 L of solution 1
10 mol of solute x +
+ 1 mol of solute x
10 L of water +
1 L of water

Solution 1 Solution 2

1) Density 2) Gibbs free energy 3) Molar heat capacity 4) Concentration

Key: 2
Sol: Solution – 1 which contain 10 mole x.
n( x) 10
M1    1molar
V( L ) 10
Solution –2 contain 1 L of solution–1 + 1 mole of solute x +1 L of water
Total volume of solution – 2 = 2L
Total moles of x in solution – 2 = 2 mole
2 mole
M2   1molar
2L
Solution – 1 and solution – 2 are equimolar. Hence density molar heat capacity and
concentration of solution – 1 and solution – 2 are same. But the  G  Gibbs free energy
change of the process of preparation of solution- 2 is negative because the formation of
solution is positive entropy driven process whose G is negative (spontaneous process).

55. In the following reactions, which one is NOT correct?


N  NCl  CN
CuCN KCN



1)

N  NCl 
H PO
3 2 2  H O


2)

N  NCl  I
Potassium Iodide


3)

N  NCl  OEt
EtOH


4)
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Key: 4
Sol:

N  NCl 
EtOH +CH 3CHO



56. Identify the correct statements from the following

O

and are metamers

A) O
CN NC
and are functional isomers
B)

C) OH and OH are position isomers

NH 2 and NH are homologous

D)
Choose the correct answer from the options given below:
1) A, B & C only 2) A & B Only 3) B & C only 4) C & D only
Key: 2
Sol:
O

and are metamers

A) O

CN NC
and are functional isomers
B)

C) OH and OH have different molecular formula.

Hence they are not a pair of isomers.

NH 2 and NH
D) They are not homologues ,
they differ in functional group.
57. The metal ions that have the calculated spin-only magnetic moment value of 4.9 B.M.
are:
A) Cr 2 B) Fe 2 C) Fe3 D) Co 2 E) Mn3
Choose the correct answer from the options given below:
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1) A, C and E only 2) A, D and E only 3) A, B and E only 4) B and E only
Key: 3
Sol: The spin-only magnetic moment formula is =  BM  n  n  2 
Where n = number of unpaired electrons in d –orbital.
A) Cr – (24):  Ar  3d 5 4 s1
Cr 2 :  Ar  3d 4
d 4, n  4
 BM  4  4  2   24  4.89
B) Fe-(26) :  Ar  3d 6 4 s 2
Fe 2 :  Ar  3d 6
d 6  d 4,n  4
 BM  4  4  2   24  4.89
C) Fe-(26):  Ar  3d 6 4 s 2
Fe3 :  Ar  3d 5
n5
 BM  5  5  2   35  5.91
D) Co- (27):  Ar  3d 7 4 s 2
Co 2 :  Ar  3d 7
d7  d3
n3
 BM  3  3  2   15  3.87
E) Mn - (25):  Ar  3d 5 4 s 2
Mn3 :  Ar  3d 4
d4
n4
 BM  4  4  2   24  4.89
58. In a reaction A  B  C , initial concentrations of A and B are related as  A0  8 B 0 .
The half lives of A and B are 10 min and 40 min, respectively. If they start to disappear at
the same time. Both following first order kinetics, after how much time will the
concentration of both the reactants be same?
1) 40 min 2) 60 min 3) 80 min 4) 20 min
Key: 1
Sol:  A0  8 B0
Half life of A = 10 min
Half life of B = 40 min

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Order with respect to A = 1
Order with respect to B = 1
Let Initial concentration of A be 8 molar then initial concentration of B is 1 molar.
At 40 min (four half life of A )
 A 8 1
 A  40   molar
2 16 2
At 40 min (one half life of B )
 B 1
 B   0  molar
2 2
At 40 min, the concentration of A and B are equal.
59. Among 109 g (each) of the following elements, which one will have the highest number
of atoms? Element: Pb, Po,Pr and Pt
1) Pb 2) Pt 3) Po 4) Pr
Key: 4
Sol: Number of atoms  number of moles
weight
Number of atoms 
G. Awt
Given that weight of given elements are equal.

1
Number of atoms 
G. Awt
Among the give list of elements, Pr has the minimum gram atomic weight. Hence Pr
contain maximum number of atoms.

60. Match the List – I with List – II

List –I List –II

(Molecules/ion) (Hybridization of
central atom )
A PF5 I dsp 2
B SF6 II sp 3d
C Ni  CO 4 III sp3d 2
D
 PtCl4 2 IV sp3

Choose the correct answer from the options given below:

1) A  III , B  I , C  IV , D  II 2) A  IV , B  I , C  II , D  III
3) A  I , B  II , C  III , D  IV 4) A  II , B  III , C  IV , D  I
Key: 4
Sol:
Molecule/ion  Hybridisation
A) PF5  sp3d
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3 2
B) SF6  sp d
C) Ni  CO 4  sp 3
2
D)  PtCl4   dsp 2
61. Given below are two statements:
Statement – I: A catalyst cannot alter the equilibrium constant  K c  of the reaction,
temperature remaining constant.
Statement – II: A homogenous catalyst can change the equilibrium composition of a
system, temperature remaining constant.
In the light of the above statements, choose the correct answer from the options given
below
1) Both statement – I and statement – II are false
2) Statement – I is false but Statement – II is true
3) Statement – I is true but statement – II is false
4) Both Statement – I and statement – II are true
Key: 4
Sol: A catalyst cannot alter the equilibrium constant  K c  of the reaction, (at constant
temperature). A homogeneous catalyst can change the equilibrium composition of a
system.
62. Which of the following postulate of Bohr’s model of hydrogen atom is not in agreement
with quantum mechanical model of an atom?
1) The electron in a H atom’s stationary state moves in a circle around the nucleus.
2) An atom in a stationary state does not emit electromagnetic radiation as long as it stays
in the same state.
3) An atom can take only certain distinct energies E1, E2 , E3 , etc. These allowed states of
constant energy are called the stationary states of atom.
4) When an electron makes a transition from a higher energy stationary state to a lower
energy stationary state, then it emits a photon of light.
Key: 1
Sol: According to the Bhor’s postulate, the electron in H – atoms stationary state moves in a
circle around the nucleus, but according to quantum mechanical model of an atom, it is
impossible to locate the accurate position and velocity of the electron and the existence
of circular orbits at a accurate distance is over ruled.
63. Given below are two statements:
Statement – I: The N  N single bond is weaker and longer than that of P  P single
bond.
Statement – II: Compounds of group 15 elements in + 3 oxidation states readily undergo
disproportionation reactions.
In the light of the above statements, choose the correct answer from the options given
below

1) Both statement – I and statement – II are false

2) Statement – I is false but Statement – II is true
3) Statement – I is true but statement – II is false
4) Both Statement – I and statement – II are true
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Key: 1
Sol: Because of inter electronic repulsion of non bonding electrons, N – N single bond is
weaker that P – P single bond. But N – N single bond is shorter than P – P single bond. In
case of group – 15 elements, +3 is one of the common oxidation state. Elements in their
common oxidation state does not participate in disproportionation reaction rapidly.
64 Identify  A ,  B  and C  , respectively in the following reaction sequence:
 
N 2 Cl

NaNO2 , HCl KI 2 Na
 A 
273 278 K
  B  
 C 
Dry ether

NH 2 Cl

I
 A  B C 
1)
NO2 I

 A  B C 
2)
NH 2 Cl

 A  B C 
3)
NH 2 I

 A  B C 
4)

Key: 4
Sol:

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 
NH 2 N 2 Cl
I
NaNO , HCl
2 KI

   N 2  KCl
273 278 K

Dry ether 2 Na

+2NaI

65. In the following system, PCl5  g  PCl3  g   Cl2  g  at equilibrium, upon addition of
xenon gas at constant T & p, the concentration of
1) PCl5 , PCl3 & Cl2 remain constant 2) PCl3 will increase
3) PCl5 will increase 4) Cl2 will decrease
Key: 2
Sol:  PCl3( g )  Cl2( g )
PCl5( g ) 
Since the products side  PCl3 and Cl 2  has more moles of gas (2 moles) than the
reactant side  PCl5 ,1mole  the equilibrium will shift to the right.
 Addition an inert gas at constant pressure increases the total volume of the system.
 The concentration of PCl3 and Cl2 will increase and the concentrate of will PCl5
decrease.
66. Which of the following statements are correct?
A) The process of adding an electron to a neutral gaseous atom is always exothermic.
B) The process of removing an electron from an isolated gaseous atom is always
endothermic.
C) The 1st ionization energy of boron is less than that of beryllium.
D) The electronegativity of C is 2.5 in CH 4 and CCl4
E) Li is the most electropositive among elements of group I.
Choose the correct answer from the options given below:
1) B and D only 2) B, C and E only 3) B and C only 4) A, C and D only
Key: 3
Sol: A) The process of adding an electron to a neutral gaseous atom is generally exothermic
because energy is released when an electron is added. But it’s not always exothermic.
For example adding an electron to a uni-negative ion is endothermic.
B) The process removing an electron from an isolated gaseous atom is always
endothermic as it required energy to overcome the attraction between the electron and the
nucleus.
C) B5  1s 2 2 s 2 2 p1, Be4  1s 2 2s 2

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The 1st ionization energy of Boron is less than that of Beryllium. This is because the
added electron in Boron occupies a 2p orbital which is further from the nucleus and
shielded by the 2s electrons.  IE : B  Be
D) The electro negativity of carbon is approximately 2.5 electro negativity is an intrinsic
property of an atom and is not affected by the type of molecule it is in  CH 4 or CCl4  .
E) Electro positivity of Li is lesser than that group I order of electro positivity:
Li   Na   Ic  Rb  Cs
67. Which compound would give 3-methyl-6-oxoheptanal upon ozonolysis?

1) 2) 3) 4)
Key: 1
Sol:

O
O
3 

Zn  H 2O O
H

3-methyl-6-oxoheptanal

O
O3
  O
Zn  H 2O
H
5-methyl-6-oxoheptanal

O3
O
  O
Zn  H 2O
H

4-methyl-6-oxoheptanal

O
O3
  CHO
Zn  H 2O

2-methyl-6-oxoheptanal
68. 2 moles each of ethylene glycol and glucose are dissolved in 500 g of water. The boiling
point of the resulting solution is:

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1
(Given: Ebullioscopic constant of water  0.52 K kg mol )
1) 379.2 K 2) 277.3 K 3) 375.3 K 4) 377.3 K
Key: 4
Sol: 2 moles of ethylene glycol (A) in 500 g water
2
 m A   1000  4 molal
500
2 moles of glucose (B) in 500 g water
2
 m B    1000  4 molal
500
 mTotal  8 molal
Tb  iK b m  1  0.52  8  4.16
Tb  Tb  Tb0
Tb  Tb  Tb0  373.15  4.16  377.3K
69. The least acidic compound, among the following is:
EtO OH SO3H

COOH
EtO2C H
A) B) C) D)
1) A 2) B 3) C 4) D
Key: 4
EtO OH

Sol: A)
More acidic due to the resonance stabilization of the phenoxide ion after deprotonation.
SO3H

B)
More acidic due to a sulphonic acid group   SO3H  .

COOH
C)
More acidic due to carboxylic acidic group  COOH  .
D) EtO2C H

As ester group and terminal alkyne. The hydrogen on the terminal is weakly acidic.
70. Correct order of limiting molar conductivity for cations in water at 298 K is:
1) H   Ca 2   Mg 2   K   Na  2) H   Na   K   Ca 2  Mg 2 
3) Mg 2  H   Ca 2  K   Na  4) H   Na   Ca 2  Mg 2   K 
Key: 1
Sol: Limiting molar conductivity order H   Ca 2   Mg 2   K   Na 
Ion Limiting molar conductivity
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 S cm2 mol 1 
H 349.6
Na  50.1
K 73.5
Ca 2 119.0
Mg 2 106.0

SECTION-II (NUMERICAL VALUE TYPE)

This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is in Decimal
then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10
and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
71. Given:
H  sub C  graphite    710 kJ mol 1
C  H H   414 kJ mol 1
 H  H H   436 kJ mol 1
C  C H   611 kJ mol 1
The H f  for CH 2  CH 2 is______ kJ mol 1 (nearest integer value)
Key: 25
Sol: 2C  CH 2  CH 2 g  : H O
 2 H 2 g   f    1
 graphite 
 solid 
2C graphite  2 H 2 
 CH 2  CH 2 g  : H r      2
 gas 
H r  2 BE H  H   4 BE C  H   BE C C   2  436   4  414   611  1395 kJ
Given that
C solid  
 C gas ; 710kJ

2C solid  
 2C gas ; 1420kJ    3
(2 mol )
Eq-2 +eq-3
 2C  2 H 2 
 CH 2  CH 2 ; H r  1395 kJ
( gas )
2C 
 2C gas  ; H  1420 kJ
( solid )
______________________________________
2C  2 H 2   CH 2  CH 2 ( gas ); H  25 kJ
( solid ) ( gas )
72. The number of optical isomers exhibited by the iron complex (A) obtained from the
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following reaction is _______.
FeCl3  KOH  H 2C2O4  A
Key: 2
Sol: Step – I: H 2C2O4  2 KOH 
 K 2C2O4  2 H 2O

 Fe  OH 3  3KCl
Step – II: FeCl3  3KOH 

Step – III: Fe  OH 3  3K 2C2O4  3KOH 

 K 3  Fe  C2O4 3   3H 2O

A is K3  Fe  C2O4 3   2 optical isomers are possible.

73. Consider the following reactions
A  NaCl  H 2 SO4  CrO2Cl2  Side Pr oducts
Little
amount
CrO2Cl2 Vapour   NaOH  B  NaCl  H 2O
B  H   C  H 2O
The number of terminal ' O ' present in the compound ' C ' is _____.
Key: 6
Sol: K 2Cr2O7  4 NaCl  6 H 2 SO4 
 2CrO2Cl2  2 KHSO4  4 NaHSO4  3H 2O
A
CrO2Cl2  4 NaOH 
 Na2CrO4  2 NaCl  2 H 2O
B
2 Na2CrO4  H 2 SO4 
 Na2Cr2O7  Na2 SO4  H 2O
C
O O
Cr O
Cr
O O

O O
Terminal “O” atom are 6.
74. During estimation of nitrogen by Duma’s method of compound X  0.42 g 
H
N

N
H
X
______ mL of N 2 gas will be liberated at STP. (Nearest integer)
(Given molar mass in g mol 1 : C :12, H :1, N :14 )
Key: 109
Sol: mass of x = 0.4 g

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w 0.42
moles of n  x    N 2 gas at STP
gm 86
0.42
moles of n   22.400  109.3
80
75. 0.5 g of an organic compound on combustion gave 1.46 g of CO2 and 0.9 g of H 2O .
The percentage of carbon in the compound is ______. (nearest integer)
[Given: Molar mass (in g mol 1 ) C :12, H :1, O :16 ]
Key: 80
 y y
Sol: C x H y   x   O2   xCO2  H 2O
 4 2
12 wt CO2
%C    100
44 wt of organic compound
12 1.46
%C    100  79.63  80%
44 0.5

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