Student's Solution Copy [Code - 31307]

13th_ Batch 25(V1 to V11) (V2 to V12)_ Anushaashan (25ALV1 to 25ALV5) Eng Hindi_PT-
1_[Mains Pattern]
13th JEE (M) - Phase 1
KOTA

Date: 04-Aug-2025 Duration: 3 Hours Max Marks: 300

Maths - Section A

1. Answer: B 3. Answer: B

Sol: Sol:
x − 8 ≥ 0, 8 − x ≥ 0 Given : Graph of |y| = f (x), where
ax + bx + c has maximum vertical
2

⇒ x = 8
height 4
when x = 8 . L.H.S = 0 , R.H.S = 0 ∵ All quadratic functions have a
parabolic graph.
⇒ x = 8 is only solution The lowest or the highest point on a
2. Answer: C parabola is called the vertex. The
vertex has the x-coordinate denoted
Sol: by x = − 2ab

P = {a, a + 1,a + 2,
The y-coordinate of the vertex is the
… … a + m − 1}
maximum or minimum value of the
function.
m
{2a + m − 1} = 2 m
If the y-coordinate has maximum
2
value then parabola opens downward
⇒ 2a + m = 5 ...(i)
i.e. a <0
Q = {b, b + 1, b + 2,

… … b + 2 m − 1} ∵It is given that graph of the function

has maximum vertical height i.e. y-
2 m

2
{2 b + 2 m − 1} = m coordinate.
⇒ b + m = 1 ...(ii)
∴ a < 0

(b + 2 m − 1)−(a + m − 1) = 1009
4. Answer: D
b − a + m = 1009 ...(iii) Sol:
5 m
⇒ 1 − m −
2
+
2
+ m = 1009 Required elements to be added in R
(b,a), (c,b), (a,c), (c,a), (a,a), (b,b),
m

2
= 1010. 5⇒ m = 2021 (c,c)
5. Answer: A 8. Answer: A

Sol: Sol:
sin(π[x])
On putting y = 0 in the given relation,
x +1
2
we get
here π [x] is integral multiple of π, so
f (x) + (x) = kf (x) f(0)
sin (π[x]) = 0 ⇒ Range of f (x) =0
⇒ 2f(x) = kf (x) [∴ f (0) = 1]
6. Answer: C
⇒k=2
Sol:
x 2
9. Answer: D
⎧
⎪ sin x, x > 0
⎪ x
Sol:
f(x) = ⎨ 0 x = 0
2
⎪
⎩
⎪ 2 −1 ≤ x − 4x + 5 ≤ 1
x
sin x x < 0
−x

⇒ x = 2
2
⎧
⎪ sin x x > 0 π
2
x + ax + = 0
f(x) = ⎨ 0 x = 0
2

⎩
⎪ π
2 ⇒ a = −( + 2)
− sin x x < 0 4

g(x) = e
−|x| 10. Answer: A

2 −|x| Sol:
⎧ sin (e ) x > 0
⎪
⎪

f0g(x) =
∞ −1 2
⎨ 0 , x = 0 ∑ tan ( )
n=1 2
n +n+4
⎪
⎩
⎪ 2 −|x|
− sin (e ) x < 0
2

∞
=
n(n+1)
−1
∑ tan { }
Now L.H.L =
2 −|0−h|
lim (sin (e )) n=1 4
1+
h→0 n(n+1)

2 0 2
= sin (e ) = sin (1) 2

−
2

∞ ∞
= −1 n n+1

2 –h 2 0 2 ∑ tan { }= ∑
R.H.L. = lim (sin e ) = sin e = sin 1 n=1
1+
2
.
2 n=1

+
n n+1
h→0

−1 2 −1 2
{tan ( )− tan ( )}
f(0) = 0 n n+1

L.H.L. = R.H.L ≠ f(0) = {tan

−1
(
2
)− tan
−1
(
2
)}
1 2
−1 2 −1 2
Hence fog (x) is discontinuous but not +{tan (
2
)− tan (
3
)}+. . . . . . ∞

diff. of x = 0, terms
Therefore the correct option is (3). = tan−1 2
7. Answer: B Therefore, the correct answer is (A)
Sol: 11. Answer: C
3. f (f
−1
(x))= x Sol:

tan(f
−1
(x))+cot(f
−1
(x)) − 2 = x
we have f(x) g(x) ≥ 0
2 −1
( x +5x+6+cos x)

y +
1
− 2 = x so (sin–1 x − x) ≥0
y positive ∀x∈ [ −1, 1 ]

Therefore, the correct answer is (B) ⇒ sin–1 x − x ≥ 0 ⇒ sin–1x ≥ x

hence x ∈ [0, 1]
12. Answer: A Sol:

2 1 3 4
A= [ ] ,B= [ ]
4 1 2 3

3 −4
and C = [ ]
−2 3

9 − 8 0
Now BC = [ ]
0 −8 + 9

1 0
= [ ] = I
0 1 2×2

1 0
∵ I2 = I = [ ]
0 1

1 0 1 0
[ ] = [ ]
0 1 0 1

⇒ I2 = I3 = ..... In = I

now
2
A(BC)
= tr(A) + tr( + tr(
ABC
) )
2 4

3
A(BC)
+ tr( 8
) +…...+ ∞

= tr(A) + tr( +
A I
)
2

2
A (I)
tr( 4
) +…...+ ∞

= tr(A) + tr( +
A
1
)
2

tr +…∞
A
( 2
)
2

sum = tr(A) + 1

2
tr(A)

+ 1
2
tr(A) + … ∞
2

sum = tr(A)

[1 +
1

2
+
1
+. .... +∞] .....(1)
4

Infinite G.P.

a=1, r= 1

2
<1

∴ sum of infinite series of G.P.

S∞ =
a
=
1
1
=2
1−r 1−
2

from (1)

sum = tr(A) × 2 = 2 tr(A) ...(2)

now tr(A) = 2 + 1 = 3
 ∴ sum = 2 × 3 = 6 15. Answer: A
13. Answer: D

Sol:

For non trivial Solution

∣ 1 − cos θ cos 2θ ∣
∣ ∣
− cos θ 1 − cos θ = 0
∣ ∣
∣ cos 2θ −cosθ 1 ∣

using C1 ➝C 1 − C3

2
∣ 2 sin θ − cos θ cos 2θ ∣
∣ ∣
∣ 0 1 − cos θ ∣= 0
∣ ∣
2
∣ −2 sin θ − cos θ 1 ∣

∣ 1 − cos θ cos 2θ ∣
2 ∣ ∣
2 sin θ 0 1 − cos θ = 0
∣ ∣
∣ −1 −cosθ 1 ∣

or
2 2
sin θ = 0 1 [1 − cos θ]
2 2
−1 [cos θ]−1[cos θ− cos 2θ]

2
sin θ −
2 2 2
[cos θ − (cos θ − sin θ))]

2 2
sin θ − sin θ = 0

hence D = 0 ∀ θ ∈ R

⇒ (D)

14. Answer: A

Sol:

Coefficient of x in Δ(x) = Δ (0)

′

= 0

⇒ k = 0

⇒ {k} = 0
Sol: 16. Answer: B

2x + 3y − z = 0 Sol:

x + ky − 2z = 0
x
f( ) − f (0)
1 x n
L ≡ lim f ( ) = lim
x n x−0

2x − y + z = 0
x→0 x→0

Let x
= p
for non - trivial Solutions, Δ = 0 n

f (p) − f (0)
1
∣2 3 −1 ∣ ⇒ L = lim = f ' (0)
np n
∣ ∣ p→0
1 k −2 =0 1
∣ ∣ =
n
∣2 −1 1 ∣
1 ∞ n x
∴ lim ∑ (−1) f ( ) =
2(k − 2) − 3(1 + 4) x→0
x n=1 n

∞ n 1 ∞ n−1

− 1(−1 − 2k) = 0 ∑
n=1
(−1)
n
= ∑
n=1
(−1)
1
= − In 2
2k − 4 − 15 + 1 + 2k = 0 n

17. Answer: D
4k = 18⇒k = 9/2
Sol:
Now,2x − y + z = 0

2x + z = y Let Pn =
1
2
+
2
2
+. .. +
n
2
1+n 2+n n+n

2x

y
+
z

y
=1 Now, Pn <
1
2
+
2
2
+. .. +
n
2
1+n 1+n 1+n

= 0 ....(1)
x z
2 ⋅ + − 1 1
y y = 2
(1 + 2 + 3+. .. + n)
1+n

also 2x − z = − 3y n(n+1)
=
2
2(1+n )
2x

y
−
z

y
+ 3 = 0 ....(2)
Also,
1 2 3
Pn > 2
+ 2
+ 2

add (1) and (2)

n+n n+n n+n
n
+. .. + 2
n+n

=0
x
4 ⋅ + 2
y
n(n+1)
=
2
−1 2(n+n )
x
=
y 2
n(n+1) n(n+1)
Thus, < Pn <
2x + 3y = z 2(n+n )
2
2(1+n )
2

3y n(n+1)
=1
2x

z
+
z
or lim
2
< lim
n→∞ 2(n+n ) n→∞

y n(n+1)
2 ⋅
x

z
+ 3 ⋅
z
− 1 = 0.....(3) Pn < lim
2
2(1+n )
n→∞

also 2x − y + z = 0 1
1(1+ )
n

2x − y = − z or = lim
1
< lim
n→∞ 2( +1) n→∞
n

y
2x

z
−
z
+ 1 = 0 ....(4) 1(1+
1

n
)

Pn < lim
1

from (3) − (4)

n→∞ 2( +1)
2
n

y
or
1 1 1
= < lim Pn <
z 2 2 2
n→∞

2x + 3y − z = 0
or lim Pn =
1

2
x→∞
3x − z = − 2x
3y
= 0 ...(5)
z
− + 2
x x

y
put = − 2 in (5)
z
= −4
x x

x y z 1
∴ y
+
z
+
x
+ k =
2
18. Answer: C 20. Answer: C

Sol: Sol:

∵ 1∞ form
π −1
⎧ + tan x x ∈ [−1, 1]
⎪
⎪ 4
⎪
1
f (x) = ⎨ (x − 1) x > 1
2
⎪
1+tan(lnx) ⎪
⎩
⎪
1 1
(−x − 1) x < −1
lim [ −1] 2
1−tanlnx lnx
∴ ex→1
at x = 1
2 tan(lnx) 1
lim [ ⋅ ]
ex→1
(lnx) 1−tanlnx
= e2 f(1) = π

Therefore, the correct answer is (C) f(1+) = 0

19. Answer: B ∴ discontinuous ⇒ non diff.
Sol: at x = – 1
f(x) is continuous if f(–1) = 0
it is continuous at x = 1
f(–1–) = 1

2
{+1 − 1} =0
⇒ 5=5=a+b⇒a+b=5
...(1) cont. at x = –1
1
it is continuous at x = 3 ⎧
⎪
⎪ 1+x
2
x ∈ [−1, 1]
⎪

a + 3b = b + 15 ⇒ a + 2b = 15
′ 1
f (x) = ⎨ x > 1
2

...(2) ⎪
⎪
⎩
⎪ 1
− x < −1
2
it is continuous at x = 5
at x = –1,
b + 25 = 30
f’(–1–) = – 1
and
⇒ b=5 2

b =5 not satisfies the equation (1) f’(–1+) = 1

and (2)
So, at x = –1 it is non differentiable.
⇒ f is not continuous for any values of
a and b.
 Maths - Section B

21. Answer: 2 23. Answer: 1

Sol: Sol:

Let α + β + γ = θ lim sin

2

n→∞

Hence, cos(α + β)+cos(β + α)+

2
cos(γ + α)= cos(θ − α)+ (π√(n!) − (n!)))
cos(θ − β)+cos(θ − γ)

2
= cosθ ∑ cosα+sinθ ∑ sinα lim sin
n→∞

2 2
= 2 cos θ + 2 sin θ = 2
2
((n!) π − π√(n!) − (n!))
Hence, a = 2

2
√x −4 2
∴ lim = lim sin
n→∞
x→2 √x−2+√x−√2

2
√x −4(√x−2+√x+√2) ⎛ ⎞
=
π(n!)
lim ⎜ ⎟
x→2 (√x−2+√x−√2) 2
⎝ n!+√(n!) −(n!) ⎠

(√x−2+√x+√2)

2 π
=sin ( ) = 1.
2
√(x−2)(x+2)
= 2√2 lim = 2
x→2
2(x−2)+2√x×√x−2 24. Answer: 4

22. Answer: 0 Sol:

2

Sol:
4b −9a

Lim f(x)=e 2b
= e
3

x→0
Since f is periodic with period 2 and
f (x) = x∀ x ∈ [0, 1] also f (x) is even ⇒ 4b
2
− 6b − 9a= 0∀b ∈ R
⇒ symmetry about y-axis
−1
D ≥ 0 ⇒ a ≥
graph of is as shown
4
∴ f (x)

f (3. 14) = 4 − 3. 14 = 0. 86
25. Answer: 4 Sol:

Given functional relation,

x+y–1
f(xy) = f(x) + f(y) + xy
, ∀ x, y >
0, .....(i)

Now,
f (x+h)–f (x)
f'(x) = lim
h
h→0

h
f (x(1+ ))–f (1.x)
x

= lim
h
h→0

h
x+1+ –1
= {f(x) + f +
1 h x
lim (1 + )
h x h
h→0 x ( 1+ )
x

}
x+1–1
−(f (x) + f (1) + )
x.1

= lim
h→0
h h h
f ( 1+ ) –f (1) x+ –x ( 1+ )
x x x
( + h
)
h
hx. ( 1+ )
x

⇒ f'(x) = lim
h→0

h
h
f ( 1+ ) –f (1)
x –h
x
( + )
h
h
x.
x hx. ( 1+ )
x

= lim
h
→0
x

h
1
f (1+ )–f (1)
x –1
1 x
( × + lim )
h x h
x h→0 x(1+ )
x

(As h 0⇒ x 0)
h
→ →

f '(1)
f ' (x) = + –x
1 1
2
x x

f'(x) = + –x
2 1 1
⇒ 2
x x

(∴f'(1) = 2)

⇒ f'(x) = x1 + 1
2
x

Integrating both sides, we get

f(x) = lnx – 1

x
+C ---- (2)

Putting x = y = 1 in equation (i), we

get

f(1) = –1

Thus, from (2), C = 0

∴ f(x) = ln x – 1

f(e100) = ln e100 –
1
100
e

= 100 – 1
100
e
= 100–

∴ [f(e100)] = [100–] = 99

∴ Requried quantity = 99–95 = 4.

Therefore, the correct answer is 4.

 Physics - Section A

1. Answer: C 3. Answer: A

Sol: Sol:
→
Let ˆ
A = 6 î + 2 ĵ + 3k &
→
ˆ
B = 3 î − 6 ĵ − 2k ...(i)

∣ ˆ ∣
î ĵ k
→ ∣→ ∣
ˆ
A × B =∣ 6 2 3 ∣= 14 î + 21 ĵ − 42k
∣ ∣
∣3 −6 −2 ∣

Unit vector perpendicular to both ...(ii)

vectors is :
ˆ
14 î +21 ĵ −42k
⇒
Adding (1) and (2)
2 2 2
√14 + ( −21 ) + ( −42 )

14 î +21 ĵ−42k̂ m1g − m2g = (m1 + m2) a

=
√2401

= 2.5 ms-2
( 5−3 ) 10
a=
( 5+3 )
7 ( 2 î +3 ĵ−6k̂ )

⇒=
49 For m2 :

=
2 î +3 ĵ−6k̂
s = 4m
7

u=0
2. Answer: B
υ2 − u2 = 2as
Sol:
∴ υ2 − 0 = 2 × 2.5 × 4
Let the initial velocity of car be 'u'.
Time of flight will be given by, u= 2√5 ms-1
2uy
t =
g
= 2 Therefore, the correct answer is (A)

where, uy = component of velocity in

vertical direction. Now distance
covered by the car will be;

1 2
xcar = u × 2 + × 1 × (2) = 2u + 2
2

Now distance traveled by the ball;

xball = u × 2

Now, xcar − xball = 2u + 2 − 2u = 2m

So, option (B) is correct.

4. Answer: C 6. Answer: B

Sol: Sol:

from the diagram we can see

Component of Y gets cancelled and x
componenet is in -ve direction.

Relative velocity of image with respect

h = l - l cosθ
to object is in negative x-direction as
υ
2
= 2 gh = 2gl(1 – cosθ) shown in figure.

In position A, there is only tangential Therefore, the correct answer is (B)

acceleration 7. Answer: C
2

(ar = 0, as ar =
u
= 0) Sol:
l

mgsinθ
aA = at = = gsinθ
m

...(i)

In position B, there is only radial

acceleration, because tangential force
is zero. So, tangential acceleration is
zero.
2
υ
∴ aB = ar = = 2g(1 − cosθ)
l

...(ii)

Given, aA = aB Suppose fish is situated at a distance

x from the water surface and Bird is
Equating equations (i) and (ii), we get
at a distance of h from surface
θ ≈ 53 º so y = μh + x

5. Answer: A
Differentiating w.r.t time
Sol: dy dh dx
= μ +
dt dt dt
p2 −p1
W e have = 0.2
p1
9 = μV + Vfish
bird
p2
⇒ = 1.2
p1
4
9 = Vbird + 3
3
k2 −k1 k2
so ( ) × 100 = ( − 1) × 100
k1 k1 3
VBird = (9 − 3) = 4. 5m/s
4
2 2
p p
2
= ( 2
− 1) × 100 (sin ce k = )
p 2m
1

= ((1.2)2 – 1) × 100 = 44 %
8. Answer: A 11. Answer: D

Sol:
kq×2
EM =
2 2
r cos α

2kqcosα
EP = 2
r

EM 1
= 3
= 27
EP cos α

1/3
1
cosα = ( ) ⇒ cosα = 1/3
27

9. Answer: A

Sol:

√2 sin 30° = sin e

e = 45°

Deviation = 45° _ 30° = 15°

10. Answer: A

Sol:
Q
E = 2
4πε0 x

dE −Q
= 3
dx 2πε0 x

Qq(2a) Qqa
F = 3
= 3
2πε0 x πε0 x
Sol:

12 −2
a = = 2 ms
6

20 − f = 2 × 2 ⇒ f = 16N
12. Answer: A

a =
12
= 2 ms
−2 Sol:
6

f = 2 × 2 = 4N Given :
Q ω = a − bt

dω
Now angular acceleration α = = −b
dt

st
From 1 equation of motion

2 2
ω = ω + 2αθ
f i

2
0 = a − 2bθ
2
a
θ =
2b

13. Answer: A
12 −2
a =
6
= 2 ms Sol:
f = 4 × 2 = 8N
− dU
F =
R
dx

14. Answer: C

Sol:

For static equillibrium,

force due to gravity on both block ≤

force due to friction on both blocks

2mg sin θ ≤ mg (μ1 cosθ + μ2 cosθ)

12 −2 2tanθ ≤ μ1 + μ2
a = = 2 ms
6

6 − f = 2 × 2 ⇒ f = 2N μ1 +μ2
tanθmax =
2

S
15. Answer: C

Sol:
1 2 1 2 2
K. E. = mv = m × a t
2 2

1 2 2S
K. E. = ma ×
2 a

K. E ∝ S

a =
12
= 2 ms
−2 Therefore, the correct answer is (C)
6

20 − f = 4 × 2 ⇒ f = 12N 16. Answer: C

T Sol:
μ2 μ1 μ2 −μ1
Use v
−
u
=
R
for refraction at
both
17. Answer: D 19. Answer: C

Sol: Sol:

2
kq
Fe = electrostatic force = =
when the plane mirror is rotated by an
2
r

2
angle θ then the reflected ray is
= centripetal force =
mv
Fc
r rotated by angle 2θ
on balancing force For the ray not to come out of water,
T cosα = mg . . . . .(i) the minimum value of should be such
2
2
that
kq mv
T sinα = +
r
2 r
reflected angle = critical angle
from eq
n
(i), T > mg
− 1
2θ = θc = sin ( )
μ

from eq
n
(ii), T > Fe
1 −1 3
2 ∴ θ = sin ( )
If is removed then
mv 2 4
q T sinα =
r

Therefore, the correct answer is (C).

speed of ball has to be increased to
maintain 20. Answer: B
the angle.
Sol:
Therefore, the correct answer is (D) 2 2
ac = k rt
18. Answer: A
P = Fv
Sol: 2
v 2 2
= k rt
r

v = krt

Ft = mkr

2 2
2 2 2
Fnet = √(mk
2 2
rt ) + (2 mk r t )
→
–2kλ î
←−−−−−→≡←
− E =
4kλ 2kλ 2kλ
R

R R R

Electric field along vertical direction

cancel each other, net field along
horizontal direction.

Enet= –λ
î

P = Fv cosθ = mk2r2 t
2πε0 R
 Physics - Section B

21. Answer: 5 24. Answer: 4

Sol: Sol:

VR = 10 sin 30°

10
VR = = 5m/s
2
If upper string is cut F1 = 0
22. Answer: 2
Given a = 6 m/s2
Sol: ⇒ 6 = g −
F2

FE = Tsin 15° and mg = Tcos 15°

....(1)
FE
tan 15° =
mg

When suspended in a liquid

FE /K
tan 15° =
ρ
I
mg ( 1− )
ρs

FE F2
....(2)
1
= ⇒ 6 = 10 −
mg ρ m
l
K ( 1− )
ρs

⇒ F2 = 4m
From equation (1) and (2) we get
ρl If lower string is cut F2 = 0
K(1 − )= 1
ρs

i.e.,
0.8
K(1 − )= 1 ⇒ K = 2
1.6

Note; one can use directly the

following formula to get K
ρ
K =
ρ −ρL
b
. g −
F1
= a1 ⇒ a1 = 4m/s
2
b m

23. Answer: 45

Sol:

For prism we have,

∠i + ∠e = ∠A + ∠δ ...(i)

if i = 15 , then e = 60

and δ = 30

From eq. (i)

15 + 60 = A + 30

⇒ A = 45°
25. Answer: 5

Sol:

Given: Mass of block (m) = 2 kg

FBD of block A:

By the resolution of force

mg sinθ + T = ma ... (1)

FBD of block B:

mg– T = ma ...... (2)

From equation (1) and (2)

mg sinθ + T = mg– T

⇒ 2T = mg sinθ − mg

o o 1
∵ θ = 30 ∴ sin 30 =
2

mg mg
2T = mg − =
2 2

mg 2×10
∴ T = = = 5 N
4 4
 Chemistry - Section A

1. Answer: A 5. Answer: B

Sol: Sol:

SN1 reaction For H2O2 neq

1
= 0.5 × 25 × 2 = 25
meq
2. Answer: C
vf = 2
Sol:
For KMnO4 neq = 0.2 × 50 × 5 = 50
O. C. −−−
− → N2 2

meq
0.4 g 60 mL
Vf = 5
PV = nRT
So H2O2 is Limiting Reagent
PV 700 60 1
n = = × ×
RT 760 1000 0.0821×300 So Left KMnO4 = 50–25 meq
n = 0.002243 = 25 meq.
mass N2 = 0. 002243 × 28= 0. 0628
moles =
25
= 5 moles
2

WN
0.0628
neq of O2 = 0.025
2
%N2 = × 100= × 100
WO.C. 0.4
6.28
= = 15. 70%
moles O2 = = 0.0125 moles
0.025
0.4
2

T = 300 K
6. Answer: A
PT = 715 mm Hg
Sol:
q tension = 15 mm Hg
(P) IF7 have a very complex shape
PN = 715 − 15 = 700 mm Hg (pentagonal bipyramidal shape) and
its dipole moment is either zero or
2

3. Answer: D close to it and thus, IF7 is non-polar

and non-planar.
Sol:
(Q) The SO2 molecule is planar has
Fact based bent shaped and polar because of the
electronegativity difference between
4. Answer: A
sulphur and oxygen.
Sol:
(R) In SF4 , there is a lone electron
pair around the sulfur atom and thus,
the molecule is polar and has a non-
planar structure.

(S) CS2 (Carbon disulfide) is nonpolar

because of its symmetric (linear or
planar) shape.

E = priority groups are on the The correct answer is

opposite sides, (P) → (4); (Q) → (1); (R) → (2); (S) → (3)

Z = Priority groups are on the same 7. Answer: C

side,
Sol:

In case of (C) option, CH3 O− is a

strong nucleophile in DMSO and
confirms SN 2.
8. Answer: C 10. Answer: B

Sol: Sol:

Let the organic compound is CxHyOz A → P, Q, R, S; B → Q;

C → P, Q; D → P, Q, R, S

(A) No plane
y
V= (x +
4
−
z

2
)V ⇒
y
....(i)
z
x + − = 1
4 2
of symmetry
y
x= 2
⇒ y = 2x ....(ii)
y y
(B) No
z
1 + (x + − ) = x +
4 2 2

y
plane of symmetry
....(iii)
z
⇒ 4
+
2
= 1

from (i) , (ii) and (iii)

(C) No plane of
x=1

y=2 symmetry

z=1 (D)

⇒ CH2O = 30 gram/mol

9. Answer: D

Sol:

Shape → square planar

11. Answer: B 15. Answer: A

Sol: Sol:

Let mass of HCl be x 2Cu+2 + 4I −⟶ Cu2I2 + I 2

∴ mass of H2SO4 is 0.1−x ⇒ No. of moles of pure

+2
Cu = 0. 7 × 0. 15 = 0. 105 mole
Moles of HCl = { molecular
x
∵
36.5

weight of HCl = 36.5 g/mol ⇒ No. of moles of

+2
No. of moles of pure Cu
I2 =
HCl + AgNO3 ➝ AgCl ↓ + HNO3 2
0.105
= moles
Moles of HCl = moles of AgCl
2

⇒ No. of equivalents of
Mass of AgCl = 0.1435g
equivalents
0.105
I2 = × 2 = 0. 105
2
Molecular weight of AgCl =
143.3g/mol ⇒ No. of equivalent of I2 = No. of
equivalents of hypo
Moles of AgCl = = 10−3
wt 0.1435
=
m wt 143.3
0. 105 = 0. 120 × NHypo
−3
= 10
x
∴
36.5
⇒ Normality of hypo solution = 0.875
x = 36.5 × 10−3 N

Mass of HCl(x) = 36.5 × 10−3 = ⇒ Molarity of hypo solution

0.875
0.0365 g =
1
= 0. 875 M

Mass of H2SO4 = 0.1 − 36.5 × 10−3 =

0.0635g

% weigh of H2SO4 =
weight of H2 SO4
× 100
Total wieght of mixture

% weight of H2SO4 = × 100 =

0.635

0.1

63.5%

12. Answer: C

Sol:

CHCl3 is polar while CH4 and CCl4

are nonpolar. So, dipole moment order
is:
CHCl3 > CH4 = CCl4

13. Answer: C

Sol:

14. Answer: C

Sol:

Fact based
16. Answer: A 17. Answer: A

Sol: Sol:

To find the value of (y1 − y2 ), first we It is said that two P – Cl bonds are
need to find the value of y1 and y2 stronger and three P–Cl bonds are
which are the respective equivalent weaker.
weights of NH3 and N2 .
As we know that there are 3
To find the equivalent weights we equational bonds and 2 axial bonds
need to find the n-factor of both axial bonds are basically.
because equation (1)

Eq. wt. = Mol. wt. /n − factor

So, first let's find out the n-factor of

NH3 and N2 , using it we will find their

equivalent weights. The reaction is :

Bond strength is inversely
N2 + 3H2 → 2 NH3 proportional to the bond length.
Hence, the longer bond is not
For N2 : Initially the oxidation state of stronger.
N atoms here is 0. But later it is
converted into N−3 in NH3 . This Hence, the correct answer is (a)
menas that 1 atom of N shares 3 18. Answer: A
electrons with H atoms and so 2N
atoms will share in total 6 electrons. Sol:
So, the n-factor of N2 is 6. − − −
CH3 S > CH3 O > CH3 COO > CH3 OH
Molecular weight of N2 is x2 and
equivalent weight is y2 (givenn in the 19. Answer: B
question). Sol:
So, using equation (1) : y2 = x2 /6
Strength of H-bond a polarity of H-
....(2) atom a EN of atom attach to the H-
atom.
For NH3 : Above we just proved how
2N atoms or 2 moles of NH3 are 20. Answer: C
taking 6 electrons. So, 1 mole of NH3
will take 3 electrons. Hence the n- Sol:
factor of NH3 will be 3. Poorer the base better will be the
Molecular weight of NH3 is x1 and its leaving group.
equivalent weight is y1 (given in the
question).

So, using equation (1) :

y1 = x1 /3 ...(3)

Now use the values of y2 and y1 from

equations (2) and (3) to calculate
(y1 − y2 ).

y1 − y2 = (x1 /3) − (x2 /6)

= (2x1 − x2 )/6

So, the correct option is : (A)

(2x1 − x2 )/6
 Chemistry - Section B

21. Answer: 30 23. Answer: 2

Sol: Sol:

Bleaching powder
KI+HCl Na2 S2 O3
−
−−−−→ I2 −−−−→ I + Na2 S4 O6

The redox changes are as follows:

− −
I2 + 2e → 2I

2+ +5/2 −
2(S ) → (S ) + 2e
4

Meq. of bleaching powder = Meq. of

available Cl2 = Meq. of liberated I2 =
Meq. of Na2S2O3 used.

Meq. of available Cl2 in 25 ml

bleaching powder solution = Meq. of
Na2S2O4 used = 24.35 × 1
10

Meq. of available Cl2 in 500 ml

bleaching powder solution =
1 500
24.35 ×
10
×
25
= 48. 7 24. Answer: 5

Meq. of available Cl2 in 500 ml Sol:

bleaching powder solution =
w
× 1000 = 48.7
71
( )
2

Weight of Cl2 = 1.729g.

% of available Cl2 in Bleaching powder

1.729
= × 100= 30.33%
5.7

25. Answer: 04
% of available Cl2 in bleaching
powder is 30 Sol:
22. Answer: 4 O
+
⟶ 5 (π * 2p )
1
2

Sol: + 1
He ⟶ 1 (σ * 1s )
2

The structure of H4P4O12 is :

− 1
H ⟶ 1 (σ * 1s )
2

− 2 1
O ⟶ 7 (π * 2p = π * 2p )
2

H4P4O12 contains 4 P-OH bonds, 4 P

= O bonds, 4 P-O-P bonds .

Hence the number of P-O-P bridge

bonds in H4P4O12 are 4.