PHA046_A3

PHA046_A3
Safety Data Sheet
INTERTHANE 990 PART B
Bulk Sales Reference No.: PHA046
SDS Revision Date: 03/28/2016
SDS Revision Number: A3

1. Identification of the preparation and company

1.1. Product identifier
Product Identity INTERTHANE 990 PART B
Bulk Sales Reference Number PHA046
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended Use See Technical Data Sheet.
Application Method See Technical Data Sheet.

1.3. Details of the supplier of the safety data sheet

Company Name International Paint Ltda

ARGENTINA:
Ruta Panamericana Km 37,5
Garin, Buenos Aires
PO Box: B1606DQE
AKZONOBEL CHILE:
Calle Limache 3363 Local 3, El Salto
Viña del Mar, Chile
C.P. 2520642 - Rut 76.048140-8
BRAZIL:
Avenida Paiva, 999 - Neves
Sao Goncalo, RJ
24426-148 Brazil

Emergency
Suatrans Cotec 0800 7071 767 or 0800 7077 022 or 0800 172020 or
55*2*7500 (24 hr)
International Paint ARGENTINA:
+54 3327 44 7777
CHILE:
+56 32 267 1174
BRAZIL:
+55 21 2199-7100
Poison Control Center (Brazil) 0800-0148110 or +55 11 3069-8800
Medical Service (Argentina) +54 3327 44 7144 or +54 3327 44 7282
Firefighter/HSE (Argentina) +54 3327 44 7123
Customer Service ARGENTINA:
+54 3327 44 7777 Fax: +54 3327 44 7738
CHILE:
+56 32 267 1174 Fax: +56 32 263 1496
BRAZIL:
+55 21 2199-7100 Fax: +55 21 2199-7124
2. Hazard identification of the product
2.1. Classification of the substance or mixture
Flam. Liq. 3;H226
Skin Irrit. 2;H315
Eye Irrit. 2;H319
Skin Sens. 1;H317
Resp. Sens. 1;H334
STOT SE 3;H335
Aquatic Chronic 3;H412

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2.2. Label elements

Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.

Danger.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking.
P235 Keep cool.
P240 Ground / bond container and receiving equipment.
P241 Use explosion-proof electrical / ventilating / light / equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist / vapours / spray.
P261 Avoid breathing dust / fume / gas / mist / vapours / spray.
P262 Do not get in eyes, on skin, or on clothing.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352 IF ON SKIN: Wash with soap and water.
P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+312 IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if
present and easy to do - continue rinsing.
P331 Do NOT induce vomiting.
P333+313 If skin irritation or a rash occurs: Get medical advice/attention.
P337 If eye irritation persists:.
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor / physician.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P370 In case of fire: Use water spray, fog, or regular foam..
P403+233 Store in a well ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents / container in accordance with local / national regulations.
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State
and Federal Hazardous Substances regulations.
Ingredient/Chemical Designations Weight %
Hexamethylene diisocyanate 100
CAS Number: 0000822-06-0
Hexamethylene diisocyanate homopolymer 50 - 75
CAS Number: 0028182-81-2
10 - 25

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Petroleum naphtha
CAS Number: 0064742-95-6
BUTYL ACETATE 1.0 - 10
CAS Number: 0000123-86-4

4. First aid measures

4.1. Description of first aid measures
General Remove contaminated clothing and shoes. Get medical attention immediately. Wash
clothing before reuse. Thoroughly clean or destroy contaminated shoes.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
Skin In case of contact, immediately flush skin with soap and plenty of water. Get medical
attention immediately.
Ingestion If swallowed, immediately contact Poison Control Center at 1-800-854-6813. DO NOT
induce vomiting unless instructed to do so by medical personnel. Never give anything
by mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayed
Overview NOTICE: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage.
Intentional misuse by deliberately concentrating and inhaling the contents may be
harmful or fatal. Avoid contact with eyes, skin and clothing. May cause allergic
respiratory reaction. Repeated exposure to Hexamethylene Diisocyanate may cause
lung damage, loss of memory, loss of coordination, defatting of the skin, dermatitis,
and conjunctivitis.
Inhalation Harmful if inhaled. May cause lung injury. May cause mucous membrane and
respiratory tract irritation, tightness of chest, headache, shortness of breath and dry
cough. May cause asthma-like symptoms to occur. Vapors may affect the brain or
nervous system causing dizziness, headache or nausea.
Eyes Causes severe eye irritation. Avoid contact with eyes.
Skin Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion Harmful if swallowed. May cause abdominal pain, nausea, vomiting, diarrhea, or
drowsiness.
Chronic effects
5. Fire-fighting measures
5.1. Extinguishing media
Appropriate Water in form of fog, Co2, foam or dry chemical dust.
Extinguishing Methods
Inappropriate Direct water spray into fire
Extinguishing Methods
Specific Hazards Can liberate toxic fumes or gases during the burning. For decomposition see section
10.
5.2. Special hazards arising from the substance or mixture
Special Methods Evacuate the area and to fight the fire at a safe distance upwind. Use water in fog to
cool containers near the fire. Keep runoff from entering sewer. Extinguishing water
must be disposed according to local legislation.
5.3. Advice for fire-fighters
Firefighter Protection In fire case, to use personal respiratory device and suits for protection.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions ELIMINATE ALL IGNITION SOURCES (no smoking, flares, sparks or flames in
immediate area). Use only non-sparking equipment to handle spilled material and
absorbent. Do not touch or walk through spilled material.
Public Safety Call Suatrans Cotec 0800 7071 767 or 0800 7077 022 or 0800 17 2020 or 55*2*7500
(24 hr) for emergency response. Isolate spill or leak area immediately for at least 25
to 50 meters in all directions. Keep unauthorized personnel away. Stay upwind. Keep
out of low areas. Ventilate closed spaces before entering. LARGE SPILLS: Consider
initial downwind evacuation for at least 300 meters. Stop leak if you can do so
without risk. Prevent entry into waterways, sewers, basements or confined areas. A
vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry
earth, sand, or other non-combustible material and transfer to containers. Use
non-sparking tools to collect absorbed material.

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6.2. Environmental precautions
Environmental Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
Precations basements or confined areas. A vapor suppressing foam may be used to reduce
vapors. Absorb or cover with dry earth, sand, or other non-combustible material and
transfer to containers. Use non-sparking tools to collect absorbed material.
6.3. Methods and material for containment and cleaning up
Clean Up Method Cover with sand or other non-cumbustible material. Transfer absorbed material with a
non-sparking tool.
7. Handling and storage
7.1. Precautions for safe handling
Handle the packages with care in order to avoid damage and spillage.
Be aware of the precautions referred to on the label.
Avoid contact with the eyes and the skin. Avoid swallowing of vapor and the pulverizations. Be aware of the
precautions referred to on the label. Use personal protection equipment according to the section 8.
No smoking, drinking or eating in the application areas.
All the ignition sources (hot surfaces, sparks, unprotected flames, etc.) must be excluded from the areas of
manufacturing and application. The storage areas, the preparation and the application must be well ventilated.
The product can be carried electrostatically. Always use grounding cables when transferring solvents or
product. The operators must use adequate outfits which shall not develop static current. (at least 60% of
natural fiber) and anti-static shoes.
Solvents based products: The solvent vapors are heavier than the air and can concentrate on the floor and
explosive mixtures may be formed with the air .
Water based products: It does not require special cares for not being inflammable or explosive. Use only the
indicated personal protection equipments.

7.2. Conditions for safe storage, including any incompatibilities

Store between 40-100F (4-38C).

8. Exposure controls and personal protection

8.1. Control parameters
Exposure
CAS No. Ingredient Source Value
0000123-86-4 BUTYL ACETATE ACGIH 150 ppm TWA200 ppm STEL
Brazil
0000822-06-0 Hexamethylene diisocyanate ACGIH 0.005 ppm TWA
Brazil
0028182-81-2 Hexamethylene diisocyanate ACGIH
homopolymer Brazil
0064742-95-6 Petroleum naphtha ACGIH
Brazil

Health Data
CAS No. Ingredient Source Value
0000123-86-4 BUTYL ACETATE NIOSH Mucous membrane and eye irritation; high
concentrations cause nervous
system effects in animals
0000822-06-0 Hexamethylene diisocyanate NIOSH Respiratory effects and
sensitization pulmonary irritation (Listed
under
0028182-81-2 Hexamethylene diisocyanate NIOSH
homopolymer
0064742-95-6 Petroleum naphtha NIOSH

Carcinogen Data
CAS No. Ingredient Source Value
0000123-86-4 BUTYL ACETATE OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No;
Group 4: No;
0000822-06-0 Hexamethylene OSHA Select Carcinogen: No
diisocyanate NTP Known: No; Suspected: No
IARC

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Group 1: No; Group 2a: No; Group 2b: No; Group 3: No;
Group 4: No;
0028182-81-2 Hexamethylene OSHA Select Carcinogen: No
diisocyanate NTP Known: No; Suspected: No
homopolymer
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No;
Group 4: No;
0064742-95-6 Petroleum naphtha OSHA Select Carcinogen: No
NTP Known: No; Suspected: No
IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No;
Group 4: No;

8.2. Exposure controls

Respiratory Protection Select equipment to provide protection from the ingredients listed in Section 3 of this
document. Ensure fresh air entry during application and drying. If you experience eye
watering, headache or dizziness or if air monitoring demonstrates dust, vapor, or mist
levels are above applicable limits, wear an appropriate, properly fitted respirator
(NIOSH approved) during and after application. Follow respirator manufacturer's
directions for respirator use.
Eye and face Avoid contact with eyes. Protective equipment should be selected to provide
protection protection from exposure to the chemicals listed in Section 8 of this document.
Depending on the site-specific conditions of use, safety glasses, chemical goggles,
and/or head and face protection may be required to prevent contact. The equipment
must be thoroughly cleaned, or discarded after each use.
Skin and body Protective equipment should be selected to provide protection from exposure to the
protection chemicals listed in Section 8 of this document. Depending on the site-specific
conditions of use, protective gloves, apron, boots, head and face protection may be
required to prevent contact. The equipment must be thoroughly cleaned, or discarded
after each use.
Engineering Controls Prevent build-up of vapors by opening all windows and doors to achieve
cross-ventilation.
Special Precations Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure. Use good personal hygiene practices.
Wash hands before eating, drinking, using toilet facilities, etc. Promptly remove soiled
clothing and wash clothing thoroughly before reuse. Shower after work using plenty of
soap and water.
9. Physical and chemical properties
Appearance Yellow Liquid
Odour threshold Not Measured
pH No Established Limit
Melting point / freezing point Not Measured
Initial boiling point and boiling range 146 (°C) 295 (°F)
Flash Point 50 (°C) 122 (°F)
Evaporation rate (Ether = 1) Not Measured
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: No Established Limit
Upper Explosive Limit: No Established Limit
Vapour pressure (Pa) Not Measured
Vapor Density Heavier than air
Specific Gravity 1.06
Solubility in Water Not Measured
Partition coefficient n-octanol/water (Log
Not Measured
Kow)
Auto-ignition temperature Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) No Established Limit Not Measured
Refer to the Technical Data Sheet or label where information is
VOC %
available.

10. Stability and reactivity

10.1. Reactivity
Keep away from alkaline or strong strong acid to prevent probable exothermal reactions.

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10.2. Chemical stability
This product is stable
10.3. Possibility of hazardous reactions
Dangerous Polymerization will not occur. Heat and vapors in excess can be generated when inproperly used.
10.4. Conditions to avoid
Keep away from alkaline or strong strong acid to prevent probable exothermal reactions.
Strong oxidizing agents
10.5. Incompatible materials
Strong oxidizing agents
10.6. Hazardous decomposition products
Can liberate toxic vapors in the welding process. The vapors can produce Dioxide and Monoxide of Carbon.
11. Toxicological information
Acute toxicity

NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling
the contents may be harmful or fatal. No additional information provided for this product. See Sections 3 and 8
for chemical specific data.

Ingredient Oral LD50, Skin LD50, Inhalation Inhalation

mg/kg mg/kg Vapor LD50, Dust/Mist LD50,
mg/L/4hr mg/L/4hr
Hexamethylene diisocyanate - No data No data No data No data available
(822-06-0) available available available
Hexamethylene diisocyanate 5,000.00, Rat - No data No data 3.00, Rat -
homopolymer - (28182-81-2) Category: 5 available available Category: 4
Petroleum naphtha - (64742-95-6) 6,800.00, Rat - 3,400.00, No data No data available
Category: NA Rabbit - available
Category: 5
BUTYL ACETATE - (123-86-4) 10,700.00, Rat 17,600.00, No data No data available
- Category: NA Rabbit - available
Category: NA

Item Category Hazard

Acute Toxicity (mouth) Not Classified Not Applicable
Acute Toxicity (skin) Not Classified Not Applicable
Acute Toxicity (inhalation) Not Classified Not Applicable
Skin corrosion/irritation 2 Causes skin irritation.
Eye damage/irritation 2 Causes serious eye irritation.
Sensitization (respiratory) 1 May cause allergy or asthma symptoms of
breathing difficulties if inhaled.
Sensitization (skin) 1 May cause an allergic skin reaction.
Germ toxicity Not Classified Not Applicable
Carcinogenicity Not Applicable
Reproductive Toxicity Not Applicable
Specific target organ systemic toxicity 3 May cause respiratory irritation.
(single exposure)
Specific target organ systemic Not Applicable
Toxicity (repeated exposure)
Aspiration hazard Not Classified Not Applicable

12. Ecological information

12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations
Directive 199/45/CE and is classified according to the same as for the environment. For details, see sections
8 and 11. There are no data available on the product. Avoid contamination of drains or watercourses

Aquatic Ecotoxicity

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96 hr LC50 fish,
48 hr EC50 crustacea, ErC50 algae,
Ingredient
mg/l mg/l mg/l
Hexamethylene diisocyanate - 82.80, Danio rerio 89.10, Daphnia 77.40 (72 hr), Desmodesmus
(822-06-0) magna subspicatus
Hexamethylene diisocyanate 100.00, Danio rerio 100.00, Daphnia
homopolymer - (28182-81-2) magna 100.00 (72 hr), Scenedesmus
subspicatus
Petroleum naphtha - 6.14, Daphnia magna 19.00 (72 hr), Selenastrum
(64742-95-6) 9.22, Oncorhynchus capricornutum
mykiss
BUTYL ACETATE - (123-86-4) 18.00, Pimephales 32.00, Artemia salina
promelas 674.70 (72 hr), Scenedesmus
subspicatus

12.2. Persistence and degradability

No data available
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available

13. Disposal considerations

13.1. Waste treatment methods

General Note: Disposal must be in accordance with the federal, state and local regulations.
Method of treatment Product: The treatment and the disposal of the product must in accordance the local
and disposal legislation.
Remaining portions of the product: Residues that will not be used must be discarded
in accordance the local legislation. Used packing: Do not reuse the packing. Recycle
if appropriate or discard in accordance the local legislation.
14. Transport information

14.1. UN number UN 1263

14.2. UN proper shipping name PAINT RELATED MATERIAL
14.3. Transport hazard class(es)

Domestic Surface Transportation IMO / IMDG (Ocean Transportation)

Proper Shipping PAINT RELATED IMDG Proper PAINT RELATED
Name MATERIAL Shipping Name MATERIAL
Hazard Class 3 IMDG Hazard Class 3 - Flammable and
Combustible liquid
UN / NA Number UN 1263 UN / NA Number UN 1263
Packaging Group III IMDG Packing Group III
CERCLA/DOT RQ 11 gal. / 100 lbs. System Reference 3
Code
Risk Number 30 EMS F-E,S-E
Marine Pollutant No
Air Transport (ICAO-ITI / IATA-DGR)
Proper Shipping PAINT RELATED
Name MATERIAL
Hazard Class 3
UN / NA Number UN 1263
Packaging Group III

14.4. Packing group III

14.5. Environmental hazards

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IMDG Marine Pollutant: No

14.6. Special precautions for user

Not Applicable
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable
15. Regulatory information
Regulatory Overview Decreto 2.657, from 3/07/98, regarding the Safety in the Utilization of Chemical
Products at Work.
Act # 96.044 of 18/05/88. Regulations of Road Transport of Dangerous Products.
Decreto 1.797, of 25/01/1996, Bill of Hazardous Products in the Mercosul range.
Resolution ANTT # 420, of 12/02/2004: complementary instructions to the Regulation
of Road Transport of Hazardous Products.
Decreto 3214 of MTE
NBR 7500: Identification for the road transport, the handling, the moving and the
storage of products.
NBR 7501: Terminology Transport of Hazardous Products.
NBR 7503: Road transport of hazardous products emergency form and envelope
Features, dimensions and filling.
NBR 9735: Set of equipments for Emergency in the Road Transport of Hazardous
Products Procedures. All ingredients of this product are listed on the TSCA (Toxic
Substance Control Act) Inventory or are not required to be listed on the TSCA
Inventory.
WHMIS Classification B3 D2A

16. Other information

The information contained in this Material Safety Data Sheet (MSDS) has the purpose of being a description
of the product safety requirements, which were obtained from the literature and current legislation specific
about raw materials/ingredients. Thus, the accuracy of the data contained herein is not, expressly or implicitly,
assured by the Manufacturer. The product shall not be used for purposes other than the ones specified by the
Manufacturer. The user is always liable for taking all required measures to comply with the provisions in this
MSDS, as well as with the requirements expressed in the regulations and effective legislation.
Bibliographic references:
- Council Directive 67/548/EEC of June 27, 1967.
- Work and Job department clause # 3.214 of June 08, 1978.
- ABNT NBR 14725 (parts I,II,III and IV) Chemical products Information on safety, health and
environment.
Specific use: product meant only for professional use, check the product data sheet.
CAS: Chemical Abstract Service register number It s a register number indicated by the American
Chemical Society, which identifies only a specific chemical component.

PHA046_A3
End of Document
Your attention is drawn to the disclaimer on the Product Data Sheet which with
this Safety Data Sheet and the package labelling comprise an integral information
system about this product. Copies of the Product Data Sheet are available from
International Paint on request or from our Internet sites : www.yachtpaint.com ,
www.international-marine.com, www.international-pc.com

PHA046 - SDS Revision Number: A3 - SDS Revision Date: 07/24/2012 8/8