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With dedication, these resources will help you prepare for the MDCAT without any cost Don't let financial constraints hold you back. At Prep Titans, we're here ° sa ree to success! Your Well reas = PREP TITANS! iS G 6S 3%WwW KIPSimres UNIT-8 (A-SERIES) TOPIC: FUNDAMENTAL PRINCIPLES OF ORGANIC CHEMISTRY v CHEMISTRY OF HYDROCARBONS Q.1 Types of carbon atom in iso-butane is/are A. Primary only B. Primary and Secondary C. Primary and Tertiary D. Primary. Secondary and Tertiary Q.2_ Which functional groups can show chain isomer A. Alkane only B. Alkyl halide and alcohol C. Aldehyde and carboxylic acids D. All can show Q.3 Which functional group is present in the given structure. HCOOCHs A Carboxylic acid Bokister © Aldehyde D. Ketone Q.4 Number of sigma bonds in propane formed by sp?-sp! overlapping are AA B2 C3 D4 Q.5 In which functional group nitrogen atom is sp? hybridized A.-CN B-CONH: C.C-NH D. NO; Q.6 2-Methylpropene reacts with HBr to give A. Iso-butyl bromide B Tent. butyl bromide C. See. butyl bromide D. None of these Q.7 Which reagent can be used to distinguish between Iso-butane and Iso-butylene A. Ammoniacal silver nitrate B. 1% Alkaline KMnOs C.BniCCh D, Both Band C Q.8 Which of the following statements are correct concerning delocalized electrons: A. Blectrons donot belong to a single atom rons are shared by three or more atoms D. All are correct Q.9 Molecular formula of Phenanthrene is A Cite B Cully ©. Cultix D Cullo Q.10 Starting with 2-butene, which of the following are more suitable preparing 2-Butyne agents for A. HBr: HYNi; Za B. HBr, Zvil% HeNi © BryCCh: ZW": HYNi 2 Will not give substitution reaction A. Acetylene B. Ethane: ©. Propene D. Benzene Q.12_ Which type of isomerism can exhibit by Propen-2-ol and acetone A. Position B. Tautomerism C Metamensm D. Skeletal isomerism . Q.13_ Which of the following compounds will react most readily with bromine in cc A. CHSCH.CHy B (ClCH C. CH: = CHCH) D.(CH uC Q.14 Which of the following statements about ethene, C2Hs, is incorrect A, H-C-II bond angles are approximately 109.5° B. There is a total of five sigma bonds. C. The carbon atoms are sp? hybridized. D. The H-C-H bond angles are approximately 120° CHEMISTRY MOCAT UNIT-8 (A-SERIES) PAGE 10F44 ENTRY TESTS 7 rene? Ws KIPS[Eretest ee nED 2g ~ af} 2 Q.1S Which compound is not a functional group isomer of the other three A. Acetone B. Propylene epoxide C. Acetaldehyde D. Propen-2-ol Q.16 In which of the following reaction benzene ring is retained A, Chlorination in sunlight B. Catalytic oxidation C. Chlorination with FeCl D. Hydrogenation Q.17 Which of the following are the isomers of CsHoOH A. 1-Butanol. jutanol. Iso-butyl alcohol Qs Qs Q.20 Q2 Q.22 Q.23 Q24 Q.26 Q27 Q.28 Q29 Q30 B. 1-Butanol, 2-Methyl-1-propanol, 2-Butanol CC. 1-Butanol, 2-Butanol, 2-Methyl-1-propanol, 2-Methyl-2-propanol D. 1-Butanol, 2-Butanol. Iso-propy! aleohol, Tert. Butyl alcohol A compound of formula C3Hx does not react with bromine in CCl in the dark, The compound could be A. Alkane ByAlkene C. Cycloalkane D, Cycloalkene Geometric isomerism is shown by A. Lactic acid B. 1-Butene C. 1.1-Dicholoroethene D. Mak What is the predieted|shape, bond angle, and hybridization forCH; A. Trigonal planar, 120°, sp? B. Trigonal planar, 120°. sp* C. Trigonal planar, 109.5% sp* D. Trigonal pyramidal, 120°, sp? Bromination of benzaldchyde is the type of reaction A. Electrophilic adi B. Nucleophile addition C. Electrophilic substitution D. Nucleophilic substitution A compound with molecular formula CcH12 can add only one mole of hydrogen in presence of Ni-catalyst, the compound is ‘A. Hexene B/Hexyne C, Benzene D.Cyclohexene Identify the group when substituted on benzene, makes benzene more reactive towards electrophile é A.-OCH3 B.NO: c. -CHs D. Alll are equal reactive Which pair does not show metamerism A. Methoxy propane and Ethoxy ethane B, Methyl n-propyl ketone and Diethyl ketone C.n-Propyl amine and Ethyl methyl amine D. All of above Chlorine free radicals react with methane by : A. Donating their free-radical electron to methane to form chloromethane B. Abstracting a hydrogen atom from methane, and producing HC! and a methyl radical C. Forming a carbanion intermediate that rapidly dissociates to produce chloromethane D. Forming a carbonium ion intermediate that rapidly dissociates to form chloromethane IUPAC name of the compound HC = C - CH: - CH = CH: A. 1-Penten-4-yne B. 4-Penten-I-yne C. 2-Penten-3-yne D. 1-Pentyn-2-ene Which isomerism is possible for 2-Chloro-3-methylbutane ‘A. Functional group isomerism B. Metamerism C. Cis-trans isomerism D. Positional isomerism The order of reactivity of halogens when they react with alkanes A. > Fr > Cl > Bre B.h>Ch>Br>F C.h> Br > Ch > Fr D. Br CH2=CH2, reagent is used for the reaction A. Aq. KOH B, Ale. KOH C. ZnClz * D. P20s CHEMISTRY MDCAT UNIT-8 (A-SERIES) PAGE 20F 4wy KIPSists (POF Q31 Q.32 Q.33 Q34 Q35 Q36 Q.37 Q38 Q39 Q40 Qa41 Q.42 Q.43 Q44 Q4s Q.46 ; = TUPAC name of isobutylene is A. 2-Methyl-1-butene B, 2-Methyl-I-propene C. 2-Butene D. 2-Methyl-2-propene Which of the following is free radical ACI B.NO:' Gal p.cr The hydrocarbon which does nof show acidic nature is A. Ethyne B. Propyne C. 2-Butyne D. 1-Butyne Butanone is the product, when 1-butyne.reacts with HzO in the presence of H2SO4/HgSOs, this reaction proceeds through the formation of A. 1-Butanol B.2-Butanol , C. Buten-2-ol D. Butten-1-o1 Acetylene + 2HBr <> “X”, what is “X" in given reaction A. 1.2-Dibromoethane B. 1, 1-Dibromoethane C. 1,1-Dibromoethene D. 1.2-Dibromoethene Which of the following issmost reactive A. Butane B. Butyne C. Butene D.Benzene All of the following are fused ring aromatic’compounds except one A. Naphthalene . B. Anthracene C. Diphenylmethane B. Phenanthrene When 1,2-Dichloropentane are treated with zinc dust, we get A. 1-Pentene B. 2-Pentene G..1-Pentyne D.2-Pemyne Reduction of benzene by using Pt occur in presence of. ‘A. CH;COOH B. HCHO C. CH30H D. ZnCh The nitration of benzene take place when it is heated with Cone. HNOs and Cone. H2SOs in, ALI Bnie2) Cc. De1:3, 1,3-Cyclopentadiene is an example of A. Aromatic compounds i B. Acyclic compounds C. Homoeyclic compounds D. Heterocyclic compounds ‘The IUPAC name of CHs ~ CH(C2Hs)- CH2— C(CH3)2 — CH -Dimethyl 4-ethyl pentane . 2,2-Dimethy! heptane C. Iso-Octane D. 2,2, 4-Trimethyl hexane Saturated hydrocarbons show chain isomerism and the first hydrocarbon which show this phenomenon has at least carbons A2 lames C4 DES Imino group is present in ‘A. CH3NH2 B, HCONH2 C.CH2= NH D. (NH2)2CO Which one of the following compounds is heterocyclic A. Anthracene B. Phenol C. Pyridine D. Aniline 5 All can be used as dehydrating agents for dehydration of alcohols except A. Al03 B. Dilute H2SO4 C. PsO10 D. Allof these CHEMISTRY MDCAT UNIT-8 (A-SERIES) 5 PAGE 3.OF 4, eae yoy KIPS [ENT TESTS “x 2 QA7_ In the addition of HBr to propene, Jrhich one will be added first AH B.Br c.Brt D. H® Q.48_ Least reactive compound towards electrophilic substitution reaction A. Chlorobenzene B. Phenol C. Benzene D. Benzoic acid Q.49 During initiation step for chlorination of methane, the bond that undergoes homolytic cleavage to produce free radical is A. CI-Cl B.O-H ccc D.H-H Q.50 When ethene is polymerized, polyethene is formed, mark correct statement about this reaction A. No pi bond in polyethene! B. Each C issp’ hybrid C. Molecular mass of polyethene is multiple ofethene D. Alll are correct Q51: When benzene is treated with CH3Clin the presence of AICb, toluene is the product, new bond formed is A.C-C B.C-O - GO=0 D.O-H Q.52_ 2,2,3,3 tetrabromobutane when treated with Zn in the presence of CHsOH, product formed is A. Butane B. 2-Butene C. 1-Butyne D. 2-Butyne Q53_ In Electrophilic addition reaction of alkyne, A.No change of hybridization occurs B. No hiange of molecular mass occurs C.Pijbondiisiconvertedinto sigma bond. D#Allare correct Q.54 The central carbon atom of methyl free radical contains A. 6-electrons, B. 8-clectrons C. 7-electrons D. 3-electrons Q55 All of the following alkene adds HBr, and gives a product according to ie 3 rule except A. Propene B. 1-Butene C..3-Methyl-1-butene D. 2,3-Dimethyl-2-biitene Q.56 The IUPAC name of divinyl acetylene is A. 1,5-Hexadiehe-3-yne B, 1,4-Pentadiene C. 1,5-Hexadiene D. None of the above Q.57 Which one of the following is polycyclic aromatic hydrocarbons A. p-Diphenyl benzene B. Anthracene - C. Biphenyl D, All of these Q.58- Ethyl phenyl ketone is produced by reaction of benzene with in presence of AICh A. Ethanoyl chloride +B. Propyl chloride C. Ethyl chloride D. Propangyl chloride Q.59 In 1,4-Pentadiene the ratio of o and x bonds are AT B.6:1 C.1:6 D.1:7 Q.60 The namés of functional groups in the following compound X are cu.cucomcu, cHicn A. Primary alcohol, nitrile and benzene ring B. Secondary alcohol, nitrile and aryl ring C. Secondary alcohol, nitrile and phenol ring D. Secondary-alcohol, amine’and benzene ring CHEMISTRY MDCAT UNIT-8 (A-SERIES) i PAGE 4OF 4KIPS PREPARATIONS bi ©OO©OOOEOHGOB8OOO ©OGOGOOEODOOOOO @OOOOQOOOQOOOOOS®O ©OO@OQOOQOOOGOOOO aAanOoANMS Trqunuwmumnwnn ® ©OOOQOQOOOHBOOOHOOO ©OOSOOOOODOOOOOS® ©0©00900900000008 QOOQOOOOQOEDOHOOOOO tN mM nwo hr. et nw QO©OOOQOOQOHOOOSSOO 08090080080 900090 QOOQOQOQOEODOGOOOOS GOB OOOLHOQOHOQOOO wn eonod ©8O©OQOQOOGOBOHOOO BLOQQOOOOOQOOO8O ©O©OOSEOQOOQOHOGHOOO COOQQEOOQOQOOGOLO 24 2s 26 27 ANmMeNonwaagAaagangsy CH/UNIT# 08 Cc SUBJECT:Prep Titans 3 MDCAT Community - 4 groups i) es pat Tics Nolen) el 16) Add groups (Ng Announcements Let's Turn Dreams into Stethoscopes *\! 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