SDS # 536

Safety Latest Revision: May 2017

Data Page 1 of 9
Sheet Selectrode Industries, Inc.
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1. PRODUCT AND COMPANY IDENTIFICATION:
PRODUCT NAME: 1221, 1225
MANUFACTURER: Selectrode Industries, Inc.
230 Broadway
Huntington Station, NY 11746 U.S.A.
Phone: 631-547-5470
Fax: 631-547-5475
E-mail: [email protected]
EMERGENCY TELEPHONE NUMBER: 631-547-5470
___________________________________________________________________________________
2. HAZARD IDENTIFICATION:
Emergency Overview: This product is normally not considered hazardous as shipped. Avoid eye contact or inhalation of
dust from the product. When this product is used in a welding process, the most important hazards are welding fumes, heat,
radiation and electric shock.
Classification of the Substance/Mixture

CLP/GHS Classification (1272/2008):

Skin Sensitization, Category 1
Respiratory Sensitization, Category 1
Carcinogenicity, Category 2
Specific Target Organ Toxicity (Repeated Exposure), Category 1
Hazardous to the Aquatic Environment – Chronic Hazard, Category 4

EU Classification (67/548/EEC):
Toxic (T), Harmful (Xn), Irritant (Xi), Dangerous for the Environment (N), Carcinogen Category 3, R48/23, R40,
R42/43, R43, R53

Hazardous Classification per 29CFR 1910.1200 (Rev. July 1, 2012):

Skin Sensitization, Category 1
Respiratory Sensitization, Category 1
Carcinogenicity, Category 2
Specific Target Organ Toxicity (Repeated Exposure), Category 1
Hazardous to the Aquatic Environment – Chronic Hazard, Category 4

Labelling:

Symbols:
Signal Word: Danger
Hazard Statements:
H317 – May cause an allergic skin reaction.
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H351 – Suspected of causing cancer.
H372 – Causes damage to respiratory system, eyes, brain and nervous system through prolonged or repeated exposure.
H413 – May cause long lasting harmful effects to aquatic life.
Precautionary Statements:
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P260 – Do not breathe dust/fume/gas/mist/vapours/spray.
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P264 – Wash skin and hair thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear protective gloves/eye protection/face protection.
P281 – Use personal protective equipment as required.
P285 – In case of inadequate ventilation wear respiratory protection.
P302+P352 – IF ON SKIN: Wash with plenty of soap and water.
P304+P341 – IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P308+P313 – IF exposed or concerned: Get medical advice/attention.
P314 – Get medical advice/attention if you feel unwell.
P333+P313 – IF skin irritation or rash occurs: Get medical advice/attention.
P342+P311 – If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P363 – Wash contaminated clothing before reuse.
P405 – Store locked up.
P501 – Dispose of contents/container in accordance with local/regional/national/international regulations.
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3. COMPOSITION / INFORMATION ON INGREDIENTS:
Chemical CAS # Range OSHA PEL ACGIH-TLV Carcinogenicity EU Classification CLP/GHS Hazardous
Identity % (mg/m3) (mg/m3) (67/548/EEC) Classification Classification per
(1272/2008) 29CFR 1910.1200
(Rev. July, 2012)
Calcium 1317-65-3 1-11 5 ( as CaO ) 10 No Not Dangerous Not Hazardous Not Hazardous
Carbonate
#Chromium 7440-47-3 15-25 1.0 (Metal) 0.5 ((Metal) Yes
.05 (Cr II & Cr 0.5 (Cr IIII
Not Dangerous (H400) Aquatic (H400) Aquatic
IIII Compounds) Acute 1 Acute 1
Compounds) 0.05(Cr VI
0.005(Cr VI Soluble
Compounds) Compounds)
0.01 ( Cr VI
Insoluble
Compounds)
#Manganese 7439-96-5 .3-5 5 1 No
(Xn) R48 (H373) STOT (H373) STOT
RE 2 RE 2
#Nickel 7440-02-0 1-7 1 1 Yes Carc. Cat. 3 (H317) Skin (H317) Skin
(Xn) R40 Sens. 1 Sens. 1
(H351) Carc. 2 (H351) Carc. 2
(Xi) R43
(H372) STOT (H372) STOT
(T) R48/23
RE 1 RE 1
Titanium 13463-67-7 5-15 15 10 No Carc. Cat. 3 (H351) Carc. 2 (H351) Carc. 2
Dioxide
(Xn) R40
Molybdenum 7439-98-7 .05-9 15 10 No
(H228) Flam. (H228) Flam.
(F) R11
Sol. 1 Sol. 1
Potassium 1312-76-1 1-11 NR 5 No (H315) Skin (H315) Skin
Silicate (Xi) R36/38 Irrit.. 2 Irrit.. 2
(H319) Eye (H319) Eye
Irrit.. 2A Irrit.. 2A
Iron 7439-89-6 1-5 10 ( as Fe2O3 ) 5 ( as Fe2O3 ) No
Not Dangerous Not Hazardous Not Hazardous
Potassium 12030-97-6 1-11 NR NR No Not Dangerous Not Hazardous Not Hazardous
Titanate
Silicon 14808-60-7 1-11 .1 .1 Yes (Xn) R48/20 (H373) STOT (H373) STOT
Dioxide
RE 2 RE 2
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#Cobalt 7440-48-4 30-40 .05 .02 No (Xn) (H317) Skin (H317) Skin
R42/43 Sens. 1 Sens. 1
(H334) Resp. (H334) Resp.
(N) R53
Sens. 1 Sens. 1
(H413) Aquatic (H413) Aquatic
C. 4 C. 4
Tungsten 7440-33-7 0-10 5 5 No (H228) Flam. (H228) Flam.
(F) R11
Sol. 1 Sol. 1
(Xi) R36/38 (H315) Skin (H315) Skin
Irrit.. 2 Irrit.. 2
(H319) Eye (H319) Eye
Irrit.. 2A Irrit.. 2A
Important This section covers the materials of which the products manufactured. The fumes and gases produced during normal use of this product are covered in section 10.
The term “Hazardous” in “Hazardous Material” should be interpreted as a term required and defined in OSHA Hazard Communication Standard 29CFR 1910-1200 and it does
not necessarily imply the existence of hazard. The chemicals or compounds reportable by Section 313 of SARA are marked by the symbol #.
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4. FIRST AID MEASURES:
Inhalation: Remove to fresh air immediately or administer oxygen. Get medical attention immediately.
Skin: Flush skin with large amounts of water. If irritation develops and persists, get medical attention.
Eye: Flush eyes with water for at least 15 minutes. Get medical attention.
Ingestion: Obtain medical attention immediately if ingested. Rinse mouth.
Electric Shock: Disconnect and turn off the power. Use a nonconductive material to pull victim away from contact with live
parts or wires. Immediately contact a physician.
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5. FIRE-FIGHTING MEASURES:
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Welding arcs and
sparks can ignite combustible and flammable materials. Use the extinguishing media recommended for the burning material
and fire situation.
Unsuitable Extinguishing Media: Not applicable
Specific Hazards Arising From Chemical: Arcs and sparks can ignite combustibles and flammable products. Iron
Oxides, Manganese/manganese oxides, Chromium oxides, Nickel/nickel oxides, Molybdenum oxide, Tungsten, Cobalt/cobalt
oxides
Protective Equipment: Fire fighters should wear complete protective clothing including self-contained breathing apparatus.
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6. ACCIDENTAL RELEASE MEASURES:
Personal Precautions: Refer to section 8.
Environment Precautions: Refer to section 13.
Cleaning Measures: Solid objects may be picked up and placed into a container. Liquids or pastes should be scooped up
and placed into a container. Wear proper protective equipment while handling these materials. Do not discard as refuse. Do
not allow product to reach sewage system.
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7. HANDLING AND STORAGE:
Precautions for Safe Handling: Handle with care to avoid stings or cuts. Wear gloves when handling welding
consumables. Avoid exposure to dust. Do not ingest. Some individuals can develop an allergic reaction to certain materials.
Retain all warning and identity labels.
Conditions for Safe Storage: Store in dry place in closed packages. Keep separate from chemical substances like acids
and strong bases, which could cause chemical reactions.
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8. EXPOSURE CONTROLS/ PERSONAL PROTECTION:
Engineering Controls: Avoid exposure to welding fumes, radiation, spatter, electric shock, heated materials and dust.
Ensure sufficient ventilation, local exhaust, or both, to keep welding fumes and gases from breathing zone and general area.
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Keep work place and protective clothing clean and dry. Train welders to avoid contact with live electrical parts and insulate
conductive parts. Check condition of protective clothing and equipment on a regular basis.
Exposure limits: Use industrial hygiene equipment to ensure that exposure does not exceed applicable national exposure
limits. The limits defined under section 3 can be used as guidance. Unless noted, all values are for 8 hour time weighted
average. For information about welding fume analysis refer to section 10.
Biological limits: No available data
Personal protection:
Respiratory protection: Use an air purifying dust respirator when welding or brazing in a confined space, or when local
exhaust or ventilation is not sufficient to keep exposure values within safe limits.
Hands protection: Wear appropriate gloves to prevent skin contact.

EN 12477: Protection gloves for welders

Requirements (EN Type A Type B

Levels)
Abrasion (Cycles) 2 (500) 1 (100)
Cut (Factor) 1 (1.2) 1 (1.2)
Tear (Newton) 2 (25) 1 (10)
Puncture (Newton) 2 (60) 1 (20)
Burning Behaviour 3 2
Contact Heat 1 1
Convective Heat 2 -
Small Splashes 3 2
Dexterity 1 (11) 4 (6.5)

Type B gloves are recommended when high dexterity is required as for TIG welding, while type A gloves are
recommended for other welding processes. The contact temp (ºC) is 100 and the threshold time (seconds) >15.
Eyes protection: Welder’s helmet or face shield with colour absorbing lenses. Shield and filter to provide protection from
harmful UV radiation, infra red and molten metal approved to standard EN379. Filter shade to be a minimum of
shade 9.
Skin protection: Heat-resistant protective clothing. Wear safety boots, apron, arm and shoulder protection. Keep
protective clothing clean and dry. Clothing should be selected to suit the level, duration and purpose of the welding activity.

Class 1
Impact of Spatter 15 Drops
Heat Transfer (radiation) RHTI 24 ≥ 7 seconds
Process Manual welding with light formation of spatter and drops
• Gas Welding
• TIG Welding
• MIG Welding
• Micro plasma welding
• Brazing
• Spot Welding
• MMA Welding (with rutile-covered electrode)
Environmental Operation of machines
Conditions • Oxygen cutting machines
• Plasma cutting machines
• Resistance welding machines
• Machines for thermal spraying
• Bench welding
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Class 2
Impact of Spatter 25 Drops
Heat Transfer (radiation) RHTI 24 ≥ 16 seconds
Process Manual welding with heavy formation of spatter and drops
• MMA welding (with basic or cellulose-covered electrodes)
• MAG welding (with CO2 or mixed gases)
• MIG Welding (with high current)
• Self shielded flux core arc welding
• Plasma cutting
• Gouging
• Oxygen cutting
• Thermal spraying
Environmental Operation of machines
Conditions • In confined spaces
• At overhead welding/cutting or in comparable constrained
positions
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9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance: Solid.
Color: Grey 1225/ Grey
Odour: Odourless
Odour Threshold: Not Available
pH Value: Not Available
Melting Point/Melting Range: 2200 - 2500° F, 1204 - 1370° C
Freezing Point: Not Available
Boiling Point/Boiling Range: Not Available
Flash point: Not Available
Evaporation Rate: Not Available
Self-in flammability: Not Available
Explosion limits: Not Available
Vapour pressure: Not Available
Vapour density: Not Available
Density at 20ºC: Not Available
Relative density: 6-9 g/cm3
Solubility: Insoluble in water.
Partition coefficient: Not Available
Auto-ignition temperature: Not Available
Decomposition temperature: Not Available
Other Information: No available data.
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10. STABILITY AND REACTIVITY:
Chemical Stability: This product is stable under normal conditions.
Hazardous Reactions: Contact with chemical substances like acids or strong bases cause generation of gas.
Conditions to Avoid: Not applicable.
Incompatible Materials: Reacts with acid.
Hazardous Decomposition Products: When this product is used in a welding process, hazardous decomposition product
would include those from volatilization, reaction or oxidation of the material listed in section 3 and those from the base metal
and coating. The amount of fumes generated from this product varies with welding parameters and dimensions.
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Refer to applicable national exposure limits for fume compounds, including those exposure limits for fume compounds found in
section 3. Manganese has a low exposure limit, in some countries that may be easily exceeded. Reasonably expected
gaseous products would include carbon oxides, nitrogen oxides and ozone. Air contaminants around the welding area can be
affected by the welding process and influence the composition and quality of fumes and gases produced.
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11. TOXICOLOGICAL INFORMATION:
Signs and Symptoms of Overexposure: Inhalation of welding fumes and gases can be dangerous to your health.
Classification of welding fumes is difficult because of varying base materials, coatings, air contaminants and processes. The
Internal Agency for Research on Cancer has classified welding fumes as possible carcinogenic to humans (Group 2B).
Acute Effects: Overexposure to welding fumes may result in symptoms like metal fume fever, dizziness, nausea, dryness or
irritation of the nose, throat or eyes. Prolonged inhalation of crystalline silica may result in silicosis, a disabling pulmonary
fibrosis characterized by fibrotic changes and military nodules in the lungs, a dry cough, shortness of breath, emphysema,
decreased chest expansion and increased susceptibility to tuberculosis. May cause sensitisation by skin contact

LD/LC50 Values that are relevant for classification

Calcium Carbonate 1317-65-3
Oral LD50 >2000 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rat)
Inhalation LC50 >3 mg/L/4hr. (rat)

LD/LC50 Values that are relevant for classification

Chromium 7440-47-3
Oral LD50 19.8 mg/kg (rat) (highly toxic)

LD/LC50 Values that are relevant for classification

Manganese 7439-96-5
Oral LD50 9000 mg/kg (rat)

LD/LC50 Values that are relevant for classification

Nickel 7440-02-0
Oral LD50 >9000 mg/kg (rat)
Inhalation LC50 >10.2 mg/L/1 hr (rat)

LD/LC50 Values that are relevant for classification

Titanium Dioxide 13463-67-7
Oral LD50 >10000 mg/kg (rat)
Dermal LD50 >10000 mg/kg (rabbit)

LD/LC50 Values that are relevant for classification

Iron 7439-89-6
Oral LD50 30000 mg/kg (rat)

LD/LC50 Values that are relevant for classification

Molybdenum 7439-98-7
Oral LD50 4461 mg/kg (rat)
Inhalation LC50 5.1 mg/L/4hr. (rat)
Dermal LD50 >2000 mg/kg (rabbit)

LD/LC50 Values that are relevant for classification

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Cobalt 7440-48-4
Oral LD50 6171 mg/kg (rat)

Chronic Effects: Overexposure to welding fumes may affect pulmonary function and eyes. Overexposure to manganese and
manganese compounds above safe exposure limits can cause irreversible damage to the central nervous system, including the
brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and
spastic gait. Prolonged inhalation of titanium dioxide (Classified by 2B by IARC) above safe exposure limits can cause cancer.
Prolonged inhalation of crystalline silica (Classified 1 by IARC and K by NTP) above safe exposure limits can cause cancer.
Prolonged inhalation of cobalt (Classified 2B by IARC) above safe exposure limits can cause cancer.
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12. ECOLOGICAL INFORMATION:
Toxicity: Welding rods contain metals which are considered to be very toxic towards aquatic organisms. Finely divided
welding rods are therefore considered harmful to aquatic organisms.
Persistence and Degradability: The welding rods consist of elements that can not degrade any further in the environment.
Bio accumulative Potential: Welding rods contain heavy metals which bio accumulates in the food chain. The following
figures are the bio concentration factor (BCF) for the substances on their own.
BCF:
Chromium, BCF: 200
Manganese, BCF: 59052
Nickel, BCF: 16
Iron, BCF: 140000
Cobalt, BCF: 4000
Mobility in Soil: Welding rods are not soluble in water or soil. Particles formed by working welding rods can be transported
in the air.
Other Adverse Effects: In massive form, welding rods present no hazards to the aquatic environment.
Welding materials could degrade into components originating from the materials used in the welding process. Avoid exposure
to conditions that could lead to accumulation in soils or groundwater. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
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13. DISPOSAL CONSIDERATIONS:
Product: For product elimination, consult recycling companies or appropriate local authority.
USA RCRA: This product is not considered hazardous waste if discarded. Residue from welding consumables and processes
could degrade and accumulate in soils and groundwater. Welding slag from this product typically contains mainly the following
components originating from the coating of the electrode.
Package: May be disposed in approved landfills provided local regulations are observed.
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14. TRANSPORT INFORMATION:
UN-number: Welding rods are not classified as dangerous goods for transport and has no UN number.
UN proper shipping name: Welding rods are not classified as dangerous goods for transport and has no UN proper
shipping name.
Transport hazard class: Welding rods are not classified as dangerous goods for transport.
Packing group: There are not any special precautions with which a user should or must comply or be aware of in connection
with transport or conveyance either within or outside premises.
Environmental hazards: Welding rods are not environmentally hazardous according to the criteria of the UN Model
Regulations (as reflected in the IMDG Code, ADR, RID and AND) and/or a marine pollutant to the IMDG Code.
Special precautions for users: There are not any special precautions which a user should or must comply or be aware of
in connection with transport or conveyance either within or outside premises of the welding rod.
Transport in Bulk According to Annex III MARPOL 73/78 and the IBC Code: Welding rods in massive form do not
subject under MARPOL 73/78 and the IBC Code. Not applicable – product is transported only in packaged form.
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15. REGULATORY INFORMATION:
Safety, health and environment regulations/legislation specific for the substance or mixture: Read and understand the
manufacturer’s instructions, your employer’s safety practices and the health and safety instructions on the label. Observe any
federal and local regulations. Take precautions when welding and protect yourself and others.
Warning: Welding fumes and gases are hazardous to your health and may damage lungs and other organs. Use adequate
ventilation. Electric shock can kill. Arc rays and sparks can injure eyes and burn skin. Wear correct hand, head, eye and
body protection.
Chemical safety assessment: No
USA: Under the OSHA Hazard Communication Standard, this product is considered hazardous.
CALIFORNIA PROPOSITION 65: WARNING: This product contains chemicals including [Titanium Dioxide, Nickel,
Chromium, Cobalt], which are known to the State of California to cause cancer. For more information go to
www.P65Warnings.ca.gov.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [Chromium], which is
known to the State of California to cause birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov. (California Health & Safety Code § 25249.5 et seq.)
United States EPA Toxic Substance Control Act: All constituents of this product are on the TSCA inventory list or are excluded
from listing.
EPCRA/SARA Title III Toxic Chemicals
The following metallic components are listed as SARA 313 “Toxic Chemicals” and potential subject to annual SARA reporting.
See Section 3 for weight percentage.

Ingredient Name Disclosure Threshold

Chromium 1.0 (Metal)
Manganese 5 mg/m3
Nickel 1 mg/m3
Cobalt .05 mg/m3
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16. OTHER INFORMATION:
The information in this document is believed to be correct as of the date issued. However, no warranty is expressed to be
implied regarding the accuracy or completeness of this information. This information and product are furnished on the condition
that the person receiving them shall make his own determinations as to the suitability of the product for his particular purpose
and on the condition that he assumes the risk of his use thereof.
This Material Safety Data Sheet complies with the EC directives 91/155/EEC and 93/112/EEC, including modifications
2001/58/EC.
Complies with OSHA Communication Standard 29 CFR 1910.1200 and Superfund Amendments and
Reauthorization Act (SARA) of 1986 Public Law 99-499

Hazard Statements:
H228 – Flammable solid
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H334 – May allergy or asthma symptoms or breathing difficulties if inhaled.
H351 – Suspected of causing lung cancer.
H372 – Causes damage to organs through prolonged or repeated exposure.
H373 – May cause damage to organs through prolonged or repeated exposure.
H400 – Very toxic to aquatic life
H413 – May cause long lasting harmful effects to aquatic life.
R-Phrases:
R11 – Highly flammable
R36/38 – Irritating to eyes and skin.
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R40 – Limited evidence of a carcinogenic effect.
R42/43 – May cause sensitization by inhalation and skin contact.
R43 – May cause sensitization by skin contact.
R48 – Danger of serious damage to health by prolonged exposure.
R48/20 – Harmful: danger of serious damage to health by prolonged exposure through inhalation.
R48/23 – Toxic: danger of serious damage to health by prolonged exposure through inhalation.
R53 – May cause long-term adverse effects in the aquatic environment.
S-Phrases:
S9 – Keep containers in a well-ventilated place.
S15 – Keep away from heat.
S16 – Keep away from source of ignition – No smoking.
S22 – Do not breathe dust.
S24 – Avoid contact with skin.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 – After contact with skin, wash immediately with plenty of water.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S43 – In case of fire, use fire-fighting equipment on basis class D.
S61 – Avoid release to the environment.

End of the document.