Instruction Manual

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HI 96711C
Free and Total Chlorine
ISM

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www.
1.800.561.8187
www.hannainst.com

1
 PRELIMINARY EXAMINATION GENERAL DESCRIPTION

[email protected]
Please examine this product carefully. Make sure that the instrument is not damaged. If any The HI 96711 is an auto diagnostic portable microprocessor meter that benefits from Hanna’s
damage occurred during shipment, please notify your Dealer. years of experience as a manufacturer of analytical instruments. It has the advanced optical
Each HI 96711C Ion Selective Meter is supplied complete with: system based on a special tungsten lamp and a narrow band interference filter that allows most
• Two Sample Cuvettes and Caps accurate and repeatable readings. All instruments are factory calibrated and the electronic and
• CAL CHECK standard cuvettes optical design minimizes the need of frequent calibration.
• 9V Battery With the powerful CAL CHECKTM validation function, you are able to validate good performance
of your instrument at any time. The validation procedure is extremely user friendly. Just use the
• Scissors
exclusive HANNA ready-made, NIST traceable standards to verify the performance of the
• Cloth for wiping cuvettes
instrument and recalibrate if necessary.
• Instruction Manual
All instruments are splash waterproof and the lamp and filter units are protected from dust or dirt
• Instrument Quality Certificate by a transparent cup. This makes the instruments fulfill field applications. Display messages aid
• Rigid carrying case the user in routine operation. The meter has an auto-shut off feature that will turn off the
instrument after 10 minutes of non use in measurement mode or after 1 hour if left in
calibration mode.
The meter uses an exclusive positive-locking system to ensure that the cuvette is in the same

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position every time it is placed into the measurement cell. It is designed to fit a cuvette with a
larger neck making it easier to add both sample and reagents. The cuvette is made from special
optical glass to obtain best results.
The HI 96711 meter measures the free and total chlorine (Cl2) content in water samples in the

www.
0.00 to 5.00 mg/L (ppm) range. The method is an adaptation of the USEPA Method 330.5 for
wastewater, and Standard Method 4500-Cl G for drinking water.
The reagents are in powder form and supplied in packets. The amount of reagent is precisely
dosed to ensure the maximum repeatability.

1.800.561.8187
ABBREVIATIONS

°C: degree Celsius

°F: degree Fahrenheit
USEPA: US Environmental Protection Agency
mg/L: milligrams per liter. mg/L is equivalent to ppm (parts per million)
Note:Save all packing material until you are sure that the instrument works correctly. Any mL: milliliter
defective item must be returned in its original packing. mV: millivolts

4 5
 Dear Customer,
Thank you for choosing a Hanna product. This manual will provide you with the necessary
information for the correct use of the instrument. Please read it carefully before using the meter. If

[email protected]
you need additional technical information, do not hesitate to e-mail us at [email protected].

TABLE OF CONTENTS

PRELIMINARY EXAMINATION ................................................................................................ 4

GENERAL DESCRIPTION ....................................................................................................... 5
ABBREVIATIONS .................................................................................................................. 5
SPECIFICATIONS ................................................................................................................... 6
PRECISION AND ACCURACY .................................................................................................. 6
PRINCIPLE OF OPERATION ................................................................................................... 7
FUNCTIONAL DESCRIPTION .................................................................................................. 9
ERRORS AND WARNINGS .................................................................................................. 11
GENERAL TIPS FOR AN ACCURATE MEASUREMENT ............................................................. 13

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STARTUP ........................................................................................................................... 15
RANGE SELECTION ............................................................................................................. 15
MEASUREMENT PROCEDURE ............................................................................................. 16
VALIDATION PROCEDURE ................................................................................................... 18
CALIBRATION PROCEDURE ................................................................................................. 20

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GLP ................................................................................................................................... 23
BATTERY MANAGEMENT .................................................................................................... 24
BATTERY REPLACEMENT .................................................................................................... 24
ACCESSORIES ..................................................................................................................... 25
WARRANTY ........................................................................................................................ 26

1.800.561.8187
All rights are reserved. Reproduction in whole or in part is prohibited without the written consent of the copyright owner,
Hanna Instruments Inc., Woonsocket, Rhode Island, 02895 , USA.

2 3
 SPECIFICATIONS PRINCIPLE OF OPERATION

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Range Free Cl2 0.00 to 5.00 mg/L Absorption of Light is a typical phenomenon of interaction between electromagnetic radiation and
Total Cl2 0.00 to 5.00 mg/L matter. When a light beam crosses a substance, some of the radiation may be absorbed by
Resolution 0.01 mg/L from 0.00 to 3.50 mg/L; 0.10 mg/L above 3.50 mg/L atoms, molecules or crystal lattices.
Accuracy ±0.03 mg/L ±3% of reading @ 25°C
If pure absorption occurs, the fraction of light absorbed depends both on the optical path length
Typical EMC Deviation ±0.01 mg/L
Light Source Tungsten lamp through the matter and on the physical-chemical characteristics of the substance according to the
Light Detector Silicon Photocell with narrow band interference filter @ 525nm. Lambert-Beer Law:
Method Adaptation of the USEPA method 330.5 and Standard Method 4500-Cl G. -log I/Io = ελ c d
The reaction between chlorine and the DPD reagent causes a pink tint or
in the sample. A = ελ c d
Environment 0 to 50°C (32 to 122°F); max 95% RH non-condensing
Battery Type 1 x 9 volt Where:
Auto-Shut off After 10' of non-use in measurement mode; -log I/Io = Absorbance (A)
after 1 hour of non-use in calibration mode; Io = intensity of incident light beam
with last reading reminder. I = intensity of light beam after absorption
Dimensions 192 x 104 x 69 mm (7.6 x 4.1 x 2.7") ελ = molar extinction coefficient at wavelength λ
Weight 360 g (12.7 oz.).

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c = molar concentration of the substance
REQUIRED REAGENTS d = optical path through the substance
Code Unit Description Quantity/test
HI 93701-0 Free Cl2 DPD Powder Reagent 1 packet
HI 93711-0 Total Cl2 DPD Powder Reagent 1 packet Therefore, the concentration "c" can be calculated from the absorbance of the substance as the
other factors are known.

www.
Photometric chemical analysis is based on the possibility to develop an absorbing compound
PRECISION AND ACCURACY from a specific chemical reaction between sample and reagents. Given that the absorption of a
compound strictly depends on the wavelength of the incident light beam, a narrow spectral
Precision is how closely repeated measurements bandwidth should be selected as well as a proper central wavelength to optimize measurements.
agree with each other. Precision is usually The optical system of Hanna's HI 96 series colorimeters is based on special subminiature

1.800.561.8187
expressed as standard deviation (SD). tungsten lamps and narrow-band interference filters to guarantee both high performance and
Accuracy is defined as the nearness of a test reliable results.
result to the true value.
Although good precision suggests good accuracy,
precise results can be inaccurate. The figure
explains these definitions. In a laboratory using
a standard solution of 1.00 mg/L chlorine and a
representative lot of reagent, an operator obtained HI 96 series block diagram (optical layout)
with a single instrument a standard deviation of
0.02 mg/L.

6 7
 PRELIMINARY EXAMINATION GENERAL DESCRIPTION

[email protected]
Please examine this product carefully. Make sure that the instrument is not damaged. If any The HI 96711 is an auto diagnostic portable microprocessor meter that benefits from Hanna’s
damage occurred during shipment, please notify your Dealer. years of experience as a manufacturer of analytical instruments. It has the advanced optical
Each HI 96711C Ion Selective Meter is supplied complete with: system based on a special tungsten lamp and a narrow band interference filter that allows most
• Two Sample Cuvettes and Caps accurate and repeatable readings. All instruments are factory calibrated and the electronic and
• CAL CHECK standard cuvettes optical design minimizes the need of frequent calibration.
• 9V Battery With the powerful CAL CHECKTM validation function, you are able to validate good performance
of your instrument at any time. The validation procedure is extremely user friendly. Just use the
• Scissors
exclusive HANNA ready-made, NIST traceable standards to verify the performance of the
• Cloth for wiping cuvettes
instrument and recalibrate if necessary.
• Instruction Manual
All instruments are splash waterproof and the lamp and filter units are protected from dust or dirt
• Instrument Quality Certificate by a transparent cup. This makes the instruments fulfill field applications. Display messages aid
• Rigid carrying case the user in routine operation. The meter has an auto-shut off feature that will turn off the
instrument after 10 minutes of non use in measurement mode or after 1 hour if left in
calibration mode.
The meter uses an exclusive positive-locking system to ensure that the cuvette is in the same

.com
position every time it is placed into the measurement cell. It is designed to fit a cuvette with a
larger neck making it easier to add both sample and reagents. The cuvette is made from special
optical glass to obtain best results.
The HI 96711 meter measures the free and total chlorine (Cl2) content in water samples in the

www.
0.00 to 5.00 mg/L (ppm) range. The method is an adaptation of the USEPA Method 330.5 for
wastewater, and Standard Method 4500-Cl G for drinking water.
The reagents are in powder form and supplied in packets. The amount of reagent is precisely
dosed to ensure the maximum repeatability.

1.800.561.8187
ABBREVIATIONS

°C: degree Celsius

°F: degree Fahrenheit
USEPA: US Environmental Protection Agency
mg/L: milligrams per liter. mg/L is equivalent to ppm (parts per million)
Note:Save all packing material until you are sure that the instrument works correctly. Any mL: milliliter
defective item must be returned in its original packing. mV: millivolts

4 5
A microprocessor controlled special tungsten lamp emits radiation which is first optically
conditioned and beamed to the sample contained in the cuvette. The optical path is fixed by the FUNCTIONAL DESCRIPTION
diameter of the cuvette. Then the light is spectrally filtered to a narrow spectral bandwidth, to

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obtain a light beam of intensity Io or I. INSTRUMENT DESCRIPTION
The photoelectric cell collects the radiation I that is not absorbed by the sample and converts
it into an electric current, producing a potential in the mV range.
The microprocessor uses this potential to convert the incoming value into the desired measuring 1) RANGE/GLP/ key
unit and to display it on the LCD. 2) CAL CHECK key
The measurement process is carried out in two phases: first the meter is zeroed and then the 3) ZERO/CFM key
actual measurement is performed. 4) READ/ /TIMER key
The cuvette has a very important role because it is an optical element and thus requires 5) ON/OFF key
particular attention. It is important that both, the measurement and the calibration (zeroing) 6) Liquid Crystal Display (LCD)
cuvettes, are optically identical to provide the same measurement conditions. Whenever possible
7) Cuvette alignment indicator
use the same cuvette for both. It is necessary that the surface of the cuvette is clean and not
scratched. This to avoid measurement interference due to unwanted reflection and absorption of 8) Cuvette holder
light. It is recommended not to touch the cuvette walls with hands.
KEYPAD DESCRIPTION
Furthermore, in order to maintain the same conditions during the zeroing and the measuring
• ON/OFF: to turn the meter on and off.
phases, it is necessary to close the cuvette to prevent any contamination.

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• ZERO/CFM: this is a bi-functional key. Just press to zero the meter prior to measurement,
or confirm edited values. In calibration mode press to confirm factory calibration restore.
• READ/ /TIMER: this is a multi-functional key. In measurement mode, press to make a
measurement, or press and hold for three seconds to start a pre-programmed countdown prior
to measurement. In GLP mode press to view the next screen.

www.
• CAL CHECK: this is a bi-functional key. Just press to perform the validation of the meter, or
press and hold for three seconds to enter calibration mode.
• RANGE/GLP/ : this is a multi-functional key. Just press to change the parameter. Press
and hold for three seconds to enter GLP mode. In calibration mode press to edit the date and time.

1.800.561.8187
OPERATING MODES
• Measurement mode: default operation mode, enables both validation and measurement.
• Calibration mode: may be entered by keeping CAL CHECK pressed for three seconds (the
“CAL” tag appears), it enables calibration of the instrument.
• GLP mode: may be entered by keeping RANGE/GLP/ pressed for three seconds (“GLP”
appears), it enables consulting of user calibration date or restore factory calibration.

8 9
 SPECIFICATIONS PRINCIPLE OF OPERATION

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Range Free Cl2 0.00 to 5.00 mg/L Absorption of Light is a typical phenomenon of interaction between electromagnetic radiation and
Total Cl2 0.00 to 5.00 mg/L matter. When a light beam crosses a substance, some of the radiation may be absorbed by
Resolution 0.01 mg/L from 0.00 to 3.50 mg/L; 0.10 mg/L above 3.50 mg/L atoms, molecules or crystal lattices.
Accuracy ±0.03 mg/L ±3% of reading @ 25°C
If pure absorption occurs, the fraction of light absorbed depends both on the optical path length
Typical EMC Deviation ±0.01 mg/L
Light Source Tungsten lamp through the matter and on the physical-chemical characteristics of the substance according to the
Light Detector Silicon Photocell with narrow band interference filter @ 525nm. Lambert-Beer Law:
Method Adaptation of the USEPA method 330.5 and Standard Method 4500-Cl G. -log I/Io = ελ c d
The reaction between chlorine and the DPD reagent causes a pink tint or
in the sample. A = ελ c d
Environment 0 to 50°C (32 to 122°F); max 95% RH non-condensing
Battery Type 1 x 9 volt Where:
Auto-Shut off After 10' of non-use in measurement mode; -log I/Io = Absorbance (A)
after 1 hour of non-use in calibration mode; Io = intensity of incident light beam
with last reading reminder. I = intensity of light beam after absorption
Dimensions 192 x 104 x 69 mm (7.6 x 4.1 x 2.7") ελ = molar extinction coefficient at wavelength λ
Weight 360 g (12.7 oz.).

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c = molar concentration of the substance
REQUIRED REAGENTS d = optical path through the substance
Code Unit Description Quantity/test
HI 93701-0 Free Cl2 DPD Powder Reagent 1 packet
HI 93711-0 Total Cl2 DPD Powder Reagent 1 packet Therefore, the concentration "c" can be calculated from the absorbance of the substance as the
other factors are known.

www.
Photometric chemical analysis is based on the possibility to develop an absorbing compound
PRECISION AND ACCURACY from a specific chemical reaction between sample and reagents. Given that the absorption of a
compound strictly depends on the wavelength of the incident light beam, a narrow spectral
Precision is how closely repeated measurements bandwidth should be selected as well as a proper central wavelength to optimize measurements.
agree with each other. Precision is usually The optical system of Hanna's HI 96 series colorimeters is based on special subminiature

1.800.561.8187
expressed as standard deviation (SD). tungsten lamps and narrow-band interference filters to guarantee both high performance and
Accuracy is defined as the nearness of a test reliable results.
result to the true value.
Although good precision suggests good accuracy,
precise results can be inaccurate. The figure
explains these definitions. In a laboratory using
a standard solution of 1.00 mg/L chlorine and a
representative lot of reagent, an operator obtained HI 96 series block diagram (optical layout)
with a single instrument a standard deviation of
0.02 mg/L.

6 7
DISPLAY ELEMENTS DESCRIPTION
ERRORS AND WARNINGS
5 6 7

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The instrument shows clear messages when erroneous condition appears. Messages are also displayed
4 8 when the obtained values are outside expected range. The beeper is playing a beep on errors.
3
9
2 a) on zero reading
10
1
Light High: There is too much light to perform a measurement.
Please check the preparation of the zero cuvette.
1) The measuring scheme (lamp, cuvette, detector), appears during different phases of zero or
reading measurement
2) Error messages and warnings
3) The battery icon indicates the charge state of the battery
Light Low: There is not enough light to perform a measurement.
4) The hourglass appears when an internal check is in progress
Please check the preparation of the zero cuvette.
5) Status messages
6) The chronometer appears when the reaction timer is running
7) The month, day and date icons appear when a date is displayed

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8) Four digit main display
9) Measuring units No Light: The instrument cannot adjust the light level. Please
10) Four digit secondary display check that the sample does not contain any debris.

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b) on sample reading

Inverted cuvettes: The sample and the zero cuvette are inverted.

1.800.561.8187
Zero: A zero reading was not taken. Follow the instructions of
the measurement procedure for zeroing the meter.

10 11
DISPLAY ELEMENTS DESCRIPTION
ERRORS AND WARNINGS
5 6 7

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The instrument shows clear messages when erroneous condition appears. Messages are also displayed
4 8 when the obtained values are outside expected range. The beeper is playing a beep on errors.
3
9
2 a) on zero reading
10
1
Light High: There is too much light to perform a measurement.
Please check the preparation of the zero cuvette.
1) The measuring scheme (lamp, cuvette, detector), appears during different phases of zero or
reading measurement
2) Error messages and warnings
3) The battery icon indicates the charge state of the battery
Light Low: There is not enough light to perform a measurement.
4) The hourglass appears when an internal check is in progress
Please check the preparation of the zero cuvette.
5) Status messages
6) The chronometer appears when the reaction timer is running
7) The month, day and date icons appear when a date is displayed

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8) Four digit main display
9) Measuring units No Light: The instrument cannot adjust the light level. Please
10) Four digit secondary display check that the sample does not contain any debris.

www.
b) on sample reading

Inverted cuvettes: The sample and the zero cuvette are inverted.

1.800.561.8187
Zero: A zero reading was not taken. Follow the instructions of
the measurement procedure for zeroing the meter.

10 11
 Under range: A blinking “0.00” indicates that the sample Battery low: The battery must be replaced soon.
absorbs less light than the zero reference. Check the procedure
and make sure you use the same cuvette for reference (zero) and

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measurement.

Dead battery: This indicates that the battery is dead and must
Over Range: A flashing value of the maximum concentration
be replaced. Once this indication is displayed, normal operation
indicates an over range condition. The concentration of the
of the instrument will be interrupted. Change the battery and
sample is beyond the programmed range: dilute the sample and
restart the meter.
re-run the test.

c) during calibration procedure

GENERAL TIPS FOR AN ACCURATE MEASUREMENT
Standard Low: The standard reading is less than expected.
The instructions listed below should be carefully followed during testing to ensure best accuracy.

• Color or suspended matter in large amounts may cause

.com
interference, therefore these should be removed by
treatment with active carbon and by prior filtration.
Standard High: The standard reading is higher than expected.
• For a correct filling of the cuvette: the liquid in the

www.
cuvette forms a concavity on the top; the bottom of this
concavity must be at the same level of the 10 mL mark.

d) other errors and warnings • Proper use of the powder reagent packet:
(a) use scissors to open the powder packet;
Cap error: Appears when external light enters in the analysis (b) push the edges of the packet to form a spout;

1.800.561.8187
cell. Assure that the cuvette cap is present. (c) pour out the content of the packet.

Cooling lamp: The instrument waits for the lamp to cool down.

12 13
A microprocessor controlled special tungsten lamp emits radiation which is first optically
conditioned and beamed to the sample contained in the cuvette. The optical path is fixed by the FUNCTIONAL DESCRIPTION
diameter of the cuvette. Then the light is spectrally filtered to a narrow spectral bandwidth, to

[email protected]
obtain a light beam of intensity Io or I. INSTRUMENT DESCRIPTION
The photoelectric cell collects the radiation I that is not absorbed by the sample and converts
it into an electric current, producing a potential in the mV range.
The microprocessor uses this potential to convert the incoming value into the desired measuring 1) RANGE/GLP/ key
unit and to display it on the LCD. 2) CAL CHECK key
The measurement process is carried out in two phases: first the meter is zeroed and then the 3) ZERO/CFM key
actual measurement is performed. 4) READ/ /TIMER key
The cuvette has a very important role because it is an optical element and thus requires 5) ON/OFF key
particular attention. It is important that both, the measurement and the calibration (zeroing) 6) Liquid Crystal Display (LCD)
cuvettes, are optically identical to provide the same measurement conditions. Whenever possible
7) Cuvette alignment indicator
use the same cuvette for both. It is necessary that the surface of the cuvette is clean and not
scratched. This to avoid measurement interference due to unwanted reflection and absorption of 8) Cuvette holder
light. It is recommended not to touch the cuvette walls with hands.
KEYPAD DESCRIPTION
Furthermore, in order to maintain the same conditions during the zeroing and the measuring
• ON/OFF: to turn the meter on and off.
phases, it is necessary to close the cuvette to prevent any contamination.

.com
• ZERO/CFM: this is a bi-functional key. Just press to zero the meter prior to measurement,
or confirm edited values. In calibration mode press to confirm factory calibration restore.
• READ/ /TIMER: this is a multi-functional key. In measurement mode, press to make a
measurement, or press and hold for three seconds to start a pre-programmed countdown prior
to measurement. In GLP mode press to view the next screen.

www.
• CAL CHECK: this is a bi-functional key. Just press to perform the validation of the meter, or
press and hold for three seconds to enter calibration mode.
• RANGE/GLP/ : this is a multi-functional key. Just press to change the parameter. Press
and hold for three seconds to enter GLP mode. In calibration mode press to edit the date and time.

1.800.561.8187
OPERATING MODES
• Measurement mode: default operation mode, enables both validation and measurement.
• Calibration mode: may be entered by keeping CAL CHECK pressed for three seconds (the
“CAL” tag appears), it enables calibration of the instrument.
• GLP mode: may be entered by keeping RANGE/GLP/ pressed for three seconds (“GLP”
appears), it enables consulting of user calibration date or restore factory calibration.

8 9
• It is important that the sample does not contain any debris.
This would corrupt the reading.
STARTUP

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• Each time the cuvette is used, the cap must be tightened Prepare the instrument for measurement as follows:
to the same degree. • Unpack the instrument by removing the dust protection sleeve from the instrument cuvette
holder.
• Whenever the cuvette is placed into the measurement • Place the battery in the instrument as described in the “BATTERY REPLACEMENT” chapter.
cell, it must be dry outside, and completely free of • Place the instrument on a flat table.
fingerprints, oil or dirt. Wipe it thoroughly with HI 731318 • Do not place the instrument under direct sun light.
or a lint-free cloth prior to insertion.

• Shaking the cuvette can generate bubbles in the sample, causing higher readings. To obtain RANGE SELECTION
accurate measurements, remove such bubbles by swirling or by gently tapping the cuvette.
The HI 96711 can measure Free chlorine when range P1 is selected or Total chlorine when
• Do not let the reacted sample stand too long after reagent is added, or accuracy will be lost. range P2 is selected. To change the active range follow the procedure:

• It is possible to take multiple readings in a row, but it is recommended to take a new zero
reading for each sample and to use the same cuvette for zeroing and measurement. • Turn the meter on by pressing ON/OFF. The

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display briefly shows all tags on.
• After the reading it is important to discard immediately the sample, otherwise the glass
might become permanently stained.
• After startup, the range identification number is
displayed on the secondary LCD as P1 or P2.

www.
• All the reaction times reported in this manual are referred to 20°C (68°F). As a general rule
of thumb, they should be doubled at 10°C (50°F) and halved at 30°C (86°F).
Code Parameter
• In order to maximize accuracy, prior to a measurement follow the validation procedure to
be sure that the instrument is properly calibrated. If necessary, calibrate the instrument. P1 Free Chlorine
P2 Total Chlorine

1.800.561.8187
• Press RANGE/GLP/ to change the range.
The range can be changed any time when the
instrument is in measurement mode.
The selected range is memorized and the selection
remaines unchanged at power off or when the
battery is removed.

14 15
 Under range: A blinking “0.00” indicates that the sample Battery low: The battery must be replaced soon.
absorbs less light than the zero reference. Check the procedure
and make sure you use the same cuvette for reference (zero) and

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measurement.

Dead battery: This indicates that the battery is dead and must
Over Range: A flashing value of the maximum concentration
be replaced. Once this indication is displayed, normal operation
indicates an over range condition. The concentration of the
of the instrument will be interrupted. Change the battery and
sample is beyond the programmed range: dilute the sample and
restart the meter.
re-run the test.

c) during calibration procedure

GENERAL TIPS FOR AN ACCURATE MEASUREMENT
Standard Low: The standard reading is less than expected.
The instructions listed below should be carefully followed during testing to ensure best accuracy.

• Color or suspended matter in large amounts may cause

.com
interference, therefore these should be removed by
treatment with active carbon and by prior filtration.
Standard High: The standard reading is higher than expected.
• For a correct filling of the cuvette: the liquid in the

www.
cuvette forms a concavity on the top; the bottom of this
concavity must be at the same level of the 10 mL mark.

d) other errors and warnings • Proper use of the powder reagent packet:
(a) use scissors to open the powder packet;
Cap error: Appears when external light enters in the analysis (b) push the edges of the packet to form a spout;

1.800.561.8187
cell. Assure that the cuvette cap is present. (c) pour out the content of the packet.

Cooling lamp: The instrument waits for the lamp to cool down.

12 13
 • After a few seconds, the display will
MEASUREMENT PROCEDURE show “-0.0-”. The meter is now zeroed
and ready for measurement.

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To compensate the meter for the sample turbidity or color, the measurement takes place in two
phases. First, the meter is zeroed using the unreacted sample. After the reagents are added the
reacted sample is measured. • Remove the cuvette.
Important note: Free and Total Chlorine have to be measured separately with fresh unreacted
samples if both values are requested. • Add the content of one packet of the
specific test reagent, for:
• Turn the meter on by pressing ON/OFF. Free Chlorine: 1 packet of HI 93701-0
The display briefly shows all tags on. or
Total Chlorine: 1 packet of HI 93711-0

• When the beeper sounds briefly and the

LCD displays dashes, the meter is ready.
• Replace the cap and shake gently for 20
The blinking “ZERO” indicates that the
seconds (or 2 minutes in case of seawater
instrument needs to be zeroed first.
analysis).

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• Pay attention to the selected range.
• Replace the cuvette into the cuvette holder
To change the range, simply press
and ensure that the notch on the cap is
RANGE/GLP/ .
positioned securely into the groove.

www.
• Fill the cuvette with 10 mL of unreacted
• Press and hold READ/ /TIMER for three
sample, up to the mark, and replace the
seconds. The display will show the
cap.
countdown prior to measurement. An
audible “beep” indicates the end of

1.800.561.8187
countdown period.
• Place the cuvette into the cuvette holder
and ensure that the notch on the cap is
positioned securely into the groove.
• Alternatively, wait for 1 minute for free
chlorine or 2’30’’ for total chlorine and
just press READ/ /TIMER.
• Press ZERO/CFM and the lamp, cuvette In both cases, the lamp, cuvette and
and detector icons will appear on the detector icons will appear on the display,
display, depending on the measurement depending on the measurement phase.
phase.

16 17
• It is important that the sample does not contain any debris.
This would corrupt the reading.
STARTUP

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• Each time the cuvette is used, the cap must be tightened Prepare the instrument for measurement as follows:
to the same degree. • Unpack the instrument by removing the dust protection sleeve from the instrument cuvette
holder.
• Whenever the cuvette is placed into the measurement • Place the battery in the instrument as described in the “BATTERY REPLACEMENT” chapter.
cell, it must be dry outside, and completely free of • Place the instrument on a flat table.
fingerprints, oil or dirt. Wipe it thoroughly with HI 731318 • Do not place the instrument under direct sun light.
or a lint-free cloth prior to insertion.

• Shaking the cuvette can generate bubbles in the sample, causing higher readings. To obtain RANGE SELECTION
accurate measurements, remove such bubbles by swirling or by gently tapping the cuvette.
The HI 96711 can measure Free chlorine when range P1 is selected or Total chlorine when
• Do not let the reacted sample stand too long after reagent is added, or accuracy will be lost. range P2 is selected. To change the active range follow the procedure:

• It is possible to take multiple readings in a row, but it is recommended to take a new zero
reading for each sample and to use the same cuvette for zeroing and measurement. • Turn the meter on by pressing ON/OFF. The

.com
display briefly shows all tags on.
• After the reading it is important to discard immediately the sample, otherwise the glass
might become permanently stained.
• After startup, the range identification number is
displayed on the secondary LCD as P1 or P2.

www.
• All the reaction times reported in this manual are referred to 20°C (68°F). As a general rule
of thumb, they should be doubled at 10°C (50°F) and halved at 30°C (86°F).
Code Parameter
• In order to maximize accuracy, prior to a measurement follow the validation procedure to
be sure that the instrument is properly calibrated. If necessary, calibrate the instrument. P1 Free Chlorine
P2 Total Chlorine

1.800.561.8187
• Press RANGE/GLP/ to change the range.
The range can be changed any time when the
instrument is in measurement mode.
The selected range is memorized and the selection
remaines unchanged at power off or when the
battery is removed.

14 15
• At the end of measurement, the instrument • Press ZERO/CFM and the lamp, cuvette
directly displays concentration in mg/L of and detector icons will appear on the
free or total chlorine and the range display, depending on the measurement

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number on the LCD. phase.

INTERFERENCES • After a few seconds, the display will

Bromine (positive error) Oxidized Manganese and Chromium (positive error) show “-0.0-”. The meter is now zeroed
Chlorine dioxide (positive error) Ozone (positive error) and ready for validation.
Iodine (positive error)
In case of water alkalinity greater than 250 mg/L CaCO3 or acidity greater than 150 mg/L CaCO3 • Remove the cuvette.
the color of the sample may develop only partially, or may rapidly fade. To resolve this,
neutralize the sample with diluted HCl or NaOH.
In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately • Place the specific CAL CHECKTM Standard
2 minutes after adding the powder reagent. Cuvette B into the cuvette holder, for:
Free Chlorine: B, HI 96701-11
or
VALIDATION PROCEDURE Total Chlorine: B, HI 96711-11

.com
Ensure that the notch on the cap is
Use the validation procedure to ensure that the instrument is properly calibrated. positioned securely into the groove.
Warning: Do not validate the instrument with any standard solutions other than the HANNA CAL
CHECKTM Standards, otherwise erroneous results will be obtained.
• Press CAL CHECKTM and the lamp, cuvette

www.
Note: The validation is performed only for the selected parameter. For full validation of the
instrument, the following procedure must be performed for each parameter. and detector icons together with “CAL
CHECK” will appear on the display,
• Turn the meter on by pressing ON/OFF. depending on the measurement phase.

• When the beeper sounds briefly and the • At the end of the measurement the display

1.800.561.8187
LCD displays dashes, the meter is ready. will show the validation standard value.

• Place the CAL CHECK TM Standard The reading should be within specifications as reported in the CAL CHECKTM Standard
Cuvette A into the cuvette holder and Certificate. If the value is found out of the specifications, please check that the cuvettes are free
ensure that the notch on the cap is of fingerprints, oil or dirt and repeat validation. If results are still found out of specifications,
positioned securely into the groove. then recalibrate the instrument.

18 19
 • After a few seconds, the display will
MEASUREMENT PROCEDURE show “-0.0-”. The meter is now zeroed
and ready for measurement.

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To compensate the meter for the sample turbidity or color, the measurement takes place in two
phases. First, the meter is zeroed using the unreacted sample. After the reagents are added the
reacted sample is measured. • Remove the cuvette.
Important note: Free and Total Chlorine have to be measured separately with fresh unreacted
samples if both values are requested. • Add the content of one packet of the
specific test reagent, for:
• Turn the meter on by pressing ON/OFF. Free Chlorine: 1 packet of HI 93701-0
The display briefly shows all tags on. or
Total Chlorine: 1 packet of HI 93711-0

• When the beeper sounds briefly and the

LCD displays dashes, the meter is ready.
• Replace the cap and shake gently for 20
The blinking “ZERO” indicates that the
seconds (or 2 minutes in case of seawater
instrument needs to be zeroed first.
analysis).

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• Pay attention to the selected range.
• Replace the cuvette into the cuvette holder
To change the range, simply press
and ensure that the notch on the cap is
RANGE/GLP/ .
positioned securely into the groove.

www.
• Fill the cuvette with 10 mL of unreacted
• Press and hold READ/ /TIMER for three
sample, up to the mark, and replace the
seconds. The display will show the
cap.
countdown prior to measurement. An
audible “beep” indicates the end of

1.800.561.8187
countdown period.
• Place the cuvette into the cuvette holder
and ensure that the notch on the cap is
positioned securely into the groove.
• Alternatively, wait for 1 minute for free
chlorine or 2’30’’ for total chlorine and
just press READ/ /TIMER.
• Press ZERO/CFM and the lamp, cuvette In both cases, the lamp, cuvette and
and detector icons will appear on the detector icons will appear on the display,
display, depending on the measurement depending on the measurement phase.
phase.

16 17
• At the end of measurement, the instrument • Press ZERO/CFM and the lamp, cuvette
directly displays concentration in mg/L of and detector icons will appear on the
free or total chlorine and the range display, depending on the measurement

[email protected]
number on the LCD. phase.

INTERFERENCES • After a few seconds, the display will

Bromine (positive error) Oxidized Manganese and Chromium (positive error) show “-0.0-”. The meter is now zeroed
Chlorine dioxide (positive error) Ozone (positive error) and ready for validation.
Iodine (positive error)
In case of water alkalinity greater than 250 mg/L CaCO3 or acidity greater than 150 mg/L CaCO3 • Remove the cuvette.
the color of the sample may develop only partially, or may rapidly fade. To resolve this,
neutralize the sample with diluted HCl or NaOH.
In case of water with hardness greater than 500 mg/L CaCO3, shake the sample for approximately • Place the specific CAL CHECKTM Standard
2 minutes after adding the powder reagent. Cuvette B into the cuvette holder, for:
Free Chlorine: B, HI 96701-11
or
VALIDATION PROCEDURE Total Chlorine: B, HI 96711-11

.com
Ensure that the notch on the cap is
Use the validation procedure to ensure that the instrument is properly calibrated. positioned securely into the groove.
Warning: Do not validate the instrument with any standard solutions other than the HANNA CAL
CHECKTM Standards, otherwise erroneous results will be obtained.
• Press CAL CHECKTM and the lamp, cuvette

www.
Note: The validation is performed only for the selected parameter. For full validation of the
instrument, the following procedure must be performed for each parameter. and detector icons together with “CAL
CHECK” will appear on the display,
• Turn the meter on by pressing ON/OFF. depending on the measurement phase.

• When the beeper sounds briefly and the • At the end of the measurement the display

1.800.561.8187
LCD displays dashes, the meter is ready. will show the validation standard value.

• Place the CAL CHECK TM Standard The reading should be within specifications as reported in the CAL CHECKTM Standard
Cuvette A into the cuvette holder and Certificate. If the value is found out of the specifications, please check that the cuvettes are free
ensure that the notch on the cap is of fingerprints, oil or dirt and repeat validation. If results are still found out of specifications,
positioned securely into the groove. then recalibrate the instrument.

18 19
 • Remove the cuvette.
CALIBRATION PROCEDURE
• Place the specific CAL CHECKTM Standard

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Note: It is possible to interrupt calibration procedure at any time by pressing CAL CHECK or
ON/OFF keys. Cuvette B into the cuvette holder, for:
Warning: Do not calibrate the instrument with standard solutions other than the HANNA CAL Free Chlorine: B, HI 96701-11
CHECKTM Standards, otherwise erroneous results will be obtained. or
When calibrating, only the selected range is affected. Total Chlorine: B, HI 96711-11
• Turn the meter on by pressing ON/OFF.
• Ensure that the notch on the cap is
• When the beeper sounds briefly and the positioned securely into the groove.
LCD displays dashes, the meter is ready.
• Press READ/ /TIMER and the lamp,
• To change the range, simply press cuvette and detector icons will appear on
RANGE/GLP/ . the display, depending on the
measurement phase.
• Press and hold CAL CHECK for three

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seconds to enter calibration mode. The • After measurement the instrument will
display will show “CAL” during show for three seconds the CAL CHECKTM
calibration procedure. The blinking Standard value.
“ZERO” asks for instrument zeroing.

www.
Note:If the display shows “STD HIGH”, the
• Place the CAL CHECKTM Standard Cuvette
standard value was too high. If the
A into the cuvette holder and ensure that
display shows “STD LOW”, the
the notch on the cap is positioned securely
standard value was too low. Verify
into the groove.
that both CAL CHECKTM Standard
Cuvettes, A and B are free from

1.800.561.8187
• Press ZERO/CFM and the lamp, cuvette fingerprints or dirt and that they are
and detector icons will appear on the inserted correctly.
display, depending on the measurement
phase.
• Then the date of the last calibration (e.g.:
”01.08.2009”) appears on the display,
• After a few seconds the display will show
or “01.01.2009 if the factory calibration
“-0.0-”. The meter is now zeroed and
was selected before. In both cases the
ready for calibration. The blinking
year number is blinking, ready for date
“READ” asks for reading calibration
input.
standard.
20 21
 BATTERY MANAGEMENT ACCESORIES

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To save battery, the instrument shuts down after 10 minutes of non-use in measurement mode and after
1 hour of non-use in calibration mode. REAGENT SET
If a valid measurement was displayed before HI 93701-01 Reagents for 100 Free Chlorine tests
auto shut off, the value is displayed when the HI 93701-03 Reagents for 300 Free Chlorine tests
instrument is switched on. The blinking “ZERO” HI 93711-01 Reagents for 100 Total Chlorine tests
means that a new zero has to be performed. HI 93711-03 Reagents for 300 Total Chlorine tests
One fresh battery lasts for around 750 measurements, depending on the light level.
The remaining battery capacity is evaluated at the instrument startup and after each measurement. OTHER ACCESORIES
The instrument displays a battery indicator with three levels as follows: HI 96701-11 CAL CHECKTM Standard Cuvettes for Free Chlorine (1 set)
• 3 lines for 100 % capacity HI 96711-11 CAL CHECKTM Standard Cuvettes for Total Chlorine (1 set)
• 2 lines for 66 % capacity HI 721310 9V battery (10 pcs.)
• 1 line for 33 % capacity HI 731318 Cloth for wiping cuvettes (4 pcs.)
• Battery icon blinking if the capacity is under 10 %. HI 731331 Glass cuvettes (4 pcs.)
If the battery is empty and accurate measurements can’t be taken anymore, the instrument HI 731335 Caps for cuvettes (4 pcs.)
shows “dEAd bAtt” and turns off. HI 741218 Carrying case

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To restart the instrument, the battery must be replaced with a fresh one.
HI 93703-50 Cuvette cleaning solution (230 mL)

BATTERY REPLACEMENT

www.
To replace the instrument’s battery, follow the steps:

• Turn the instrument off by pressing ON/OFF.

• Turn the instrument upside down and remove the battery cover by turning it counterclockwise.

1.800.561.8187
• Extract the battery from its location and replace it with a fresh one.
• Insert back the battery cover and turn it clockwise to close.

24 25
 • Remove the cuvette.
CALIBRATION PROCEDURE
• Place the specific CAL CHECKTM Standard

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Note: It is possible to interrupt calibration procedure at any time by pressing CAL CHECK or
ON/OFF keys. Cuvette B into the cuvette holder, for:
Warning: Do not calibrate the instrument with standard solutions other than the HANNA CAL Free Chlorine: B, HI 96701-11
CHECKTM Standards, otherwise erroneous results will be obtained. or
When calibrating, only the selected range is affected. Total Chlorine: B, HI 96711-11
• Turn the meter on by pressing ON/OFF.
• Ensure that the notch on the cap is
• When the beeper sounds briefly and the positioned securely into the groove.
LCD displays dashes, the meter is ready.
• Press READ/ /TIMER and the lamp,
• To change the range, simply press cuvette and detector icons will appear on
RANGE/GLP/ . the display, depending on the
measurement phase.
• Press and hold CAL CHECK for three

.com
seconds to enter calibration mode. The • After measurement the instrument will
display will show “CAL” during show for three seconds the CAL CHECKTM
calibration procedure. The blinking Standard value.
“ZERO” asks for instrument zeroing.

www.
Note:If the display shows “STD HIGH”, the
• Place the CAL CHECKTM Standard Cuvette
standard value was too high. If the
A into the cuvette holder and ensure that
display shows “STD LOW”, the
the notch on the cap is positioned securely
standard value was too low. Verify
into the groove.
that both CAL CHECKTM Standard
Cuvettes, A and B are free from

1.800.561.8187
• Press ZERO/CFM and the lamp, cuvette fingerprints or dirt and that they are
and detector icons will appear on the inserted correctly.
display, depending on the measurement
phase.
• Then the date of the last calibration (e.g.:
”01.08.2009”) appears on the display,
• After a few seconds the display will show
or “01.01.2009 if the factory calibration
“-0.0-”. The meter is now zeroed and
was selected before. In both cases the
ready for calibration. The blinking
year number is blinking, ready for date
“READ” asks for reading calibration
input.
standard.
20 21
DATE INPUT
GLP
• Press RANGE/GLP/ to edit the desired
year (2009-2099). If the key is kept

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In GLP mode, the last user calibration date can be verified and the factory calibration can be
pressed, the year number is automatically
restored.
increased.
or
LAST CALIBRATION DATE
• When the correct year has been set, press
ZERO/CFM or READ/ /TIMER to To display the calibration date:
confirm. Now the display will show the
month blinking. • Press and hold for three seconds
RANGE/GLP/ to enter GLP mode. The
• Press RANGE/GLP/ to edit the desired calibration month and day will appear on
month (01-12). If the key is kept pressed the main display and the year on the
the month number is automatically secondary display.
increased. • If no calibration was performed, the
factory calibration message, “F.CAL” will
• When the correct month has been set, or
appear on the main display and the
press ZERO/CFM or READ/ /TIMER instrument returns to measurement mode

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to confirm. Now the display will show after three seconds.
the day blinking.
FACTORY CALIBRATION RESTORE
• Press RANGE/GLP/ to edit the desired

www.
day (01-31). If the key is kept pressed It is possible to delete the calibration and
the day number is automatically increased. restore factory calibration.
• Press and hold for three seconds
Note:It is possible to change the editing RANGE/GLP/ to enter GLP mode.
from day to year and to month by
pressing READ/ /TIMER. • Press READ/ /TIMER to enter in the

1.800.561.8187
factory calibration restore screen. The
• Press ZERO/CFM to save the calibration instrument asks for confirmation of user
date. calibration delete.
• Press ZERO/CFM to restore the factory
• The instrument displays “Stor” for one
calibration or press RANGE/GLP/ again
second and the calibration is saved.
to abort factory calibration restore.
• The instrument will return automatically • The instrument briefly indicates “donE”
to measurement mode by displaying upon restoration of factory calibration prior
dashes on the LCD. to returning to measurement mode.
22 23
DATE INPUT
GLP
• Press RANGE/GLP/ to edit the desired
year (2009-2099). If the key is kept

[email protected]
In GLP mode, the last user calibration date can be verified and the factory calibration can be
pressed, the year number is automatically
restored.
increased.
or
LAST CALIBRATION DATE
• When the correct year has been set, press
ZERO/CFM or READ/ /TIMER to To display the calibration date:
confirm. Now the display will show the
month blinking. • Press and hold for three seconds
RANGE/GLP/ to enter GLP mode. The
• Press RANGE/GLP/ to edit the desired calibration month and day will appear on
month (01-12). If the key is kept pressed the main display and the year on the
the month number is automatically secondary display.
increased. • If no calibration was performed, the
factory calibration message, “F.CAL” will
• When the correct month has been set, or
appear on the main display and the
press ZERO/CFM or READ/ /TIMER instrument returns to measurement mode

.com
to confirm. Now the display will show after three seconds.
the day blinking.
FACTORY CALIBRATION RESTORE
• Press RANGE/GLP/ to edit the desired

www.
day (01-31). If the key is kept pressed It is possible to delete the calibration and
the day number is automatically increased. restore factory calibration.
• Press and hold for three seconds
Note:It is possible to change the editing RANGE/GLP/ to enter GLP mode.
from day to year and to month by
pressing READ/ /TIMER. • Press READ/ /TIMER to enter in the

1.800.561.8187
factory calibration restore screen. The
• Press ZERO/CFM to save the calibration instrument asks for confirmation of user
date. calibration delete.
• Press ZERO/CFM to restore the factory
• The instrument displays “Stor” for one
calibration or press RANGE/GLP/ again
second and the calibration is saved.
to abort factory calibration restore.
• The instrument will return automatically • The instrument briefly indicates “donE”
to measurement mode by displaying upon restoration of factory calibration prior
dashes on the LCD. to returning to measurement mode.
22 23
 BATTERY MANAGEMENT ACCESORIES

[email protected]
To save battery, the instrument shuts down after 10 minutes of non-use in measurement mode and after
1 hour of non-use in calibration mode. REAGENT SET
If a valid measurement was displayed before HI 93701-01 Reagents for 100 Free Chlorine tests
auto shut off, the value is displayed when the HI 93701-03 Reagents for 300 Free Chlorine tests
instrument is switched on. The blinking “ZERO” HI 93711-01 Reagents for 100 Total Chlorine tests
means that a new zero has to be performed. HI 93711-03 Reagents for 300 Total Chlorine tests
One fresh battery lasts for around 750 measurements, depending on the light level.
The remaining battery capacity is evaluated at the instrument startup and after each measurement. OTHER ACCESORIES
The instrument displays a battery indicator with three levels as follows: HI 96701-11 CAL CHECKTM Standard Cuvettes for Free Chlorine (1 set)
• 3 lines for 100 % capacity HI 96711-11 CAL CHECKTM Standard Cuvettes for Total Chlorine (1 set)
• 2 lines for 66 % capacity HI 721310 9V battery (10 pcs.)
• 1 line for 33 % capacity HI 731318 Cloth for wiping cuvettes (4 pcs.)
• Battery icon blinking if the capacity is under 10 %. HI 731331 Glass cuvettes (4 pcs.)
If the battery is empty and accurate measurements can’t be taken anymore, the instrument HI 731335 Caps for cuvettes (4 pcs.)
shows “dEAd bAtt” and turns off. HI 741218 Carrying case

.com
To restart the instrument, the battery must be replaced with a fresh one.
HI 93703-50 Cuvette cleaning solution (230 mL)

BATTERY REPLACEMENT

www.
To replace the instrument’s battery, follow the steps:

• Turn the instrument off by pressing ON/OFF.

• Turn the instrument upside down and remove the battery cover by turning it counterclockwise.

1.800.561.8187
• Extract the battery from its location and replace it with a fresh one.
• Insert back the battery cover and turn it clockwise to close.

24 25