Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_NUCLEUS-BT Paper -1(Adv-2022-P1-Model) Date: 24-08-2025
Time: 09.00Am to 12.00Pm RPTA-07 Max. Marks: 180*

KEY SHEET
MATHEMATICS
0.65-
1 14 2 3 32 4 2.6 5 17 6 1
0.67
7 9 8 10 9 ABD 10 ABC 11 BC 12 BC

13 AB 14 AB 15 D 16 A 17 B 18 A

PHYSICS
19 3 20 8 21 9 22 0.5 23 6 24 1.25

25 4 26 2.25 27 BCD 28 ABC 29 BD 30 AC

31 AB 32 ACD 33 C 34 A 35 A 36 B

CHEMISTRY

37 3 38 7 39 5 40 7 41 2 42 3

43 7 44 5 45 ABCD 46 ABCD 47 AC 48 CD

49 ACD 50 ABC 51 A 52 A 53 B 54 A
 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s

SOLUTIONS
MATHEMATICS
1. From the first radical sign
x 2  y 2  16 i.e. interior of a circle with circle  0, 0  and radius 4.
y

x
O

From the 2nd radical sign, y  x

3
i.e. th of the circle  Required area  12
4
1
f  x   sin 1 x  cos 1 x  tan 1    tan 1  x 
x
   
x   1, 0  f  x     0 x   0,1 f  x    
2 2 2 2
y

1,  

 0,  2 
x
 1, 0 1, 0 

1  
Required area (shaded region)  2    1  sq. units
2 2 2
t 2
t sin t
2. We have A  t    sin x 2 dx; B  t  
0
2
t t t

2  sin x dx 2
2  sin x dx2
2 sin x 2 dx
At 
 lim  lim 0
 lim 0
 lim 0
t 0 B  t  t 0 t sin t 2 t 0
3  sin t  2 t 0 t3
t . 2 
 t 
At  2sin t 2 2
Hence lim  lim  .
t 0 B  t  t 0 3t 2 3
3. required area = 1 2 X 2 X 2  (2 X 2)  1 2 (2 X 2)  8

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D C

 2, 2   4, 2 

A  2, 0   4, 0  B  6, 0 

Draw the graph of x  y  x  y  1.

4. Clearly x=1 is a root of f(x)=0.
& f ' (1)  0 & f " (1)  0& f '" (1)  0 and leading coefficient of f(x)=1  f ( x)  ( x  1)4

 0,1  2, 1

2
required area is 3   ( x  1)4 dx  14 5  2.8
1
x
x2
5. For 0  x  1, F ( x)   1  x  dx  x 
0
2
1 x
For 1  x  2, F ( x)   1  x  dx   odx  1 2  0  1 2 .
0 1
1 2 x
(2  x)3
For 2  x  3, F ( x)   1  x  dx   o.dx    2  x  dx. = 1 2 
2

0 1 2
3


 x  x / 2, 0  x  1
2


 F ( x )  1 ,1  x  2  F(1.275)= 1
2 2

 2  x
3
1
 2 ,2  x  3
 3

   1 (2  x)3 
1 2 3
2 17
Required area = xx dx   1 dx      dx 
2 2 2 3  12
0 1 2

6. Put x  tan  and y  tan  .Then 1  x  sec  , 1  y 2  sec  and the equation becomes
2

sec   sec   A(tan  sec   tan  sec  )

cos   cos   sin   sin  
  A 
cos  cos   cos  cos  
 cos   cos   A(sin   sin  )
       
 2 cos cos  2 A sin cos
2 2 2 2
 
 cot  A      2 cot 1 A
2
tan 1 x  tan 1 y  2 cot 1 A.

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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s
1  1  dy
Differentiating this, we get    0, ,
1  x  1  y 2  dx
2

Which is a differential equation of degree 1.

dx dy dx dy
7. We have, x  y 2  x y  2
dy dx dy dx
Taking positive sign,
2
 dy   dy  dy x  x 2  8 y
2   x    y  0  
 dx   dx  dx 4
But no solution exist, as it does not pass through 1, 1
Now, taking negative sign,
2
 dy   dy  dy  x  x 2  8 y
2   x    y  0  
 dx   dx  dx 4
dy dv
Let x 2  8 y  v 2  2 x  8  2v
dx dx
dv dv
So, v  x   x  v   1  v   x  c  x 2  8 y   x  C
dx dx
So, curves are x 2  8 y  x  2 and x 2  8 y   4  x 
 On squaring, we get 2 y  x  1 and x  y  2
3 1 5 m
 Clearly, required area      given 
4 2 4 n
So,  m  n  Least  5  4  9
8. Integrating factor = e x
So ye x   xe     x dx
Case – I
x2
If     0, ye x  c
2
1 x2 1 
It passes through (1,1)  C  e  So ye x  e
2 2
for   1
x2  x  1
y  e   e   e x   A
2  2
Case – II
If     0
x.e    x 1
ye x    e    x dx
   
x xe    x e     x
 ye   c
       2
e   e  
 so c  e  
       2

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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s
x
e
y      x  1  e 
 x

   
2

 x e   e   
e   2 
         
 
If     1
ex  e2 e 2 
y  2 x  1  e x  e   
4  2 4
ex  1  e2 
y   x    e x  e     c 
2 2  4
y
9. Let  v & solve
x
y
 sin  log e x  & (x sin  log ex   x   x sin  log ex   1  0
x

10. S 2   e x  sin 6 ax  cos 4 ax dx
0
2
Let I   e x  cos 6 ax  cos 4 ax dx, put x    y


I  e  e x  sin 6 ay  cos 4 ay dy  e S 2 ,.....
0

S 2 1  e  e 2  e3  e 4  1
A  x for all a  R 
S2 e 1
 1
11.  f  x  t  dt  xf  x   x 2  f   tx  dt
0 0
x x
dv
  f  t  dt  xf  x   x 2  f   v 
0 0
x
x
  f  t  dt  xf  x   x  f  x   f  0    2 xf  x   3 x
0

 f  x   2 f  x   2 xf   x   3 let y  f  x 
dy dy 1 3
 2x  y 3  y
dx dx 2 x 2x
 IF  x
3
 y x xdx  c
2x
y x  3 x  c sin ce f  0   3
Hence correct options are (B,C)
12. Let G  x   e x cos xf  x 
 G '  x   0 from given condition
 G  x  is non-increasing function.
G  b   eb cos bf  b   0
 f  b   0.
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But f  x  is non negative  f  b   0

Similarly f  7   0
x 2  3x  2  f  7   0  x 2  3x  2  0
f  x   sin  x 
lim  f 'b   
x b  x  4
13. (A) Since eln  x 1  x  1, thus eln  x 1 y
 x 1  y
 x  10 i.e., x  1 or  x  1  0
And   x  1  y   x  1 . .
Thus the region represented by inequalities   x  1  y   x  1 and x  1 i.e., 1  x  1
is as shown below

1
Thus required area is the area of ABC   4  2   4 square units.
2
2
2
(B) Required area A     sin x  x   2  dx  2

 2 sq units

(C) Area of quadrilateral ABCD is maximum when area of ACD is maximum

 distance of D from AC is maximum i.e.  cos   sin   is maximum.
 
 2 cos     is maximum
 4
7
  .
4
1
(D) Area  4 ln x dx
0
1
 4  ln xdx
0

 4  x ln x  x 0  4
1

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14.

Y  y  y   X  x  , So, Yp   0, y  xy 
dy 1  x2
So, x 2   xy   1 
2

dx x2
 dy 
 dx can not be positive i.e f  x  cannot beincrea sin g in first quadrant for x   0,1 
Hence,
1  x2 cos 2  d
 dy    x
dx  y   
sin 
; Put x  sin 

 y    cos ec d   sin  d

 y  ln  cos ec  cot    cos   C
 1  1  x2 
 y  ln    1 x2  C
 x 
 
 1  1  x2 
 y  ln    1 x2
 x 
 
as  y 1  0 
15. (P) f  x   x  x 2  sin 1 x, x   1,1
f  x   0, x   1, 0 , f  x   0x   0,1
0 1
A     sin 1 x  x  x 2 dx    sin 1 x  x  x 2  dx   1
1 0

(Q) Area will be minimum if (0,2) is ,mid-point of chord

 1
(R) 1  x  y  2 A  4 2    6
 2

k
k 2 1
 x2  k2 1
(S) A  0     
2
x kx  dx
6  k 2  1  
2
k  1
6 k2  2  2
 k 
By A.M  G.M equality holds k=1
16. (P)

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Case(i )
x0
x 3x
y   x  60   60
4 4
LHS  ve, not possible
Case  ii 
Let 0  x  60
x 5x 5x
y   x  60   60 &  60  0  x  48
4 4 4
Case  iii 
x  60
x 3 x
y    x  60    60
4 4
3x
 60  0
4
 x   60,80

 Required area =480

2 x  x2
(Q) Clearly f  x  
2
Since 2x+2y=3; passes through A 1,  and B  ,1 so bounded area
1 1
 2 2 
A=area OAB=2[area OCM+area CMNA-area ONA]
1 3 3 1  3 1  1 1 1 
 2  X X     X    2 x  x 2  dx 
2 4 4 2  4 2  4 2 0 
5
  24 A  5
24

1
6!7! 14!
A   x 6 1  x  dx  using   function  A1 
7
(R)   23.3.7.11.13
0
14! 6!7!

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(S)

A required area is the shaded region  4 2  2  1

17. (P)

Area=2
(Q)

The line x  y  1 meet the circle at point (2,1) and (1,2) in the first quadrant. The
5
5 x 5 5x 1
shaded area =   5  x dx 
2
5  x 2  sin 1
 1  tan 1
2 2 2 2 2 5 2
1
The area of the triangle with vertices 1,0  ,  2,0  and  2,1 is
2
1 5 1
The desired area =  5  8   1  tan 1 
2 2 2
 1 1
 4  20   tan 1   4  20 tan 1  4  20cot 1 3
4 2 3
2
et
t et2
y 1 2 c 1

2 2
(c) y   et dt  ce  t Ltt   - Ltt  2  t2 =
2 2 t 2 tet te 2

x  1
 x2  x2  x2
(D) f '( x)  e 2
, f 1 ( x)   x. e 2
f 11 ( x)  e 2 2

Let circle be  x  a    y  a   r 2 directional thrice and estimate a and r and get

2 2
18.

 y  x y  1  y   y   y  1  0
1 1 2 1

So P  y  x and Q  1  y1   y1 
2

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PHYSICS
19. For refraction at plane surface,
1 μ
u  (2 R  x )   0
v (2 R  x)
 2R  x 
For refraction at curved surface,  u    R  
 μ 
μ 1 μ 1
  
v'  2R  x   R
 R 
 μ 
μ
 v'  ....(i )
μ 1 μ

R 2 R  Rμ  x
Now, in order to form the final image on O itself this ray should seem to be coming from
centre of curvature C .
So v'  ( R  x )
3
From Eqs. (i) and (ii) and substituting μ 
2
9 R  145 R 2 3R
2 x 2  9 Rx  8R 2  0  x   x  3cm
4 4
20. Focal length doubles on cutting perpendicular to axis as power is halved, i.e. it will be 60
cm for each piece.
For 1st refraction,
1 1 1
   u  30 cm
u 20 60
This acts as an object for second refraction.
2nd refraction,
1 1 1 v 60
  v  60 cm m  2
v 30 60 u 30
A' A
4 cm
8 cm

B
x
20 cm

30 cm

B'
60 cm

Coordinates of final image are ( 40 cm, 4 cm ).  x  40 and y  4

x 40
 y  4 8
10 10

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21. Magnification, from given figure,
v OB OC  cot60
| m |   
 cot 2 60  1 / 3
u OA OC  cot30
Velocity of image  vi  is related to velocity of object ( v0 ) by the relation
2
1 v
vi  m v0    v0  0
2

 3 9
22. Consider a ray incident grazingly on top of the elliptical cross-section as shown

>

b
>

ae

By Snell's law, n1sin90  n2sinθ

ae
n1  n2 
b 2  (ae) 2
n2 b2 1  e2 1 n
 1  1   e  1
n1 a 2 e2 e 2
e n2

A
0
45
2 cm
750
C D

B
27.46 cm
23.
BAD  750
BD
AB
tan 750 
 BD  2 2  3  7.46cm  
Hence DP =20 cm i.e., the ray emerging from the prism passes through the centre of
curvature of the mirror.
24.

θ
θ
θ
θ
x 1200
300
1200
300 



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tan   3
  60
3 sin   1 sin     300
R x
0

2sin 30 sin1200
R R 3 3 3
  sin   
sin120 0
2  sin  2 2
3
sin  
4
25. When the lens is at mean position image is formed at focus (point ) at a distance from
the lens.
When the lens is at extreme position as shown in figure, axis of the lens tilts by  , so
incident wave makes angle  with the axis. As per rules of ray tracing this beam will be
focussed in focal plane at point which can be located using the incident ray passing
through optical centre of the lens.
Focal plane
Axis

f sec


O θ Q

P
f Focus

So, distance travelled by point of convergence as lens moves from mean

1
to extreme position ( th oscillation) is OQ  OP  fsecθ  f  f (secθ  1) Therefore,
4
in one oscillation, the convergence or image point moves 4 times this distance.
 1  cosθ 
Required distance  4 f (secθ  1)  4 f  
 cosθ 
26. Angle of incidence at which reflected ray is 100% polarised called Brewster angle α is
related to refractive index n as
5 5
n  tanα  n   As α  tan 1 
3 3
Now, corresponding to minimum value of y for which ray parallel to x -axis emerges in
air from OB in grazing emergence as shown. Therefore, incidence angle will be critical
angle C .

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B
A

>
900
5 
y n
3

O
5
By Snell's law, sinC  1  sin90
3
3
 sinC   C  37  θ  90  C  53
5
dy 4  dy 
 tanθ  tan53    As, slope  
dx 3  dx 
d  x2 
4 4 2 4

dx 3
 y  x2  2x   x  y 

3 3 9
27. Image I formed after reflection from concave mirror will be as shown.
2u
3u

S >
>
>

>
X
O O' I

u u v

t  thickness
O' is the intermediate image formed after refraction from the slab, shifted w.r.t. object
 1
O by S  t 1  
 n
Therefore, irrespective of position of slab, distance between O and O' is constant. So
velocity of O' is equal to that of O i.e. u.
Now, for reflection, velocity of image w.r.t. mirror ( vim ) is related to velocity of object
w.r.t. mirror ( vom ) by the relation vim   m 2 vom
(m  magnification)  vi  vm  m 2  vo  vm 
 vi  m2 vo  vm 1  m 2  … (i)
As per sign convention,
Velocity of object, vo  u ...(ii)
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Velocity of mirror, vm  2u

Putting values of vo and vm from
Eq. (ii) and Eq. (iii) in Eq. (i), we get
 
 vi  m 2 (u )  (2u ) 1  m 2
 2u  um  u  2  m 
2 2

 Speed of image  v  u  2  m   u
i
2

28. v of butterfly (object) w.r.t mirror

 v B  v M  6ˆj  (3i)
ˆ
 3iˆ  6ˆj
  v0 , m  x ˆi   v0 , m  y ˆj
f ( 12)
Magnification of image of butterfly in mirror, m   2
f  u (12)  (6)
Velocity of image of butterfly w.r.t mirror in x -direction, is given by
 vi,m  x   m 2  v0,m  x
  vi ,m  x  22 (3)  12 m / s
 vi , x  vm , x  12 m / s
 vi , x  12  vm, x  12  (3)
 vi , x  15 m / s .....(i)
For -direction,
f
hi  mh0  h0
f u
Differentiating w.r.t. time, we get
dhi f du mdh0
  h0 
dt ( f  u ) dt 2
dt

 vi,m  y  ( f f u )2   v0,m x h0  m  v0,m  y

( 12)  3
  2  6  11 m / s
( 12  ( 6)) 2
 vi , y  11 m / s ...... (ii)
From Eqs. (i) and (ii), velocity of image in mirror is
 vi , y  11 m / s ...... (ii)
 Relative image velocity w.r.t.
butterfly  v  v B  ( 15iˆ  11j) ˆ  6ˆj  15iˆ  5jˆ
1
Thus, relative velocity makes angle tan 1 with vertical as shown in figure
3

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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s


15
Also, for refraction at plane surface
vobject  nr
vimage 
ni
here, ni  Refractive index of medium of incidence
nr  refractive index of medium of refraction
On refraction from water surface

4
6
w.r.t. interface) 3  8m / s
1
(in y -direction)
velocity of image of butterfly w.r.t. fish is
ˆ ˆ
v B, F  v B  v F ˆ  7.5iˆ  5.5jˆ  15i  11j
 8ˆj  (7.5iˆ  2.5j)
2
This is parallel to butterfly's image velocity in mirror.
1 1 1 1 1 1
29. For refraction by lens       v  15cm
v u f v 30 10
Thus, image by lens will be formed at O' , a distance 15 cm towards right of the lens as
shown in figure f '  30 c
f  10 cm

<
<
O
O '' O'

30cm 15cm x  15 cm
v v

O' will act as object for reflection at mirror. Therefore distant of object O' from mirror
will be, as shown in the figure, equal to
u  ( x  15)
1 1 1
For reflection of mirror,  
v' u' f'
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1 1 1 30 x  450
    v' 
v' ( x  15) 30 45  x
Differentiating w.r.t. time t , we get
dv' 900 dx
 
dt (45  x ) dt 2

dv'
As v' is image distance w.r.t. mirror, will be image velocity w.r.t. mirror ( vi ,m ).
dt
dx
Also as is position of cart w.r.t. lens is velocity of cart w.r.t. lens, which will be
dt
double the velocity of centre of rollers which are in pure rolling. Top point moves with
double the velocity of centre. Therefore,
900
vi ,m   2vroller
(45  x) 2
900 (45  x) 2
  2 
(45  x) 2 600
 3 cm / s
 vi  vm  3 cm / s
 vi  3  vm  3  2  vroller
(45  x) 2
 3 2
600
(45  x) 2
 3
300
900
vi ,m   2vroller
(45  x) 2
900 (45  x) 2
 2
(45  x )2 600
 3 cm / s
 vi  vm  3 cm / s
 vi  3  vm  3  2  vroller
(45  x )2
 3 2
600
(45  x )2
 3
300
For x  60 cm ,
(45  60) 2
vi  3 
300
 3.75 cm / s

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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s
Magnification due to lens,
v 15 1
m1   
u 30 2
Magnification due to mirror,
v' 30 x  450 30
m2   
u' (45  x)( x  15) 45  x
For x  60 cm ,
30
m2  2
45  60
Therefore, net magnification
1
m  m1  m2   2  1
2
30. The figure shows a strip at a distance x of thickness dx , As μ of material increases with
x , ray will deviate continuously as shown. By Snell's law, between O and A ,

2R
Y
θ
O 

900 X

2R
1 sin90   sinθ
2R  x
2R  x
 tanθ 
(2 R )2  (2 R  x) 2
dy 2R  x
 
dx (2 R )2  (2 R  x )2
y x
2R  x
 dy   dx
0 0 (2 R ) 2  (2 R  x )2
 y  (2 R) 2  (2 R  x) 2
 y 2  ( x  2 R ) 2  (2 R ) 2
which is equation of circle of radius 2R centred at (2 R, 0) . Also, equation of
hemispherical surface is
x2  y 2  R2  y 2  R2  x2

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2
Putting this value of y in equation of trajectory, we can find coordinates of point where
the ray comes out of hemisphere, as
R 2  x2  ( x  2R)2  4R 2

R
 x   y  R2  x2
4
2
R 15 R
 R    2

4 4
 0.97 R
From the diagram,
y 15 16 1
sinδ     0  δ  30
2R 8 8 2
31.
f f
t
n0
S
★

St St
2 2

S
S t t
 2f
2 2n0
1 
S  t   1  4 f
 n0 
 1
S  4 f  1   t
 n0 
Also
S t t
  f
2 2n0
 1
S  2 f  1   t
 n0 

32.

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 A
>
θ
90  2θ C r

>
h1
>
>i h2
2θ 2 
B

i  90  30  180
 90  30,  sin i  1 sin r ,  cos 3  1  sin r
cos 
 cos 3  sin  90    ,  
cos 3
h1 BC AB
AB  , In ABC ,  , h2  BC sin 2
sin 2 sin  sin 3
3 1  2  1 3   2
33.   
v u R1 R2
2 5 / 3 2  (3 / 2) 144
  ,v  .......(i)
v 12 12 13
 144 
v 1  13  5 / 3 10
 mT      .......(ii)
u 3 12 2 13
2
  144  
 
v
2
   13   5 / 3 120
mL     1       .......(iii)
u
   3   12  2 169
 
 120  480
Ax  (5cos 37 )   mm
 169  169
 10  30
Ay  (5sin 37 )    mm
 13  13
 120  96
vx  (1cos 37 )   m/sec
 169  169
 10  6
v y  (1sin 37 )    m/sec
 13  13
34. Calculate the apparent distances and differentiate
35. A-(q); B-(p); C-(r); D- (s)
36. Calculate the position of image at any instant t in terms of R and differentiate

CHEMISTRY
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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s
37. KEY: 3
SOL: Three Compounds are less acidic
38. KEY: 7
SOL: i,iv,v,viii,x,xi,xii
39. KEY: 5
SOL: phenols coupling does not take place in strong basic medium
O OEt
CO 2Et

H3O O
 O

OEt
 EtOH
  Et 

HO 2C N
N O N EtO2C N

CO 2Et   keto acid
OEt

CO2

N 2 H4 , OEt  O

(wolf kishnes
N reduction)
N
40. key-7
Molecular mass of ethene = 28
Molecular mass of vinyl chloride = 62.5
Empirical formula mass of copolymer =90.5
62.5  100
Mass percentage eof vinyl chloride in the copolymer is  69.06
90.5
41. Key:2
SOLUTION:

42. KEY: 3
SOL: Double Michael Addition
43. KEY: 7
SOL: Refer NCERT
44. KEY - 5
Cl O
H 2O /  (can give Iodoform)
(i) 
Cl

 (does not give iodoform)

(ii) 
H 3O

OH
O O

O
(iii) 
I 2 / NaOH
  CHI 3
O
O
O
(iv)   keto ester does not give Iodoform

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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s
O O
O
Hg  OAC  / H O  NaBH (can give iodoform)
(v) 
2 2

4


O
I 2 NaOH
 vi  C C CH 3  Can ' t give Idoform

O
I 2 NaOH
 vii  CH 2 C CH 3  can give Iodoform 

CH 3
O
I 2 NaOH
 viii  H 3C C C CH 3  Can give Idoform

CH 3
O O

 ix  CN 
I 2 / NaOH
  Can ' t give Idoform 
45. ABCD are correct
46. KEY: ABCD
Solution:
O
O
O
H2SO4 Zn KMnO4 phenol
C21H16O3
Δ Δ H2SO4

H3 C CH3
HO
OH
47. Key: AC
Sol: Conceptual, Modified question from NCERT.
48. CD

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 Sri Chaitanya IIT Academy 24-08-25_Sr.Super60_NUCLEUS-BT_Jee-Adv(2022-P1)_RPTA-07_Key& Sol’s
HO OH
COOH (  Ve) FeCl3 Test

(  Ve) Cerric ammonium nitrate test

(  Ve) NaOH Test

( Ve) NaHCO3 Test

Sol : OH

49. KEY: ACD

50. KEY:ABC
SOL-AB,,C are correct
51. KEY: A
SOL: 1-S,2-R,3-Q,4-P
52. KEY:A
SOL. A-PS B-QS C-PS D-PRS
53. KEY: B
O

H3C
O (i) LiAlH4 H3C
OH
O (ii) dil H+
CH3 OH
O
O
H3C CH3

O (i) excess CH3MgCl O

(ii) H+
H3C O H3 C O

O
(i) LiAlH4
3 CH 3OH
H3CO OCH3 (ii) dil H+
O Ph OH
H+

Ph CH3 H2O HO CH3

54 . KEY: A
SOL: P-3,4; Q-2,3,4; R-1,2; S-1,5

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