Bonding
Bonding
Chapter:
Bonding
Lecture given by
Dr. Md. Anwarul Azim Akhand
Professor
Dept. of Genetic Engineering and Biotechnology
University of Dhaka
Chemical Bonds: How atoms Form Molecules
• When the outermost energy level of an atom is not completely
filled by electrons, one may think of it as having either unfilled
spaces or extra electrons in that energy level, depending on
whether it is easier for the atom to gain or lose electrons.
• For example, an atom of oxygen, with two electrons in the first
energy level and six in the second, has two unfilled spaces in
the second electron shell; an atom of magnesium has two
extra electrons in its outermost shell.
Mg can donate 2 electrons and O
• The most chemically stable configuration for any atom is to can accept 2 electrons
have its outermost shell filled.
• Therefore, for these two atoms to attain that state, oxygen
must gain two electrons, and magnesium must lose two
electrons.
• Because all atoms tend to combine so that the extra electrons
in the outermost shell of one atom fill the spaces of the
outermost shell of the other atom, oxygen and magnesium
combine so that the outermost shell of each atom has the full
complement of eight electrons. Ionic bond
Chemical Bonds: How atoms Form Molecules
• The valence, or combining capacity, of an atom is the number of extra or missing
electrons in its outermost electron shell.
• For example, hydrogen has a valence of 1 (one unfilled space, or one extra electron),
oxygen has a valence of 2 (two unfilled spaces), carbon has a valence of 4 (four unfilled
spaces, or four extra electrons), and magnesium has a valence of 2 (two extra electrons).
• Basically, atoms achieve the full complement of electrons in their outermost energy shells
by combining to form molecules, which are made up of atoms of one or more elements. A
molecule that contains at least two different kinds of atoms, such as H2O (the water
molecule), is called a compound. In H2O, the subscript 2 indicates that there are two
atoms of hydrogen; the absence of a subscript indicates that there is only one atom of
oxygen.
• Molecules hold together because the valence electrons of the combining atoms form
attractive forces, called chemical bonds, between the atomic nuclei. Chemical bonding,
therefore, refers to the formation of a chemical bond between two or more atoms,
molecules or ions to give rise to a chemical compound. These chemical bonds are what
keep the atoms together in the resulting compound.
• Therefore, valence may also be viewed as the bonding capacity of an element. Because
energy is required for chemical bond formation, each chemical bond possesses a certain
amount of potential chemical energy.
Types of Chemical Bonds
• When substances participate in chemical bonding and yield compounds, the stability of
the resulting compound can be determined by the type of chemical bonds it contains.
• The type of chemical bonds formed varies in strength and properties. There are four
primary types of chemical bonds which are formed by atoms or molecules to yield
compounds. These types of chemical bonds include:
1. Ionic Bonds
2. Covalent Bonds
3. Hydrogen Bonds
4. Metallic Bonds
• These types of bonds in chemical bonding are formed from the loss, gain or sharing of
electrons between two atoms/molecules.
Types of Chemical Bonds: Ionic Bond
• Ionic bonding is a type of chemical bonding which involves a transfer of electrons from
one atom or molecule to another.
• Here, an atom loses an electron, which is, in turn, gained by another atom.
• When such an electron transfer takes place, one of the atoms develops a negative charge
and is now called the anion. The other atom develops a positive charge and is called the
cation.
• The presence of two oppositely charged ions results in a strong attractive force between
them. This force is an ionic or electrovalent bond.
• Ionic bonds form between atoms with large differences in electronegativity, whereas
covalent bonds formed between atoms with smaller differences in electronegativity.
• The ionic bond gains strength from the difference in charge between the two atoms, i.e.,
the greater the charge disparity between the cation and the anion, the stronger the ionic
bond.
Example of Ionic Bond
Example of Ionic Bond
• See another example of the reaction between magnesium and chlorine as ionic bond
formation. The magnesium atom has two electrons in its outermost shell. By losing two
electrons from its M shell its L shell becomes the outermost shell that has a stable octet.
So, a net positive charge is developed on this magnesium atom, giving a magnesium
cation Mg2+.
• On the other hand, the chlorine atom has seven electrons in its outermost shell.
Therefore, it needs only one electron to complete its octet. It can gain this one electron
from the electrons lost by the magnesium atom to become magnesium ion. As two
electrons are lost by a magnesium atom while one chlorine atom can gain only one
electron, two atoms of chlorine combine with one atom of magnesium to form
magnesium chloride.
Example of Ionic Bond
Electronic
Element Reaction Formed ion
config.
• Now when Na reacts with Cl, reaction 1 and reaction 3 will take place and the resultant
compound will be NaCl.
• When Na reacts with O, reaction 1 and reaction 4 will take place and the resultant
compound will be Na2
• When Ca reacts with Cl, reaction 2 and reaction 3 will take place and the resultant
compound will be CaCl2.
• When Ca reacts with O, reaction 2 and reaction 4 will take place and the resultant
compound will be CaO.
Properties of Ionic Bond
Due to the presence of a strong force of attraction between cations and anions in ionic
bonded molecules, the following properties are observed:
• The ionic bonds are the strongest of all the bonds.
• The ionic bond has charge separation, and so they are the most reactive of all the bonds in
the proper medium.
• The ionic bonded molecules have high melting and boiling point.
• The ionic bonded molecules in their aqueous solutions or in the molten state are good
conductors of electricity. This is due to the presence of ions which acts as charge carriers.
Types of Chemical Bonds: Covalent Bond
• A covalent bond indicates the sharing of electrons between atoms.
• Compounds that contain carbon (also called organic compounds) commonly exhibit this
type of chemical bonding.
• This sharing of electrons happens because the atoms must satisfy the octet (noble gas
configuration) rule while bonding.
• One pair of electrons shared between two atoms constitutes a single covalent bond,
generally referred to as a single bond. An unshared pair of valence electrons is called a
lone pair.
• The pair of electrons which are shared by the two atoms now extend around the nuclei of
atoms, leading to the creation of a molecule. Covalent bonding can be achieved in two
ways: Sharing of electrons between atoms of the same kind, for example, formation of H 2,
Cl2, O2, etc. Sharing of electrons between atoms of different kinds, for example, formation
of CH4, H2O, NH3, etc.
• Example: Two atoms of hydrogen (H) combine to form hydrogen (H2) gas. Each atom of
hydrogen has one electron and would be more stable with two electrons. There is no
reason why one hydrogen atom would donate its electron and the other accept it. Instead,
the two hydrogen atoms can share their electrons: H· + H· → H:H
• One atom of carbon (C) combines with four atoms of hydrogen (H) to form methane (CH 4).
Example of Covalent Bond
Properties of Covalent Bond
A covalent bond is formed between two similar This type of bond is formed between a metal
electronegative non-metals and non-metal
Bonds formed from covalent bonding have a Ionic bonds have no definite shape
definite shape
Low melting point and boiling point High melting point and boiling point
Low polarity and more flammable High polarity and less flammable
Covalent bonds are in a liquid or gaseous state At room temperature, ionic bonds have a solid
at room temperature state.
• Compared to ionic and covalent bonding, Hydrogen bonding is a weaker form of chemical
bonding.
• It is a type of polar covalent bonding between oxygen and hydrogen, wherein the hydrogen
develops a partial positive charge.
• This implies that the electrons are pulled closer to the more electronegative oxygen atom.
• This creates a tendency for the hydrogen to be attracted towards the negative charges of
any neighbouring atom.
• This type of chemical bonding is called a hydrogen bond and is responsible for many of the
properties exhibited by water.
Types of Chemical Bonds: Hydrogen Bond
• Solubility: Lower alcohols are soluble in water because of the hydrogen bonding which can
take place between water and alcohol molecules.
• Volatility: As the compounds involving hydrogen bonding between different molecules have
a higher boiling point, they are less volatile.
• Viscosity and surface tension: The substances which contain hydrogen bonding exist as
associated molecules. So, their flow becomes comparatively difficult. They have higher
viscosity and high surface tension.
• The lower density of ice than water: In the case of solid ice, hydrogen bonding gives rise to
a cage-like structure of water molecules. As a matter of fact, each water molecule is linked
tetrahedral to four water molecules. The molecules are not as closely packed as they are in a
liquid state. When ice melts, this case-like structure collapses, and the molecules come
closer to each other. Thus for the same mass of water, the volume decreases and density
increases. Therefore, ice has a lower density than water at 273 K. That is why ice floats.
Types of Chemical Bonds: Metallic Bond
• A metallic bond is formed in the case of metals that form metallic lattices in which
positively charged metal ions are surrounded by electrons.
• Metallic bonding is a type of chemical bonding and is responsible for several
characteristic properties of metals such as their shiny lustre, their malleability, and their
conductivities for heat and electricity.
• This lattice structure and the fact that metal ions are attracted to the delocalized
electrons grants metals high melting and boiling points.
• Metals are the best electricity conductors due to the motion of the electrons.
• Metallic bonds differ from covalent and ionic bonds because it is formed by the attraction
of positively charged metal nuclei and their delocalized valence electrons between two or
more metal atoms.
• The factors that affect the strength of a metallic bond include:
Total number of delocalized electrons.
Magnitude of positive charge held by the metal cation.
Ionic radius of the cation
An illustration describing the way electrons are
delocalized over a rigid lattice of metal ions in a
metallic bond is provided below.
Metallic Bonding in Sodium and Magnesium
• The electron configuration of sodium is 1s22s22p63s1; it contains one electron in its
valence shell. In the solid-state, metallic sodium features an array of Na + ions that are
surrounded by a sea of 3s electrons.
• However, it would be incorrect to think of metallic sodium as an ion since the sea of
electrons is shared by all the sodium cations, quenching the positive charge.
• An illustration describing the metallic bonding in
sodium is shown.
• The softness and low melting point of sodium
can be explained by the relatively low number of
electrons in the electron sea and the relatively
small charge on the sodium cation.
• For example, metallic magnesium consists of an
array of Mg2+ ions. The electron sea here contains
twice the number of electrons than the one in
sodium (since two 3s electrons are delocalized
into the sea, 1s22s22p63s2). Due to the greater
magnitude of charge and the greater electron
density in the sea, the melting point of
magnesium (~650oC) is significantly higher than
that of sodium.
Properties of Metallic Bond
• Thermal conductivity: Metals conduct heat because the free electrons are able to
transfer energy away from the heat source and also because vibrations of atoms
(phonons) move through a solid metal as a wave.
Properties of Metallic Bond
• Malleability and Ductility: When an ionic crystal (such as sodium chloride crystal) is
beaten with a hammer, it shatters into many smaller pieces. This is because the atoms in
the crystals are held together in a rigid lattice that is not easily deformed. The
introduction of a force (from the hammer) causes the crystal structure to fracture,
resulting in the shattering of the crystal.
In the case of metals, the sea of electrons in the metallic bond enables the deformation
of the lattice. Therefore, when metals are beaten with a hammer, the rigid lattice is
deformed and not fractured. This is why metals can be beaten into thin sheets. Since
these lattices do not fracture easily, metals are said to be highly ductile.
• Metallic Luster: Metals tend to be shiny or display metallic luster. They are opaque once a
certain minimum thickness is achieved. The electron sea reflects photons off the smooth
surface. There is an upper-frequency limit to the light that can be reflected. When light is
incident on a metallic surface, the energy of the photon is absorbed by the sea of
electrons that constitute the metallic bond. The absorption of energy excites the
electrons, increasing their energy levels. These excited electrons quickly return to their
ground states, emitting light in the process. This emission of light due to the de-excitation
of electrons attributes a shiny metallic lustre to the metal.
Properties of Metallic Bond
• High Melting and Boiling Points: As a result of powerful metallic bonding, the attractive
force between the metal atoms is quite strong. In order to overcome this force of
attraction, a great deal of energy is required. This is the reason why metals tend to have
high melting and boiling points. The exceptions to this include zinc, cadmium, and
mercury (explained by their electron configurations, which end with ns 2).
The metallic bond can retain its strength even when the metal is in its melt state. For
example, gallium melts at 29.76oC but boils only at 2400oC. Therefore, molten gallium is a
non volatile liquid.
Difference among Ionic, Covalent and Metallic Bonds
Occurs during the transfer of Occurs when 2 atoms share their The attraction of metal
electrons valence electrons cations/atoms and delocalized
electrons
Binding energy is higher than the Binding energy is higher than the Binding energy is less than
metallic bond metallic bond covalent and ionic bond
Present only in one state: solid- Present only in all 3 states: solid, Present only in one state: solid-
state liquid, gases state
Linear Linear
AB3 3 0 BF3, BCl3
Trigonal
Planer
Trigonal
Planer
AB4 4 0 Bent CH4, CCl4
Tetrahedral Tetrahedral
Geometry of some covalent
molecules based on VSEPR theory
Molecular No of Bond No of Lone Molecular Shape of the Examples
Type Pairs Pairs geometry molecule
AB3L 3 1 NH3
AB5 5 0 PF5
Tetrahedral Bent
AB4L 4 1 SF4
AB2L3 2 3 XeF2
T-shaped
Trigonal bipyramidal
Linear
Trigonal bipyramidal
Geometry of some covalent
molecules based on VSEPR theory
Molecular No of Bond No of Lone Molecular Shape of the Examples
Type Pairs Pairs geometry molecule
Octahedral Octahedral
AB5L 5 1 ClF5
AB4L2 4 2 XeF4
Octahedral Square pyramidal