Republic of the Philippines
Department of Education
Region III
DIVISION OF NUEVA ECIJA
AROMATICY AND
NOMENCLATURE OF
AROMATIC COMPOUND
ALLYNN A. JUNIO PEÑARANDA NATIONAL HIGH SCHOOL
Science Teacher Peñaranda, Nueva Ecija
Prayer
2
PERFECT
Different Classifications of
Hydrocarbons
PNHS
Review : Aliphatic
Hydrocarbons
PNHS 5
What am I?
Hexane
PNHS 6
What am I?
hept-3-ene
PNHS 7
What am I?
2-hexyne
CH3CH2CH2C≡CCH3
PNHS 8
What am I?
2-methylpropane
PNHS 9
What am I?
trans-2-butene
PNHS 10
What am I?
cyclopentane
PNHS 11
SPOT THE
DIFFERENCE
Which is aromatic? PNHS
m I
A tic?
m a
aro
Activity 1: “Am I Aromatic?”
Am I cyclic? (Yes/No)
14
“Am I Aromatic?”
a. Am I cyclic? (Yes / No )
b. Do I have alternating double and single bonds? (Yes / No)
c. Are all of my carbon atoms hybridized? (Yes / No )
d. How many pi bonds do I have? (1; 2; 3; 4)
e. How many pi electrons do I have (1; 2; 3; 4)
15
“Am I Aromatic?”
a. Am I cyclic? (Yes / No )
b. Do I have alternating double and single bonds? (Yes / No)
c. Are all of my carbon atoms hybridized? (Yes / No )
d. How many pi bonds do I have? (1; 2; 3; 4)
e. How many pi electrons do I have (1; 2; 3; 4)
16
Differences between Aromatic,
Antiaromatic
and Nonaromatic
17
Is benzene aromatic?
a. Is this molecule cyclic?
b. Does it have an alternating single and double
bonds?
c. Are all carbon atoms of this molecule hybridized?
d. Is it planar?
e. Does it follows huckle’s rule?
18
Benzene, an Aromatic Compound
Benzene is
• an aromatic compound.
• It was isolated from other hydrocarbon by Michael Faraday In 1825
• Its molecular formula is C6H6.
• a ring of six C atoms, each bonded to one H atom.
• Friedrich August Kekulé suggested the structure of benzene
• a flat ring structure drawn with three alternating double bonds.
• represented by two structures, because the electrons are shared
equally among all the C atoms.
• represented by a line-angle structural formula using a circle in the
center instead of the alternating double bonds.
General, Organic, and Biological Chemistry: Structures of Life, 5/e © 2016 Pearson Education, Inc.
Karen C. Timberlake
Nomenclature Aromatic
Compounds
When a benzene ring is a substituent, — C 6H5,
it is named as a phenyl group.
3-phenyl-1-butene
20
Nomenclature Aromatic
Compounds
chlorobenzene
bromobenzene 21
Nomenclature Aromatic
Compounds
22
Nomenclature Aromatic
Compounds
23
Some Representative
Aromatic Compounds
24
Chemistry Link to Health:
Common Aromatic Compounds
Toluene is used as a reactant to make drugs, dyes,
and explosives such as TNT (trinitrotoluene).
The benzene ring is also found in some amino acids
The benzene ring is found in pain relievers such as
aspirin, acetaminophen, and ibuprofen; and in
flavorings such as vanillin.
25
Common Aromatic Compounds
Naphthalene has long been used as a primary
ingredient in mothballs due to its ability to repel
insects and prevent damage to clothing and fabrics.
It acts as a fumigant that releases a gas toxic to
insects and pests
26
Activity time
my
a ke ”
“M ctur e
ru
st
Safety Rules and Guidelines
Be careful in handling sharp objects. Keep the object
pointed away from yourself and other people at all
times
Always be aware of hazards and risks
Know the hazards of the activity and anticipate dangers
BE SAFETY CONSCIOUS AT ALL TIMES!
Activity 2: “ Make my structure
baby”
1. I am a six carbon atom ring with six pi electrons that are free to
delocalized. I am conjugated, planar that is why sp3 is out of sight.
In my first and third carbon, substituents methyl are holding tight..
2. I am made up of two rings fused together., planar, fully conjugated,
and sp2 hybridized. I have 10 pi electrons freely moving around my
carbons to delocalized . Chemists call me naphthalene but to your
mom, simply a mothballs is my name.
3. I am cyclic , planar,sp2 nybridized and fully conjugated, with 3 pi
bonds moving around my six carbon-ring. My common name is
toluene but in IUPAC naming, my parent name is benzene with an
alkyl group that was formed when one hydrogen was removed from
methane.
4. Each of my carbon atoms is sp2 hybridized. In addition, I am cylic,
conjugated and planar. But I am sad to say that I only have 4 sigma
Quiz
Identify the following as aromatic, antiaromatic or
nonaromatic.
Answer the following:
Select the correct name for each compound.
4. A. chlorocyclohexane
B. chlorobenzene
C. 1-chlorobenzene
5. A. 1,2-dimethylbenzene
B. 1,4-dimethylbenzene
C. 1,3-dimethylbenzene
Assignment (Additional Activity)
Each group will brainstorm on what you have learned about aromatic
hydrocarbons. Each group will present the concept in your most creative
way. May it be in the form of dancing (dance formation), singing, jingle,
poetry, etc.
Criteria: Content – 20 points; Artistry – 10 points; Teamwork – 10 points
32
Thank you and God Bless!
- ALLYNN A.
JUNIO
ChemistryTeacher
PNHS
