Chapter 6 Thermo
Chapter 6 Thermo
1. Introduction
inequality of Clausius
Heat is transferred in two places, the boiler and the
condenser. Therefore,
heat engine refrigerator or heat pump
du= CpdT
ds= CpdT/T
(T2/T1)=(v2/v1)^(1-k)
• ds=0= Cvln(T2/T1)+RLn(v2/v1)
• Cvln(T2/T1)=Rln(v2/v1)
• Ln(T2/T1)=R/Cvln(v2/v1)
• (T2/T1)=(v2/v1)^(R/Cv)
• R/Cv=(Cp-Cv)/Cv= Cp/Cv-1=k-1
• (T2/T1)=(v2/v1)^(1-k)
28
due to irreversibilities occurring inside the system
caused by the processes such as friction, unrestrained
expansions, and the internal transfer of energy
(redistribution) over a finite temperature difference.
40
Notes