ALKYNES THE HYPER-VERSATILE BUILDING BLOCKS OF CHEMISTRY
Cyclopropanation Modified Simmons-Smith reaction
Allenes Homologous
Eneynes Conjugated
Eneynes Oligomerization
1,3-butadienes
Amines Hydroamination
Aldehydes/Carboxy Acids Allylic
Diketones 1,4- and 1,5- disubstituted
1,3,5-triketones
Hexaethynylbenzenes
[4]-radialenes
Carbocycles Conjugated 2- substituted cycloheptadienes
Carbocycles 2-cyclopentenones
Carbocycles 9-alkylidene-9 H- fluorenes
Carbocycles Synthesis of civetone via ring-closing metathesis
Heterocycles Pyrazoles & Isoxazoles
Heterocycles Maleic Anhydrides
Heterocycles 1,2,3-triazoles (‘click chemistry’)
Heterocycles pyrroles
Heterocycles Benzofurans, indoles, isocoumarins
Heterocycles Benzopyrans and coumarins
Heterocycles 2-substituted furo[3,2-b]pyridines
Heterocycles Isoquinolines
Heterocycles bispyrrolopyrimidines
Heterocycles 2,3-dihydrofurans

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