CHEMICAL AND ELECTRO-CHEMICAL
ENERGY BASED PROCESSES
INTRODUCTION
• The metal is removed from the work piece
through controlled etching or chemical attack
of the work piece material in contact with a
chemical solution
CHEMICAL MACHINING
In this method , the metal is removed by ion
displacement of the work piece material in
contact with a chemical solution
Examples
1. Electro-chemical machining (ECM)
2. Electro-chemical Grinding (ECG)
3. Electro-chemical Honing (ECH)
4. Electro-chemical Deburring (ECD)
Chemical Machining
Processes in ECM
Maskant coating
Cleaning
Drying
Dipping in chemical solution
Stirring & Heating – For uptain Uniform Depth
washing
Maskant Coating
Selective Machining
The selective portions (un-machining areas)
covered by resistant material. called maskants
CLEANING
• Trichloroethylene vapour
Or
• Solution of mild alkaline at 85 – 90 degree
celcius
The above solutions are used to remove oil and dust
from the work piece
Drying
After cleaning the work piece is dried in air
Dipping in Chemical solution
• Caustic soda - for Aluminium
• Hydrochloric acid and nitric acid – for steel
• Iron chloride – for stainless steel
The metal is removed by the chemical conversion of
metal into metallic salt
Dipping time will varies from amount of material to
removed from work piece
Stirring & Heating
For obtain uniform depth of metal removal ,
temperature control and stirring of chemical
reagent is important
washing
• To prevent further reaction after require
shape obtained, the metal is cleaned properly
ETCHANT (CHEMICAL SOLUTION)
MASKANTS
• Scribed and Peeled Maskants
• Photo resists Maskants
METHODS OF MASKANTS
Scribed and Peeled Maskants
For ordinary work piece a paint like material
sprayed or dipped or brushed over the metal
Maskant
.
Photo resists
Maskants
• For close tolerance and
dimensional accuracy
needed places
• Paint spray type work is
done for preparing
master copy
• The master drawing is
photographed and it
reduced to the size of
the finished part
Photo resists
Maskants
• Then the material is
placed over the work
piece.
• And it exposed to UV
light to harden
• Then its dipped in
organic solution for
maskanting.
• Finally it dipped in
chemical solution for
machining
.
.
.
Electro-chemical Machining (ECM)
Principle
Faraday,s Law of Electrolysis
FIRST LAW
Amount of metal deposited directly
proportional to quantity of electricity
SECOND
LAW
Amount of Change in metal is directly
proportional to its electrochemical
equivalent of the material
Basic electroplating concept
• So work piece Negative terminal (Cathode)
• Things to be coated is connected to positive Terminal
(Anode)
ECM – REVERSE OF
ELECTROPLATING
Our objective is - Metal should be removed
from the work piece
So work piece positive terminal (Anode)
Tool is connected to Negative Terminal (Cathode)
When current is passed , the work piece loses metal
and the dissolved metal is carried out by circulating
an electrolyte between them
.
TOOL
- Titanium , stainless steel,
brass and copper
ELECTROLYTE
-Sodium Nitrate
SERVO MOTOR
- To Control Tool Feed
Rate
Tool and Work piece
Gap 0.05 – 0.5mm
Electrochemical Machining (ECM)
• Reverse of electroplating
• Work material must be a conductor
• Material removal by anodic dissolution
• Electrical energy + chemical energy
Voltage 5-30 volts
Electrolyte Velocity 30 – 60 m/s
Current 20 -300A/cm2
During process -------
• Due to applied voltage, the current flows through
the electrolyte with positively charged ions and
negatively charged ions.
• The positive ions move towards the tool (Cathode)
while negative ions move towards work piece (Anode)
So , Electro-chemical Reaction takes place due to this flow.
ELECTRO-CHEMICAL GRINDING (ECG)
OR
ELECTROLYTIC GRINDING
.
PRINCIPLE
Machining operation by the combined
action of Electro-chemical effect and
conventional grinding operation
90 % - Metal removed by chemical Action
10 % -Metal removed by Grinding Action
Electro-chemical Grinding (ECG)
Work Piece
+Ve Terminal
Grinding Wheel
- Ve Terminal
D.C.Voltage 3 – 30 V
Gap 0.025mm
ELECTROLYTE
Sodium Nitrate
Sodium Chloride
Potassium Nitrate
+ Water
Grinding Wheel – Fine Diamond Particle
Grinding Wheel speed – 900 -1800 m/min
PROCESS PARAMETERS
1. Current Density
100 – 200 A / cm2
The MRR increases with the Increase of Current
Density – which results high Surface Finish
PROCESS PARAMETERS
2. Electrolyte
Sodium Nitrate
Sodium Chloride
Potassium Nitrate
The MRR increases with the correct composition
of electrolyte with water – which results high
Surface Finish
Maintained at a Temperature
of 15 – 30 Degree Celcius
PROCESS PARAMETERS
3. Feed Rate
Slow feed Poor Surface Finish
High feed Excess Tool Wear –
Poor Surface Finish
Optimum feed Good Surface Finish
ADVANTAGES OF ECG
1. Life of the grinding wheel is high (because 90% material
removed by chemical process)
2. No heat is produced in the process so the work surfaces
are free from cracks.
3. Less cutting force only required
4. Good surface finish is obtained.
5. Work material not subjected to any structural changes
6. Burr free and stress free components are made.
7. No Frequent dressing of grinding wheel required.
DIS -ADVANTAGES OF ECG
1. High initial cost
2. Power consumption is high
3. MRR is lower than conventional method
4. Non – conducting material cannot be machined.
5. Need safety things for acid usage in process.
6. Maintenance cost is high
Applications of ECG
Its best suited for
1. precision grinding on hard materials
2. Cutting of hard material with thin sections
without any damage
ELECTRO-CHEMICAL HONING
for Internal grinding
Combined action
of electro-
Chemical attack
and Honing stone
effect
MRR is 10 times faster than conventional internal
Grinding
Less tool Wear
Less Pressure is required between Honing tool and
work piece
Burr Free and Stress free Components are produced
Tolerance 0.012mm
Work Piece + Ve Terminal (Anode)
Tool -Ve Terminal (Cathode)
Gap = 0.075 to 0.125 mm
Electrolyte Supply = 112 lit /min
Voltage = 25 V
Advantages of ECH
Problem -1
GIVEN DATA
PROBLEM-2
Electro Chemical Machining Process

Electro Chemical Machining Process

  • 1.
  • 2.
    INTRODUCTION • The metalis removed from the work piece through controlled etching or chemical attack of the work piece material in contact with a chemical solution
  • 3.
    CHEMICAL MACHINING In thismethod , the metal is removed by ion displacement of the work piece material in contact with a chemical solution
  • 4.
    Examples 1. Electro-chemical machining(ECM) 2. Electro-chemical Grinding (ECG) 3. Electro-chemical Honing (ECH) 4. Electro-chemical Deburring (ECD)
  • 5.
  • 6.
    Processes in ECM Maskantcoating Cleaning Drying Dipping in chemical solution Stirring & Heating – For uptain Uniform Depth washing
  • 7.
    Maskant Coating Selective Machining Theselective portions (un-machining areas) covered by resistant material. called maskants
  • 8.
    CLEANING • Trichloroethylene vapour Or •Solution of mild alkaline at 85 – 90 degree celcius The above solutions are used to remove oil and dust from the work piece
  • 9.
    Drying After cleaning thework piece is dried in air
  • 10.
    Dipping in Chemicalsolution • Caustic soda - for Aluminium • Hydrochloric acid and nitric acid – for steel • Iron chloride – for stainless steel The metal is removed by the chemical conversion of metal into metallic salt Dipping time will varies from amount of material to removed from work piece
  • 11.
    Stirring & Heating Forobtain uniform depth of metal removal , temperature control and stirring of chemical reagent is important
  • 12.
    washing • To preventfurther reaction after require shape obtained, the metal is cleaned properly
  • 13.
  • 14.
  • 15.
    • Scribed andPeeled Maskants • Photo resists Maskants METHODS OF MASKANTS
  • 16.
    Scribed and PeeledMaskants For ordinary work piece a paint like material sprayed or dipped or brushed over the metal
  • 17.
  • 18.
    Photo resists Maskants • Forclose tolerance and dimensional accuracy needed places • Paint spray type work is done for preparing master copy • The master drawing is photographed and it reduced to the size of the finished part
  • 19.
    Photo resists Maskants • Thenthe material is placed over the work piece. • And it exposed to UV light to harden • Then its dipped in organic solution for maskanting. • Finally it dipped in chemical solution for machining
  • 20.
  • 21.
  • 22.
    Principle Faraday,s Law ofElectrolysis FIRST LAW Amount of metal deposited directly proportional to quantity of electricity SECOND LAW Amount of Change in metal is directly proportional to its electrochemical equivalent of the material
  • 23.
    Basic electroplating concept •So work piece Negative terminal (Cathode) • Things to be coated is connected to positive Terminal (Anode)
  • 24.
    ECM – REVERSEOF ELECTROPLATING Our objective is - Metal should be removed from the work piece So work piece positive terminal (Anode) Tool is connected to Negative Terminal (Cathode) When current is passed , the work piece loses metal and the dissolved metal is carried out by circulating an electrolyte between them
  • 25.
    . TOOL - Titanium ,stainless steel, brass and copper ELECTROLYTE -Sodium Nitrate SERVO MOTOR - To Control Tool Feed Rate Tool and Work piece Gap 0.05 – 0.5mm
  • 26.
    Electrochemical Machining (ECM) •Reverse of electroplating • Work material must be a conductor • Material removal by anodic dissolution • Electrical energy + chemical energy Voltage 5-30 volts Electrolyte Velocity 30 – 60 m/s Current 20 -300A/cm2
  • 27.
    During process ------- •Due to applied voltage, the current flows through the electrolyte with positively charged ions and negatively charged ions. • The positive ions move towards the tool (Cathode) while negative ions move towards work piece (Anode) So , Electro-chemical Reaction takes place due to this flow.
  • 28.
  • 29.
    PRINCIPLE Machining operation bythe combined action of Electro-chemical effect and conventional grinding operation 90 % - Metal removed by chemical Action 10 % -Metal removed by Grinding Action
  • 30.
    Electro-chemical Grinding (ECG) WorkPiece +Ve Terminal Grinding Wheel - Ve Terminal D.C.Voltage 3 – 30 V
  • 31.
    Gap 0.025mm ELECTROLYTE Sodium Nitrate SodiumChloride Potassium Nitrate + Water Grinding Wheel – Fine Diamond Particle Grinding Wheel speed – 900 -1800 m/min
  • 32.
    PROCESS PARAMETERS 1. CurrentDensity 100 – 200 A / cm2 The MRR increases with the Increase of Current Density – which results high Surface Finish
  • 33.
    PROCESS PARAMETERS 2. Electrolyte SodiumNitrate Sodium Chloride Potassium Nitrate The MRR increases with the correct composition of electrolyte with water – which results high Surface Finish Maintained at a Temperature of 15 – 30 Degree Celcius
  • 34.
    PROCESS PARAMETERS 3. FeedRate Slow feed Poor Surface Finish High feed Excess Tool Wear – Poor Surface Finish Optimum feed Good Surface Finish
  • 35.
    ADVANTAGES OF ECG 1.Life of the grinding wheel is high (because 90% material removed by chemical process) 2. No heat is produced in the process so the work surfaces are free from cracks. 3. Less cutting force only required 4. Good surface finish is obtained. 5. Work material not subjected to any structural changes 6. Burr free and stress free components are made. 7. No Frequent dressing of grinding wheel required.
  • 36.
    DIS -ADVANTAGES OFECG 1. High initial cost 2. Power consumption is high 3. MRR is lower than conventional method 4. Non – conducting material cannot be machined. 5. Need safety things for acid usage in process. 6. Maintenance cost is high
  • 37.
    Applications of ECG Itsbest suited for 1. precision grinding on hard materials 2. Cutting of hard material with thin sections without any damage
  • 38.
    ELECTRO-CHEMICAL HONING for Internalgrinding Combined action of electro- Chemical attack and Honing stone effect
  • 39.
    MRR is 10times faster than conventional internal Grinding Less tool Wear Less Pressure is required between Honing tool and work piece Burr Free and Stress free Components are produced Tolerance 0.012mm
  • 40.
    Work Piece +Ve Terminal (Anode) Tool -Ve Terminal (Cathode) Gap = 0.075 to 0.125 mm Electrolyte Supply = 112 lit /min Voltage = 25 V
  • 41.
  • 42.
  • 43.
  • 46.