Hydrogen

What is Hydrogen?                                                                 Electricity is a secondary source of energy. Secondary sources of energy
                                                                                  —energy carriers—are used to store, move, and deliver energy in easily
Hydrogen is the simplest element known to exist. An atom of hydrogen              usable form. We convert energy to electricity because it is easier for us to
has one proton and one electron. Hydrogen has the highest energy                  transport and use. Try splitting an atom, building a dam, or burning coal
content of any common fuel by weight, but the lowest energy content               to run your television. Energy carriers make life easier.
by volume. It is the lightest element and a gas at normal temperature
                                                                                  Hydrogen is one of the most promising energy carriers for the future. It is
and pressure.
                                                                                  a high efficiency, low polluting fuel that can be used for transportation,
Hydrogen is also the most abundant gas in the universe, and the source            heating, and power generation in places where it is difficult to use
of all the energy we receive from the sun. The sun is basically a giant ball      electricity. Since hydrogen gas is not found on Earth, it must be
of hydrogen and helium gases. In a process called fusion, four hydrogen           manufactured. There are several ways to do this.
atoms combine to form one helium atom, releasing energy as radiation.
This radiant energy is our most abundant energy source. It gives us light         How is Hydrogen Made?
and heat and makes plants grow. It causes the wind to blow and the rain
to fall. It is stored as chemical energy in fossil fuels. Most of the energy we   Industry produces the hydrogen it needs by a process called steam
use originally came from the sun.                                                 reforming. High-temperature steam separates hydrogen from the
                                                                                  carbon atoms in methane (CH4). The hydrogen produced by this method
Hydrogen as a gas (H2), however, doesn’t exist naturally on Earth. It is          isn’t used as a fuel, but for industrial processes. This is the most cost-
found only in compound form. Combined with oxygen, it is water (H2O).             effective way to produce hydrogen today, but it uses fossil fuels both in
Combined with carbon, it forms organic compounds such as methane                  the manufacturing process and as the heat source.
(CH4), coal, and petroleum. It is found in all growing things—biomass.
Hydrogen is also one of the most abundant elements in the Earth’s crust.          Another way to make hydrogen is by electrolysis—splitting water
                                                                                  into its basic elements—hydrogen and oxygen. Electrolysis involves
Most of the energy we use today comes from fossil fuels. Only seven               passing an electric current through water to separate the atoms
percent comes from renewable energy sources. Usually renewable                    (2H2O + electricity = 2H2 + O2). Hydrogen collects at the cathode and
sources are cleaner, and can be replenished in a short period of time. We         oxygen at the anode.
won’t run out of hydrogen either.
                                                                                  Hydrogen produced by electrolysis is extremely pure, and electricity
Every day we use more fuel, principally coal, to produce electricity.             from renewable sources can power the process, but it is very expensive
                                                                                  at this time. Today, hydrogen from electrolysis is ten times more costly
                                                                                  than natural gas and three times more costly than gasoline per Btu.
                                                                                  On the other hand, water is abundant and renewable, and technological
     Hydrogen Life Cycle                                                          advances in renewable electricity could make electrolysis a more
                                                                                  attractive way to produce hydrogen in the future.
                Primary Renewable Energy Source                                   There are also several experimental methods of producing hydrogen.
                                                                                  Photoelectrolysis uses sunlight to split water molecules into its
                        Hydrogen Production                                       components. A semiconductor absorbs the energy from the sun and
        Hydrogen                                                                  acts as an electrode to separate the water molecules.
                                                       Water                      In biomass gasification, wood chips and agricultural wastes are super-
                                     Oxygen
                                                                                  heated until they turn into hydrogen and other gases. Biomass can also
         Storage and                                                              be used to provide the heat.
                                                Environment
          Transport
                                                                                  Scientists have also discovered that some algae and bacteria produce
                                     Oxygen                                       hydrogen under certain conditions, using sunlight as their energy
                                                       Water                      source. Experiments are underway to find ways to induce these microbes
        Hydrogen
                                                                                  to produce hydrogen efficiently.
                        Hydrogen Utilization                                      Nearly every region of the country (and the world) has one or more
                                                                                  resources that can be used to produce hydrogen. It can be produced at
                            Useful Energy
                                                                                  large central facilities or at small distributed facilities for local use. One of
                                                                                  its main advantages is its flexibility.



54                                                                                                                                    Secondary Energy Infobook
Hydrogen Uses                                                                   SPACE SHUTTLE
  The U.S. hydrogen industry currently produces about nine million metric
  tons of hydrogen a year. Most of this hydrogen is used for industrial
  applications such as refining, treating metals, and food processing.
  At the present time, hydrogen’s main use as a fuel is in the NASA space
  program. Liquid hydrogen is the fuel that has propelled the space
  shuttle and other rockets since the 1970s. Hydrogen fuel cells power
  the shuttle’s electrical systems, producing pure water, which is used by
  the crew as drinking water.
  In the future, however, hydrogen will join electricity as an important
  energy carrier, since it can be made safely from renewable energy
  sources and is virtually non-polluting. It will also be used as a fuel
  for zero-emissions vehicles, to heat homes and offices, to produce
  electricity, and to fuel aircraft. Cost is the major obstacle.
  The first widespread use of hydrogen will probably be as an additive
  to transportation fuels. Hydrogen can be combined with gasoline,
  ethanol, methanol, and natural gas to increase performance and reduce           NASA uses hydrogen as a fuel source in the space shuttles.
  pollution. Adding just five percent hydrogen to gasoline can reduce
  nitrogen oxide (NOX) emissions by 30 to 40 percent in today’s engines.
  An engine converted to burn pure hydrogen produces only water and                Hydrogen Fuel Cell
  minor amounts of NOX as exhaust.                                                 A fuel cell consists of an electrolyte
  A few hydrogen-powered vehicles are on the road today, but it will be            membrane sandwiched between
                                                                                   two catalyst–coated electrodes                                          ELECTRICITY OUT
  awhile before you can walk into your local car dealer and drive away in          (anode and cathode). Oxygen (air)
  one. Today about 58 hydrogen fuel stations are operating in 20 states,           passes through one electrode and
  but not all are open to the public.                                              hydrogen through the other,
  Can you imagine how huge the task would be to quickly change the
                                                                                   generating electricity, water, and
                                                                                   heat
  gasoline-powered transportation system we have today? (Just think of
  the thousands of filling stations across the country and the production
  and distribution systems that serve them.) Change will come slowly to




                                                                                                                                       MEMBRANE
                                                                                                                                                  C AT H O D E
  this industry, but hydrogen is a versatile fuel; it can be used in many


                                                                                                                               ANODE
                                                                                           HYDROGEN IN                                                                 AIR IN
  ways.
  The space shuttle uses hydrogen fuel cells (batteries) to run its
  computer systems. The fuel cells basically reverse electrolysis—
  hydrogen and oxygen are combined to produce electricity. Hydrogen
  fuel cells are very efficient and produce only water as a by-product, but
  they are expensive to build.
  With technological advances, small fuel cells could someday power
                                                                                                          WATER AND HEAT OUT
  electric vehicles and larger fuel cells could provide electricity in remote
  areas. Because of the cost, hydrogen will not produce electricity on a
  wide scale in the near future. It may, though, be added to natural gas to       Future of Hydrogen
  reduce emissions from existing power plants.                                    Before hydrogen can make a significant contribution to the U.S. energy
  As the production of electricity from renewables increases, so will the         picture, many new systems must be designed and built. There must be
  need for energy storage and transportation. Many of these sources—              large production and storage facilities and a distribution system. And
  especially solar and wind—are located far from population centers               consumers must have the technology to use it.
  and produce electricity only part of the time. Hydrogen may be the
                                                                                  The use of hydrogen raises concerns about safety. Hydrogen is a volatile
  perfect carrier for this energy. It can store the energy and distribute
                                                                                  gas with high energy content. Early skeptics had similar concerns about
  it to wherever it is needed. It is estimated that transmitting electricity
                                                                                  natural gas and gasoline—even about electricity. People were afraid to
  long distances is four times more expensive than shipping hydrogen
                                                                                  let their children too near the first light bulbs. As hydrogen technologies
  by pipeline.
                                                                                  develop, safety issues will be addressed. Hydrogen can be produced,
                                                                                  stored, and used as safely as other fuels.
                                                                                  The goal of the U.S. Department of Energy’s Hydrogen Program is for
                                                                                  hydrogen to produce ten percent of our total energy demand by the
                                                                                  year 2030. Hydrogen can reduce our dependence on foreign oil and
                                                                                  provide clean, renewable energy for the future.


© 2011 The NEED Project     P.O. Box 10101, Manassas, VA 20108   1.800.875.5029    www.NEED.org                                                                                 55

Hydrogen s

  • 1.
    Hydrogen What is Hydrogen? Electricity is a secondary source of energy. Secondary sources of energy —energy carriers—are used to store, move, and deliver energy in easily Hydrogen is the simplest element known to exist. An atom of hydrogen usable form. We convert energy to electricity because it is easier for us to has one proton and one electron. Hydrogen has the highest energy transport and use. Try splitting an atom, building a dam, or burning coal content of any common fuel by weight, but the lowest energy content to run your television. Energy carriers make life easier. by volume. It is the lightest element and a gas at normal temperature Hydrogen is one of the most promising energy carriers for the future. It is and pressure. a high efficiency, low polluting fuel that can be used for transportation, Hydrogen is also the most abundant gas in the universe, and the source heating, and power generation in places where it is difficult to use of all the energy we receive from the sun. The sun is basically a giant ball electricity. Since hydrogen gas is not found on Earth, it must be of hydrogen and helium gases. In a process called fusion, four hydrogen manufactured. There are several ways to do this. atoms combine to form one helium atom, releasing energy as radiation. This radiant energy is our most abundant energy source. It gives us light How is Hydrogen Made? and heat and makes plants grow. It causes the wind to blow and the rain to fall. It is stored as chemical energy in fossil fuels. Most of the energy we Industry produces the hydrogen it needs by a process called steam use originally came from the sun. reforming. High-temperature steam separates hydrogen from the carbon atoms in methane (CH4). The hydrogen produced by this method Hydrogen as a gas (H2), however, doesn’t exist naturally on Earth. It is isn’t used as a fuel, but for industrial processes. This is the most cost- found only in compound form. Combined with oxygen, it is water (H2O). effective way to produce hydrogen today, but it uses fossil fuels both in Combined with carbon, it forms organic compounds such as methane the manufacturing process and as the heat source. (CH4), coal, and petroleum. It is found in all growing things—biomass. Hydrogen is also one of the most abundant elements in the Earth’s crust. Another way to make hydrogen is by electrolysis—splitting water into its basic elements—hydrogen and oxygen. Electrolysis involves Most of the energy we use today comes from fossil fuels. Only seven passing an electric current through water to separate the atoms percent comes from renewable energy sources. Usually renewable (2H2O + electricity = 2H2 + O2). Hydrogen collects at the cathode and sources are cleaner, and can be replenished in a short period of time. We oxygen at the anode. won’t run out of hydrogen either. Hydrogen produced by electrolysis is extremely pure, and electricity Every day we use more fuel, principally coal, to produce electricity. from renewable sources can power the process, but it is very expensive at this time. Today, hydrogen from electrolysis is ten times more costly than natural gas and three times more costly than gasoline per Btu. On the other hand, water is abundant and renewable, and technological Hydrogen Life Cycle advances in renewable electricity could make electrolysis a more attractive way to produce hydrogen in the future. Primary Renewable Energy Source There are also several experimental methods of producing hydrogen. Photoelectrolysis uses sunlight to split water molecules into its Hydrogen Production components. A semiconductor absorbs the energy from the sun and Hydrogen acts as an electrode to separate the water molecules. Water In biomass gasification, wood chips and agricultural wastes are super- Oxygen heated until they turn into hydrogen and other gases. Biomass can also Storage and be used to provide the heat. Environment Transport Scientists have also discovered that some algae and bacteria produce Oxygen hydrogen under certain conditions, using sunlight as their energy Water source. Experiments are underway to find ways to induce these microbes Hydrogen to produce hydrogen efficiently. Hydrogen Utilization Nearly every region of the country (and the world) has one or more resources that can be used to produce hydrogen. It can be produced at Useful Energy large central facilities or at small distributed facilities for local use. One of its main advantages is its flexibility. 54 Secondary Energy Infobook
  • 2.
    Hydrogen Uses SPACE SHUTTLE The U.S. hydrogen industry currently produces about nine million metric tons of hydrogen a year. Most of this hydrogen is used for industrial applications such as refining, treating metals, and food processing. At the present time, hydrogen’s main use as a fuel is in the NASA space program. Liquid hydrogen is the fuel that has propelled the space shuttle and other rockets since the 1970s. Hydrogen fuel cells power the shuttle’s electrical systems, producing pure water, which is used by the crew as drinking water. In the future, however, hydrogen will join electricity as an important energy carrier, since it can be made safely from renewable energy sources and is virtually non-polluting. It will also be used as a fuel for zero-emissions vehicles, to heat homes and offices, to produce electricity, and to fuel aircraft. Cost is the major obstacle. The first widespread use of hydrogen will probably be as an additive to transportation fuels. Hydrogen can be combined with gasoline, ethanol, methanol, and natural gas to increase performance and reduce NASA uses hydrogen as a fuel source in the space shuttles. pollution. Adding just five percent hydrogen to gasoline can reduce nitrogen oxide (NOX) emissions by 30 to 40 percent in today’s engines. An engine converted to burn pure hydrogen produces only water and Hydrogen Fuel Cell minor amounts of NOX as exhaust. A fuel cell consists of an electrolyte A few hydrogen-powered vehicles are on the road today, but it will be membrane sandwiched between two catalyst–coated electrodes ELECTRICITY OUT awhile before you can walk into your local car dealer and drive away in (anode and cathode). Oxygen (air) one. Today about 58 hydrogen fuel stations are operating in 20 states, passes through one electrode and but not all are open to the public. hydrogen through the other, Can you imagine how huge the task would be to quickly change the generating electricity, water, and heat gasoline-powered transportation system we have today? (Just think of the thousands of filling stations across the country and the production and distribution systems that serve them.) Change will come slowly to MEMBRANE C AT H O D E this industry, but hydrogen is a versatile fuel; it can be used in many ANODE HYDROGEN IN AIR IN ways. The space shuttle uses hydrogen fuel cells (batteries) to run its computer systems. The fuel cells basically reverse electrolysis— hydrogen and oxygen are combined to produce electricity. Hydrogen fuel cells are very efficient and produce only water as a by-product, but they are expensive to build. With technological advances, small fuel cells could someday power WATER AND HEAT OUT electric vehicles and larger fuel cells could provide electricity in remote areas. Because of the cost, hydrogen will not produce electricity on a wide scale in the near future. It may, though, be added to natural gas to Future of Hydrogen reduce emissions from existing power plants. Before hydrogen can make a significant contribution to the U.S. energy As the production of electricity from renewables increases, so will the picture, many new systems must be designed and built. There must be need for energy storage and transportation. Many of these sources— large production and storage facilities and a distribution system. And especially solar and wind—are located far from population centers consumers must have the technology to use it. and produce electricity only part of the time. Hydrogen may be the The use of hydrogen raises concerns about safety. Hydrogen is a volatile perfect carrier for this energy. It can store the energy and distribute gas with high energy content. Early skeptics had similar concerns about it to wherever it is needed. It is estimated that transmitting electricity natural gas and gasoline—even about electricity. People were afraid to long distances is four times more expensive than shipping hydrogen let their children too near the first light bulbs. As hydrogen technologies by pipeline. develop, safety issues will be addressed. Hydrogen can be produced, stored, and used as safely as other fuels. The goal of the U.S. Department of Energy’s Hydrogen Program is for hydrogen to produce ten percent of our total energy demand by the year 2030. Hydrogen can reduce our dependence on foreign oil and provide clean, renewable energy for the future. © 2011 The NEED Project P.O. Box 10101, Manassas, VA 20108 1.800.875.5029 www.NEED.org 55