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Signal 300 es msds

This safety data sheet provides information on the product SIGNAL. It contains hazards identification, composition/information on ingredients, first aid measures, and other important safety and handling information. The product is classified as harmful if swallowed, may cause respiratory irritation, and is very toxic to aquatic life with long lasting effects. It contains the active ingredient cypermethrin.

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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 1 / 17 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : SIGNAL Product code : 400000003975 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Sub- stance/Mixture : Seed treatment Recommended restrictions on use : Agriculture, For professional users only. 1.3 Details of the supplier of the safety data sheet Manufacturer or supplier's details Company: Chemtura Europe Limited Brooklands Farm, Cheltenham Road Evesham, Worcestershire United Kingdom WR11 2LS Telephone : +44 1386 425500 Prepared by sds.request@arysta.com Further information for the safety data sheet : sds.request@arysta.com 1.4 Emergency telephone number Emergency telephone num- ber: +44 (0) 1235 239 670 (NCEC) For additional emergency telephone numbers see section 16 of the Safety Data Sheet. SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 H302: Harmful if swallowed.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 2 / 17 Specific target organ toxicity - single ex- posure, Category 3, Respiratory system H335: May cause respiratory irritation. Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life. Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word : Warning Hazard statements : H302 Harmful if swallowed. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ va- pours/ spray. P273 Avoid release to the environment. Response: P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P391 Collect spillage. Storage: P403 + P233 Store in a well-ventilated place. Keep con- tainer tightly closed. Disposal: P501 Dispose of contents/ container to an ap- proved waste disposal plant. Hazardous components which must be listed on the label: Cypermethrin (cis/trans +/- 40/60) Supplemental Hazard Statements : EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Additional Labelling: EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 3 / 17 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumula- tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification Concentration (% w/w) Cypermethrin (cis/trans +/- 40/60) 52315-07-8 257-842-9 Acute Tox. 4; H302 Acute Tox. 4; H332 STOT SE 3; H335 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 >= 25 - < 30 ethane-1,2-diol 107-21-1 203-473-3 Acute Tox. 4; H302 >= 1 - < 10 1,2-benzisothiazol-3(2H)-one 2634-33-5 220-120-9 Acute Tox. 4; H302 Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Acute 1; H400 < 0.05 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures If inhaled : Remove to fresh air. Obtain medical attention. In case of skin contact : Remove contaminated clothing and shoes. Wash off with warm water and soap. If symptoms persist, call a physician. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. If swallowed : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : irritant effects Risks : Harmful if swallowed.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 4 / 17 May cause respiratory irritation. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam (on small fires) Carbon dioxide (CO2) Dry chemical Water spray Unsuitable extinguishing media : Water spray jet 5.2 Special hazards arising from the substance or mixture Specific hazards during fire- fighting : No information available. 5.3 Advice for firefighters Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Wear suitable protective equipment. Avoid contact with skin and eyes. 6.2 Environmental precautions Environmental precautions : Discharge into the environment must be avoided. Do not contaminate surface water. Do not allow material to contaminate ground water system. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Shovel into suitable container for disposal. Dam up.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 5 / 17 Large spills should be collected mechanically (remove by pumping) for disposal. 6.4 Reference to other sections For personal protection see section 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapour or mist. Use with adequate ventilation. Wash thoroughly after handling. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep in a dry, cool place. Other data : Stable under recommended storage conditions. 7.3 Specific end use(s) Specific use(s) : Seed treatment SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form of exposure) Control parameters Basis ethane-1,2-diol 107-21-1 TWA 20 ppm 52 mg/m3 2000/39/EC Further information Identifies the possibility of significant uptake through the skin, Indicative STEL 40 ppm 104 mg/m3 2000/39/EC Further information Identifies the possibility of significant uptake through the skin, Indicative TWA (Vapour) 20 ppm 52 mg/m3 GB EH40 Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. TWA (particles) 10 mg/m3 GB EH40 Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL (Vapour) 40 ppm 104 mg/m3 GB EH40 Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 6 / 17 8.2 Exposure controls Personal protective equipment Eye protection : Safety glasses with side-shields Hand protection Remarks : Impervious butyl rubber gloves Skin and body protection : Impervious clothing Respiratory protection : In the case of vapour formation use a respirator with an ap- proved filter. Respirator with a vapour filter (EN 141) SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : viscous liquid Colour : red Odour : mild characteristic Odour Threshold : No data available pH : 4 - 7, 1 % : No data available Boiling point/boiling range : 108 °C Flash point : does not flash Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : Not explosive Lower explosion limit : Not explosive Vapour pressure : No data available Relative vapour density : No data available Relative density : 1.08 Density : 1.1 g/cm3
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 7 / 17 Solubility(ies) Water solubility : dispersible Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : 123 mPa.s (20 °C) Viscosity, kinematic : No data available Explosive properties : Not explosive 9.2 Other information Self-Accelerating decomposi- tion temperature (SADT) : Method: No information available. Oxidizing potential : The substance or mixture is not classified as oxidizing. SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Hazardous polymerisation does not occur. 10.4 Conditions to avoid Conditions to avoid : Extremes of temperature and direct sunlight. 10.5 Incompatible materials Materials to avoid : Oxidizing agents Strong acids and strong bases 10.6 Hazardous decomposition products No decomposition if stored and applied as directed. SECTION 11: Toxicological information
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 8 / 17 11.1 Information on toxicological effects Acute toxicity Product: Acute oral toxicity : LD50 (Rat, female): 307.3 mg/kg Method: OECD Test Guideline 425 GLP: yes Acute inhalation toxicity : Remarks: Based on available data, the classification criteria are not met. Acute toxicity estimate: > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method Acute dermal toxicity : LD50 (Rat): > 2,200 mg/kg Method: OECD Test Guideline 402 GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Acute oral toxicity : LD50 (Rat): 287 mg/kg GLP: yes Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Acute inhalation toxicity : LC50 (Rat): 3.28 mg/l Test atmosphere: dust/mist GLP: yes Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg GLP: yes ethane-1,2-diol: Acute oral toxicity : LD50 (Rat, female): 4,700 mg/kg Acute dermal toxicity : LD50 (Rabbit): 10,670 mg/kg 1,2-benzisothiazol-3(2H)-one: Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Skin corrosion/irritation Product: Species: Rabbit
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 9 / 17 Method: OECD Test Guideline 404 Result: No skin irritation GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Species: Rabbit Result: No skin irritation GLP: yes Serious eye damage/eye irritation Product: Species: Rabbit Method: OECD Test Guideline 405 Result: slight irritation GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Species: Rabbit Result: No eye irritation GLP: yes Respiratory or skin sensitisation Product: Species: Guinea pig Method: Magnusson-Kligmann-Test Result: Did not cause sensitisation on laboratory animals. GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. GLP: yes Germ cell mutagenicity Product: Germ cell mutagenicity- As- sessment : Based on available data, the classification criteria are not met. Components: Cypermethrin (cis/trans +/- 40/60): Germ cell mutagenicity- As- sessment : negative
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 10 / 17 Carcinogenicity Product: Carcinogenicity - Assess- ment : Based on available data, the classification criteria are not met. Components: Cypermethrin (cis/trans +/- 40/60): Carcinogenicity - Assess- ment : negative Reproductive toxicity Product: Reproductive toxicity - As- sessment : Based on available data, the classification criteria are not met. Components: Cypermethrin (cis/trans +/- 40/60): Effects on fertility : General Toxicity - Parent: No observed adverse effect level: 10 mg/kg bw/day Effects on foetal develop- ment : Teratogenicity: No observed adverse effect level: 70 mg/kg bw/day STOT - single exposure Product: Assessment: May cause respiratory irritation. STOT - repeated exposure Product: Assessment: Based on available data, the classification criteria are not met. Repeated dose toxicity Components: Cypermethrin (cis/trans +/- 40/60): Species: Dog NOAEL: 500 ppm (12.5 mg/kg bw/d ) Exposure time: 90 d GLP: yes SECTION 12: Ecological information
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 11 / 17 12.1 Toxicity Product: Toxicity to fish : Remarks: Information refers to the main component. Toxicity to daphnia and other aquatic invertebrates : Remarks: Information refers to the main component. Toxicity to algae : Remarks: Information refers to the main component. Components: Cypermethrin (cis/trans +/- 40/60): Toxicity to fish : LC50 (Salmo gairdneri): 0.0028 mg/l Exposure time: 96 h GLP: yes Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.0003 mg/l Exposure time: 48 h GLP: yes Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): > 0.1 mg/l M-Factor (Acute aquatic tox- icity) : 1,000 Toxicity to fish (Chronic toxic- ity) : NOEC: 0.00003 mg/l Species: Pimephales promelas (fathead minnow) Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity) : NOEC: 0.00004 mg/l Exposure time: 21 d M-Factor (Chronic aquatic toxicity) : 1,000 12.2 Persistence and degradability Product: Biodegradability : Remarks: No data available Components: Cypermethrin (cis/trans +/- 40/60): Biodegradability : Result: Not readily biodegradable. Stability in water : Hydrolysis: at 25 °C(> 100 d) Photodegradation :
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 12 / 17 12.3 Bioaccumulative potential Product: Bioaccumulation : Remarks: No data available Components: ethane-1,2-diol: Partition coefficient: n- octanol/water : log Pow: -1.3 12.4 Mobility in soil Product: Mobility : Remarks: No data available Components: Cypermethrin (cis/trans +/- 40/60): Stability in soil : Soil temperature: 21 °C Remarks: cis isomer Soil temperature: 21 °C Remarks: trans isomer 12.5 Results of PBT and vPvB assessment Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.. 12.6 Other adverse effects Product: Additional ecological informa- tion : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects. SECTION 13: Disposal considerations 13.1 Waste treatment methods Product : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. Offer surplus and non-recyclable solutions to a licensed dis- posal company. Contaminated packaging : Empty remaining contents.
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 13 / 17 Dispose of as unused product. Do not re-use empty containers. SECTION 14: Transport information 14.1 UN number ADN : UN 3082 ADR : UN 3082 RID : UN 3082 IMDG : UN 3082 IATA : UN 3082 14.2 UN proper shipping name ADN : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) ADR : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) RID : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) IMDG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) IATA : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) 14.3 Transport hazard class(es) ADN : 9 ADR : 9 RID : 9 IMDG : 9 IATA : 9 14.4 Packing group ADN Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9 ADR Packing group : III
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 14 / 17 Classification Code : M6 Hazard Identification Number : 90 Labels : 9 Tunnel restriction code : (E) RID Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9 IMDG Packing group : III Labels : 9 EmS Code : F-A, S-F IATA Packing instruction (cargo aircraft) : 964 Packing instruction (passen- ger aircraft) : 964 Packing instruction (LQ) : Y964 Packing group : III Labels : Miscellaneous 14.5 Environmental hazards ADN Environmentally hazardous : yes ADR Environmentally hazardous : yes RID Environmentally hazardous : yes IMDG Marine pollutant : yes 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mix- ture Regulation (EC) No 649/2012 of the European Parlia- ment and the Council concerning the export and import of dangerous chemicals : Not applicable REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : Not applicable
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 15 / 17 Regulation (EC) No 1005/2009 on substances that de- plete the ozone layer : Not applicable Regulation (EC) No 850/2004 on persistent organic pol- lutants : Not applicable Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Quantity 1 Quantity 2 E1 ENVIRONMENTAL HAZARDS 100 t 200 t Water contaminating class (Germany) : WGK 3 highly water endangering Classification according VwVwS, Annex 4. 15.2 Chemical Safety Assessment No information available. SECTION 16: Other information Full text of H-Statements H302 : Harmful if swallowed. H315 : Causes skin irritation. H317 : May cause an allergic skin reaction. H318 : Causes serious eye damage. H332 : Harmful if inhaled. H335 : May cause respiratory irritation. H400 : Very toxic to aquatic life. H410 : Very toxic to aquatic life with long lasting effects. Full text of other abbreviations Acute Tox. : Acute toxicity Aquatic Acute : Acute aquatic toxicity Aquatic Chronic : Chronic aquatic toxicity Eye Dam. : Serious eye damage Skin Irrit. : Skin irritation Skin Sens. : Skin sensitisation STOT SE : Specific target organ toxicity - single exposure (Q)SAR - (Quantitative) Structure Activity Relationship; ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agree- ment concerning the International Carriage of Dangerous Goods by Road; ASTM - American So- ciety for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; DIN - Standard of the German Institute for Standardi- sation; ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equip- ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra- tion; ICAO - International Civil Aviation Organization; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISO - International Organisation for Standardi-
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 16 / 17 zation; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; OECD - Organization for Economic Co-operation and Development; OPPTS - Of- fice of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self- Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TRGS - Technical Rule for Hazardous Substances; UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative; DSL - Domestic Substances List (Canada); KECI - Korea Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); AICS - Australian Inventory of Chemical Sub- stances; IECSC - Inventory of Existing Chemical Substances in China; ENCS - Existing and New Chemical Substances (Japan); ISHL - Industrial Safety and Health Law (Japan); PICCS - Philip- pines Inventory of Chemicals and Chemical Substances; NZIoC - New Zealand Inventory of Chemicals; TCSI - Taiwan Chemical Substance Inventory; CMR - Carcinogen, Mutagen or Re- productive Toxicant; GLP - Good Laboratory Practice Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. GB / EN Carechem24 International Worldwide Coverage Emergency Phone Number Europe: All European Countries +44 (0) 1235 239 670 (NCEC) Asia Pacific: East / South East Asia – Regional Number +65 3158 1074 Australia +61 2801 44558 New Zealand +64 9929 1483 China +86 532 8388 9090 China Taiwan +86 10 5100 3039 Japan +81 345 789 341 Indonesia 00780 3011 0293 Malaysia +60 3 6207 4347 Thailand 001800 1 2066 6751 Korea +65 3158 1285 +82 (0)234 798 401
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 17 / 17 Vietnam +65 3158 1255 India +65 3158 1198 0800 100 7479 Pakistan +65 3158 1329 Philippines +65 31581203 Sri Lanka +65 3158 1195 Emergency Phone Number +65 3158 1200 Middle East / Africa: Arabic speaking countries +44 (0) 1235 239 671 South Africa +27 21 300 2732 All other countries +44 (0) 1235 239 670 America United States of America and Canada +1866 928 0789 +1 215 207 0061 Latin America: Brazil +55 113 711 9144 Mexico +52 555 004 8763 Chile +56 225 829 336 All other countries +44 (0) 1235 239 670

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Signal 300 es msds

  • 1.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 1 / 17 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : SIGNAL Product code : 400000003975 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Sub- stance/Mixture : Seed treatment Recommended restrictions on use : Agriculture, For professional users only. 1.3 Details of the supplier of the safety data sheet Manufacturer or supplier's details Company: Chemtura Europe Limited Brooklands Farm, Cheltenham Road Evesham, Worcestershire United Kingdom WR11 2LS Telephone : +44 1386 425500 Prepared by [email protected] Further information for the safety data sheet : [email protected] 1.4 Emergency telephone number Emergency telephone num- ber: +44 (0) 1235 239 670 (NCEC) For additional emergency telephone numbers see section 16 of the Safety Data Sheet. SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Acute toxicity, Category 4 H302: Harmful if swallowed.
  • 2.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 2 / 17 Specific target organ toxicity - single ex- posure, Category 3, Respiratory system H335: May cause respiratory irritation. Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life. Chronic aquatic toxicity, Category 1 H410: Very toxic to aquatic life with long lasting effects. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : Signal word : Warning Hazard statements : H302 Harmful if swallowed. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ va- pours/ spray. P273 Avoid release to the environment. Response: P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P391 Collect spillage. Storage: P403 + P233 Store in a well-ventilated place. Keep con- tainer tightly closed. Disposal: P501 Dispose of contents/ container to an ap- proved waste disposal plant. Hazardous components which must be listed on the label: Cypermethrin (cis/trans +/- 40/60) Supplemental Hazard Statements : EUH401 To avoid risks to human health and the environment, comply with the instructions for use. Additional Labelling: EUH208 Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
  • 3.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 3 / 17 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumula- tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.2 Mixtures Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification Concentration (% w/w) Cypermethrin (cis/trans +/- 40/60) 52315-07-8 257-842-9 Acute Tox. 4; H302 Acute Tox. 4; H332 STOT SE 3; H335 Aquatic Acute 1; H400 Aquatic Chronic 1; H410 >= 25 - < 30 ethane-1,2-diol 107-21-1 203-473-3 Acute Tox. 4; H302 >= 1 - < 10 1,2-benzisothiazol-3(2H)-one 2634-33-5 220-120-9 Acute Tox. 4; H302 Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Acute 1; H400 < 0.05 For explanation of abbreviations see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures If inhaled : Remove to fresh air. Obtain medical attention. In case of skin contact : Remove contaminated clothing and shoes. Wash off with warm water and soap. If symptoms persist, call a physician. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. If swallowed : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : irritant effects Risks : Harmful if swallowed.
  • 4.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 4 / 17 May cause respiratory irritation. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam (on small fires) Carbon dioxide (CO2) Dry chemical Water spray Unsuitable extinguishing media : Water spray jet 5.2 Special hazards arising from the substance or mixture Specific hazards during fire- fighting : No information available. 5.3 Advice for firefighters Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Wear suitable protective equipment. Avoid contact with skin and eyes. 6.2 Environmental precautions Environmental precautions : Discharge into the environment must be avoided. Do not contaminate surface water. Do not allow material to contaminate ground water system. 6.3 Methods and material for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Shovel into suitable container for disposal. Dam up.
  • 5.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 5 / 17 Large spills should be collected mechanically (remove by pumping) for disposal. 6.4 Reference to other sections For personal protection see section 8. SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapour or mist. Use with adequate ventilation. Wash thoroughly after handling. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep in a dry, cool place. Other data : Stable under recommended storage conditions. 7.3 Specific end use(s) Specific use(s) : Seed treatment SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational Exposure Limits Components CAS-No. Value type (Form of exposure) Control parameters Basis ethane-1,2-diol 107-21-1 TWA 20 ppm 52 mg/m3 2000/39/EC Further information Identifies the possibility of significant uptake through the skin, Indicative STEL 40 ppm 104 mg/m3 2000/39/EC Further information Identifies the possibility of significant uptake through the skin, Indicative TWA (Vapour) 20 ppm 52 mg/m3 GB EH40 Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. TWA (particles) 10 mg/m3 GB EH40 Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL (Vapour) 40 ppm 104 mg/m3 GB EH40 Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.
  • 6.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 6 / 17 8.2 Exposure controls Personal protective equipment Eye protection : Safety glasses with side-shields Hand protection Remarks : Impervious butyl rubber gloves Skin and body protection : Impervious clothing Respiratory protection : In the case of vapour formation use a respirator with an ap- proved filter. Respirator with a vapour filter (EN 141) SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : viscous liquid Colour : red Odour : mild characteristic Odour Threshold : No data available pH : 4 - 7, 1 % : No data available Boiling point/boiling range : 108 °C Flash point : does not flash Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : Not explosive Lower explosion limit : Not explosive Vapour pressure : No data available Relative vapour density : No data available Relative density : 1.08 Density : 1.1 g/cm3
  • 7.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 7 / 17 Solubility(ies) Water solubility : dispersible Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : 123 mPa.s (20 °C) Viscosity, kinematic : No data available Explosive properties : Not explosive 9.2 Other information Self-Accelerating decomposi- tion temperature (SADT) : Method: No information available. Oxidizing potential : The substance or mixture is not classified as oxidizing. SECTION 10: Stability and reactivity 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Hazardous polymerisation does not occur. 10.4 Conditions to avoid Conditions to avoid : Extremes of temperature and direct sunlight. 10.5 Incompatible materials Materials to avoid : Oxidizing agents Strong acids and strong bases 10.6 Hazardous decomposition products No decomposition if stored and applied as directed. SECTION 11: Toxicological information
  • 8.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 8 / 17 11.1 Information on toxicological effects Acute toxicity Product: Acute oral toxicity : LD50 (Rat, female): 307.3 mg/kg Method: OECD Test Guideline 425 GLP: yes Acute inhalation toxicity : Remarks: Based on available data, the classification criteria are not met. Acute toxicity estimate: > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method Acute dermal toxicity : LD50 (Rat): > 2,200 mg/kg Method: OECD Test Guideline 402 GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Acute oral toxicity : LD50 (Rat): 287 mg/kg GLP: yes Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Acute inhalation toxicity : LC50 (Rat): 3.28 mg/l Test atmosphere: dust/mist GLP: yes Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg GLP: yes ethane-1,2-diol: Acute oral toxicity : LD50 (Rat, female): 4,700 mg/kg Acute dermal toxicity : LD50 (Rabbit): 10,670 mg/kg 1,2-benzisothiazol-3(2H)-one: Acute oral toxicity : Acute toxicity estimate: 500 mg/kg Method: Converted acute toxicity point estimate Skin corrosion/irritation Product: Species: Rabbit
  • 9.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 9 / 17 Method: OECD Test Guideline 404 Result: No skin irritation GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Species: Rabbit Result: No skin irritation GLP: yes Serious eye damage/eye irritation Product: Species: Rabbit Method: OECD Test Guideline 405 Result: slight irritation GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Species: Rabbit Result: No eye irritation GLP: yes Respiratory or skin sensitisation Product: Species: Guinea pig Method: Magnusson-Kligmann-Test Result: Did not cause sensitisation on laboratory animals. GLP: yes Components: Cypermethrin (cis/trans +/- 40/60): Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. GLP: yes Germ cell mutagenicity Product: Germ cell mutagenicity- As- sessment : Based on available data, the classification criteria are not met. Components: Cypermethrin (cis/trans +/- 40/60): Germ cell mutagenicity- As- sessment : negative
  • 10.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 10 / 17 Carcinogenicity Product: Carcinogenicity - Assess- ment : Based on available data, the classification criteria are not met. Components: Cypermethrin (cis/trans +/- 40/60): Carcinogenicity - Assess- ment : negative Reproductive toxicity Product: Reproductive toxicity - As- sessment : Based on available data, the classification criteria are not met. Components: Cypermethrin (cis/trans +/- 40/60): Effects on fertility : General Toxicity - Parent: No observed adverse effect level: 10 mg/kg bw/day Effects on foetal develop- ment : Teratogenicity: No observed adverse effect level: 70 mg/kg bw/day STOT - single exposure Product: Assessment: May cause respiratory irritation. STOT - repeated exposure Product: Assessment: Based on available data, the classification criteria are not met. Repeated dose toxicity Components: Cypermethrin (cis/trans +/- 40/60): Species: Dog NOAEL: 500 ppm (12.5 mg/kg bw/d ) Exposure time: 90 d GLP: yes SECTION 12: Ecological information
  • 11.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 11 / 17 12.1 Toxicity Product: Toxicity to fish : Remarks: Information refers to the main component. Toxicity to daphnia and other aquatic invertebrates : Remarks: Information refers to the main component. Toxicity to algae : Remarks: Information refers to the main component. Components: Cypermethrin (cis/trans +/- 40/60): Toxicity to fish : LC50 (Salmo gairdneri): 0.0028 mg/l Exposure time: 96 h GLP: yes Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): 0.0003 mg/l Exposure time: 48 h GLP: yes Toxicity to algae : EC50 (Selenastrum capricornutum (green algae)): > 0.1 mg/l M-Factor (Acute aquatic tox- icity) : 1,000 Toxicity to fish (Chronic toxic- ity) : NOEC: 0.00003 mg/l Species: Pimephales promelas (fathead minnow) Toxicity to daphnia and other aquatic invertebrates (Chron- ic toxicity) : NOEC: 0.00004 mg/l Exposure time: 21 d M-Factor (Chronic aquatic toxicity) : 1,000 12.2 Persistence and degradability Product: Biodegradability : Remarks: No data available Components: Cypermethrin (cis/trans +/- 40/60): Biodegradability : Result: Not readily biodegradable. Stability in water : Hydrolysis: at 25 °C(> 100 d) Photodegradation :
  • 12.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 12 / 17 12.3 Bioaccumulative potential Product: Bioaccumulation : Remarks: No data available Components: ethane-1,2-diol: Partition coefficient: n- octanol/water : log Pow: -1.3 12.4 Mobility in soil Product: Mobility : Remarks: No data available Components: Cypermethrin (cis/trans +/- 40/60): Stability in soil : Soil temperature: 21 °C Remarks: cis isomer Soil temperature: 21 °C Remarks: trans isomer 12.5 Results of PBT and vPvB assessment Product: Assessment : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.. 12.6 Other adverse effects Product: Additional ecological informa- tion : An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life with long lasting effects. SECTION 13: Disposal considerations 13.1 Waste treatment methods Product : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. Offer surplus and non-recyclable solutions to a licensed dis- posal company. Contaminated packaging : Empty remaining contents.
  • 13.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 13 / 17 Dispose of as unused product. Do not re-use empty containers. SECTION 14: Transport information 14.1 UN number ADN : UN 3082 ADR : UN 3082 RID : UN 3082 IMDG : UN 3082 IATA : UN 3082 14.2 UN proper shipping name ADN : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) ADR : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) RID : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) IMDG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) IATA : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cypermethrin) 14.3 Transport hazard class(es) ADN : 9 ADR : 9 RID : 9 IMDG : 9 IATA : 9 14.4 Packing group ADN Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9 ADR Packing group : III
  • 14.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 14 / 17 Classification Code : M6 Hazard Identification Number : 90 Labels : 9 Tunnel restriction code : (E) RID Packing group : III Classification Code : M6 Hazard Identification Number : 90 Labels : 9 IMDG Packing group : III Labels : 9 EmS Code : F-A, S-F IATA Packing instruction (cargo aircraft) : 964 Packing instruction (passen- ger aircraft) : 964 Packing instruction (LQ) : Y964 Packing group : III Labels : Miscellaneous 14.5 Environmental hazards ADN Environmentally hazardous : yes ADR Environmentally hazardous : yes RID Environmentally hazardous : yes IMDG Marine pollutant : yes 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mix- ture Regulation (EC) No 649/2012 of the European Parlia- ment and the Council concerning the export and import of dangerous chemicals : Not applicable REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : Not applicable
  • 15.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 15 / 17 Regulation (EC) No 1005/2009 on substances that de- plete the ozone layer : Not applicable Regulation (EC) No 850/2004 on persistent organic pol- lutants : Not applicable Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Quantity 1 Quantity 2 E1 ENVIRONMENTAL HAZARDS 100 t 200 t Water contaminating class (Germany) : WGK 3 highly water endangering Classification according VwVwS, Annex 4. 15.2 Chemical Safety Assessment No information available. SECTION 16: Other information Full text of H-Statements H302 : Harmful if swallowed. H315 : Causes skin irritation. H317 : May cause an allergic skin reaction. H318 : Causes serious eye damage. H332 : Harmful if inhaled. H335 : May cause respiratory irritation. H400 : Very toxic to aquatic life. H410 : Very toxic to aquatic life with long lasting effects. Full text of other abbreviations Acute Tox. : Acute toxicity Aquatic Acute : Acute aquatic toxicity Aquatic Chronic : Chronic aquatic toxicity Eye Dam. : Serious eye damage Skin Irrit. : Skin irritation Skin Sens. : Skin sensitisation STOT SE : Specific target organ toxicity - single exposure (Q)SAR - (Quantitative) Structure Activity Relationship; ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agree- ment concerning the International Carriage of Dangerous Goods by Road; ASTM - American So- ciety for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008; DIN - Standard of the German Institute for Standardi- sation; ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equip- ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra- tion; ICAO - International Civil Aviation Organization; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISO - International Organisation for Standardi-
  • 16.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 16 / 17 zation; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; OECD - Organization for Economic Co-operation and Development; OPPTS - Of- fice of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self- Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TRGS - Technical Rule for Hazardous Substances; UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative; DSL - Domestic Substances List (Canada); KECI - Korea Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); AICS - Australian Inventory of Chemical Sub- stances; IECSC - Inventory of Existing Chemical Substances in China; ENCS - Existing and New Chemical Substances (Japan); ISHL - Industrial Safety and Health Law (Japan); PICCS - Philip- pines Inventory of Chemicals and Chemical Substances; NZIoC - New Zealand Inventory of Chemicals; TCSI - Taiwan Chemical Substance Inventory; CMR - Carcinogen, Mutagen or Re- productive Toxicant; GLP - Good Laboratory Practice Further information The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. GB / EN Carechem24 International Worldwide Coverage Emergency Phone Number Europe: All European Countries +44 (0) 1235 239 670 (NCEC) Asia Pacific: East / South East Asia – Regional Number +65 3158 1074 Australia +61 2801 44558 New Zealand +64 9929 1483 China +86 532 8388 9090 China Taiwan +86 10 5100 3039 Japan +81 345 789 341 Indonesia 00780 3011 0293 Malaysia +60 3 6207 4347 Thailand 001800 1 2066 6751 Korea +65 3158 1285 +82 (0)234 798 401
  • 17.
    SAFETY DATA SHEET accordingto Regulation (EC) No. 1907/2006 SIGNAL Version 5.2 Revision Date: 14.09.2015 MSDS Number: 400000003975 Country: GB Language: EN 17 / 17 Vietnam +65 3158 1255 India +65 3158 1198 0800 100 7479 Pakistan +65 3158 1329 Philippines +65 31581203 Sri Lanka +65 3158 1195 Emergency Phone Number +65 3158 1200 Middle East / Africa: Arabic speaking countries +44 (0) 1235 239 671 South Africa +27 21 300 2732 All other countries +44 (0) 1235 239 670 America United States of America and Canada +1866 928 0789 +1 215 207 0061 Latin America: Brazil +55 113 711 9144 Mexico +52 555 004 8763 Chile +56 225 829 336 All other countries +44 (0) 1235 239 670