The Mole Concept
Eggs come in dozens
12 eggs = 1 dozen
Atoms come in moles
6.02 x 1023
atoms = 1 mole = NA
NA is a ginormous number!
How big is it?
One mole of softballs would be the size of
the Earth!
8.1 Avogadro’s Number and the Mole
 Atoms are so tiny that one mole of atoms is
about a handful.
 The mass of a mole of atoms = the atomic mass
in grams on the Periodic Table.
 1 mole of C atoms is 12.01 grams
 1 mole of Na atoms is 22.99 grams
 What is the mass of one mole of Ne atoms?
The Mole
sulfur
water
mercury
sodium chloride
copper
lead
sugar
Mole Examples
1. How many calcium atoms are in 0.250 moles of calcium?
2. Calculate the moles of 3.75 x 1027
molecules of oxygen gas?
6.02 x 1023
atoms or mlcls or 1 mol
1 mol 6.02 x 1023
atoms or mlcls
0.250 mol Ca (6.02 x 1023
atoms/1 mol) = 1.51 x 1023
Ca atoms
3.75 x 1027
mlcls O2 (1 mol/6.02 x 1023
mlcls) = 6230 mol O2
8.2 Mole Calculations I: Avogadro’s
Number
The Mole Concept PowerPoint Presentation
Molar mass tells us how much mass is in one
mole of substance.
Periodic Table masses are in units of (g/mol).
Very important – the units are grams per 1
mole, not just grams
How many grams in one mole of:
 carbon?
 gold?
 sodium?
What do they all have in common?
They all have 6.02 x 1023
atoms!
12.01 g/mol
196.97 g/mol
22.99 g/mol
8.3 Molar Mass
Calculate the molar mass of barium hydroxide.
1.What is the formula?
2.Add up the mass for every atom.
Ba: 137.33 g/mol +
O: 2 (16.00) g/mol +
H: 2 (1.01) g/mol =
171.35 g/mol
Ba(OH)2
Molar Mass
 Use Molar Mass as (g/mol) or (mol/g)
 How many grams is 1.667 moles of oxygen
gas?
 1.667 mol O2 ( 32.00 g/mol) = 53.34 g O2
 How many moles is 45 grams of silver?
 45 g Ag ( mol/ 107.87 g) = 0.42 mol Ag
 How many grams is 0.0554 moles of water?
 0.0554 mol H2O (18.02g /mol) = 0.998 g H2O
8.4 Grams to Moles (Mole Calcs II)
8.5 Molar Volume
(Volume of 1 mole of gas at STP)
Volume of 1 mole of gas
Gases are mostly empty space so they ALL
have the same volume despite different
mass
22.4 L per 1 mole of any gas at STP
 STP is Standard Temperature and Pressure
 0°C and 1 atm
For Gases only at STP:
22.4 L / 1 mol or 1 mol / 22.4 L
What is the mass of 4.50 L of chlorine gas at STP?
4.50 L Cl2 (1mol / 22.4L) (70.90 g/mol) = 14.2 g Cl2
What is the volume of 1.25 moles of gas
at STP?
1.25 mol ( 22.4 L / 1 mol) = 28.0 L gas
Density
d = = me
molar volu
mass
molar
volume
mass
Calculate the density of ammonia gas, NH3, at STP.
d = (17.04 g/mol ) / ( 22.4 L/mol ) = 0.761 g/L
8.6 Mole Calcs III
Example
How many grams does 17.35 liters of neon
gas weigh at STP? How many atoms is this?
17.35 L = 15.6 grams Ne












mol
1
g
20.18
L
22.4
mol
1














mol
1
atoms
10
x
6.02
L
22.4
mol
1 23
17.35 L = 4.66x1023
atoms Ne
8.7 Percent Composition
= mass % of each element in a compound
You divide the total element molar mass by the total
compound molar mass.
% = (element / compound) x 100
%H = (2.02 g H / 18.02 g H2O) x 100 = 11.2% H
%O = (16.00 g O / 18.02 g H2O) x 100 = 88.79% O
Note the %’s should add up to 100% total
Example Problem
Find the percent composition for TNT, C7H5(NO2)3
Total molar mass is 227.15 grams per mole
% C = (84.07g / 227.15g) x 100 = 37.01% C
% H = (5.05g / 227.15g) x 100 = 2.22%H
% N = (42.03g / 227.15g) x 100 = 18.50%N
% O = (96.00g / 227.15g) x 100 = 42.26%O
Try at home
How many liters will 3.425 grams of carbon
dioxide gas occupy at STP? 1.74 L
How many molecules are in 3.425 grams of
carbon dioxide? 4.68 x 1022
molecules
What will be the mass of 3.0 x 1015
molecules of carbon dioxide? 2.2 x 10-7
grams
Questions
1) How many molecules are in 1.25 g of
copper?
2) What is the mass of 35.6 L of xenon gas at
STP?
3) What is the mass percent of carbon in aspirin
(C9H8O4)?

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The Mole Concept PowerPoint Presentation

  • 2. Eggs come in dozens 12 eggs = 1 dozen Atoms come in moles 6.02 x 1023 atoms = 1 mole = NA NA is a ginormous number! How big is it? One mole of softballs would be the size of the Earth! 8.1 Avogadro’s Number and the Mole
  • 3.  Atoms are so tiny that one mole of atoms is about a handful.  The mass of a mole of atoms = the atomic mass in grams on the Periodic Table.  1 mole of C atoms is 12.01 grams  1 mole of Na atoms is 22.99 grams  What is the mass of one mole of Ne atoms? The Mole
  • 5. 1. How many calcium atoms are in 0.250 moles of calcium? 2. Calculate the moles of 3.75 x 1027 molecules of oxygen gas? 6.02 x 1023 atoms or mlcls or 1 mol 1 mol 6.02 x 1023 atoms or mlcls 0.250 mol Ca (6.02 x 1023 atoms/1 mol) = 1.51 x 1023 Ca atoms 3.75 x 1027 mlcls O2 (1 mol/6.02 x 1023 mlcls) = 6230 mol O2 8.2 Mole Calculations I: Avogadro’s Number
  • 7. Molar mass tells us how much mass is in one mole of substance. Periodic Table masses are in units of (g/mol). Very important – the units are grams per 1 mole, not just grams How many grams in one mole of:  carbon?  gold?  sodium? What do they all have in common? They all have 6.02 x 1023 atoms! 12.01 g/mol 196.97 g/mol 22.99 g/mol 8.3 Molar Mass
  • 8. Calculate the molar mass of barium hydroxide. 1.What is the formula? 2.Add up the mass for every atom. Ba: 137.33 g/mol + O: 2 (16.00) g/mol + H: 2 (1.01) g/mol = 171.35 g/mol Ba(OH)2 Molar Mass
  • 9.  Use Molar Mass as (g/mol) or (mol/g)  How many grams is 1.667 moles of oxygen gas?  1.667 mol O2 ( 32.00 g/mol) = 53.34 g O2  How many moles is 45 grams of silver?  45 g Ag ( mol/ 107.87 g) = 0.42 mol Ag  How many grams is 0.0554 moles of water?  0.0554 mol H2O (18.02g /mol) = 0.998 g H2O 8.4 Grams to Moles (Mole Calcs II)
  • 10. 8.5 Molar Volume (Volume of 1 mole of gas at STP)
  • 11. Volume of 1 mole of gas Gases are mostly empty space so they ALL have the same volume despite different mass 22.4 L per 1 mole of any gas at STP  STP is Standard Temperature and Pressure  0°C and 1 atm
  • 12. For Gases only at STP: 22.4 L / 1 mol or 1 mol / 22.4 L What is the mass of 4.50 L of chlorine gas at STP? 4.50 L Cl2 (1mol / 22.4L) (70.90 g/mol) = 14.2 g Cl2 What is the volume of 1.25 moles of gas at STP? 1.25 mol ( 22.4 L / 1 mol) = 28.0 L gas
  • 13. Density d = = me molar volu mass molar volume mass Calculate the density of ammonia gas, NH3, at STP. d = (17.04 g/mol ) / ( 22.4 L/mol ) = 0.761 g/L
  • 15. Example How many grams does 17.35 liters of neon gas weigh at STP? How many atoms is this? 17.35 L = 15.6 grams Ne             mol 1 g 20.18 L 22.4 mol 1               mol 1 atoms 10 x 6.02 L 22.4 mol 1 23 17.35 L = 4.66x1023 atoms Ne
  • 16. 8.7 Percent Composition = mass % of each element in a compound You divide the total element molar mass by the total compound molar mass. % = (element / compound) x 100 %H = (2.02 g H / 18.02 g H2O) x 100 = 11.2% H %O = (16.00 g O / 18.02 g H2O) x 100 = 88.79% O Note the %’s should add up to 100% total
  • 17. Example Problem Find the percent composition for TNT, C7H5(NO2)3 Total molar mass is 227.15 grams per mole % C = (84.07g / 227.15g) x 100 = 37.01% C % H = (5.05g / 227.15g) x 100 = 2.22%H % N = (42.03g / 227.15g) x 100 = 18.50%N % O = (96.00g / 227.15g) x 100 = 42.26%O
  • 18. Try at home How many liters will 3.425 grams of carbon dioxide gas occupy at STP? 1.74 L How many molecules are in 3.425 grams of carbon dioxide? 4.68 x 1022 molecules What will be the mass of 3.0 x 1015 molecules of carbon dioxide? 2.2 x 10-7 grams
  • 19. Questions 1) How many molecules are in 1.25 g of copper? 2) What is the mass of 35.6 L of xenon gas at STP? 3) What is the mass percent of carbon in aspirin (C9H8O4)?